Attachment 2 - Safety Data Sheets.pdf

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Identification of the substance Carechlor Registration number (REACH) 01-2119488154-34-xxxx

CAS number 7681-52-9

1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses NSF 60

Food Grade IMO approved Compliant with EN 901:2013 industrial use

Uses advised against Do not use for squirting or spraying. Do not use for products which come into direct contact with the skin. Do not use for products which come in-to contact with foodstuffs. Do not use for private purposes (household).

1.3 Details of the supplier of the safety data sheet

Marine Care B.V.

Oude Maasweg 35, Port number 4005 3197 KJ Rotterdam-Botlek Netherlands

Telephone: +(31) 10 29 50 342 e-mail: operations@marinecare.nl Website: www.marinecare.nl e-mail (competent person) lab@marinecare.nl (Laboratory)

1.4 Emergency telephone number

Emergency information service +(31) 10 29 50 342

Poison centre

Country Name Postal code/ city

Telephone Telefax Opening hours

Netherlands Nationaal Vergiftigingen Inform-atie Centrum

+31 88 755 8000 Mon - Fri 00:00 - 23:59

Norway Norwegian Poison Information Centre

+47 22 559 13 00 Mon - Fri 00:00 - 23:59

United Kingdom National Poison Information Ser-vice (NPIS)

+44 121 507 4123 Mon - Fri 00:00 - 23:59

United States Infotrac +1 800-535-5053 Mon - Fri 00:00 - 23:59

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Revision: 18.12.2023

Netherlands: en Page: 1 / 14

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

Section Hazard class Category Hazard class and cat-egory

Hazard state-ment

2.16 substance or mixture corrosive to metals 1 Met. Corr. 1 H290

3.2 skin corrosion/irritation 1B Skin Corr. 1B H314

3.3 serious eye damage/eye irritation 1 Eye Dam. 1 H318

4.1A hazardous to the aquatic environment - acute hazard 1 Aquatic Acute 1 H400

4.1C hazardous to the aquatic environment - chronic hazard 3 Aquatic Chronic 3 H412

For full text of abbreviations: see SECTION 16.

The most important adverse physicochemical, human health and environmental effects Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epidermis and into the dermis. Spillage and fire water can cause pollution of watercourses.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)

- Signal word danger

- Pictograms

GHS05, GHS09

- Hazard statements H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

H410 Very toxic to aquatic life with long lasting effects.

- Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P390 Absorb spillage to prevent material damage.

P391 Collect spillage.

P501 Dispose of contents/container to industrial combustion plant.

- Supplemental hazard information EUH031 Contact with acids liberates toxic gas.

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 2 / 14

2.3 Other hazards

Results of PBT and vPvB assessment

According to the results of its assessment, this substance is not a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances

Name of substance Carechlor

Identifiers

REACH Reg. No 01-2119488154-34-xxxx

CAS No 7681-52-9

EC No 231-668-3

Purity 10 – 15 %

Specific Conc. Limits M-Factors ATE Exposure route

- M-factor (acute) = 10 -

Molecular formula ClO.Na

Molar mass 75,45 g/mol

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes

Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth.

Following inhalation If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respirat-ory tract irritation, consult a physician. Provide fresh air.

Following skin contact Wash with plenty of soap and water.

Following eye contact Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart.

Following ingestion Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed Symptoms and effects are not known to date.

4.3 Indication of any immediate medical attention and special treatment needed none

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 3 / 14

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

Water spray, Alcohol resistant foam, BC-powder, Carbon dioxide (CO2)

Unsuitable extinguishing media Water jet

5.2 Special hazards arising from the substance or mixture

Substance or mixture corrosive to metals.

Hazardous combustion products Hydrogen chloride (HCl)

5.3 Advice for firefighters

In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately.

Fight fire with normal precautions from a reasonable distance.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel

Remove persons to safety.

For emergency responders Wear breathing apparatus if exposed to vapours/dust/spray/gases.

6.2 Environmental precautions

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. If sub-stance has entered a water course or sewer, inform the responsible authority.

6.3 Methods and material for containment and cleaning up

Advice on how to contain a spill

Covering of drains

Advice on how to clean up a spill Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binder

Appropriate containment techniques Use of adsorbent materials.

Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area.

6.4 Reference to other sections

Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materi-als: see section 10. Disposal considerations: see section 13.

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 4 / 14

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Recommendations

- Measures to prevent fire as well as aerosol and dust generation Use local and general ventilation. Use only in well-ventilated areas.

- Handling of incompatible substances or mixtures Do not mix with acids.

Advice on general occupational hygiene Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.

7.2 Conditions for safe storage, including any incompatibilities Managing of associated risks

- Corrosive conditions Store in corrosive resistant container with a resistant inner liner.

- Specific designs for storage rooms or vessels Do not keep the container sealed.

- Packaging compatibilities Only packagings which are approved (e.g. acc. to ADR) may be used.

7.3 Specific end use(s)

See section 16 for a general overview.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limit values (Workplace Exposure Limits) this information is not available

Human health values

Relevant DNELs and other threshold levels

Endpoint Threshold level Protection goal, route of exposure

Used in Exposure time

DNEL 1,55 mg/m³ human, inhalatory worker (industry) chronic - local effects

DNEL 1,55 mg/m³ human, inhalatory worker (industry) chronic - systemic effects

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 5 / 14

Environmental values

Relevant PNECs and other threshold levels

Endpoint Threshold level Organism Environmental compartment Exposure time

PNEC 0,03 mg/l microorganisms sewage treatment plant (STP) short-term (single instance)

PNEC 11,1 mg/kg (top) predators water short-term (single instance)

8.2 Exposure controls

Appropriate engineering controls

General ventilation.

Individual protection measures (personal protective equipment)

Eye/face protection Wear eye/face protection.

Skin protection

- Hand protection Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

- Other protection measures Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.

Wash hands thoroughly after handling.

Respiratory protection In case of inadequate ventilation wear respiratory protection.

Environmental exposure controls Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state liquid

Colour yellow

Odour Chlorine

Melting point/freezing point not determined

Boiling point or initial boiling point and boiling range not determined

Flammability non-combustible

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 6 / 14

Lower and upper explosion limit not determined not relevant

Flash point not applicable

Auto-ignition temperature not determined

Decomposition temperature not relevant pH (value) >11,5 (base)

Kinematic viscosity not determined

Solubility(ies)

Water solubility miscible in any proportion

Partition coefficient

Partition coefficient n-octanol/water (log value) not relevant (inorganic)

Vapour pressure not determined

Density and/or relative density

Density 1,23 g/cm³

Relative vapour density information on this property is not available

Particle characteristics not relevant (liquid)

9.2 Other information

Information with regard to physical hazard classes there is no additional information

Other safety characteristics

Miscibility Completely miscible with water.

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 7 / 14

SECTION 10: Stability and reactivity

10.1 Reactivity

Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". It's a reactive substance.

Substance or mixture corrosive to metals.

10.2 Chemical stability

See below "Conditions to avoid".

10.3 Possibility of hazardous reactions

No known hazardous reactions.

10.4 Conditions to avoid

There are no specific conditions known which have to be avoided.

10.5 Incompatible materials

There is no additional information.

Release of toxic materials with:

Acids

10.6 Hazardous decomposition products

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 Classification according to GHS (1272/2008/EC, CLP) Acute toxicity

Shall not be classified as acutely toxic.

Skin corrosion/irritation Causes severe skin burns and eye damage.

Serious eye damage/eye irritation Causes serious eye damage.

Respiratory or skin sensitisation Shall not be classified as a respiratory or skin sensitiser.

Germ cell mutagenicity Shall not be classified as germ cell mutagenic.

Carcinogenicity Shall not be classified as carcinogenic.

Reproductive toxicity Shall not be classified as a reproductive toxicant.

Specific target organ toxicity - single exposure Shall not be classified as a specific target organ toxicant (single exposure).

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 8 / 14

Specific target organ toxicity - repeated exposure Shall not be classified as a specific target organ toxicant (repeated exposure).

Aspiration hazard Shall not be classified as presenting an aspiration hazard.

11.2 Information on other hazards

There is no additional information.

SECTION 12: Ecological information

12.1 Toxicity

Very toxic to aquatic life with long lasting effects.

Aquatic toxicity (acute)

Endpoint Value Species Exposure time

EC50 0,4 mg/l algae 96 h

Aquatic toxicity (chronic)

Endpoint Value Species Exposure time

EC50 >3 mg/l microorganisms 3 h

12.2 Persistence and degradability

Data are not available.

12.3 Bioaccumulative potential

Data are not available.

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

According to the results of its assessment, this substance is not a PBT or a vPvB.

12.6 Endocrine disrupting properties

Information on this property is not available.

12.7 Other adverse effects

Data are not available.

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 9 / 14

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Waste treatment-relevant information

Recycling/reclamation of other inorganic materials.

Sewage disposal-relevant information Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.

Waste treatment of containers/packagings It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used. Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself.

Remarks Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities.

SECTION 14: Transport information

14.1 UN number or ID number

ADR/RID/ADN UN 1791

IMDG-Code UN 1791

ICAO-TI UN 1791

14.2 UN proper shipping name

ADR/RID/ADN HYPOCHLORITE SOLUTION

IMDG-Code HYPOCHLORITE SOLUTION

ICAO-TI Hypochlorite solution

14.3 Transport hazard class(es)

ADR/RID/ADN 8

IMDG-Code 8

ICAO-TI 8

14.4 Packing group

ADR/RID/ADN II

IMDG-Code II

ICAO-TI II

14.5 Environmental hazards hazardous to the aquatic environment

14.6 Special precautions for user

Provisions for dangerous goods (ADR) should be complied within the premises.

14.7 Maritime transport in bulk according to IMO instruments

The cargo is not intended to be carried in bulk.

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 10 / 14

Information for each of the UN Model Regulations Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional information Classification code C9

Danger label(s) 8, fish and tree

Environmental hazards yes (hazardous to the aquatic environment)

Special provisions (SP) 521

Excepted quantities (EQ) E2

Limited quantities (LQ) 1 L

Transport category (TC) 2

Tunnel restriction code (TRC) E

Hazard identification No 80

International Maritime Dangerous Goods Code (IMDG) - Additional information Marine pollutant yes (hazardous to the aquatic environment)

Danger label(s) 8, fish and tree

Special provisions (SP) -

Excepted quantities (EQ) E2

Limited quantities (LQ) 1 L

EmS F-A, S-B

Stowage category B

Segregation group 8 - Hypochlorites

International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information Environmental hazards yes (hazardous to the aquatic environment)

Danger label(s) 8

Special provisions (SP) A3

Excepted quantities (EQ) E2

Limited quantities (LQ) 0,5 L

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 11 / 14

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Relevant provisions of the European Union (EU) List of substances subject to authorisation (REACH, Annex XIV) / SVHC - candidate list not relevant

National regulations (Netherlands) Algemene Beoordelingsmethodiek, ABM 2016 (general assessment methodology, GAM)

Water hazard and decontamination effort

Water hazard Water hazard designation Decontamination effort

A (1) highly toxic for aquatic organisms, may have longterm hazardous effects in aquatic en-vironment

A

SZW-lijst CMR effects not listed

15.2 Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance.

SECTION 16: Other information

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-land Waterways)

ADR Accord relatif au transport international des marchandises dangereuses par route (Agreement concern-ing the International Carriage of Dangerous Goods by Road)

ADR/RID/ADN Agreements concerning the International Carriage of Dangerous Goods by Road/Rail/Inland Waterways

(ADR/RID/ADN)

ATE Acute Toxicity Estimate

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

CMR Carcinogenic, Mutagenic or toxic for Reproduction

DGR Dangerous Goods Regulations (see IATA/DGR)

DNEL Derived No-Effect Level

EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50 % changes in response (e.g. on growth) during a specified time interval

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-fier of substances commercially available within the EU (European Union)

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 12 / 14

Abbr. Descriptions of used abbreviations

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-tions

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

ICAO-TI Technical instructions for the safe transport of dangerous goods by air

IMDG International Maritime Dangerous Goods Code

IMDG-Code International Maritime Dangerous Goods Code

M-factor Means a multiplying factor. It is applied to the concentration of a substance classified as hazardous to the aquatic environment acute category 1 or chronic category 1, and is used to derive by the summation method the classification of a mixture in which the substance is present

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

PNEC Predicted No-Effect Concentration

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-tions concerning the International carriage of Dangerous goods by Rail)

SVHC Substance of Very High Concern vPvB Very Persistent and very Bioaccumulative

Key literature references and sources for data Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures. Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU.

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Maritime Dangerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).

List of relevant phrases (code and full text as stated in section 2 and 3)

Code Text

H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H400 Very toxic to aquatic life.

H412 Harmful to aquatic life with long lasting effects.

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 13 / 14

Disclaimer This information is based upon the present state of our knowledge. This SDS has been compiled and is solely inten-ded for this product.

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Carechlor Version number: GHS 25.0 Replaces version of: 18.12.2023 (GHS 24)

Netherlands: en Page: 14 / 14

(REACH), amended by 2015/830/EU

CAREPH(-)

Hydrochloric Acid – 33-40%

1.3 Details of the supplier of the safety data sheet

Statement

2.16 Substance or mixture corrosive to

metals Cat. 1 (Met. Corr. 1) H290

Remarks For full text of H-phrases: see SECTION 16.

Code Safety phrases (S-phrases)

S9 Keep container in a well-ventilated place

S26 in case of contact with eyes, rinse immediately with plenty of water and seek medical advice

S36/37/39 Wear suitable protective clothing, gloves andeye/face protection

S45 in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)

dermis

(REACH), amended by 2015/830/EU

CAREPH(-)

Hydrochloric Acid – 33-40%

Pictograms

GHS05, GHS07

water/shower.

P304+P340 IF INHALED: Remove person to fresh air and keep at rest in a position comfortable

(REACH), amended by 2015/830/EU

CAREPH(-)

Hydrochloric Acid – 33-40%

none

(REACH), amended by 2015/830/EU

CAREPH(-)

Hydrochloric Acid – 33-40%

Recommendations

agent CAS No Identifier TWA

[ppm]

TWA

[mg/m^3

STEL

[ppm]

STEL

[mg/m^3]

SOURCE

EU Hydrogen chloride

7647-01-0 IOELV 5 8 10 15 2000/39/EC

NL Hydrochloric acid

7647-01-0 GW 8 15 SC

Notation

DNEL 8 mg/m^3 Human, inhalatory Worker (industry) Chronic – local effects

(REACH), amended by 2015/830/EU

CAREPH(-)

Hydrochloric Acid – 33-40%

Appearance

(REACH), amended by 2015/830/EU

CAREPH(-)

Hydrochloric Acid – 33-40%

Bases.

(REACH), amended by 2015/830/EU

CAREPH(-)

Hydrochloric Acid – 33-40%

Remarks

(REACH), amended by 2015/830/EU

CAREPH(-)

Hydrochloric Acid – 33-40%

Abbr. Descriptions of used abbreviations

Waterways)

(REACH), amended by 2015/830/EU

CAREPH(-)

Hydrochloric Acid – 33-40%

MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant)

PBT Persistent, Bioaccumulative and Toxic

PNEC Predicted No-Effect Concentration

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

SC Staatscourant: Regeling van de Staatssecretaris van Sociale Zaken en Werkegelegenheid

STEL Short-term exposure limit

TWA Time-weighted average vPvB very Persistent and very Bioaccumulative

Key literature references and sources for data

List of relevant phrases (code and full text as stated in chapter 2 and 3)

Code Text

H290 may be corrosive to metals

H314 causes severe skin burns and eye damage

H335 May cause respiratory irritation

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

CMR Carcinogenic, Mutagenic or toxic for Reproduction

DGR Dangerous Goods regulations (see IATA/DGR)

DMEL Derived Minimal Effect Level

DNEL Derived No-Effect Level

EmS Emergency Schedule

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

IMDG International Maritime Dangerous Goods Code

IOLV Indicative occupational exposure limit value

Trade name Caretreat Antiscalant WT® RO SI Registration number (REACH) not relevant (mixture)

1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses NSF 60

Compliant with EN 15041:2014

Uses advised against Do not use for squirting or spraying. Do not use for products which come into direct contact with the skin. Do not use for products which come in-to contact with foodstuffs. Do not use for private purposes (household).

1.3 Details of the supplier of the safety data sheet

Marine Care B.V.

Oude Maasweg 35, Port number 4005 3197 KJ Rotterdam-Botlek Netherlands

Telephone: +(31) 10 29 50 342 e-mail: operations@marinecare.nl Website: www.marinecare.nl e-mail (competent person) lab@marinecare.nl (Laboratory)

1.4 Emergency telephone number

Emergency information service +(31) 10 29 50 342

Poison centre

Country Name Postal code/ city

Telephone Telefax Opening hours

Netherlands Nationaal Vergiftigingen Inform-atie Centrum

+31 88 755 8000 Mon - Fri 00:00 - 23:59

Norway Norwegian Poison Information Centre

+47 22 559 13 00 Mon - Fri 00:00 - 23:59

United Kingdom National Poison Information Ser-vice (NPIS)

+44 121 507 4123 Mon - Fri 00:00 - 23:59

United States Infotrac +1 800-535-5053 Mon - Fri 00:00 - 23:59

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Caretreat Antiscalant WT® RO SI Version number: GHS 5.1 Replaces version of: 21.03.2019 (GHS 4)

Revision: 12.01.2023

Netherlands: en Page: 1 / 13

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

Section Hazard class Category Hazard class and cat-egory

Hazard state-ment

2.16 substance or mixture corrosive to metals 1 Met. Corr. 1 H290

3.2 skin corrosion/irritation 1A Skin Corr. 1A H314

3.3 serious eye damage/eye irritation 2 Eye Irrit. 2 H319

For full text of abbreviations: see SECTION 16.

The most important adverse physicochemical, human health and environmental effects Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epidermis and into the dermis.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)

- Signal word danger

- Pictograms

GHS05

- Hazard statements H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

- Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P390 Absorb spillage to prevent material damage.

P501 Dispose of contents/container to industrial combustion plant.

- Hazardous ingredients for labelling Phosphonic Acid Compound

2.3 Other hazards

of no significance

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Caretreat Antiscalant WT® RO SI Version number: GHS 5.1 Replaces version of: 21.03.2019 (GHS 4)

Netherlands: en Page: 2 / 13

SECTION 3: Composition/information on ingredients

3.1 Substances

Not relevant (mixture)

3.2 Mixtures

Description of the mixture

Name of substance Identifier Wt% Classification acc. to GHS Pictograms

Phosphonic Acid Compound CAS No 13598-36-2

EC No 237-066-7

Index No 015-157-00-0

REACH Reg. No 01-2119488030-46-xxxx

10 – < 25 Acute Tox. 4 / H302 Skin Corr. 1A / H314

Name of substance Specific Conc. Limits M-Factors ATE Exposure route

Phosphonic Acid Compound - - 1.580 mg/kg oral

For full text of abbreviations: see SECTION 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes

Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth.

Following inhalation If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respirat-ory tract irritation, consult a physician. Provide fresh air.

Following skin contact Wash with plenty of soap and water.

Following eye contact Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart.

Following ingestion Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed Symptoms and effects are not known to date.

4.3 Indication of any immediate medical attention and special treatment needed none

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Caretreat Antiscalant WT® RO SI Version number: GHS 5.1 Replaces version of: 21.03.2019 (GHS 4)

Netherlands: en Page: 3 / 13

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

Water spray, BC-powder, Carbon dioxide (CO2)

Unsuitable extinguishing media Water jet

5.2 Special hazards arising from the substance or mixture

Substance or mixture corrosive to metals.

Hazardous combustion products Phosphorus oxides (PxOy)

5.3 Advice for firefighters

In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately.

Fight fire with normal precautions from a reasonable distance.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel

Remove persons to safety.

For emergency responders Wear…