GT-5_Ammonia_Delivery_Procedures_GT5-05.docx

DOCX document 79 KB Posted

Attached to
Furnishing and Delivering of Ammonium Hydroxide for Glenarm Power Plant
Solicitation number
2023-IFB-MS-634
Issued by
Los Angeles County, California

About this file

This document is a Standard Operating Procedure (SOP) for 19% Ammonia Delivery Procedures at the Pasadena Water & Power Glenarm Power Plant, detailing precise operational protocols for ammonia tank filling and safety management. The procedure covers three primary phases: pre-delivery preparation, ammonia delivery process, and post-delivery procedures, with comprehensive step-by-step instructions for operators and delivery personnel. The process involves multiple critical safety checks, including valve alignments, indicator light verifications, confined space entry permits, personal protective equipment requirements, and specific operational steps for safely receiving and managing ammonia deliveries.

The document extensively outlines safety protocols and hazard mitigation strategies, emphasizing chemical exposure risks, personal protective equipment specifications, and confined space entry guidelines. Key safety measures include mandating specific protective clothing (impervious materials, boots, gloves), requiring eyewash and safety shower availability, specifying respiratory protection requirements, and establishing strict monitoring procedures for atmospheric conditions and potential chemical hazards. The procedure is specifically designed for managing 19% ammonia deliveries to the GT-5 tank (AST-TNK-1010) at the Glenarm Power Plant, which is part of a Selective Catalytic Reduction (SCR) system for controlling nitrogen oxides emissions in the plant's five natural gas-fired combustion turbines.

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Pasadena Water & Power Glenarm Power Plant

Glenarm Power Plant Standard Operating Procedures GT-5 Glenarm GT5-05 19% Ammonia Delivery Procedures to GT-5 Tank AST-TNK-1010

Prior to Ammonia Delivery:

1. Ensure the fill valve on the GT-5 19% ammonia tank is open.

2. Ensure the vapor return valve on the GT-5 19% ammonia tank is open.

3. Ensure the 3-way fill valve (5-AST-DV-1007-1) is aligned to GT-5 tank.

4. Verify that the indicator light for fill is showing GREEN.

5. Ensure the 3-way vapor return valve (5-AST-DV-9008-1) is aligned to GT-5 tank.

6. Verify that the indicator light for vapor return is showing GREEN.

7. Ensure the valve for the ammonia drain pot discharge line is open at the tank.

8. Prepare confined space entry permit.

NOTE: Please verify that the 3M GVP-404 Cartridge used on PAPR is not expired.

9. Ammonia pit entry must be in compliance with NH3 pit JSA (Attached: Appendix A).

10. Ensure the drain pot drain valve is closed.

11. Ensure the recirc line from 19% ammonia pump discharge to drain line is closed.

12. Open the 19% ammonia return pump discharge valve.

13. Open the 19% ammonia return pump suction valve.

14. Open the 19% vapor return line low point drain valve.

15. Open air supply to 19% ammonia return pump to start pump.

16. Run pump until vapor return line is completely drained.

17. Secure 19% vapor return line low point drain valve.

18. Open the 19% fill line low point drain valve.

19. Open air supply to 19% ammonia return pump to start pump.

20. Run pump until fill line is completely drained.

21. Secure 19% fill line low point drain.

22. Secure 19% ammonia return pump suction and discharge valves.

23. Egress from confined space.

Ammonia Delivery:

1. Delivery is to be conducted in accordance with the ammonia delivery company’s established written procedures (Attached: Appendix B).

2. Station one operator at GT-5 19% ammonia tank to verify level and check for leaks etc. while offloading ammonia.

3. Station second operator at ammonia unloading station with delivery driver.

4. Switch Glenarm monitor screens to cameras 18 and 20.

5. Walk driver through system/discuss safety features: emergency shutdown procedures, location of safety shower/eyewash station, location of the 3-way valves and indicator lights.

6. Verify that shower and eyewash station are operational.

7. Cordon off delivery piping and truck with tape.

8. Ensure ammonia being delivered concentration is 19%.

9. Unlock 19% fill and vapor return connection valves.

10. Ensure driver attaches grounding strap to delivery truck.

11. Make announcement to all hands that ammonia delivery has started.

12. Ensure non-essential personnel are clear from unloading area during offload.

13. Give driver OK to start filling 19% ammonia tank.

14. Monitor trenches for ammonia leaks during the duration of offload.

15. Secure filling immediately in the event of a leak.

16. Secure filling immediately in the event of a high-high audible or visual alarm.

17. Secure filling immediately if tank level in the 19% ammonia indication reaches 95%.

18. Upon completion of offload secure and lock 19% unloading station connection valves

After Delivery is Complete:

1. Re-enter ammonia pit in compliance with NH3 pit JSA.

2. Ensure the recirculating line form 19% ammonia pump discharge to drain line is closed.

3. Open the 19% ammonia return pump discharge valve.

4. Open the 19% ammonia return pump suction valve.

5. Open the 19% vapor return line low point drain valve.

6. Open air supply to 19% ammonia return pump to start pump.

7. Run pump until vapor return line is completely drained.

8. Secure 19% vapor return line low point drain valve.

9. Open the 19% fill line low point drain valve.

10. Open air supply to 19% ammonia return pump to start pump.

11. Run pump until fill line is completely drained.

12. Secure 19% fill line low point drain.

13. Secure 19% ammonia return pump suction and discharge valves.

14. Egress from confined space.

References: GT-5 P&ID drawing #PWPG-5-DW-AST-302-001, GT-3&4 F&ID drawing #20001-090 and #20001-P-006-02

Job Hazard Analysis

Hazards Hazard Descriptions Hazard Control Measures Chemical A chemical that exposes a person by absorption Personal Protective Equipment (PPE)-eyewash (Toxic) through the skin, inhalation, or through the blood fountain and safety shower should be available

stream that causes illness, disease, or death.in the work area. Wear impervious protective
The amount of chemical exposure is critical inclothing, including boots, gloves, lab coat, apron
determining hazardous effects. Check Safety Dataor coveralls, as appropriate, to prevent skin
Sheet (SDS) for chemical hazard information.Contact. Neoprene and nitrile rubber are
recommended materials.
Eye Protection-tight fitting chemical safety and
splash-proof googles and/or a splash-proof face
shield must be worn if there is a likelihood of
exposure. Persons subject to ammonia exposuremust not wear contact lenses.
Respiratory Protection-unless ventilation is
adequate to keep airborne concentrations below
the exposure standard, wear approved respiratory
protection such as an ammonia canister mask or
an approved air supplied respirator (PAPR).
ChemicalA chemical that, when it comes into contact with Personal Protective Equipment (PPE)-eyewash
(Corrosive) skin, metal, or other materials, damages thefountain and safety shower should be available
materials. Acids and bases are examples ofin the work area. Wear impervious protective
corrosives.clothing, including boots, gloves, lab coat, apron
or coveralls, as appropriate, to prevent skin
Contact. Neoprene and nitrile rubber are
recommended materials.
Eye Protection-tight fitting chemical safety and
splash-proof googles and/or a splash-proof face
shield must be worn if there is a likelihood of
exposure. Persons subject to ammonia exposuremust not wear contact lenses.
Respiratory Protection-unless ventilation is
adequate to keep airborne concentrations below
the exposure standard, wear approved respiratory
protection such as an ammonia canister mask or
an approved air supplied respirator (PAPR).

Confined Space Toxic atmosphere due to the presence or ingress Confined Space Entry Permit-entry supervisor

of hazardous substances. Oxygen deficiency, must completely fill out the permit, reviewed by
oxygen enrichment, flammable or explosive entrants and posted near the permit-required
atmosphere, flowing liquid or free flowing solids, confined space’s entrance. Entry must comply with
excessive heat.all provisions of the facility confined space entry
program. When applicable, systems shall be secured
in accordance with PWP LOTO/Hold Card Policy
procedures. Air monitoring for oxygen, flammables,
hydrogen sulfide, ammonia, etc. must be conducted
prior to entry by the entry supervisor. Monitoring
for ammonia shall be performed using the Dräger
ammonia monitoring device. Adequate forced air

ventilation must be provided at point of entry.

Personal Protective Equipment (PPE)-entrants
must don the waist belt portion of powered air
purifying respirator (PAPR) prior to entry. All
extraction equipment and harnesses that will be
used are required to be inspected and readied prior
to entry. Entrants must wear full body harness
with front and rear D rings. The entrant will attach
the extraction lifeline to the “D” clip on the full body
harness prior to breaking the plane of entry.
Entrants must carry personal aqueous ammoniamonitor at all time while in the confined space.

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