Exhibit_C_SDS.pdf
PDF 241 KB Posted
- Solicitation number
- SPE605-26-R-1000
- Issued by
-
Defense Logistics Agency Energy
About this file
This is a Safety Data Sheet (SDS) for Fuel Oil, Reclaimed (FOR), prepared in accordance with federal regulations (Federal Register Vol. 77, No. 58, dated March 26, 2012). The document was created by Fleet Logistics Center Norfolk Fuel Department in Portsmouth, Virginia, with an emergency contact number of 757-322-9044. The product is classified as a combustible liquid mixture containing various petroleum fuels and used lubricating oils, with a composition range of 60-100% diesel fuel (No. 2) and minor components including naphthalene (1-5%), distillates petroleum hydrotreated heavy paraffinic (1-5%), benzene trimethyl (1-5%), ethylbenzene (0.1-1%), and phosphorodithioic acid zinc salts (0.1-1%).
The material presents multiple hazards requiring careful handling. It is classified as a flammable liquid (Category 4) with a flash point of 60-93°C, causes serious eye irritation (Category 2A), and may cause cancer (Category 1B) as well as organ damage through prolonged exposure (Category 2 STOT RE). Physical and chemical properties include a relative density of 0.83-0.9, kinematic viscosity of 2-15 cSt at 40°C, and complete insolubility in water. For transport, the product is designated as NA1202 (Combustible liquid, n.o.s.) under Department of Transportation regulations with Packing Group III and quantity limitations of 60 liters for passenger aircraft/rail and 220 liters for cargo aircraft. The SDS specifies comprehensive personal protective equipment requirements including chemical-resistant gloves, eye protection, face shields, protective clothing, and NIOSH-approved respirators. Storage must occur in dry, cool, well-ventilated areas in tightly closed containers, with disposal requiring consultation with pollution control authorities and licensed hazardous-waste contractors.
View the file
Other files
On GovTribe
Work with this file
- Download the original file
- Contacts named in this file
- Similar government files
- Ask GovTribe AI about this file
Text version
Fuel Oil, Reclaimed (FOR) Safety Data Sheet Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 06/22/2015 Supersedes: 08/31/1998 Version: 1.0
06/22/2015 Fuel Oil, Reclaimed (FOR) Page 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name : Fuel Oil, Reclaimed (FOR)
Product form : Mixture
Other means of identification : A blend of various petroleum fuels and used lubricating oils Petroleum hydrocarbons
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Fleet Logistics Center Norfolk Fuel Dept.
4501 Cedar Lane Portsmouth, VA 23703 757-322-9006
1.4. Emergency telephone number
Emergency number: 757-322-9044
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 4 H227 Eye Irrit. 2A H319 Carc. 1B H350
STOT RE 2 H373
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :
GHS07
GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H227 - Combustible liquid H319 - Causes serious eye irritation H350 - May cause cancer H373 - May cause damage to organs (blood, central nervous system, respiratory system) through prolonged or repeated exposure
Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from sparks, open flames, heat. - No smoking P260 - Do not breathe mist, vapours P264 - Wash hands, forearms and face thoroughly after handling P280 - Wear eye protection, face protection, protective clothing, protective gloves P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention P314 - Get medical advice/attention if you feel unwell P337+P313 - If eye irritation persists: Get medical advice/attention P370+P378 - In case of fire: Use carbon dioxide (CO2), dry extinguishing powder, foam to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous waste
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS US)
No data available
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/22/2015 Fuel Oil, Reclaimed (FOR) 2/1
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier %
Fuels, diesel, no. 2 (CAS No) 68476-34-6 60 - 100
Naphthalene (CAS No) 91-20-3 1 - 5
Distillates, petroleum, hydrotreated heavy paraffinic (CAS No) 64742-54-7 1 - 5
Benzene, trimethyl- (CAS No) 25551-13-7 1 - 5
Ethylbenzene (CAS No) 100-41-4 0.1 - 1
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS No) 68649-42-3 0.1 - 1
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : If exposed or concerned, get medical attention/advice. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before re-use. Never give anything to an unconscious person.
First-aid measures after inhalation : IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if breathing is affected. If breathing is difficult, supply oxygen.
First-aid measures after skin contact : IF ON SKIN (or clothing): Remove affected clothing and wash all exposed skin with water for at least 15 minutes. If irritation develops or persists, get medical attention.
First-aid measures after eye contact : IF IN EYES: Immediately flush with plenty of water for at least 15 minutes. Remove contact lenses if present and easy to do so. If pain, blinking, or irritation develops or persists, get medical attention. Continue rinsing.
First-aid measures after ingestion : IF SWALLOWED: rinse mouth thoroughly. Do not induce vomiting without advice from poison control center or medical professional. Get medical attention if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes serious eye irritation. May cause cancer.
Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : May cause skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : May cause gastrointestinal irritation.
Chronic symptoms : May cause cancer.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry powder. Water spray. Water fog.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Combustible liquid.
Explosion hazard : Heating may cause an explosion.
Reactivity : No dangerous reactions known under normal conditions of use.
5.3. Advice for firefighters
Precautionary measures fire : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Do not dispose of fire-fighting water in the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Self-contained breathing apparatus.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Evacuate area. Ventilate area. Keep upwind. Spill should be handled by trained clean-up crews properly equipped with respiratory equipment and full chemical protective gear (see Section 8).
6.1.1. For non-emergency personnel
Protective equipment : Wear Protective equipment as described in Section 8.
Emergency procedures : Evacuate unnecessary personnel.
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/22/2015 Fuel Oil, Reclaimed (FOR) 3/1
6.1.2. For emergency responders
Protective equipment : Wear suitable protective clothing, gloves and eye or face protection. Approved supplied-air respirator, in case of emergency.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Methods for cleaning up : Eliminate ignition sources. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Sweep or shovel spills into appropriate container for disposal. This material and its container must be disposed of in a safe way, and as per local legislation.
6.4. Reference to other sections
See Sections 8 and 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Handle in accordance with good industrial hygiene and safety procedures. Do not handle until all safety precautions have been read and understood. Do not get in eyes, on skin, or on clothing. Avoid breathing vapours, mist. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a dry, cool and well-ventilated place. Keep the container tightly closed. Avoid temperature extremes.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Fuels, diesel, no. 2 (68476-34-6)
ACGIH TWA (mg/m³) 100 mg/m³ inhalable fraction and vapor, as total hydrocarbons, listed under diesel fuel
Remark (OSHA) OELs not established
Naphthalene (91-20-3)
ACGIH TWA (ppm) 10 ppm
ACGIH STEL (ppm) 15 ppm
Remark (ACGIH) 5 ppm TWA notice of intended changes TLVs
OSHA PEL (TWA) (mg/m³) 50 mg/m³
OSHA PEL (TWA) (ppm) 10 ppm
Ethylbenzene (100-41-4)
ACGIH TWA (ppm) 20 ppm
Remark (ACGIH) upper respiratory tract irritation; kidney damage (nephropathy); cochlear impairment
OSHA PEL (TWA) (mg/m³) 435 mg/m³
OSHA PEL (TWA) (ppm) 100 ppm
OSHA PEL (STEL) (mg/m³) 545 mg/m³
OSHA PEL (STEL) (ppm) 125 ppm
Distillates, petroleum, hydrotreated heavy paraffinic (64742-54-7)
Remark (ACGIH) OELs not established
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3)
Remark (ACGIH) OELs not established
Benzene, trimethyl- (25551-13-7)
ACGIH TWA (ppm) 25
Remark (ACGIH) CNS impair; asthma; hematologic eff
OSHA PEL (TWA) (mg/m³) 125
OSHA PEL (TWA) (ppm) 25
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/22/2015 Fuel Oil, Reclaimed (FOR) 4/1
8.2. Exposure controls
Appropriate engineering controls : Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof equipment with flammable materials. Ensure adequate ventilation, especially in confined areas.
Personal protective equipment : Gloves. Protective goggles. Wear chemically impervious apron over labcoat and full coverage clothing.
Hand protection : Use gloves chemically resistant to this material when prolonged or repeated contact could occur. Gloves should be classified under Standard EN 374 or ASTM F1296. Suggested glove materials are: Neoprene, Nitrile/butadiene rubber, Polyethylene, Ethyl vinyl alcohol laminate, PVC or vinyl. Suitable gloves for this specific application can be recommended by the glove supplier.
Eye protection : Wear eye protection, including chemical splash goggles and a face shield when possibility exists for eye contact due to spraying liquid or airborne particles.
Skin and body protection : Wear long sleeves, and chemically impervious PPE/coveralls to minimize bodily exposure.
Respiratory protection : Use NIOSH-approved dust/particulate respirator. Where vapor, mist, or dust exceed PELs or other applicable OELs, use NIOSH-approved respiratory protective equipment.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Oily liquid.
Color : Dark. Brown.
Odor : Petroleum-like odour.
Odor Threshold : No data available pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : 60 - 93 °C (140 - 200 °F) (ASTM D93)
Auto-ignition temperature : 257 °C (495 °F) (Based on NFPA "Fuel Oil No. 2")
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : 0.83 - 0.9
Solubility : Insoluble in water. Completely soluble in oil.
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : 2 - 15 cSt @ 40 °C
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.8 - 7.5 vol % (Based on NFPA "Fuel Oil No. 2")
9.2. Other information
SECTION 10: Stability and reactivity
10.1. Reactivity
No dangerous reactions known under normal conditions of use.
10.2. Chemical stability
Stable under recommended handling and storage conditions (see section 7).
10.3. Possibility of hazardous reactions
None known.
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/22/2015 Fuel Oil, Reclaimed (FOR) 5/1
10.4. Conditions to avoid
10.5. Incompatible materials
Strong oxidizers.
10.6. Hazardous decomposition products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
LD50 oral rat 1110 mg/kg
LC50 inhalation rat (mg/l) > 340 mg/m³ 1 h
LD50 oral rat 3500 mg/kg
LD50 dermal rabbit 15400 mg/kg
LC50 inhalation rat (mg/l) 17.2 mg/l/4h
Benzene, trimethyl- (25551-13-7)
LD50 oral rat 8970 mg/kg
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : May cause cancer.
IARC group 2B - Possibly carcinogenic to humans
National Toxicology Program (NTP) Status 3 - Reasonably anticipated to be Human Carcinogen
IARC group 2B - Possibly carcinogenic to humans
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure)
: Not classified
Aspiration hazard : Not classified
Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : May cause skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : May cause gastrointestinal irritation.
Chronic symptoms : May cause cancer.
SECTION 12: Ecological information
12.1. Toxicity
Ecology - general : No information available.
12.2. Persistence and degradability
Persistence and degradability No information available.
12.3. Bioaccumulative potential
Bioaccumulative potential No information available.
12.4. Mobility in soil
Ecology - soil No information available.
12.5. Other adverse effects
Other adverse effects : No data available.
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/22/2015 Fuel Oil, Reclaimed (FOR) 6/1
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods : Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Do not allow the product to be released into the environment.
SECTION 14: Transport information
In accordance with DOT
Transport document description : NA1202, Diesel Fuel, 3, III
DOT NA no. : NA1202
Proper Shipping Name (DOT) : Combustible liquid, n.o.s.
Contains: Petroleum hydrocarbons
Department of Transportation (DOT) Hazard Classes
: 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : III - Minor Danger
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 60 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 220 L
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel.
Additional information
Other information : No supplementary information available.
Transport by sea
No additional information available
Air transport
SECTION 15: Regulatory information
15.1. US Federal regulations
All chemical substances in this product are listed in the EPA (Environment Protection Agency) TSCA (Toxic Substances Control Act) Inventory or are exempt
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard
Cumene (98-82-8)
Section 302 (EHS) TPQ
Section 304 EHS RQ
CERCLA RQ 5000 lb
Section 313 Listed on US SARA Section 313
Section 304 EHS RQ
CERCLA RQ 1000 lb
Section 304 EHS RQ
CERCLA RQ 100 lb
15.2. International regulations
No additional information available.
15.3. US State regulations
California Proposition 65
WARNING! This product contains chemicals known to the state of California to cause cancer, birth defects, or other reproductive harm.
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/22/2015 Fuel Oil, Reclaimed (FOR) 7/1
U.S. - California - Proposition 65 - Carcinogens List
Developmental Toxicity
U.S. - California - Proposition 65 - Reproductive Toxicity - Female
U.S. - California - Proposition 65 - Reproductive Toxicity - Male
No significance risk level
(NSRL)
Yes No No No 5.8 µg/day
Developmental Toxicity
U.S. - California - Proposition 65 - Reproductive Toxicity - Female
U.S. - California - Proposition 65 - Reproductive Toxicity - Male
No significance risk level
(NSRL)
Yes No No No 54 (inhalation) µg/day
41 (oral) µg/day
Developmental Toxicity
U.S. - California - Proposition 65 - Reproductive Toxicity - Female
U.S. - California - Proposition 65 - Reproductive Toxicity - Male
No significance risk level
(NSRL)
Yes No No No Not available
Fuels, diesel, no. 2 (68476-34-6)
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Massachusetts - Right To Know List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
Kerosine, petroleum (8008-20-6)
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
Indication of changes : Revision 1.0: New SDS Created.
Revision date : 06/22/2015
Other information : Author: BCS.
NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given.
NFPA fire hazard : 2 - Must be moderately heated or exposed to relatively high temperature before ignition can occur.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.
HMIS III Rating
Health : 2*
Flammability : 2
Physical : 0
Personal Protection :
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/22/2015 Fuel Oil, Reclaimed (FOR) 8/1
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product
File details come from the government source that posted it. Updated .