SDS - E36 Runway Deicer (002).pdf

CRYOTECH E36®

Liquid Runway Deicer

Safety Data Sheet

Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by Cryotech Deicing Technology, 6103 Orthoway, Fort Madison, IA 52627

Form #MKT602 Rev. August 1, 2019

Section 2: HAZARD(S) IDENTIFICATION

PRODUCT IDENTIFIER

Liquid Runway Deicer Complies with Specification AMS 1435

RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE

Deicing/anti-icing runways, taxiways, and airside pavements

DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET

Name/Address: Cryotech Deicing Technology

6103 Orthoway Fort Madison, IA 52627 United States

Contact Information: Telephone: (800) 346-7237

Fax: (319) 372-2662 Email: deicers@cryotech.com Website: www.cryotech.com

EMERGENCY TELEPHONE NUMBER

CHEMTREC (800) 424-9300

Outside USA and Canada (703) 741-5970

CLASSIFICATION ACCORDING TO OSHA HAZCOM 2012

Hazard Class Not classified as hazardous

LABEL ELEMENTS ACCORDING TO OSHA HAZCOM 2012

There are no OSHA required label elements for this product.

CLASSIFICATION ACCORDING TO WHMIS (Canada) Hazard Class Not controlled

WHMIS Hazard Symbols Not applicable

WHMIS Signal Word Not applicable

HAZARDS NOT OTHERWISE CLASSIFIED (HNOC)

May be harmful if swallowed.

Section 1: IDENTIFICATION

Safety Data Sheet

Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by Cryotech Deicing Technology, 6103 Orthoway, Fort Madison, IA 52627

Section 4: FIRST- AID MEASURES

MIXTURES

Ingredient CAS No Wt. %

Potassium Acetate 127-08-2 50

Water 7732-18-5 50

Corrosion Inhibitors < 1

DESCRIPTION OF FIRST AID MEASURE

Eye In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, seek medical attention.

Skin As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing.

Inhalation If inhaled, remove to fresh air and get medical advice

Ingestion If swallowed, give milk or water to drink and telephone for medical advice. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.

MOST IMPORTANT SYMPTOMS / EFFECTS

Eye May cause temporary eye irritation. Symptoms may include temporary discomfort, excessive blinking, tear production, redness, and/or swelling.

May cause itching or irritation of any cut or abraded skin. Symptoms of prolonged contact may include dry skin.

Inhalation of aerosol during spraying may cause respiratory tract irritation and coughing. This product is not otherwise expected to be an inhalation hazard.

Ingestion of large quantities may cause nausea, vomiting, diarrhea and abdominal discomfort.

Skin

Inhalation

Ingestion

INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT

Note to physicians This product contains potassium acetate. Though ingestion of large amounts of potassium salts usually results in vomiting, excessive potassium absorption can cause hyperkalemia.

Specific treatments If you feel unwell, seek medical advice immediately. Show the label or safety data sheet to medical personnel if possible.

Section 3: COMPOSITION / INFORMATION ON INGREDIENTS

Safety Data Sheet

Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by Cryotech Deicing Technology, 6103 Orthoway, Fort Madison, IA 52627

Section 6: ACCIDENTAL RELEASE MEASURES

Section 7: HANDLING AND STORAGE

FLAMMABILITY

Flash Point (close cup) Nonflammable by OSHA/WHMIS criteria

Auto Ignition Not applicable

EXTINGUISHING MEDIA

Suitable Extinguishing Media Water, carbon dioxide, or dry chemical. Use extinguishing media appropriate for surrounding materials.

Unsuitable Extinguishing Media Not applicable

SPECIAL HAZARDS

Hazardous Combustion Products Normal combustion forms carbon dioxide and water.

Explosion Limits Data not available. Not considered to be an explosion hazard.

Unusual Fire Hazards None expected

SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS

Special Protective Equipment for Firefighters

Wear protective equipment suitable for surrounding environment.

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES

Avoid eye/skin contact with spilled material. Refer to Section 7 for additional handling precautions

Methods for Containment Contain and/or absorb spill with inert material (e.g. sawdust, sand, vermiculite).

Methods for Cleaning-Up Scoop up material and transfer to disposal container. If needed, wash spillage area with plenty of water.

PRECAUTIONS FOR SAFE HANDLING

Handling Avoid eye contact. Avoid breathing mist when spraying.

PRECAUTIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

Storage Store in tightly sealed original containers, away from direct heat and strong oxidizing agents. Do not store or handle product in systems constructed of wetted parts consisting of galvanized steel, zinc, or brass components.

Section 5: FIRE FIGHTING MEASURES

Safety Data Sheet

Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by Cryotech Deicing Technology, 6103 Orthoway, Fort Madison, IA 52627

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

EXPOSURE LIMITS

Exposure Limits No specific limits have been established for this product.

EXPOSURE CONTROLS

Engineering Controls No special ventilation is usually necessary; however if operating conditions create high airborne concentrations of this material, special ventilation may be needed to keep exposure to airborne contaminants below the exposure limit.

INDIVIDUAL PROTECTIVE MEASURES/PERSONAL PROTECTIVE EQUIPMENT

Eye Protection Safety glasses or goggles are recommended if splashing/spraying is possible.

Skin Protection No special skin protection is usually necessary. Chemical-resistant gloves and clothing should be used if prolonged exposure is possible to prevent drying of skin.

Respiratory Protection No special respiratory protection is usually necessary. Breathing of mist/aerosol should be avoided. If operating conditions create high airborne concentrations of this material, the use of an approved respirator is recommended.

APPEARANCE Clear, colorless to light straw colored liquid. (May be dyed blue at customer request.)

ODOR Odorless to slight vinegar odor

ODOR THRESHOLD No data available pH (20°C, 68°F) 10.5 – 11.5

FREEZING POINT -60°C (-76°F)

BOILING POINT ~ 110°C (230°F)

FLASH POINT Not applicable

EVAPORATION RATE No data available

FLAMMABILITY/EXPLOSION LIMITS Not applicable

VAPOR PRESSURE (20°C) 15 mm Hg

VAPOR DENSITY (AIR = 1) No data available

RELATIVE DENSITY 1.28

SOLUBILITY IN WATER Completely miscible

PARTITION COEFFICIENT; n-OCTANOL/WATER No data available

AUTO-IGNITION TEMPERATURE No data available

DECOMPOSITION TEMPERATURE No data available

VISCOSITY (20°C) 6.5 cP

OXIDIZING PROPERTIES Not oxidizing

EXPLOSIVE PROPERTIES Not explosive

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Safety Data Sheet

Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by Cryotech Deicing Technology, 6103 Orthoway, Fort Madison, IA 52627

Section 11: TOXICOLOGICAL INFORMATION

REACTIVITY

No dangerous reactions known under conditions of normal use.

CHEMICAL STABILITY

Stable. Polymerization will not occur.

POSSIBILITY OF HAZARDOUS REACTIONS

No dangerous reactions known under conditions of normal use.

CONDITIONS TO AVOID

Avoid prolonged contact with reactive metals such as magnesium and zinc, especially in closed systems where hydrogen gas from the oxidation of these materials may accumulate over time.

INCOMPATIBLE MATERIALS

Strong oxidizing agents; strong acids.

HAZARDOUS DECOMPOSITION PRODUCTS

May decompose into oxides of carbon.

ACUTE TOXICITY

LD50 rat-oral: > 5 g/kg.

LIKELY ROUTES OF EXPOSURE

Skin contact, eye contact, ingestion.

SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL, AND TOXICOLOGICAL CHARACTERISTICS

Eye May cause temporary eye irritation. Corneal injury is unlikely.

Skin Repeated contact may cause minor skin irritation or dry skin.

Inhalation Inhalation of aerosol during spraying may cause respiratory tract irritation and coughing. This product is not otherwise expected to be an inhalation hazard.

Ingestion Ingestion of large quantities may cause nausea, vomiting, diarrhea and abdominal discomfort.

DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT- AND LONG-TERM

EXPOSURE/NUMERICAL MEASURES OF TOXICITY

Skin Corrosion/Irritation Based on available data, the classification criteria are not met.

Serious Eye Damage/Irritation Based on available data, the classification criteria are not met.

Respiratory or Skin Sensitization Based on available data, the classification criteria are not met.

Germ Cell Mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity This product does not contain any ingredients that are considered to be carcinogens by IARC, NTP, or OSHA.

Section 10: STABILITY AND REACTIVITY

Safety Data Sheet

Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by Cryotech Deicing Technology, 6103 Orthoway, Fort Madison, IA 52627

Section 12: ECOLOGICAL INFORMATION

Section 13: DISPOSAL CONSIDERATIONS

Section 14: TRANSPORT INFORMATION

Reproductive Toxicity Based on available data, the classification criteria are not met.

STOT-Single Exposure Based on available data, the classification criteria are not met.

STOT-Repeated Exposure Based on available data, the classification criteria are not met.

Aspiration Hazard Based on available data, the classification criteria are not met.

ECOTOXICITY (AQUATIC AND TERRESTRIAL)

Not expected to cause long-term adverse effects in the aquatic or terrestrial environments.

PERSISTENCE AND DEGRADABILITY

Readily biodegradable. COD (TOD): 0.34 g O2/g deicer; BOD5 (20°C): 0.25 g O2/g deicer

BIOACCUMULATIVE POTENTIAL

Bioaccumulation is not expected.

MOBILITY IN SOIL

Adverse effects not expected.

OTHER ADVERSE EFFECTS

None expected.

WASTE TREATMENT AND METHODS OF DISPOSAL

Based on available information, this product is neither listed as a hazardous waste nor does it exhibit any of the characteristics that would cause it to be classified as a characterized hazardous waste under RCRA. This product may be absorbed onto suitable materials and disposed of in a sanitary landfill unless local, state, or provincial regulations prohibit such disposal.

TRANSPORT INFORMATION

Not regulated as dangerous goods per US DOT or IATA.

Safety Data Sheet

Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by Cryotech Deicing Technology, 6103 Orthoway, Fort Madison, IA 52627

INVENTORY LISTS

All of the components in this product are on the following inventory lists: USA (TSCA), Canada (DSL/NDSL); Europe

(EINECS)

TSCA SECTION 12(b) None of the chemicals in this product are listed under TSCA Section 12(b).

CERCLA HAZARDOUS SUBSTANCES

There is no CERCLA Reportable Quantity for this material.

SARA 311/312 CATEGORIES

Physical hazards Health hazards

Explosive No Acute toxicity (any route of exposure) No

Flammable (gases, aerosols, liquids or solids No Skin corrosion or irritation No

Oxidizer (liquid, solid or gas) No Serious eye damage or eye irritation No

Self- reactive No Respiratory or skin sensitization No

Pyrophoric (liquid or solid) No Germ cell mutagenicity No

Pyrophoric Gas No Carcinogenicity No

Self-heating No Reproductive toxicity No

Corrosive to metal No Specific target organ toxicity (single or repeated exposure)

No

Gas under pressure (compressed gas) No Aspiration hazard No

In contact with water emits flammable gas No Simple Asphyxiant No

Combustible Dust No Hazard Not Otherwise Classified (HNOC) No

Hazard Not Otherwise Classified (HNOC) No

SARA 313

None of the components in this product are subject to reporting under SARA Section 313.

CLEAN WATER ACT

None of the chemicals in this product are listed as Priority Pollutants under the CWA.

None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

STATE RIGHT-TO-KNOW:

This product does not contain components at levels which are required to be reported under the statutes of the following states: PA, MA, MN, and NJ.

Section 15: REGULATORY INFORMATION

Safety Data Sheet

Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by Cryotech Deicing Technology, 6103 Orthoway, Fort Madison, IA 52627

Section 16: OTHER INFORMATION

This product does not contain materials known to the State of California (Proposition 65) to cause cancer and/or reproductive harm at levels which would require a warning under the statute.

NFPA 704

Health 1 Fire 0 Physical Hazard 0

Hazard Rating 0-4 0-least hazardous; 4-most hazardous

HMIS – Hazardous Materials Identification System

Health 1 Fire 0 Physical Hazard 0

Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe

SDS REVISION DATE

Revision date: August 1, 2019

Expiration date: August 1, 2022 Latest version of this SDS can be obtained from Cryotech.

NOTE TO EMPLOYER

This Safety Data Sheet contains environmental, health and toxicology information for your employees. Please ensure this information is provided to them. It also contains information to help you meet community right-to-know/emergency response reporting requirements under SARA Title III and many other laws. If you resell this product, this SDS must be given to the buyer or the information incorporated in your SDS. Discard any previous edition of this SDS.

DISCLAIMER

The above information is accurate to the best of our knowledge. However, since data, safety standards, and government regulations are subject to change and the conditions of handling and use or misuse are beyond our control, GENERAL ATOMICS INTERNATIONAL SERVICES CORPORATION dba Cryotech Deicing Technology makes no warranty, either express or implied, with respect to the completeness or continuing accuracy of the information contained herein and disclaims all liability for reliance thereon. GENERAL ATOMICS INTERNATIONAL SERVICES CORPORATION dba Cryotech Deicing Technology assumes no responsibility for any injury or loss resulting from the use of the product described herein. User should satisfy himself that he has all current data relevant to his particular use.

End of Safety Data Sheet