Attachment 6 - Safety Data Sheets for NIH NPDES Permit Chemicals.pdf

PDF 661 KB Posted

Attached to
Water Treatment for NIH CUP Federal contract opportunity
Solicitation number
75N99022R00038
Issued by
Department of Health and Human Services National Institutes of Health Construction

View the file

Other files for this federal contract opportunity

Show all 17

On GovTribe

Work with this file on GovTribe

  • Download the original file
  • Contacts named in this file
  • Similar government files
  • Ask GovTribe AI about this file

Text version

19020801AN 02/08/19 ChemTreat BL126Page 1 of 11

��������������������������������
������������

Product Name: ChemTreat BL126 Product Use: Dechlorination Treatment Supplier’s Name: ChemTreat, Inc.

Emergency Telephone Number: (800)424−9300 (Toll Free) Address (Corporate Headquarters): 5640 Cox Road

Glen Allen, VA 23060 Telephone Number for Information: (800)648−4579 Date of SDS: February 8, 2019 Revision Date: February 8, 2019 Revision Number: 19020801AN

Signal Word: DANGER

GHS Classification(s): Corrosive to Metals − Category 1 Skin corrosion/irritation − Category 1c Respiratory sensitization − Category 1 Sensitization Skin − Category 1 Eye damage/irritation − Category 2a Acute Toxicity Oral − Category 4

Hazard Statement(s): H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H302 Harmful if swallowed.

Precautionary Statement(s):

Prevention: P234 Keep only in original container.

P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P264 Wash thoroughly after handling.

P270 Do not eat, drink, or smoke when using this product.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Attachment 6 NIH NPDES Allowable Chemicals Attachemtn

19020801AN 02/08/19 ChemTreat BL126Page 2 of 11

Response: P301 + 330 + 331 IF SWALLOWED: Rinse mouth.

Do NOT induce vomiting.

P303 + P361 + P353 IF ON SKIN (or hair):

Remove/take off immediately all contaminated clothing.

Rinse skin with water/shower P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER/doctor.

P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

P337 + P313 If eye irritation persists, get medical advice/attention.

P342 + P311 If experiencing respiratory symptoms:

Call a POISON CENTER/doctor.

P363 Wash contaminated clothing before reuse.

P390 Absorb spillage to prevent material damage.

Storage: P405 Store locked up.

P406 Store in a corrosive resistant container with a resistant inner liner.

Disposal: P501 Dispose of contents and container in accordance with applicable local, regional, national, and/or international regulations.

System of Classification Used: Classification under 2012 OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Hazards Not Otherwise None.

Classified:

���������(��!�����
�.!#$�&%����������(���

Component CAS Registry # Wt.% Sodium bisulfite 7631−90−5 30 − 60

Comments If chemical identity and/or exact percentage of composition has been withheld, this information is considered to be a trade secret.

19020801AN 02/08/19 ChemTreat BL126Page 3 of 11

�0� �1�����(��&23����4�����(�������(

Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell.

Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention.

Skin: Immediately remove/take off all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before re−use.

Immediately call a poison center or doctor/physician.

Ingestion: DO NOT INDUCE VOMITING. Rinse mouth. Call a POISON CENTER or doctor/physician.

Most Important Symptoms: N/D

Indication of Immediate N/A Medical Attention and Special Treatment Needed, If Necessary:

�5� �1�������1��6/������� �/�4�����(�������(

Flammability of the Product: Not flammable.

Suitable Extinguishing Media: Use extinguishing media suitable to surrounding fire.

Specific Hazards Arising from Product emits toxic gases or fumes under fire conditions.

the Chemical:

Protective Equipment: If product is involved in a fire, wear full protective clothing including a positive−pressure, NIOSH approved, self−contained breathing apparatus.

19020801AN 02/08/19 ChemTreat BL126Page 4 of 11

�7� &23���������� �������89��������(���4�����(�������(

Personal Precautions: Use appropriate Personal Protective Equipment (PPE).

Environmental Precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains, and sewers.

Methods for Cleaning up: Contain and recover liquid when possible. Flush spill area with water spray.

Other Statements: If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1−800−424−8802.

Reportable Quantity of the product is 1127 Gal.

Handling: Wear appropriate Personal Protective Equipment (PPE) when handling this product. Do not get in eyes, or on skin and clothing.

Wash thoroughly after handling. Do not ingest. Avoid breathing vapors, mist or dust.

Do not pressurize, cut or weld containers.

Storage: Store away from incompatible materials (see Section 10). Store at ambient temperatures. Keep container securely closed when not in use. Label precautions also apply to empty container. Recondition or dispose of empty containers in accordance with government regulations. For Industrial use only.

Relieve pressure in drums weekly.

Keep out of direct sunlight.

Do not freeze. Store above Freeze Point. If freezes, then mechanical mixing is required.

�<�=����(������>�?�
��������(@.!������(��
���������������������

Exposure Limits

Component Source Exposure Limits Sodium bisulfite ACGIH TLV 5 mg/m³ TWA

Engineering Controls: Use only with adequate ventilation. The use of local ventilation is recommended to control emission near the source.

19020801AN 02/08/19 ChemTreat BL126Page 5 of 11

Personal Protection

Eyes: Wear chemical splash goggles or safety glasses with full−face shield. Maintain eyewash fountain in work area.

Skin: Maintain quick−drench facilities in work area.

Wear butyl rubber or neoprene gloves. Wash them after each use and replace as necessary. If conditions warrant, wear protective clothing such as boots, aprons, and coveralls to prevent skin contact.

Respiratory: If misting occurs, use NIOSH approved organic vapor/acid gas dual cartridge respirator with a dust/mist prefilter in accordance with 29 CFR 1910.134.

�A�

Physical State and Appearance: Liquid, Light Straw, Clear Specific Gravity: 1.330 @ 20°C pH: 3.8 @ 20°C, 100.0% Freezing Point: 45°F Flash Point: N/D Odor: Strong Melting Point: N/A Initial Boiling Point and Boiling Range: 219°F Solubility in Water: Complete Evaporation Rate: N/D Vapor Density: N/D Molecular Weight: N/D Viscosity: N/A Flammability (solid, gas): N/D Flammable Limits: N/A Autoignition Temperature: N/A Density: 11.09 LB/GA Vapor Pressure: N/D

% VOC: 0

Odor Threshold N/D n−octanol Partition Coefficient N/D Decomposition Temperature N/D

19020801AN 02/08/19 ChemTreat BL126Page 6 of 11

���B� ��$����C������!�6�>�� ���8$���������!D&�!�6�

Chemical Stability: Stable at normal temperatures and pressures.

Incompatibility with Various Acids, Mineral acids, Oxidizers, Metals or metal oxides.

Substances:

Hazardous Decomposition Sulfur dioxide gas, Oxides of sulfur, Toxic vapors/fumes/gases.

Products:

Possibility of Hazardous None known.

Reactions:

Reactivity: N/D

Conditions To Avoid: N/D

�E��=���������/�����������
� !������������

Acute Toxicity

Chemical Name Exposure Type of Effect Concentration Species Sodium bisulfite Oral LD50 2000 MG/KG Rat

Carcinogenicity Category

Component Source Code Brief Description Sodium bisulfite N/E N/E N/E

Likely Routes of Exposure: N/D

Symptoms

Inhalation: N/D

Eye Contact: N/D

Skin Contact: N/D

Ingestion: N/D

Skin Corrosion/Irritation: N/D

19020801AN 02/08/19 ChemTreat BL126Page 7 of 11

Serious Eye Damage/Eye N/D Irritation:

Sensitization: N/D

Germ Cell Mutagenicity: N/D

Reproductive/Developmental N/D Toxicity:

Specific Target Organ Toxicity

Single Exposure: N/D

Repeated Exposure: N/D

Aspiration Hazard: N/D

Comments: None.

�<�������/�����������
� !������������

Ecotoxicity

Species Duration Type of Effect Test Results Ceriodaphnia dubia 48h LC50 526 mg/l Fathead Minnow 96h LC50 884 mg/l

Persistence and N/D Biodegradability:

Bioaccumulative Potential: N/D

Mobility In Soil: N/D

Other Adverse Effects: N/D

Comments: None.

19020801AN 02/08/19 ChemTreat BL126Page 8 of 11

�F$��(&���(��������
�(����������������

Dispose of in accordance with local, state and federal regulations.

���0� �E�����

�(&���������
� !������������

Controlling Regulation

UN/NA#:

Proper Shipping Name:

Technical Name:

Hazard Class:

Packing Group:

DOT

UN2693

BISULPHITES, AQUEOUS

SOLUTIONS, N.O.S.

(SODIUM BISULFITE)

PGIII

Over 1127 GA

RQ UN2693

IMDG

ICAO

TDG

ANTT

Note: N/A

���5�

�8$�&/�����������!���,
� G������*�+�,�

Inventory Status

United States (TSCA): All ingredients listed.

Canada (DSL/NDSL): All ingredients listed.

19020801AN 02/08/19 ChemTreat BL126Page 9 of 11

Federal Regulations

SARA Title III Rules

Sections 311/312 Hazard Classes

Fire Hazard: No Reactive Hazard: No Release of Pressure: No Acute Health Hazard: Yes Chronic Health Hazard: No

Other Sections

Component

Section 313 Toxic Chemical

Section 302 EHS

TPQ

CERCLA RQ

Sodium bisulfite N/A N/A 5000

Comments: None.

State Regulations

California Proposition 65: This product may contain trace amounts of chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. Sulfur dioxide

Special Regulations

Component States Sodium bisulfite MA, MN, NY, PA, WA

Compliance Information

NSF: N/A

Food Regulations: N/A

KOSHER: This product has not been evaluated for Kosher approval.

Halal: This product has not been evaluated for Halal approval.

FIFRA: N/A

Other: None

19020801AN 02/08/19 ChemTreat BL126Page 10 of 11

���7� �H3����������

HMIS Hazard Rating

Health: 2 Flammability: 0 Physical Hazard: 0

PPE: X

Notes: The PPE rating depends on circumstances of use. See Section 8 for recommended PPE.

The Hazardous Material Information System (HMIS) is a voluntary, subjective alpha−numeric symbolic system for recommending hazard risk and personal protection equipment information. It is a subjective rating system based on the evaluator’s understanding of the chemical associated risks.

The end−user must determine if the code is appropriate for their use.

Abbreviations

Abbreviation Definition < Less Than > Greater Than ACGIH American Conference of Governmental Industrial Hygienists EHS Environmental Health and Safety Dept N/A Not Applicable N/D Not Determined N/E Not Established OSHA Occupational Health and Safety Dept PEL Personal Exposure Limit STEL Short Term Exposure Limit TLV Threshold Limit Value TWA Time Weight Average UNK Unknown

Prepared by: Product Compliance Department; ProductCompliance@chemtreat.com

Revision Date: February 8, 2019

19020801AN 02/08/19 ChemTreat BL126Page 11 of 11

F$��(��������������

Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof, ChemTreat, Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will ChemTreat, Inc. be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. No representation or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature are made hereunder with respect to information or the product to which information refers.

19032601AN 03/26/19 ChemTreat CL2155Page 1 of 11

��������������������������������
������������

Product Name: ChemTreat CL2155 Product Use: Cooling Water Microbiocide Supplier’s Name: ChemTreat, Inc.

Emergency Telephone Number: (800)424−9300 (Toll Free) Address (Corporate Headquarters): 5640 Cox Road

Glen Allen, VA 23060 Telephone Number for Information: (800)648−4579 Date of SDS: March 26, 2019 Revision Date: March 26, 2019 Revision Number: 19032601AN

GHS Classification(s): Skin corrosion/irritation − Category 1b Eye damage/irritation − Category 1 Acute Toxicity Oral − Category 4 Hazardous to the aquatic environment Acute − Category 3 Sensitization Skin − Category 1

Hazard Statement(s): H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H302 Harmful if swallowed.

H402 Harmful to aquatic life.

H317 May cause an allergic skin reaction.

Precautionary Statement(s):

Prevention: P261 Avoid breathing dust/fume/gas/mist/vapors/spray.

P264 Wash thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P270 Do not eat, drink, or smoke when using this product.

P273 Avoid release into the environment.

P272 Contaminated work clothing should not be allowed out of the workplace.

19032601AN 03/26/19 ChemTreat CL2155Page 2 of 11

Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.

P301 + 330 + 331 IF SWALLOWED: Rinse mouth.

Do NOT induce vomiting.

P303 + P361 + P353 IF ON SKIN (or hair):

Remove/take off immediately all contaminated clothing.

Rinse skin with water/shower P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Immediately call a POISON CENTER or doctor/physician.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

Storage: P405 Store locked up.

Disposal: P501 Dispose of contents and container in accordance with applicable local, regional, national, and/or international regulations.

System of Classification Used: Classification under 2012 OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Hazards Not Otherwise None.

Classified:

���������(��!�����
�.!#$�&%����������(���

Component CAS Registry # Wt.% 5−chloro−2−methyl−4−isothiazolin−3−one 26172−55−4 2.95 2−methyl−4−isothiazolin−3−one 2682−20−4 1.05 Magnesium nitrate 10377−60−3 >=4.6−<=6.0 Magnesium chloride 7786−30−3 <=3.0

19032601AN 03/26/19 ChemTreat CL2155Page 3 of 11

�0� �1�����(��&23����4�����(�������(

Inhalation: Call a POISON CENTER or doctor/physician if you feel unwell.

Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.

Skin: Immediately remove/take off all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before re−use.

Immediately call a poison center or doctor/physician.

Ingestion: DO NOT INDUCE VOMITING. Rinse mouth. Call a POISON CENTER or doctor/physician.

Most Important Symptoms: N/D

Indication of Immediate N/A Medical Attention and Special Treatment Needed, If Necessary:

�5� �1�������1��6/������� �/�4�����(�������(

Flammability of the Product: Not flammable.

Suitable Extinguishing Media: Use extinguishing media suitable to surrounding fire.

Specific Hazards Arising from Use water spray to keep containers cool.

the Chemical:

Protective Equipment: If product is involved in a fire, wear full protective clothing

19032601AN 03/26/19 ChemTreat CL2155Page 4 of 11

�7� &23���������� �������89��������(���4�����(�������(

Personal Precautions: Use appropriate Personal Protective Equipment (PPE).

Environmental Precautions: This pesticide is toxic to fish and wildlife.

Do not discharge effluent containing this product into lakes, ponds, streams, estuaries, oceans or public waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit, and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA.

Methods for Cleaning up: Contain and recover liquid when possible. Flush spill area with water spray.

Other Statements: None.

Handling: Wear appropriate Personal Protective Equipment (PPE) when handling this product. Do not get in eyes, or on skin and clothing.

Wash thoroughly after handling. Do not ingest. Avoid breathing vapors, mist or dust.

Storage: Store away from incompatible materials (see Section 10). Store at ambient temperatures. Keep container securely closed when not in use. Label precautions also apply to empty container. Recondition or dispose of empty containers in accordance with government regulations. For Industrial use only.

Do not store in steel containers.

Do not store below 34°F.

Do not store above 131°F.

Store above Freeze Point.

Store in vented containers.

19032601AN 03/26/19 ChemTreat CL2155Page 5 of 11

�<�=����(������>�?�
��������(@.!������(��
���������������������

5−chloro−2−methyl−4−isothiazolin−3−one N/E N/E 2−methyl−4−isothiazolin−3−one N/E N/E Magnesium nitrate N/E N/E Magnesium chloride N/E N/E

Engineering Controls: Use only with adequate ventilation. The use of local ventilation is recommended to control emission near the source.

Personal Protection

Eyes: Wear chemical splash goggles or safety glasses with full−face shield. Maintain eyewash fountain in work area.

Skin: Maintain quick−drench facilities in work area.

Wear appropriate chemical resistant gloves.

Respiratory: If misting occurs, use NIOSH approved organic vapor/acid gas dual cartridge respirator with a dust/mist prefilter in accordance with 29 CFR 1910.134.

�A�

Physical State and Appearance: Liquid, Light Straw, Clear Specific Gravity: 1.060 − 1.073 @ 20°C pH: 2.5 − 4.5 @ 20°C, 100.0% Freezing Point: 30.2°F Flash Point: N/A Odor: Strong Melting Point: N/A Initial Boiling Point and Boiling Range: 212°F Solubility in Water: N/D Evaporation Rate: <1 Vapor Density: N/D Molecular Weight: N/D Viscosity: N/D Flammability (solid, gas): N/D Flammable Limits: N/A Autoignition Temperature: N/A Density: 8.92 LB/GA

19032601AN 03/26/19 ChemTreat CL2155Page 6 of 11

Vapor Pressure: 17 mmHg

% VOC: 0

Odor Threshold N/D n−octanol Partition Coefficient N/D Decomposition Temperature N/D

���B� ��$����C������!�6�>�� ���8$���������!D&�!�6�

Chemical Stability: Stable at normal temperatures and pressures.

Incompatibility with Various Oxidizers, Amines, Reducing agents.

Substances:

Hazardous Decomposition Oxides of nitrogen, Hydrogen chloride, Sulfur dioxide gas.

Products:

Possibility of Hazardous None known.

Reactions:

Reactivity: N/D

Conditions To Avoid: N/D

�E��=���������/�����������
� !������������

ChemTreat CL2155 Oral LD50 862 MG/KG Rat

Dermal LD50 2800 MG/KG Rabbit

Carcinogenicity Category

Component Source Code Brief Description 5−chloro−2−methyl−4−isothiazolin−3−one N/E N/E N/E 2−methyl−4−isothiazolin−3−one N/E N/E N/E Magnesium nitrate N/E N/E N/E Magnesium chloride N/E N/E N/E

Likely Routes of Exposure: N/D

19032601AN 03/26/19 ChemTreat CL2155Page 7 of 11

Symptoms

Inhalation: N/D

Eye Contact: N/D

Skin Contact: N/D

Ingestion: N/D

Skin Corrosion/Irritation: N/D

Serious Eye Damage/Eye N/D Irritation:

Sensitization: N/D

Germ Cell Mutagenicity: N/D

Reproductive/Developmental N/D Toxicity:

Specific Target Organ Toxicity

Single Exposure: N/D

Repeated Exposure: N/D

Aspiration Hazard: N/D

Comments: None.

�<�������/�����������
� !������������

Fathead Minnow 96h LC50 2.41 mg/l Ceriodaphnia dubia 48h LC50 2.59 mg/l

Persistence and N/D Biodegradability:

Bioaccumulative Potential: N/D

Mobility In Soil: N/D

19032601AN 03/26/19 ChemTreat CL2155Page 8 of 11

�F$��(&���(��������
�(����������������

PESTICIDE DISPOSAL: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.

CONTAINER DISPOSAL: Non−refillable container. Do not reuse or refill this container. Triple rinse or pressure rinse container (or equivalent) promptly after emptying. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by procedures approved by state and local authorities.

���0� �E�����

�(&���������
� !������������

UN3265

CORROSIVE LIQUID, ACIDIC,

ORGANIC, N.O.S.

(5−CHLORO−2−METHYL−4−

ISOTHIAZOLIN−3−ONE)

PGII

(5−CHLORO−2−METHYL−4−

(5−CHLORO−2−METHYL−4−

(5−CHLORO−2−METHYL−4−

���5�

�8$�&/�����������!���,
� G������*�+�,�

United States (TSCA): All ingredients listed or exempt.

Canada (DSL/NDSL): All ingredients listed or exempt.

19032601AN 03/26/19 ChemTreat CL2155Page 9 of 11

SARA Title III Rules

Sections 311/312 Hazard Classes

Fire Hazard: No Reactive Hazard: No Release of Pressure: No Acute Health Hazard: Yes

Toxic Chemical

5−chloro−2−methyl−4−isothiazolin−3−one N/A N/A N/A 2−methyl−4−isothiazolin−3−one N/A N/A N/A Magnesium nitrate Yes N/A N/A Magnesium chloride N/A N/A N/A

Comments: None.

State Regulations

California Proposition 65: None known.

Special Regulations

Component States 5−chloro−2−methyl−4−isothiazolin−3−one None.

2−methyl−4−isothiazolin−3−one None.

Magnesium nitrate MA, PA Magnesium chloride None.

Compliance Information

NSF: N/A

Food Regulations: N/A

KOSHER: This product is certified by the Orthodox Union as kosher pareve.

Only when prepared by the following ChemTreat facilities:

Ashland, VA; Eldridge, IA; Nederland, TX.

Halal: This product has not been evaluated for Halal approval.

19032601AN 03/26/19 ChemTreat CL2155Page 10 of 11

FIFRA: Registered pesticide under 40 CFR 152.10, Federal Insecticide, Fungicide and Rodenticide Act (FIFRA), EPA Registration Number: 707−316−15300.

Other: None

Comments: None.

���7�

Health: 3 Flammability: 0 Physical Hazard: 0

PPE: X

Notes: The PPE rating depends on circumstances of use. See Section 8 for recommended PPE.

The Hazardous Material Information System (HMIS) is a voluntary, subjective alpha−numeric symbolic system for recommending hazard risk and personal protection equipment information. It is a subjective rating system based on the evaluator’s understanding of the chemical associated risks.

The end−user must determine if the code is appropriate for their use.

Abbreviations

Abbreviation Definition < Less Than > Greater Than ACGIH American Conference of Governmental Industrial Hygienists EHS Environmental Health and Safety Dept N/A Not Applicable N/D Not Determined N/E Not Established OSHA Occupational Health and Safety Dept PEL Personal Exposure Limit STEL Short Term Exposure Limit TLV Threshold Limit Value TWA Time Weight Average UNK Unknown

Revision Date: March 26, 2019

19032601AN 03/26/19 ChemTreat CL2155Page 11 of 11

Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof, ChemTreat, Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will ChemTreat, Inc. be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. No representation or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature are made hereunder with respect to information or the product to which information refers.

17030701AN 03/07/17 ChemTreat CD260Page 1 of 10

��������������������������������
������������

Product Name: ChemTreat CD260 Product Use: Dechlorination Treatment Supplier’s Name: ChemTreat, Inc.

Emergency Telephone Number: (800)424−9300 (Toll Free) Address (Corporate Headquarters): 5640 Cox Road

Glen Allen, VA 23060 Telephone Number for Information: (800)648−4579 Date of SDS: March 7, 2017 Revision Date: March 7, 2017 Revision Number: 17030701AN

GHS Classification(s): Eye damage/irritation − Category 1 Skin corrosion/irritation − Category 1a Sensitization Skin − Category 1 Acute Toxicity Oral − Category 4

Hazard Statement(s): H318 Causes serious eye damage.

H314 Causes severe skin burns and eye damage.

H317 May cause an allergic skin reaction.

H302 Harmful if swallowed.

Precautionary Statement(s):

Prevention: P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P264 Wash thoroughly after handling.

P270 Do not eat, drink, or smoke when using this product.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response: None.

Storage: None.

Disposal: None.

17030701AN 03/07/17 ChemTreat CD260Page 2 of 10

System of Classification Used: Classification under 2012 OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Hazards Not Otherwise None.

Classified:

���������(��!�����
�.!#$�&%����������(���

Component CAS Registry # Wt.% Ferrous Chloride 7758−94−3 10 − 35 Hydrochloric acid 7647−01−0 1 − 5

Comments If chemical identity and/or exact percentage of composition has been withheld, this information is considered to be a trade secret.

�0� �1�����(��&23����4�����(�������(

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician.

Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.

Skin: Immediately remove/take off all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before re−use.

Immediately call a poison center or doctor/physician.

Ingestion: DO NOT INDUCE VOMITING. Rinse mouth. Immediately call a POISON CENTER or doctor/physician.

Most Important Symptoms: N/D

Indication of Immediate N/A Medical Attention and Special Treatment Needed, If Necessary:

17030701AN 03/07/17 ChemTreat CD260Page 3 of 10

�5� �1�������1��6/������� �/�4�����(�������(

Flammability of the Product: Not flammable.

Suitable Extinguishing Media: Use extinguishing media suitable to surrounding fire.

Specific Hazards Arising from None known.

the Chemical:

Protective Equipment: If product is involved in a fire, wear full protective clothing including a positive−pressure, NIOSH approved, self−contained breathing apparatus.

�7� &23���������� �������89��������(���4�����(�������(

Personal Precautions: Use appropriate Personal Protective Equipment (PPE).

Environmental Precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains, and sewers.

Methods for Cleaning up: Contain and/or absorb spill with inert material then place in suitable container.

Other Statements: If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1−800−424−8802.

Reportable Quantity of the product is 30 Gal.

Handling: Wear appropriate Personal Protective Equipment (PPE) when handling this product. Do not get in eyes, or on skin and clothing.

Wash thoroughly after handling. Do not ingest. Avoid breathing vapors, mist or dust.

Storage: Store away from incompatible materials (see Section 10). Store at ambient temperatures. Keep container securely closed when not in use. Label precautions also apply to empty container. Recondition or dispose of empty containers in accordance with government regulations. For Industrial use only.

Do not freeze. Store above Freeze Point. If freezes, then mechanical mixing is required.

17030701AN 03/07/17 ChemTreat CD260Page 4 of 10

�<�=����(������>�?�
��������(@.!������(��
���������������������

Ferrous Chloride N/E N/E Hydrochloric acid NIOSH 5 ppm Ceiling Skin

OSHA PEL 5 ppm Ceiling Skin

Engineering Controls: Use only with adequate ventilation. The use of local ventilation is recommended to control emission near the source.

Personal Protection

Eyes: Wear chemical splash goggles or safety glasses with full−face shield. Maintain eyewash fountain in work area.

Skin: Maintain quick−drench facilities in work area.

Wear butyl rubber or neoprene gloves. Wash them after each use and replace as necessary. If conditions warrant, wear protective clothing such as boots, aprons, and coveralls to prevent skin contact.

Respiratory: If misting occurs, use NIOSH approved organic vapor/acid gas dual cartridge respirator with a dust/mist prefilter in accordance with 29 CFR 1910.134.

�A�

Physical State and Appearance: Liquid, Blue/Green, Opaque Specific Gravity: 1.275 @ 20°C pH: <1.0 @ 20°C, 100.0% Freezing Point: −59.8°F Flash Point: N/A Odor: Moderate Melting Point: N/D Initial Boiling Point and Boiling Range: N/D Solubility in Water: N/D Evaporation Rate: N/D Vapor Density: N/D Molecular Weight: N/D Viscosity: N/D Flammability (solid, gas): N/D Flammable Limits: N/A

17030701AN 03/07/17 ChemTreat CD260Page 5 of 10

Autoignition Temperature: N/D Density: 11.28 LB/GA Vapor Pressure: N/D

% VOC: N/D

Odor Threshold N/D n−octanol Partition Coefficient N/D Decomposition Temperature N/D

���B� ��$����C������!�6�>�� ���8$���������!D&�!�6�

Chemical Stability: Stable at normal temperatures and pressures.

Incompatibility with Various Metals or metal oxides, Alkali sensitive metals or alloys, Substances: Oxidizers.

Hazardous Decomposition None known.

Products:

Possibility of Hazardous None known.

Reactions:

Reactivity: N/D

Conditions To Avoid: N/D

�E��=���������/�����������
� !������������

Hydrochloric acid Oral LD50 700 MG/KG Rat

Dermal LD50 >5010 MG/KG Rabbit ChemTreat CD260 N/D N/D N/D N/D

Carcinogenicity Category

Component Source Code Brief Description Ferrous Chloride N/E N/E N/E Hydrochloric acid N/E N/E N/E

Likely Routes of Exposure: N/D

17030701AN 03/07/17 ChemTreat CD260Page 6 of 10

Symptoms

Inhalation: N/D

Eye Contact: N/D

Skin Contact: N/D

Ingestion: N/D

Skin Corrosion/Irritation: N/D

Serious Eye Damage/Eye N/D Irritation:

Sensitization: N/D

Germ Cell Mutagenicity: N/D

Reproductive/Developmental N/D Toxicity:

Specific Target Organ Toxicity

Single Exposure: N/D

Repeated Exposure: N/D

Aspiration Hazard: N/D

Comments: None.

�<�������/�����������
� !������������

Fathead Minnow 96h LC50 718.4 mg/l Ceriodaphnia dubia 48h LC50 883.9 mg/l

Persistence and N/D Biodegradability:

Bioaccumulative Potential: N/D

Mobility In Soil: N/D

17030701AN 03/07/17 ChemTreat CD260Page 7 of 10

�F$��(&���(��������
�(����������������

Dispose of in accordance with local, state and federal regulations.

EPA corrosivity characteristic hazardous waste D002 when disposed of in the original product form.

���0� �E�����

�(&���������
� !������������

UN3264

INORGANIC, N.O.S.

(FERROUS CHLORIDE)

Over 30 GA

UN3264

RQ CORROSIVE LIQUID,

ACIDIC, INORGANIC, N.O.S.

(FERROUS CHLORIDE)

���5�

�8$�&/�����������!���,
� G������*�+�,�

Canada (DSL/NDSL): All ingredients listed.

Federal Regulations

SARA Title III Rules

Sections 311/312 Hazard Classes

Fire Hazard: No Reactive Hazard: No Release of Pressure: No Acute Health Hazard: Yes

17030701AN 03/07/17 ChemTreat CD260Page 8 of 10

Toxic Chemical

Ferrous Chloride N/A N/A 100 Hydrochloric acid N/A N/A 5000

Comments: None.

State Regulations

California Proposition 65: None known.

Special Regulations

Component States Ferrous Chloride None.

Hydrochloric acid MA, MN, NJ, NY, PA, WA

International Regulations

Canada

WHMIS Classification: D2B (Toxic Material) E (Corrosive Material)

Controlled Product Regulations This product has been classified in accordance with (CPR): the hazard criteria of the Controlled Products

Regulations (CPR) and the MSDS contains all the information required by the CPR.

Compliance Information

NSF: N/A

Food Regulations: N/A

KOSHER: This product has not been evaluated for Kosher approval.

FIFRA: N/A

17030701AN 03/07/17 ChemTreat CD260Page 9 of 10

���7�

Flammability: 0 Physical Hazard: 0

PPE: X

Notes: The PPE rating depends on circumstances of use. See Section 8 for recommended PPE.

The Hazardous Material Information System (HMIS) is a voluntary, subjective alpha−numeric symbolic system for recommending hazard risk and personal protection equipment information. It is a subjective rating system based on the evaluator’s understanding of the chemical associated risks.

The end−user must determine if the code is appropriate for their use.

Abbreviations

Abbreviation Definition < Less Than > Greater Than ACGIH American Conference of Governmental Industrial Hygienists EHS Environmental Health and Safety Dept N/A Not Applicable N/D Not Determined N/E Not Established OSHA Occupational Health and Safety Dept PEL Personal Exposure Limit STEL Short Term Exposure Limit TLV Threshold Limit Value TWA Time Weight Average UNK Unknown

Revision Date: March 7, 2017

17030701AN 03/07/17 ChemTreat CD260Page 10 of 10

Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof, ChemTreat, Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will ChemTreat, Inc. be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. No representation or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature are made hereunder with respect to information or the product to which information refers.

19020701AN 02/07/19 ChemTreat CT30Page 1 of 11

��������������������������������
������������

Product Name: ChemTreat CT30 Product Use: Cooling System Cleaner Supplier’s Name: ChemTreat, Inc.

Emergency Telephone Number: (800)424−9300 (Toll Free) Address (Corporate Headquarters): 5640 Cox Road

Glen Allen, VA 23060 Telephone Number for Information: (800)648−4579 Date of SDS: February 7, 2019 Revision Date: February 7, 2019 Revision Number: 19020701AN

GHS Classification(s): Skin corrosion/irritation − Category 1b Eye damage/irritation − Category 1 Acute Toxicity Dermal − Category 4 Acute Toxicity Inhalation − Category 4 Acute Toxicity Oral − Category 4

Hazard Statement(s): H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H312 Harmful in contact with skin.

H332 Harmful if inhaled.

H302 Harmful if swallowed.

Precautionary Statement(s):

Prevention: P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P264 Wash thoroughly after handling.

P270 Do not eat, drink, or smoke when using this product.

P271 Use only outdoors or in a well−ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

19020701AN 02/07/19 ChemTreat CT30Page 2 of 11

Response: P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P301 + 330 + 331 IF SWALLOWED: Rinse mouth.

Do NOT induce vomiting.

P303 + P361 + P353 IF ON SKIN (or hair):

Remove/take off immediately all contaminated clothing.

Rinse skin with water/shower P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER/doctor.

P363 Wash contaminated clothing before reuse.

Storage: P405 Store locked up.

Disposal: P501 Dispose of contents and container in accordance with applicable local, regional, national, and/or international regulations.

System of Classification Used: Classification under 2012 OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Hazards Not Otherwise None.

Classified:

���������(��!�����
�.!#$�&%����������(���

Component CAS Registry # Wt.% Tetrapotassium pyrophosphate 7320−34−5 7 − 13 Potassium hydroxide 1310−58−3 1 − 5 Alcohol (C8 − 10) ethoxylated propoxylated 68603−25−8 1 − 5

19020701AN 02/07/19 ChemTreat CT30Page 3 of 11

�0� �1�����(��&23����4�����(�������(

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician.

Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.

Skin: Immediately remove/take off all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before re−use.

Immediately call a poison center or doctor/physician.

Ingestion: DO NOT INDUCE VOMITING. Rinse mouth. Call a POISON CENTER or doctor/physician.

Most Important Symptoms: N/D

Indication of Immediate N/A Medical Attention and Special Treatment Needed, If Necessary:

�5� �1�������1��6/������� �/�4�����(�������(

Flammability of the Product: Not flammable.

Suitable Extinguishing Media: Use extinguishing media suitable to surrounding fire.

Specific Hazards Arising from None known.

the Chemical:

Protective Equipment: If product is involved in a fire, wear full protective clothing

19020701AN 02/07/19 ChemTreat CT30Page 4 of 11

�7� &23���������� �������89��������(���4�����(�������(

Personal Precautions: Use appropriate Personal Protective Equipment (PPE).

Environmental Precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains, and sewers.

Methods for Cleaning up: Contain and recover liquid when possible. Flush spill area with water spray.

Other Statements: If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1−800−424−8802.

Handling: Wear appropriate Personal Protective Equipment (PPE) when handling this product. Do not get in eyes, or on skin and clothing.

Wash thoroughly after handling. Do not ingest. Avoid breathing vapors, mist or dust.

Storage: Store away from incompatible materials (see Section 10). Store at ambient temperatures. Keep container securely closed when not in use. Label precautions also apply to empty container. Recondition or dispose of empty containers in accordance with government regulations. For Industrial use only.

Do not store or handle in aluminum, zinc, copper, or their alloys.

Do not freeze. Store above Freeze Point. If freezes, then mechanical mixing is required.

�<�=����(������>�?�
��������(@.!������(��
���������������������

Tetrapotassium pyrophosphate N/E N/E Potassium hydroxide ACGIH TLV 2 mg/m³ Ceiling Alcohol (C8 − 10) ethoxylated propoxylated N/E N/E

Engineering Controls: Use only with adequate ventilation. The use of local ventilation is recommended to control emission near the source.

19020701AN 02/07/19 ChemTreat CT30Page 5 of 11

Personal Protection

Eyes: Wear chemical splash goggles or safety glasses with full−face shield. Maintain eyewash fountain in work area.

Skin: Maintain quick−drench facilities in work area.

Wear butyl rubber or neoprene gloves. Wash them after each use and replace as necessary. If conditions warrant, wear protective clothing such as boots, aprons, and coveralls to prevent skin contact.

Respiratory: If misting occurs, use NIOSH approved organic vapor/acid gas dual cartridge respirator with a dust/mist prefilter in accordance with 29 CFR 1910.134.

�A�

Physical State and Appearance: Liquid, Smoke, Opaque Specific Gravity: 1.127 @ 20°C pH: 13.8 @ 20°C, 100.0% Freezing Point: 28°F Flash Point: N/D Odor: Mild Melting Point: N/A Initial Boiling Point and Boiling Range: ~212°F Solubility in Water: Complete Evaporation Rate: <1 Vapor Density: N/D Molecular Weight: N/D Viscosity: N/A Flammability (solid, gas): N/D Flammable Limits: N/A Autoignition Temperature: N/A Density: 9.40 LB/GA Vapor Pressure: <17.5

% VOC: 1.7

Odor Threshold N/D n−octanol Partition Coefficient N/D Decomposition Temperature N/D

19020701AN 02/07/19 ChemTreat CT30Page 6 of 11

���B� ��$����C������!�6�>�� ���8$���������!D&�!�6�

Chemical Stability: Stable at normal temperatures and pressures.

Incompatibility with Various Strong oxidizers, Acids.

Substances:

Hazardous Decomposition Oxides of carbon, Oxides of phosphorus.

Products:

Possibility of Hazardous None known.

Reactions:

Reactivity: N/D

Conditions To Avoid: N/D

�E��=���������/�����������
� !������������

Tetrapotassium pyrophosphate Oral LD50 2980 MG/KG Rat

Dermal LD50 >7940 MG/KG Rabbit Potassium hydroxide Oral LD50 365 MG/KG Rat

Carcinogenicity Category

Component Source Code Brief Description Tetrapotassium pyrophosphate N/E N/E N/E Potassium hydroxide N/E N/E N/E Alcohol (C8 − 10) ethoxylated propoxylated N/E N/E N/E

Likely Routes of Exposure: N/D

Symptoms

Inhalation: N/D

Eye Contact: N/D

Skin Contact: N/D

Ingestion: N/D

19020701AN 02/07/19 ChemTreat CT30Page 7 of 11

Skin Corrosion/Irritation: N/D

Serious Eye Damage/Eye N/D Irritation:

Sensitization: N/D

Germ Cell Mutagenicity: N/D

Reproductive/Developmental N/D Toxicity:

Specific Target Organ Toxicity

Single Exposure: N/D

Repeated Exposure: N/D

Aspiration Hazard: N/D

Comments: None.

�<�������/�����������
� !������������

Fathead Minnow 96h LC50 >1000 mg/l Ceriodaphnia dubia 48h LC50 >1000 mg/l

Persistence and N/D Biodegradability:

Bioaccumulative Potential: N/D

Mobility In Soil: N/D

19020701AN 02/07/19 ChemTreat CT30Page 8 of 11

�F$��(&���(��������
�(����������������

Dispose of in accordance with local, state and federal regulations.

EPA corrosivity characteristic hazardous waste D002 when disposed of in the original product form.

���0� �E�����

�(&���������
� !������������

UN1814

POTASSIUM HYDROXIDE

SOLUTION

N/A

���5�

�8$�&/�����������!���,
� G������*�+�,�

Canada (DSL/NDSL): All ingredients listed.

19020701AN 02/07/19 ChemTreat CT30Page 9 of 11

SARA Title III Rules

Sections 311/312 Hazard Classes

Fire Hazard: No Reactive Hazard: No Release of Pressure: No Acute Health Hazard: Yes

Toxic Chemical

Tetrapotassium pyrophosphate N/A N/A N/A Potassium hydroxide N/A N/A 1000 Alcohol (C8 − 10) ethoxylated propoxylated N/A N/A N/A

Comments: None.

State Regulations

California Proposition 65: None known.

Special Regulations

Component States Tetrapotassium pyrophosphate None.

Potassium hydroxide MA, MN, NY, PA, WA Alcohol (C8 − 10) ethoxylated propoxylated None.

Compliance Information

NSF: N/A

Food Regulations: N/A

KOSHER: This product is certified by the Orthodox Union as Kosher for Passover and year−round use.

Only when prepared by the following ChemTreat facilities:

Ashland, VA; Eldridge, IA; Nederland, TX.

Halal: This product has not been evaluated for Halal approval.

FIFRA: N/A

19020701AN 02/07/19 ChemTreat CT30Page 10 of 11

���7�

Flammability: 0 Physical Hazard: 1

PPE: X

Notes: The PPE rating depends on circumstances of use. See Section 8 for recommended PPE.

The Hazardous Material Information System (HMIS) is a voluntary, subjective alpha−numeric symbolic system for recommending hazard risk and personal protection equipment information. It is a subjective rating system based on the evaluator’s understanding of the chemical associated risks.

The end−user must determine if the code is appropriate for their use.

Abbreviations

Abbreviation Definition < Less Than > Greater Than ACGIH American Conference of Governmental Industrial Hygienists EHS Environmental Health and Safety Dept N/A Not Applicable N/D Not Determined N/E Not Established OSHA Occupational Health and Safety Dept PEL Personal Exposure Limit STEL Short Term Exposure Limit TLV Threshold Limit Value TWA Time Weight Average UNK Unknown

Revision Date: February 7, 2019

19020701AN 02/07/19 ChemTreat CT30Page 11 of 11

Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof, ChemTreat, Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will ChemTreat, Inc. be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. No representation or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature are made hereunder with respect to information or the product to which information refers.

SAFETY DATA SHEET

1. Identification

CL8845Product identifier

Other means of identification CL8845Product code

Cooling Water TreatmentRecommended use

None known.Recommended restrictions

Manufacturer/Importer/Supplier/Distributor information

Manufacturer

ChemTreat Address 5640 Cox Road Company name

Telephone 800-648-4579

Emergency phone number 800-424-9300

E-mail

United States

Not available.

Glen Allen, VA 23060

2. Hazard(s) identification

Not classified.Physical hazards

Category 1Skin corrosion/irritationHealth hazards

Category 1Serious eye damage/eye irritation

Category 1Sensitization, skin

Not classified.Environmental hazards

Not classified.OSHA defined hazards

Label elements

Signal word Danger

Hazard statement Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes serious eye damage.

Precautionary statement

Prevention Do not breathe mist/vapors. Avoid breathing mist/vapors. Wash thoroughly after handling.

Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection.

Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Storage Store locked up.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise classified (HNOC)

None known.

Supplemental information 39.48% of the mixture consists of component(s) of unknown acute oral toxicity. 33.73% of the mixture consists of component(s) of unknown acute dermal toxicity. 44.48% of the mixture consists of component(s) of unknown acute inhalation toxicity. 17.73% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 17.73% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.

1 / 8 Material name: CL8845

CL8845 Version #: 01 Issue date: 02-16-2021

SDS US

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name Common name and synonyms

202420-04-0CHLOROTOLYLTRIAZOLE

SODIUM SALT

10 - < 20

1310-73-2Sodium hydroxide (Caustic soda) 10 - < 20

26099-09-22-Butenedioic acid (Z)-, homopolymer

5 - < 10

60 - < 70Other components below reportable levels

10025-69-1Tin (ii) Chloride Dihydrate 1 - < 3

4. First-aid measures

Move to fresh air. Call a physician if symptoms develop or persist.Inhalation

Remove contaminated clothing immediately and wash skin with soap and water. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately.

Eye contact

Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Ingestion

Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result.

Most important symptoms/effects, acute and delayed

Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation.

Symptoms may be delayed.

Indication of immediate medical attention and special treatment needed

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.

General information

5. Fire-fighting measures

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media

During fire, gases hazardous to health may be formed.Specific hazards arising from the chemical

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters

Move containers from fire area if you can do so without risk.Fire fighting equipment/instructions

Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods

No unusual fire or explosion hazards noted.General fire hazards

6. Accidental release measures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist/vapors. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Personal precautions, protective equipment and emergency procedures

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Methods and materials for containment and cleaning up

Avoid discharge into drains, water courses or onto the…

This is the start of the file's text. The full file is on GovTribe.

File details come from the government source that posted it. Updated .