Amen. 3- Water Treatment Info-Biocide 9.pdf

03/24/2015Revision:

05/27/2015Printed:Biocide 9

SAFETY DATA SHEET

09/04/2014Supersedes Revision:

Product Code:

Product Name:

Category:

Company Name:

WBO9A

Biocide 9

Biocide

ZEE COMPANY, INC.

4146 South Creek Road Chattanooga, TN 37406

CHEMTRECEmergency Contact: (800)424-9300

Company EPA#: 12446Information:

(423)265-7090

Phone Number:

A biocide used to control bacteria, algae, slime, and fungi.Intended Use:

1. PRODUCT AND COMPANY IDENTIFICATION

2. HAZARDS IDENTIFICATION

P264 - Wash hands thoroughly after handling.

P270 - Do not eat, drink or smoke when using this product.

P260 - Do not breathe dust/fume/gas/mist/vapors/spray.

P280 - Wear protective gloves/protective clothing/eye protection/face protection.

P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.

P272 - Contaminated work clothing should not be allowed out of the workplace.

P362+364 - Take off contaminated clothing and wash it before reuse.

P273 - Avoid release to the environment.

GHS Precaution Phrases:

P303+361+353 - IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.

P310 - Immediately call a POISON CENTER or doctor/physician.

P363 - Wash contaminated clothing before reuse.

P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 - Immediately call a POISON CENTER or doctor/physician.

P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P310 - Immediately call a POISON CENTER or doctor/physician.

P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P311 - Call a POISON CENTER or doctor/physician.

P391 - Collect spillage.

GHS Response Phrases:

P501 - Dispose of contents/container to accordance with national and internationalGHS Storage and Disposal

H302 - Harmful if swallowed.

H314 - Causes severe skin burns and eye damage.

H317 - May cause an allergic skin reaction.

H410 - Very toxic to aquatic life with long lasting effects.

GHS Hazard Phrases:

Acute Toxicity: Oral, Category 4

Skin Corrosion/Irritation, Category 1B

Skin Sensitization, Category 1

Aquatic Toxicity (Chronic), Category 1

DangerGHS Signal Word:

Page: 1Licensed to WST Bessemer: MIRS MSDS, (c) A V Systems, Multi-region format

SAFETY DATA SHEET

09/04/2014Supersedes Revision:

regulations.

P405 - Store locked up.

Phrases:

Hazard Rating System: HEALTH

FLAMMABILITY

PPE

PHYSICAL

F

HMIS:

Potential Health Effects

(Acute and Chronic):

May cause temporary or permanent eye damage.Eye Contact:

May cause sensitization. May cause skin irritation.Skin Contact:

Irritating to respiratory system.Inhalation:

CAS # Ingredient(s)

3. COMPOSITION/INFORMATION ON INGREDIENTS

Concentration

32718-18-6 Bromochloro-5,5-dimethylimidazolidine-2,4-dione 96.0 -99.5 %

In Case of Inhalation:

4. FIRST AID MEASURES

Emergency and First Aid

Procedures:

No specific antidote. Treat symptomatically and supportively. Probable mucosal damage may contraindicate the use of gastric lavage.

Note to Physician:

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Remove contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER or doctor/physician.

In Case of Eye Contact:

Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Immediately call a POISON CENTER or doctor/physician.

In Case of Skin Contact:

If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person.

In Case of Ingestion:

Move victim to fresh air. If not breathing, give artificial respiration. Call 911 or emergency medical service.

5. FIRE FIGHTING MEASURES

Flash Pt: No data.

Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products.

Fire Fighting Instructions:

Dusts or fumes may form explosive mixtures in air. Forms explosive mixtures with combustible, organic or other easily oxidizable materials.

Flammable Properties and

Hazards:

Autoignition Pt: No data.

Explosive Limits: LEL: No data. UEL: No data.

Dry chemical or CO2. In case of exothermic decomposition and appearance of smoke, water should be used to suppress it.

Suitable Extinguishing Media:

Page: 2Licensed to WST Bessemer: MIRS MSDS, (c) A V Systems, Multi-region format

SAFETY DATA SHEET

09/04/2014Supersedes Revision:

6. ACCIDENTAL RELEASE MEASURES

Evacuate area. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Ventilate the area. Wash area with soap and water.

Steps To Be Taken In Case

Material Is Released Or

Spilled:

Wear appropriate protective clothing to minimize contact with skin. Use respirators and components tested and approved under appropriate government standards such as

NIOSH (US) or CEN (EU).

Protective Precautions, Protective Equipment and

Emergency Procedures:

Avoid release to the environment.Environmental Precautions:

7. HANDLING AND STORAGE

Avoid prolonged or repeated contact with eyes, skin, or clothing. Wash thoroughly after handling. Avoid breathing in dust from product. Use with adequate ventilation. Keep containers closed when not in use.

Precautions To Be Taken in

Handling:

Keep away from sources of ignition. Store at temperatures not exceeding 50°C/120°F.

Keep container tightly closed. Store in a cool dry place. Store away from incompatible material.

Precautions To Be Taken in

Storing:

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

OSHA TWA ACGIH TWACAS # Components (Chemical Name) Other Limits

No data. No data. 32718-18-6 Bromochloro-5,5-dimethylimidazolidine

-2,4-dione

No data.

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.

Respiratory Equipment

(Specify Type):

Chemical safety goggles.Eye Protection:

Impervious gloves.Protective Gloves:

Lab coat and/or apron.Other Protective Clothing:

Local exhaust ventilation may be necessary to control any air contaminants to within their

TLVs during the use of this product. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.

Engineering Controls

(Ventilation etc.):

Wash hands before breaks and immediately after handling the product.Work/Hygienic/Maintenance

Practices:

Page: 3Licensed to WST Bessemer: MIRS MSDS, (c) A V Systems, Multi-region format

SAFETY DATA SHEET

09/04/2014Supersedes Revision:

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical States: [ ] Gas [ ] Liquid [ X ] Solid

Melting Point: No data.

Boiling Point: No data.

Decomposition Temperature: > 160.00 C (320.0 F)

Autoignition Pt: No data.

Flash Pt: No data.

Explosive Limits: LEL: No data. UEL: No data.

Specific Gravity (Water = 1): 1.8 - 2.0

White to Off-White, Tablet.

faint halogenous odor.

Appearance and Odor:

Vapor Pressure (vs. Air or mm Hg):

9.35x10(-3) PA at 25.0 C (77.0 F)

Vapor Density (vs. Air = 1): No data.

Evaporation Rate: No data.

Solubility in Water:

Solubility Notes:

Percent Volatile:

0.22g/100mL at 25.0 C (77.0 F) Benzene: 2.5g/100g at 25C

No data. VOC Content: 0 %

10. STABILITY AND REACTIVITY

heating to decomposition. Moisture.Conditions To Avoid - Instability:

Unstable [ ] Stable [ X ]Stability:

Oxidizing agents, Bases.Incompatibility - Materials To Avoid:

Nitrogen oxides, hydrogen chloride. hydrogen bromide. chlorine. Carbon oxides.

Hazardous Decomposition or

Byproducts:

Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions:

Product will not undergo polymerization.Conditions To Avoid - Hazardous

Reactions:

Oxidizing agents, Bases, combustible materials.Reactivity:

Page: 4Licensed to WST Bessemer: MIRS MSDS, (c) A V Systems, Multi-region format

SAFETY DATA SHEET

09/04/2014Supersedes Revision:

CAS # Ingredient(s) NTP

11. TOXICOLOGICAL INFORMATION

No data available.Toxicological Information:

IARC ACGIH OSHA

CAS# 32718-18-6:

Acute toxicity, LD50, Oral, Rat, 929.0 MG/KG.

Result:

Behavioral: Somnolence (general depressed activity).

Gastrointestinal:Other changes.

Acute toxicity, LC50, Inhalation, Rat, 1.100 MG/L, 4 H.

Result:

Skin and Appendages: Other: Hair.

32718-18-6 Bromochloro-5,5-dimethylimidazolidine-2,4-dione n.a. n.a. n.a. n.a.

No data available.

12. ECOLOGICAL INFORMATION

CAS# 32718-18-6:

LC50, Rainbow Trout (Oncorhynchus mykiss), 0.400 MG/L, 96 H.

Result:

Age Effects.

LC50, Water Flea (Daphnia magna), 0.750 MG/L, 48 H.

Result:

Age Effects.

Results of PBT and vPvB assessment:

RCRA: It is the responsibility of the product user to determine at the time of disposal whether a material containing the product or derived from the product should be classified as a hazardous waste (40 CFR 261.20-24).

Disposal: Biocide or Pesticide wastes are acutely hazardous. Improper disposal or excess product or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Biocide/Pesticide or

Environmental Control Agency, or the Hazardous Waste representative at your nearest

EPA Regulation Office for guidance

Waste Disposal Method:

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

Oxidizing solid, n.o.s.(Bromo-Chloro-5,5-DimethylHydantoin)DOT Proper Shipping Name:

5.1 OXIDIZERDOT Hazard Class:

UN1479UN/NA Number: IIIPacking Group:

LAND TRANSPORT (US DOT):

Page: 5Licensed to WST Bessemer: MIRS MSDS, (c) A V Systems, Multi-region format

SAFETY DATA SHEET

09/04/2014Supersedes Revision:

Oxidizing solid, n.o.s.(Bromo-Chloro-5,5-DimethylHydantoin)TDG Shipping Name:

LAND TRANSPORT (Canadian TDG):

1479UN Number: IIIPacking Group:

5.1 - OXIDIZERHazard Class: TDG Classification:

Oxidizing solid, n.o.s.(Bromo-Chloro-5,5-DimethylHydantoin)IMDG/IMO Shipping Name:

MARINE TRANSPORT (IMDG/IMO):

1479UN Number: IIIPacking Group:

5.1 - OXIDIZERHazard Class:

IMDG MFAG Number:

IMDG EMS Page: YesMarine Pollutant:

Oxidizing solid, n.o.s.(Bromo-Chloro-5,5-DimethylHydantoin)ICAO/IATA Shipping Name:

AIR TRANSPORT (ICAO/IATA):

1479UN Number: IIIPacking Group:

5.1 - OXIDIZERHazard Class:

CAS # Ingredient(s)

15. REGULATORY INFORMATION

S. 302 (EHS) S. 304 RQ S. 313 (TRI)

EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists

32718-18-6 Bromochloro-5,5-dimethylimidazolidine-2,4-dione No No No

[X] Yes [ ] No Acute (immediate) Health Hazard

[X] Yes [ ] No Chronic (delayed) Health Hazard

[ ] Yes [X] No Fire Hazard

[ ] Yes [X] No Sudden Release of Pressure Hazard

[ ] Yes [X] No Reactive Hazard

This material meets the EPA

'Hazard Categories' defined for SARA Title III Sections

311/312 as indicated:

CAS # Ingredient(s) Canadian NPRI Canadian IDL Canadian DSL

32718-18-6 Bromochloro-5,5-dimethylimidazolidine-2,4-dione No No No

CAS # Ingredient(s) Other US EPA or State Lists

32718-18-6 Bromochloro-5,5-dimethylimidazolidine-2,4-dione CAA HAP,ODC: No; CWA NPDES: No; TSCA: No; CA

PROP.65: No

CAS # Ingredient(s) International Regulatory Lists

32718-18-6 Bromochloro-5,5-dimethylimidazolidine-2,4-dione

Canadian WHMIS Classification:

No data available.

US Regulatory information:

Primary EPA Registration # : 88714-4

This product is subject to registration under FIFRA.

All ingredients are reported in the EPA TSCA Inventory.

Canada Regulatory information:

This product complies to the Pest Control Products Act.and is considered exempt from from WHMIS classification.

Registration No.: 31033 Pest Control Products Act.

Canadian regulations: This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the SDS contains all the information required by the CPR.

Regulatory Information:

Page: 6Licensed to WST Bessemer: MIRS MSDS, (c) A V Systems, Multi-region format

SAFETY DATA SHEET

09/04/2014Supersedes Revision:

16. OTHER INFORMATION

No data available.Additional Information About

This Product:

The information accumulated herein is believed to be accurate based on the information provided, although no guarantee or warranty, either expressed or implied is made as to the accuracy or completeness of this information, whether originating with this company or not. Recipients are advised to confirm in advance of need that the information is correct, applicable and suitable to their circumstances. The conditions or methods of handling, storage, use and disposal of the product and container are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage or use of this information or product. If the product is used as a component in another product, this information may not be applicable.

Company Policy or

Disclaimer:

03/24/2015Revision Date:

Page: 7Licensed to WST Bessemer: MIRS MSDS, (c) A V Systems, Multi-region format