7. MSDS.pdf

N0241- NATURAL METHYL ANTHRANILATE

MATERIAL SAFETY DATA SHEET

1. PRODUCT AND COMPANY IDENTIFICATION:

PRODUCT CODE N0241

PRODUCT NAME NATURAL METHYL ANTHRANILATE

SUPPLIER Shanghai M & U International Trade Co., Ltd.

Rm 1717, No 598 North NuJiang Road

200333 Shanghai, China

+86-21-32515501 32515502 sales@mu-intel.com

FOR EMERGENCIES CALL CHEMTREC: 800-424-9300 (24-HOURS)

2. HAZARD IDENTIFICATION:

Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Skin irritation (Category 2), H315

Eye irritation (Category 2A), H319

Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335

Acute aquatic toxicity (Category 2), H401

Chronic aquatic toxicity (Category 2), H411

For the full text of the H-Statements mentioned in this Section, see Section 16

GHS Label elements, including precautionary statements

Pictogram

Signal word Warning

Hazard statement(s)

H315 Causes skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

H411 Toxic to aquatic life with long lasting effects

Precautionary statement(s)

P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray

P264 Wash skin thoroughly after handling

P271 Use only outdoors or in a well-ventilated area

P273 Avoid release to the environment

P280 Wear protective gloves/ eye protection/ face protection

P302 + P352 IF ON SKIN: Wash with plenty of soap and water

P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P312 Call a POISON CENTER or doctor/ physician if you feel unwell

P321 Specific treatment (see supplemental first aid instructions on this label)

P332 + P313 If skin irritation occurs: Get medical advice/ attention

P337 + P313 If eye irritation persists: Get medical advice/ attention

P362 Take off contaminated clothing and wash before reuse

P391 Collect spillage

P403 + P233 Store in a well-ventilated place; Keep container tightly closed

P405 Store locked up

P501 Dispose of contents/ container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) or not covered by GHS None

3. COMPOSITION AND INFORMATION ON INGREDIENTS:

Synonyms Methyl 2-aminobenzoate

Methyl anthranilate

Formula C8 H9 NO2

Molecular Weight 151.16 g/mol

CAS-No 134-20-3

EC-No 205-132-4

Hazardous Components Component Methyl anthranilate

Classification Skin Irrit. 2; Eye Irrit. 2A;

STOT SE 3; Aquatic Acute 2;

Aquatic Chronic 2; H315, H319, H335, H411

For the full text of the H-statements mentioned in this Section, see Section 16

4. FIRST-AID GUIDE:

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician

In case of skin contact

Wash off with soap and plenty of water. Consult a physician

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labeling (see section 2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

5. FIRE-FIGHTING GUIDE:

Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx)

Advice for firefighters Wear self contained breathing apparatus for firefighting if necessary.

Further information

6. ACCIDENTAL RELEASE GUIDE:

Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. For personal protection see section 8

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided

Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal

Reference to other sections

For disposal see section 13

7. HANDLING AND STORAGE:

Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Normal measures for preventive fire protection. For precautions see section 2

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Light sensitive

Specific end use(s) No other specific uses are stipulated

8. EXPOSURE AND PERSONAL PROTECTION:

Control parameters

Components with workplace control parameters

Contains no substances with occupational exposure limit values

Exposure controls

Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday

Personal protective equipment

Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU)

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hand

Body Protection Impervious clothing, the type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU)

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided

9. PHYSICAL AND CHEMICAL PROPERTIES:

Appearance Form: clear, liquid

Color light yellow

Odor no data available

Odor Threshold no data available pH no data available

Melting point/freezing point Melting point/range: 24 °C (75 °F) - lit

Initial boiling point and boiling range 256 °C (493 °F) - lit

Flash point 123 °C (253 °F) - closed cup

Evaporation rate no data available

Flammability (solid, gas) no data available

Upper/lower flammability or explosive limits no data available

Vapor pressure 1 hPa (1 mmHg) at 20 °C (68 °F)

Vapor density no data available

Relative density 1.168 g/cm3 at 25°C (77 °F)

Water solubility no data available

Partition coefficient: n-octanol/water no data available

Auto-ignition temperature no data available

Decomposition temperature no data available

Viscosity no data available

Explosive properties no data available

Oxidizing properties no data available

Other safety information

10. STABILITY AND REACTIVITY:

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions

Possibility of hazardous reactions

Conditions to avoid

Incompatible materials

Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents, Strong bases

Hazardous decomposition products

Other decomposition products - no data available

In the event of fire: see section 5

11. TOXICOLOGICAL INFORMATION:

Information on toxicological effects

Acute toxicity LD50 Oral - rat - 2,910 mg/kg

Remarks: Behavioral:Somnolence (general depressed activity). Behavioral:Coma.

LD50 Dermal - rabbit - > 5,000 mg/kg

Skin corrosion/irritation

Skin - rabbit

Result: Skin irritation - 24 h

Serious eye damage/eye irritation

Respiratory or skin sensitisation

Germ cell mutagenicity

Carcinogenicity

IARC

No components of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC

ACGIH

No components of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH

NTP

known or anticipated carcinogen by NTP.

OSHA

carcinogen or potential carcinogen by OSHA

Reproductive toxicity

Reproductive toxicity - mouse - Oral

Effects on Fertility: Female fertility index (e.g., # females pregnant per # sperm positive females;

# females pregnant per # females mated )

Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation

Specific target organ toxicity - repeated exposure

Aspiration hazard

Additional Information

RTECS: CB3325000

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated

Stomach - Irregularities - Based on Human Evidence

12. ECOLOGICAL INFORMATION:

Toxicity Toxicity to fish LC50 - Lepomis macrochirus - 9.12 mg/l - 96 h mortality NOEC - Oncorhynchus mykiss (rainbow trout) - 5 mg/l - 96 h

Toxicity to daphnia and other aquatic invertebrates

Persistence and degradability

Bioaccumulative potential

Mobility in soil

EC50 - Daphnia magna (Water flea) - 18.2 mg/l - 48 h

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

Toxic to aquatic life

13. DISPOSAL RECOMMENDATIONS:

Waste treatment methods

Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material

Contaminated packaging

Dispose of as unused product

14. TRANSPORTATION INFORMATION:

DOT (US)

Not dangerous goods

IMDG

IATA

15. REGULATORY INFORMATION:

REACH No

A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline

SARA 302 Components

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA

Title III, Section 302

SARA 313 Components

SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section

SARA 311/312 Hazards

Acute Health Hazard, Chronic Health Hazard

Massachusetts Right to Know Components

No components are subject to the Massachusetts Right to Know Act

Pennsylvania Right to Know Components

Methyl anthranilate CAS-No

134-20-3

New Jersey Right to Know Components

Methyl anthranilate CAS-No

134-20-3

California Prop 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm

16. OTHER INFORMATION:

Full text of H-Statements referred to under sections 2 and 3

Aquatic Acute Acute aquatic toxicity

Aquatic Chronic Chronic aquatic toxicity

Eye Irrit. Eye irritation

H315 Causes skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

H401 Toxic to aquatic life

H411 Toxic to aquatic life with long lasting effects

HMIS Rating

Health hazard 2

Chronic Health Hazard *

Flammability 1

Physical Hazard 0

NFPA Rating

Health hazard 2

Fire Hazard 1

Reactivity Hazard 0

The information in this MSDS was obtained from current and reliable sources. However, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy.

Since the conditions for use, handling, storage and disposal of this product are beyond M&U's control, it is the responsibility of the user both to determine safe conditions for use of this product and to assume liability for loss, damage, or expense arising out of the products improper use. No warranty expressed or implied regarding the product described herein will be created by or inferred from any statement or omission in the MSDS. Various federal, state, or provincial agencies may have specific regulations concerning the transportation, handling, storage, use, or disposal of this product which may not be reflected in the MSDS. The user should review these regulations to ensure full compliance

Aldrich - 411027 Page 1 of 7

SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet

Version 4.5 Revision Date 04/19/2013

Print Date 03/19/2014

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Piperidine

Product Number : 411027 Brand : Aldrich

Supplier : Sigma-Aldrich

3050 Spruce Street

SAINT LOUIS MO 63103

USA

Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For both supplier and manufacturer)

: (314) 776-6555

Preparation Information : Sigma-Aldrich Corporation Product Safety - Americas Region 1-800-521-8956

2. HAZARDS IDENTIFICATION

Emergency Overview

OSHA Hazards Flammable liquid, Toxic by inhalation., Toxic by ingestion, Toxic by skin absorption, Irritant, Corrosive

GHS Classification Flammable liquids (Category 2) Acute toxicity, Oral (Category 4) Acute toxicity, Inhalation (Category 3) Acute toxicity, Dermal (Category 3) Skin corrosion (Category 1B) Serious eye damage (Category 1) Acute aquatic toxicity (Category 3)

GHS Label elements, including precautionary statements

Pictogram

Signal word Danger

Hazard statement(s) H225 Highly flammable liquid and vapour.

H302 Harmful if swallowed.

H311 + H331 Toxic in contact with skin or if inhaled H314 Causes severe skin burns and eye damage.

H402 Harmful to aquatic life.

Precautionary statement(s) P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/ physician.

Aldrich - 411027 Page 2 of 7

HMIS Classification Health hazard: 3 Flammability: 3 Physical hazards: 0

NFPA Rating Health hazard: 3 Fire: 3 Reactivity Hazard: 0

Potential Health Effects

Inhalation Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Causes respiratory tract irritation.

Skin Toxic if absorbed through skin. Causes skin burns. Causes skin irritation.

Eyes Causes eye burns. Causes eye irritation.

Ingestion Toxic if swallowed.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms : Hexahydropyridine

Formula : C5H11N

Molecular Weight : 85.15 g/mol

Component Concentration

Piperidine

CAS-No.

EC-No.

Index-No.

110-89-4 203-813-0 613-027-00-3

90 - 100 %

4. FIRST AID MEASURES

General advice Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.

If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Continue rinsing eyes during transport to hospital.

If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5. FIREFIGHTING MEASURES

Conditions of flammability Flammable in the presence of a source of ignition when the temperature is above the flash point. Keep away from heat/sparks/open flame/hot surface. No smoking.

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special protective equipment for firefighters Wear self contained breathing apparatus for fire fighting if necessary.

Aldrich - 411027 Page 3 of 7

Hazardous combustion products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx)

Use water spray to cool unopened containers.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13).

7. HANDLING AND STORAGE

Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

Use explosion-proof equipment. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.

Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value Control parameters

Basis

Piperidine 110-89-4 TWA

1 ppm

USA. Workplace Environmental Exposure Levels

(WEEL)

Remarks Skin

Personal protective equipment

Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Splash contact Material: Fluorinated rubber Minimum layer thickness: 0.7 mm Break through time: 30 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374

Aldrich - 411027 Page 4 of 7

If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eye protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form clear, liquid

Colour colourless

Safety data pH no data available

Melting point/freezing point

Melting point/range: -13 °C (9 °F)

Boiling point 104 - 106 °C (219 - 223 °F) at 1,013 hPa (760 mmHg)

Flash point 16 °C (61 °F) - closed cup

Ignition temperature no data available

Auto-ignition temperature no data available

Lower explosion limit no data available

Upper explosion limit no data available

Vapour pressure 53 hPa (40 mmHg) at 29.2 °C (84.6 °F) 31 hPa (23 mmHg) at 20 °C (68 °F)

84.8 hPa (63.6 mmHg) at 37.8 °C (100.0 °F)

Density 0.862 g/cm3

Water solubility soluble

Partition coefficient:

n-octanol/water log Pow: 0.67

Relative vapour density

2.94

- (Air = 1.0)

Odour no data available

Odour Threshold no data available

Evapouration rate no data available

10. STABILITY AND REACTIVITY

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous reactions

Vapours may form explosive mixture with air.

Aldrich - 411027 Page 5 of 7

Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight.

Materials to avoid Strong oxidizing agents, Dicyanofurazan, N-nitrosoacetanilide, N-perchlorylpiperazine

Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx) Other decomposition products - no data available

11. TOXICOLOGICAL INFORMATION

Acute toxicity

Oral LD50 LD50 Oral - rat - 400 mg/kg

Inhalation LC50 LC50 Inhalation - mouse - 2 h - 6,000 mg/m3

Dermal LD50 LD50 Dermal - rabbit - 276 mg/kg

Other information on acute toxicity no data available

Skin corrosion/irritation Skin - rabbit - Severe skin irritation - 24 h

Serious eye damage/eye irritation Eyes - rabbit - Severe eye irritation - 24 h

Respiratory or skin sensitisation no data available

Germ cell mutagenicity

Genotoxicity in vitro - mouse - lymphocyte DNA damage

Genotoxicity in vitro - mouse - lymphocyte Mutation in mammalian somatic cells.

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

Reproductive toxicity Reproductive toxicity - rat - Inhalation Effects on Fertility: Litter size (e.g.; # fetuses per litter; measured before birth).

no data available

Teratogenicity

Developmental Toxicity - rat - Inhalation Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus).

no data available

Specific target organ toxicity - single exposure (Globally Harmonized System)

Aldrich - 411027 Page 6 of 7

Specific target organ toxicity - repeated exposure (Globally Harmonized System) no data available

Aspiration hazard no data available

Potential health effects

Inhalation Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Causes respiratory tract irritation.

Ingestion Toxic if swallowed.

Skin Toxic if absorbed through skin. Causes skin burns. Causes skin irritation.

Eyes Causes eye burns. Causes eye irritation.

Signs and Symptoms of Exposure Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea

Synergistic effects no data available

Additional Information

RTECS: TM3500000

12. ECOLOGICAL INFORMATION

Toxicity

Toxicity to fish LC50 - Leuciscus idus (Golden orfe) - 46 - 100 mg/l - 96 h

Persistence and degradability no data available

Bioaccumulative potential no data available

Mobility in soil no data available

PBT and vPvB assessment no data available

Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

Harmful to aquatic life.

13. DISPOSAL CONSIDERATIONS

Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging Dispose of as unused product.

14. TRANSPORT INFORMATION

DOT (US)

UN number: 2401 Class: 8 (3) Packing group: I Proper shipping name: Piperidine Reportable Quantity (RQ):

Marine pollutant: No Poison Inhalation Hazard: No

IMDG

Aldrich - 411027 Page 7 of 7

UN number: 2401 Class: 8 (3) Packing group: I EMS-No: F-E, S-C Proper shipping name: PIPERIDINE Marine pollutant: No

IATA

UN number: 2401 Class: 8 (3) Packing group: I Proper shipping name: Piperidine

15. REGULATORY INFORMATION

OSHA Hazards Flammable liquid, Toxic by inhalation., Toxic by ingestion, Toxic by skin absorption, Irritant, Corrosive

SARA 302 Components The following components are subject to reporting levels established by SARA Title III, Section 302:

CAS-No.

110-89-4

Revision Date 1993-04-24

SARA 313 Components SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards Fire Hazard, Acute Health Hazard

Massachusetts Right To Know Components

CAS-No.

110-89-4

Revision Date 1993-04-24

Pennsylvania Right To Know Components

Piperidine

CAS-No.

110-89-4

Revision Date 1993-04-24

New Jersey Right To Know Components

Piperidine

CAS-No.

110-89-4

Revision Date 1993-04-24

California Prop. 65 Components This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

16. OTHER INFORMATION

Copyright 2013 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only.

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.