Crafco-Mastic-Polypatch-and-Matrix-Safety-Data-Sheet.pdf

SAFETY DATA SHEET

1. Identification

Product identifier Crafco Mastic, Polypatch and Matrix Products

Other means of identification Not available.

Recommended use Pavement Patching and Repair

Recommended restrictions None known.

Manufacturer/Importer/Supplier/Distributor information

Manufacturer

Manufacturer: Crafco, Inc.

Address: 6165 West Detroit St.

Chandler, AZ 85226 USA

Contact Name: Jim Chehovits

Telephone: 602-276-0406

E-mail: jim.chehovits@crafco.com

CHEMTREC: 800-424-9300 (North America)

+ 1-703-527-3887 (International)

2. Hazard(s) identification

Not classified.Physical hazards

Not classified.Health hazards

Not classified.Environmental hazards

Not classified.OSHA defined hazards

*Hazards not stated here are "Not classified", "Not applicable" or "Classification not possible".

Label elements

None.Hazard symbol

Signal word Not applicable.

Hazard statement Not applicable.

Prevention Not applicable.

Response Not applicable.

Storage Not applicable.

Disposal Not applicable.

Hazard(s) not otherwise classified (HNOC)

None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name Common name and synonyms

64742-52-5DISTILLATES (PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC

0 - 10

14808-60-7QUARTZ 0 - 75

8052-42-4ASPHALT 10 - 40

471-34-1CALCIUM CARBONATE

Other components below reportable levels 0 - 75

0 - 10

4. First-aid measures

Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.

Get medical attention, if needed. Call a physician if symptoms develop or persist.

Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Thoroughly wash (or discard) clothing and shoes before reuse.

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Material name: Crafco Mastic, Polypatch and Matrix Products

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SDS US

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Get medical attention if irritation develops and persists.

Ingestion Rinse mouth. Do not induce vomiting. Do not use mouth-to-mouth method if victim ingested the substance. Call a POISON CENTER or doctor/physician if you feel unwell.

Most important symptoms/effects, acute and delayed

Not available.

Indication of immediate medical attention and special treatment needed

In case of ingestion, the decision of whether or not to induce vomiting should be made by the attending physician. Certain pre-existing conditions may make workers particularly susceptible to the effects of this chemical: asthma, allergies, impaired pulmonary function.

General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Discard any shoes or clothing items that cannot be decontaminated.

5. Fire-fighting measures

Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Addition of water or foam to the fire may cause frothing.

Unsuitable extinguishing media

Do not use a solid water stream as it may scatter and spread fire.

Specific hazards arising from the chemical

Fire may produce irritating, corrosive and/or toxic gases. Development of hazardous combustion gases or vapours possible in the event of a fire. The following may develop: Acrolein.

Special protective equipment and precautions for firefighters

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters should wear full protective clothing including self contained breathing apparatus. Structural firefighters protective clothing will only provide limited protection.

Fire-fighting equipment/instructions

In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. ALWAYS stay away from tanks engulfed in flame. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. In the event of fire, cool tanks with water spray. By fire, toxic gases may be formed (COx, NOx). Keep run-off water out of sewers and water sources. Dike for water control.

Specific methods In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with water spray. Use water spray to cool unopened containers.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during clean-up. Ventilate closed spaces before entering them. Do not touch or walk through spilled material.

Methods and materials for containment and cleaning up

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Dike far ahead of spill for later disposal. Following product recovery, flush area with water.

Never return spills in original containers for re-use.

Environmental precautions Prevent further leakage or spillage if safe to do so. Runoff or release to sewer, waterway or ground is forbidden.

7. Handling and storage

Precautions for safe handling The product is non-combustible. If heated, irritating vapors may be formed. Do not use in areas without adequate ventilation. Wash hands thoroughly after handling. Wash hands after handling.

Observe good industrial hygiene practices.

Conditions for safe storage, including any incompatibilities

Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a well-ventilated place. Keep the container tightly closed and dry. Store in a closed container away from incompatible materials. Keep out of the reach of children.

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueComponents FormType

PEL 5 mg/m3 Respirable fraction.CALCIUM CARBONATE (CAS 471-34-1)

15 mg/m3 Total dust.

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Material name: Crafco Mastic, Polypatch and Matrix Products

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueComponents FormType

PEL 5 mg/m3 Mist.DISTILLATES

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

US. OSHA Table Z-3 (29 CFR 1910.1000)

ValueComponents FormType

TWA 0.3 mg/m3 Total dust.QUARTZ (CAS 14808-60-7)

0.1 mg/m3 Respirable.

2.4 mppcf Respirable.

US. ACGIH Threshold Limit Values

ValueComponents FormType

TWA 0.5 mg/m3 Inhalable fraction.ASPHALT (CAS 8052-42-4)

TWA 0.025 mg/m3 Respirable fraction.QUARTZ (CAS 14808-60-7)

US. NIOSH: Pocket Guide to Chemical Hazards

ValueComponents FormType

Ceiling 5 mg/m3 Fume.ASPHALT (CAS 8052-42-4)

TWA 5 mg/m3 Respirable.CALCIUM CARBONATE (CAS 471-34-1)

10 mg/m3 Total

STEL 10 mg/m3 Mist.DISTILLATES

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

TWA 5 mg/m3 Mist.

TWA 0.05 mg/m3 Respirable dust.QUARTZ (CAS 14808-60-7)

Biological limit values No biological exposure limits noted for the ingredient(s).

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Ensure adequate ventilation, especially in confined areas.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses; chemical goggles (if splashing is possible). Wear chemical goggles; face shield (if handling molten material).

Hand protection Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style gloves.

Other Wear suitable protective clothing and eye/face protection. Use of an impervious apron is recommended.

Skin protection

Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Thermal hazards During product use, there is a risk of thermal burns.

General hygiene considerations

When using do not smoke. Avoid contact with eyes. Avoid contact with skin. Keep away from food and drink. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical properties

Appearance Solid.

Physical state Solid.

Form Solid.

Color Black. Dark brown

Odor Product is a black, semi-solid with a burnt tar odor.

Odor threshold Not available.

pH Not available.

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Material name: Crafco Mastic, Polypatch and Matrix Products

Melting point/freezing point 150 - 250 °F (65.56 - 121.11 °C) ASTM D36 Softening Point

Initial boiling point and boiling range

> 800 °F (> 426.67 °C)

Flash point > 400.0 °F (> 204.4 °C)

Evaporation rate Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower

Not available.

Flammability limit -upper (%)

Not available.

Explosive limit - lower

Not available.

Explosive limit - upper

Not available.

Vapor pressure 2.04 hPa estimated

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature > 700 °F (> 371.11 °C)

Decomposition temperature Not available.

Viscosity Not available.

Other information

Density Not Available

Percent volatile 0 %

Specific gravity 1 - 2.2

10. Stability and reactivity

Reactivity Not available.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous reactions

Hazardous polymerization does not occur.

Conditions to avoid Strong oxidizing agents.

Incompatible materials Incompatible with oxidizing agents.

Hazardous decomposition products

Upon decomposition, product emits acrid dense smoke with carbon dioxide, carbon monoxide, trace oxides of nitrogen and sulfur, and water.

11. Toxicological information

Information on likely routes of exposure

Ingestion May cause discomfort if swallowed. However, ingestion is not likely to be a primary route of occupational exposure.

Inhalation May cause irritation to the respiratory system.

Skin contact Irritating to skin.

Eye contact Causes eye irritation. Molten material will produce thermal burns.

Symptoms related to the physical, chemical and toxicological characteristics

Not available.

Information on toxicological effects

Acute toxicity

Test ResultsProduct Species

Crafco Mastic, Polypatch and Matrix Products (CAS Mixture)

LD50 Mouse

Oral

Acute

17340.7969 mg/kg estimated

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Material name: Crafco Mastic, Polypatch and Matrix Products

Test ResultsProduct Species

Rat 18934.6973 mg/kg estimated

Test ResultsComponents Species

CALCIUM CARBONATE (CAS 471-34-1)

LD50 Mouse

Oral

Acute

6450 mg/kg

Rat 6450 mg/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Defats the skin. Causes irritation.

Serious eye damage/eye irritation

Irritating to eyes.

Respiratory or skin sensitization

Respiratory sensitization Not available.

Skin sensitization Irritating to skin.

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity Contains no ingredient listed as toxic to reproduction

Specific target organ toxicity

- single exposure

Not available.

Specific target organ toxicity

- repeated exposure

Not available.

Aspiration hazard Not available.

Chronic effects Prolonged inhalation may be harmful. May cause eczema-like skin disorders (dermatitis).

12. Ecological information

Ecotoxicity This product has no known eco-toxicological effects. Not expected to be harmful to aquatic organisms.

Components Test ResultsSpecies

* Estimates for product may be based on additional component data not shown.

CALCIUM CARBONATE (CAS 471-34-1)

Aquatic

LC50Fish > 56000 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis)

Persistence and degradability Not available.

Bioaccumulative potential Not available.

Mobility in soil Not available.

Other adverse effects Not available.

13. Disposal considerations

Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations.

When this product as supplied is to be discarded as waste, it does not meet the definition of a RCRA waste under 40 CFR 261.

Hazardous waste code Not applicable.

Waste from residues / unused products

Dispose of in accordance with local regulations.

Contaminated packaging Offer rinsed packaging material to local recycling facilities.

14. Transport information

DOT

Not regulated as dangerous goods.

IATA

Not regulated as dangerous goods.

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Material name: Crafco Mastic, Polypatch and Matrix Products

IMDG

Not regulated as dangerous goods.

Not available.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Further information If the product is shipped at temperatures below 212°F (100°C), it is not regulated for transport by ground, air or vessel. If shipped above 212 deg F: "UN3257, Elevated Temperature Liquid, n.o.s.

(Asphalt mixture), 9, PG III"

15. Regulatory information

US federal regulations All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312

Hazardous chemical

No

SARA 313 (TRI reporting)

Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Safe Drinking Water Act

(SDWA)

Not regulated.

US state regulations WARNING: This product contains a chemical known to the State of California to cause cancer.

US. Massachusetts RTK - Substance List

ASPHALT (CAS 8052-42-4)

CALCIUM CARBONATE (CAS 471-34-1)

QUARTZ (CAS 14808-60-7)

US. New Jersey Worker and Community Right-to-Know Act

Not regulated.

US. Pennsylvania RTK - Hazardous Substances

ASPHALT (CAS 8052-42-4)

CALCIUM CARBONATE (CAS 471-34-1)

QUARTZ (CAS 14808-60-7)

US. Rhode Island RTK

Not regulated.

US. California Proposition 65

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

ASPHALT (CAS 8052-42-4) Listed: January 1, 1990

QUARTZ (CAS 14808-60-7) Listed: October 1, 1988

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

YesAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)

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Country(s) or region Inventory name On inventory (yes/no)*

NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)

YesEurope European Inventory of Existing Commercial Chemical Substances

(EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

YesJapan Inventory of Existing and New Chemical Substances (ENCS)

YesKorea Existing Chemicals List (ECL)

YesNew Zealand New Zealand Inventory

YesPhilippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

Issue date 02-27-2015

Version # 01

Further information HMIS® is a registered trade and service mark of the NPCA.

References ACGIH EPA: AQUIRE database US. IARC Monographs on Occupational Exposures to Chemical Agents HSDB® - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices

Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Revision Information Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Transport Information: Material Transportation Information Transport information: Further information Regulatory Information: Risk Phrases - Class.

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Material name: Crafco Mastic, Polypatch and Matrix Products