SOW. Paint Booth IPF NOLA Jun2025.pdf.crdownload.pdf

DEPARTMENT OF HOMELAND SECURITY

UNITED STATES COAST GUARD

IPF NEW ORLEANS

Test and Evaluation of IPF NOLA Paint Booth

Project location: CG Base New Orleans

1790 Saturn Blvd, New Orleans, LA 70129

POC: LT John Dunaway, John.d.dunaway@uscg.mil

New Orleans, LA

DESCRIPTION OF WORK. Industrial Hygiene survey and analysis to determine if Paint Booth ventilation is providing adequate function to effectively maintain atmospheric contaminants below 25% LEL and not above 10% PEL for industrial coatings being frequently utilized during flammable liquid spray finishing processes at Industrial Production Facility, New Orleans, LA.

Testing and analysis shall be conducted during the use of various products to include, but not limited to: Seaguard 5000, Seavoyage / Anti-Foul, and Sherloxane 800, in various coating/application processes (rag, brush/roll, airless & conventional spray), and to various surfaces (aluminum, mild steels, etc). Safety Data Sheets are attached below. Results shall be provided to POC in written report to include observed LEL and PEL during the use/ phases of all product applications and comment on compliance with applicable standards in the below references.

Note: System users will be in supplied air suits during spray application processes.

Period of Performance: 4 days of on-site testing (8 hr days)

References:

(a) USCG CAROPS Protocol Version 3.1.0 Ch 5.3 Ventilation Evaluation: Paint Booth, (b) 29 CFR

1910.94 – Ventilation, (c) American Conference of Governmental Industrial Hygienists, (2020).

Industrial Ventilation, A Manual of Recommended Practices For Design (31st ed). Cincinnati OH,

(d) American Industrial Hygiene Association (2011). The Occupational Environment: Its Evaluation, Control and Management (3rd ed). Fairfax, VA, (e) NFPA 33 Standard for Spray Application Using Flammable or Combustible Materials 2021 Edition, (f) NFPA 1 Fire Code 2021 Edition, Ch 43 Spraying, Dipping and Coating Using Flammable or Combustible Materials (g) International Fire Code (IFC) 2021 Edition, Ch 24 Flammable Finishes, (h) OSHA 1910.107 Spray finishing using flammable and combustible materials.

Security Requirements: Provide FE Base New Orleans POCs the names of the individuals operating the equipment or needing access to the CG Base for submission to the security team. Submission required greater than 48 hours from time scheduled to be on Base.

LOCATION: Industrial Production Facility & Facilities Engineering 1790 Saturn Blvd New Orleans, LA 70129

POINT OF CONTACT:

The Government Point of Contact for all (POC) LT John Dunaway John.d.dunaway@uscg.mil 571-610-5382

COORDINATION:

The Contractor shall coordinate with the POC to minimize interference with Coast Guard personnel and or operations. Regular business hours are 0700 – 1530 (7:00am – 3:30pm) central standard time. Adjustments to time will be considered but not guaranteed, on a case-by-case basis, at the request of the contractor.

LIABILITIES OF CONTRACTOR:

Any damage to government property caused by the contractor shall be repaired or replaced by the contractor at no cost to the government

SEAGUARD® 5000 HS EPOXY Hi-Solid Epoxy Coating (Part A) Red Oxide

Not available.

Liquid.

US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Emergency telephone number of the company

Section 1. Identification

Manufacturer : THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Paint or paint related material.

N11R350

N11R350Product code :

Product Information Telephone Number

: US / Canada: 1-800-524-5979 Mexico: Not Available

Transportation Emergency Telephone Number

: US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 3 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1

Classification of the substance or mixture

Signal word : Danger

Hazard pictograms :

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 19.6% (oral), 19.6% (dermal), 19.6% (inhalation)

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

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N11R350 SEAGUARD® 5000 HS EPOXY Hi-Solid Epoxy Coating (Part A)

SHW-85-NA-GHS-US

Section 2. Hazards identification

Precautionary statements

Prevention : Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools.

Take action to prevent static discharges. Use only outdoors or in a well-ventilated area.

Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.

Response : Get medical advice or attention if you feel unwell. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES:

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.

Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool.

Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

: None known.

Flammable liquid and vapor.

Causes skin irritation.

May cause an allergic skin reaction.

Causes serious eye damage.

May cause drowsiness or dizziness.

Causes damage to organs through prolonged or repeated exposure. (lungs)

:Hazard statements

Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.

Supplemental label elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:

This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure.

Section 3. Composition/information on ingredients

Other means of identification

: Not available.

Substance/mixture

CAS number/other identifiers

: Mixture

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Section 3. Composition/information on ingredients

Talc ≥25 - ≤50 14807-96-6 1-Butanol ≥10 - <20 71-36-3 Polyamide ≥10 - ≤25 68410-23-1 Phenylmethanol ≤9.8 100-51-6 Iron Oxide ≤10 1309-37-1 Fatty acids, tall-oil, reaction products with tetraethylenepentamine ≤3 68953-36-6 Triethylene Tetramine <1 112-24-3 Tetraethylene Pentamine ≤0.3 112-57-2

Ingredient name CAS number% by weight

Occupational exposure limits, if available, are listed in Section 8.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician.

Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.

Loosen tight clothing such as a collar, tie, belt or waistband.

Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.

Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Skin contact : Causes skin irritation. May cause an allergic skin reaction.

Causes serious eye damage.:Eye contact

Potential acute health effects

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Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments : No specific treatment.

Can cause central nervous system (CNS) depression.:Ingestion

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:

nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness

Adverse symptoms may include the following:

stomach pains

Adverse symptoms may include the following:

pain or irritation redness blistering may occur

Eye contact : Adverse symptoms may include the following:

pain watering redness

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.

Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

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Section 5. Fire-fighting measures Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Flammable liquid.Remark :

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

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Section 7. Handling and storage Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area.

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Talc 14807-96-6 NIOSH REL (United States, 10/2020).

TWA: 2 mg/m³ 10 hours. Form: Respirable fraction ACGIH TLV (United States, 1/2024).

TWA: 2 mg/m³ 8 hours. Form: Respirable fraction

1-Butanol 71-36-3 ACGIH TLV (United States, 1/2024).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 10/2020).

Absorbed through skin.

CEIL: 50 ppm CEIL: 150 mg/m³ OSHA PEL (United States, 5/2018).

TWA: 100 ppm 8 hours.

TWA: 300 mg/m³ 8 hours.

Polyamide 68410-23-1 None.

Phenylmethanol 100-51-6 OARS WEEL (United States, 4/2022).

TWA: 10 ppm 8 hours.

Iron Oxide 1309-37-1 NIOSH REL (United States, 10/2020). [iron oxide dust and fume] TWA: 5 mg/m³, (as Fe) 10 hours. Form: Dust and fumes ACGIH TLV (United States, 1/2024).

TWA: 5 mg/m³ 8 hours. Form: Respirable fraction OSHA PEL (United States, 5/2018).

TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust

Fatty acids, tall-oil, reaction products with tetraethylenepentamine

68953-36-6 None.

Triethylene Tetramine 112-24-3 OARS WEEL (United States, 4/2022).

Absorbed through skin.

TWA: 1 ppm 8 hours.

Tetraethylene Pentamine 112-57-2 OARS WEEL (United States, 4/2022).

Absorbed through skin. Skin sensitizer.

TWA: 5 mg/m³ 8 hours.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits (OSHA United States)

Occupational exposure limits (Canada)

CAS #

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Section 8. Exposure controls/personal protection talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada, 8/2023). Notes: the value is for particulate matter containing no asbestos and less than 1% crystalline silica.

TWA: 2 mg/m³ 8 hours. Form: Respirable CA Alberta Provincial (Canada, 3/2023).

OEL: 2 mg/m³ 8 hours. Form: Respirable particulate CA Ontario Provincial (Canada, 6/2019).

TWA: 2 mg/m³ 8 hours. Form: Respirable particulate matter.

TWA: 2 f/cc 8 hours.

CA Quebec Provincial (Canada, 2/2024).

TWAEV: 2 mg/m³ 8 hours. Form: respirable aerosol fraction CA Saskatchewan Provincial (Canada, 4/2021).

TWA: 2 mg/m³ 8 hours. Form: respirable fraction

Normal butyl alcohol 71-36-3 CA Alberta Provincial (Canada, 3/2023).

OEL: 60 mg/m³ 8 hours.

OEL: 20 ppm 8 hours.

CA British Columbia Provincial (Canada, 8/2023).

TWA: 15 ppm 8 hours.

C: 30 ppm CA Ontario Provincial (Canada, 6/2019).

TWA: 20 ppm 8 hours.

CA Saskatchewan Provincial (Canada, 4/2021).

STEL: 30 ppm 15 minutes.

TWA: 20 ppm 8 hours.

CA Quebec Provincial (Canada, 2/2024).

TWAEV: 20 ppm 8 hours.

Benzyl alcohol 100-51-6 OARS WEEL (United States, 4/2022).

TWA: 10 ppm 8 hours.

Triethylenetetramine 112-24-3 CA Ontario Provincial (Canada, 6/2019).

Absorbed through skin.

TWA: 3 mg/m³ 8 hours.

TWA: 0.5 ppm 8 hours.

Tetraethylenepentamine 112-57-2 OARS WEEL (United States, 4/2022).

Absorbed through skin. Skin sensitizer.

TWA: 5 mg/m³ 8 hours.

Ingredient name Exposure limits

1-Butanol 71-36-3 NOM-010-STPS-2014 (Mexico, 4/2016).

Absorbed through skin.

TWA: 20 ppm 8 hours.

Exposure limits

Occupational exposure limits (Mexico)

CAS #

CAS #

Biological exposure indices (United States)

No exposure indices known.

Biological exposure indices (Canada)

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N11R350 SEAGUARD® 5000 HS EPOXY Hi-Solid Epoxy Coating (Part A)

Section 8. Exposure controls/personal protection

Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

Eye/face protection

Respiratory protection :

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls

Biological exposure indices (Mexico)

No exposure indices known.

No exposure indices known.

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Section 9. Physical and chemical properties

Physical state

Melting point/freezing point

Vapor pressure

Relative density

Liquid.

Not available.

1.4

2.55 [Air = 1]

Not available.Odor pH

Red.Color

Evaporation rate 0.43 (butyl acetate = 1)

Auto-ignition temperature

Flash point

Not available.

Closed cup: 38°C (100.4°F) [Pensky-Martens Closed Cup]

Not applicable.

Not applicable.

Viscosity Kinematic (40°C (104°F)): >20.5 mm2/s (>20.5 cSt)

Not available.Odor threshold

Partition coefficient: n-octanol/water

Appearance

: 117°C (242.6°F)

: Flammable liquid.

: Lower: 1.3% Upper: 13%

Decomposition temperature : Not available.

Heat of combustion : 10.661 kJ/g

Molecular weight : Not applicable.

Boiling point, initial boiling point, and boiling range

Flammability

Lower and upper explosion limit/flammability limit

Relative vapor density

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

0.73 kPa (5.5 mm Hg)

Solubility(ies) :

Media Result cold water Not soluble

Section 10. Stability and reactivity

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.

The product is stable.Chemical stability

Reactive or incompatible with the following materials:

oxidizing materials

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

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Section 10. Stability and reactivity Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 11. Toxicological information

Acute toxicity

1-Butanol LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hours LD50 Dermal Rabbit 3400 mg/kg - LD50 Oral Rat 790 mg/kg -

Phenylmethanol LD50 Dermal Rabbit 2000 mg/kg - LD50 Oral Rat 1230 mg/kg -

Triethylene Tetramine LD50 Dermal Rabbit 805 mg/kg - LD50 Oral Rat 2500 mg/kg -

Tetraethylene Pentamine LD50 Oral Rat 3990 mg/kg -

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Not available.

Mutagenicity

Not available.

Irritation/Corrosion

Talc Skin - Mild irritant Human - 72 hours 300 ug I

1-Butanol Eyes - Severe irritant Rabbit - 0.005 Ml - Eyes - Severe irritant Rabbit - 24 hours 2 mg

Skin - Moderate irritant Rabbit - 24 hours 20 mg

Phenylmethanol Skin - Mild irritant Man - 48 hours 16 mg

Skin - Moderate irritant Pig - 100 % - Skin - Moderate irritant Rabbit - 24 hours 100 mg

Triethylene Tetramine Eyes - Moderate irritant Rabbit - 24 hours 20 mg

Eyes - Severe irritant Rabbit - 49 mg - Skin - Severe irritant Rabbit - 490 mg - Skin - Severe irritant Rabbit - 24 hours 5 mg

Tetraethylene Pentamine Eyes - Moderate irritant Rabbit - 24 hours 100 mg

Eyes - Moderate irritant Rabbit - 5 mg - Skin - Severe irritant Rabbit - 495 mg - Skin - Severe irritant Rabbit - 24 hours 5 mg

Product/ingredient name Result Score Exposure Observation

Sensitization

Not available.

Species

Information on toxicological effects

Classification

Talc - 3 - Iron Oxide - 3 -

Product/ingredient name NTPIARCOSHA

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Section 11. Toxicological information

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

1-Butanol Category 3 - Respiratory tract irritation

Category 3 Narcotic effects Phenylmethanol Category 3 - Narcotic effects

Name Category

Name Category

Talc Category 1 inhalation lungs

Aspiration hazard

Not available.

Route of exposure

Target organs

Route of exposure

Target organs

Information on the likely routes of exposure

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Can cause central nervous system (CNS) depression.:Ingestion

Skin contact : Causes skin irritation. May cause an allergic skin reaction.

Causes serious eye damage.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:

nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness

Adverse symptoms may include the following:

stomach pains

Adverse symptoms may include the following:

pain or irritation redness blistering may occur

Eye contact : Adverse symptoms may include the following:

pain watering redness

Delayed and immediate effects and also chronic effects from short and long term exposure

: Not available.

Potential acute health effects

Short term exposure

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Section 11. Toxicological information

Not available.

Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Potential chronic health effects

Numerical measures of toxicity

Oral 5485.76 mg/kg Dermal 8120.62 mg/kg

Route ATE value

Acute toxicity estimates

Potential immediate effects

: Not available.

Potential delayed effects : Not available.

Potential immediate effects

: Not available.

Long term exposure

Potential delayed effects : Not available.

Section 12. Ecological information

Bioaccumulative potential

Not available.

Product/ingredient name Aquatic half-life Photolysis Biodegradability

1-Butanol - - Readily Phenylmethanol - - Readily

Toxicity

1-Butanol Acute EC50 1983 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 1730000 µg/l Fresh water Fish - Pimephales promelas 96 hours

Phenylmethanol Acute LC50 10 ppm Fresh water Fish - Lepomis macrochirus 96 hours Triethylene Tetramine Acute EC50 3700 µg/l Fresh water Algae - Raphidocelis subcapitata 96 hours

Acute LC50 33900 µg/l Fresh water Daphnia - Daphnia magna 48 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Date of issue/Date of revision : 12/13/2024 Date of previous issue : 11/7/2024 Version : 20.01 12/16

N11R350 SEAGUARD® 5000 HS EPOXY Hi-Solid Epoxy Coating (Part A)

Section 12. Ecological information Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Section 14. Transport information

PAINT

III

PAINT. Marine pollutant (Polyamide, Fatty acids, tall-oil, reaction products with tetraethylenepentamine)

III

UN1263 UN1263

This product may be re-classified as "Combustible Liquid," unless transported by vessel or aircraft.

Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

Emergency schedules F-E, S- E

DOT

Classification

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No. Yes.

TDG

Classification

UN1263

PAINT

III

No.

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations:

2.18-2.19 (Class 3).

Mexico Classification

UN1263

PAINT

III

No.

IATA

UN1263

PAINT

III

Yes. The environmentally hazardous substance mark is not required.

The environmentally hazardous substance mark may appear if required by other transportation regulations.

Date of issue/Date of revision : 12/13/2024 Date of previous issue : 11/7/2024 Version : 20.01 13/16

N11R350 SEAGUARD® 5000 HS EPOXY Hi-Solid Epoxy Coating (Part A)

Section 14. Transport information hazardous materials in package sizes less than the product reportable quantity.

Special precautions for user

Transport in bulk according to IMO instruments

Not available.

Proper shipping name :

Not available.

: Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.

ERG No.

128 128

ERG No. ERG No.

Section 15. Regulatory information

All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided, or the upper limit reported by our supplier. Additionally, the suppliers’ information may include amounts present in the product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made during production.

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

California Prop. 65

International regulations

Montreal Protocol

Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.

Lead (as Pb) 0.000009 1-Butanol 18 71-36-3

Ingredient name CAS number% by weight

SARA 313

Date of issue/Date of revision : 12/13/2024 Date of previous issue : 11/7/2024 Version : 20.01 14/16

N11R350 SEAGUARD® 5000 HS EPOXY Hi-Solid Epoxy Coating (Part A)

Section 15. Regulatory information Australia inventory (AIIC): Not determined.

China inventory (IECSC): Not determined.

Japan inventory (CSCL): Not determined.

Japan inventory (ISHL): Not determined.

Korea inventory (KECI): Not determined.

New Zealand Inventory of Chemicals (NZIoC): Not determined.

Philippines inventory (PICCS): Not determined.

Taiwan Chemical Substances Inventory (TCSI): Not determined.

Thailand inventory: Not determined.

Turkey inventory: Not determined.

Vietnam inventory: Not determined.

International lists :

Section 16. Other information

12/13/2024

History

Date of printing

Date of issue/Date of revision

Version

Date of previous issue

Key to abbreviations :

12/13/2024

11/7/2024

20.01

Hazardous Material Information System (U.S.A.)

*Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Calculation method SKIN SENSITIZATION - Category 1 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method

Procedure used to derive the classification

Classification Justification

ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group

Date of issue/Date of revision : 12/13/2024 Date of previous issue : 11/7/2024 Version : 20.01 15/16

N11R350 SEAGUARD® 5000 HS EPOXY Hi-Solid Epoxy Coating (Part A)

Section 16. Other information

It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.

Indicates information that has changed from previously issued version.

Notice to reader

UN = United Nations

Date of issue/Date of revision : 12/13/2024 Date of previous issue : 11/7/2024 Version : 20.01 16/16

N11R350 SEAGUARD® 5000 HS EPOXY Hi-Solid Epoxy Coating (Part A)

SIGALD - 179124

The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada

SAFETY DATA SHEET

Version 6.11 Revision Date 09/06/2024

Print Date 09/07/2024

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifiers

Product name : Acetone

Product Number : 179124 Brand : SIGALD Index-No. : 606-001-00-8 CAS-No. : 67-64-1

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Synthesis of substances

Uses advised against : The product is being supplied under the TSCA R&D Exemption (40 CFR Section 720.36). It is the recipient’s responsibility to comply with the requirements of the R&D exemption. The product may not be used for a non-exempt commercial purpose under TSCA unless appropriate consent is granted in writing by MilliporeSigma.

1.3 Details of the supplier of the safety data sheet

Company : Sigma-Aldrich Inc.

3050 SPRUCE ST

ST. LOUIS MO 63103

UNITED STATES

Telephone : +1 314 771-5765 Fax : +1 800 325-5052

1.4 Emergency telephone

Emergency Phone # : 800-424-9300 CHEMTREC (USA) +1-703- 527-3887 CHEMTREC (International) 24 Hours/day; 7 Days/week

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Flammable liquids (Category 2), H225 Eye irritation (Category 2A), H319 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 GHS Label elements, including precautionary statements

Pictogram

Signal Word Danger

Hazard Statements H225 Highly flammable liquid and vapor.

H319 Causes serious eye irritation.

H336 May cause drowsiness or dizziness.

Precautionary Statements P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing mist or vapors.

P264 Wash skin thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/ eye protection/ face protection.

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.

P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 If eye irritation persists: Get medical advice/ attention.

P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

P403 + P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS Repeated exposure may cause skin dryness or cracking.

SECTION 3: Composition/information on ingredients

3.1 Substances

Formula : C3H6O Molecular weight : 58.08 g/mol CAS-No. : 67-64-1 EC-No. : 200-662-2 Index-No. : 606-001-00-8

Component Classification Concentration acetone Flam. Liq. 2; Eye Irrit. 2A;

STOT SE 3; H225, H319,

H336 Concentration limits:

>= 20 %: STOT SE 3,

H336;

<= 100 %

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1 Description of first-aid measures

General advice Show this material safety data sheet to the doctor in attendance.

If inhaled After inhalation: fresh air. Call in physician.

In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

In case of eye contact After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

If swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed No data available

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media Carbon dioxide (CO2) Foam Dry powder

Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given.

5.2 Special hazards arising from the substance or mixture

Carbon oxides Combustible.

Pay attention to flashback.

Vapors are heavier than air and may spread along floors.

Development of hazardous combustion gases or vapours possible in the event of fire.

Forms explosive mixtures with air at ambient temperatures.

5.3 Advice for firefighters

In the event of fire, wear self-contained breathing apparatus.

5.4 Further information

Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.

Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

6.2 Environmental precautions

Do not let product enter drains. Risk of explosion.

6.3 Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ).

Dispose of properly. Clean up affected area.

6.4 Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Advice on protection against fire and explosion Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.

Hygiene measures Change contaminated clothing. Preventive skin protection recommended. Wash hands after working with substance.

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition.

Storage class Storage class (TRGS 510): 3: Flammable liquids

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Ingredients with workplace control parameters Component CAS-No. Value Control parameters Basis

67-64-1

TWA 250 ppm

USA. ACGIH Threshold Limit Values (TLV)

Remarks Not classifiable as a human carcinogen STEL 500 ppm

USA. ACGIH Threshold Limit Values (TLV)

Not classifiable as a human carcinogen TWA 250 ppm

590 mg/m3 USA. NIOSH Recommended Exposure Limits

TWA 1,000 ppm 2,400 mg/m3

USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants

C 3,000 ppm

California permissible exposure limits for chemical contaminants (Title 8, Article 107)

PEL 500 ppm 1,200 mg/m3

California permissible exposure limits for chemical contaminants (Title 8, Article 107)

STEL 750 ppm 1,780 mg/m3

California permissible exposure limits for chemical contaminants (Title 8, Article 107)

Biological occupational exposure limits Component CAS-No. Parameters Value Biological specimen Basis

67-64-1

Acetone 25 mg/l Urine ACGIH - Biological Exposure Indices

(BEI)

Remarks End of shift (As soon as possible after exposure ceases)

Derived No Effect Level (DNEL) Application Area Routes of exposure Health effect Value

Workers Skin contact Long-term systemic effects 186mg/kg BW/d Consumers Ingestion Long-term systemic effects 62mg/kg BW/d Consumers Skin contact Long-term systemic effects 62mg/kg BW/d Workers Inhalation…