Keystones Safety Data Sheet (SDS).pdf

Date SDS Prepared: May 31, 2015 Page 1 of 5

1. PRODUCT IDENTIFICATION

Common Name:

Synonyms: Ceramic Tile and Wares

Manufacturer Name: Dal-Tile Corporation

Address: Headquarters Office

7834 C.F. Hawn Freeway, Dallas, TX 75217

Emergency Assistance: Environmental, Health and Safety Department

Richard Ray - (214) 309-4295

1-800-933-TILE; (214) 398-1411 (24-hour number)

Recommended Use:

2. HAZARDS IDENTIFICATION

Emergency Overview: Danger! Lung injury and Cancer Hazard

GHS Classification (Global Harmonized Standard Classification):

Carcinogenicity Category 1A (H350)

Specific target organ toxicity, single exposure; Respiratory tract irritation - Category 3 (H335)

Specific target organ toxicity, repeated exposure - Category 1A (H372)

GHS Label, Hazards and Precautionary Statements

GHS Pictogram:

Crystalline Silica: Category 3 (Respiratory tract irritation) (H335)

Categories 1A(Carcinogenicity)(H372)

Label Signal Word: Danger

Hazard Statements:

(H350) May cause CANCER (inhalation)

(H335) May cause respiratory irritation

(H372) Causes damage to organs (lung/respiratory) through prolonged or repeated exposure (inhalation)

May contain Recycled and/or Reclaimed Materials www.daltile.com/leed

SAFETY DATA SHEET

CERAMIC TILE

Ceramic Tile (For purposes of this SDS, the term “ceramic” encompasses all types of tile products manufactured/sourced by Dal-Tile Corporation.)

Tile Series: Keystone

Building Material - Tile products manufactured/sourced by Dal-Tile Corporation are environmentally preferable building materials when compared to other floor/wall coverings. As defined by guidelines issued by the Environmental Protection Agency, the American Society for

Testing & Materials, and the Federal Trade Commission, Tile is one of the most environmentally friendly building materials you can buy today. Should you desire additional information, please direct your inquiry to the address above.

Tile products are mixtures of predominantly clays, silica sand, and other natural occurring minerals that have been mixed with water and fired in a high temperature kiln. The finished, fired tiles are odorless, stable, non-flammable, and pose no immediate hazard to health.

Respiratory, hand and eye protection may be needed to prevent excess exposure to airborne particulates if dust is produced by cutting tiles during installation or if dust is produced by any other operations, including demolition/removal projects.

This document has been prepared in accordance with the Occupational Safety and Health Administration (OSHA) Hazard

Communication standard, 29 Code of Federal Regulations (CFR) 1910.1200(g), Safety Data Sheets.

http://www.daltile.com/leed

Date SDS Prepared: May 31, 2015 Page 2 of 5

2. HAZARDS IDENTIFICATION (CONT)

Precautionary Statements:

Do not handle until all safety precautions have been read and understood. (P202)

Do not breathe dust/spray. (P260 + P261)

Wash skin thoroughly after handling. (P264)

Do not eat, drink or smoke when using this product. (P270)

Wear protective gloves, protective clothing, eye protection, face protection. (P280)

Potential Health Effects:

Inhalation: Do not breathe dust. See “Health Hazards” in Section 11 for more details.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Tiles are manufactured in various shapes, sizes, and colors.

These products do not contain asbestos.

Composition EU Class

Crystalline silica as quartz CAS: 14808-60-7 (67/548/EEC)

EINECS: 238-878-4 Xn R48/20

Clays CAS: 1332-58-7 (67/548/EEC)

EINECS: 265-064-6 Xi R36/37/38

Nepheline syenite CAS: 37244-96-5 (67/548/EEC)

EINECS: N/A Xi R36/37/38

Talc CAS: 14807-96-6 (67/548/EEC)

EINECS: 238-877-9 Xi R36/37/38

Feldspar CAS: 68476-25-5 (67/548/EEC)

EINECS: 270-666-7 Xi R36/37/38

Biotite CAS: 12001-26-2 (67/548/EEC)

EINECS: 215-479-3 Xi R36/37/38

4. FIRST AID MEASURES

Eyes:

Skin: Wash thoroughly after working with tiles.

Inhalation:

Ingestion: Not applicable for intact tiles.

Have emergency eyewash station available in area where tiles are cut.

5. FIRE-FIGHTING MEASURES AND INFORMATION

Flash Point (Method Used): Not applicable

Autoignition Temperature: Not applicable

Flammable Limits (% by Volume in Air): LEL - not applicable

UEL - not applicable

Fire Extinguishing Media: None required Non-flammable

Special Fire Fighting Procedures: None required

Fire and Explosion Hazards: None

0-15

0-5

Immediately flush eyes with large amounts of water for at least 15 minutes if dust gets in eyes. Get medical attention if irritation persists.

Remove to fresh air if exposed to large amounts of tile dust. Administer artificial respiration if breathing has stopped. Keep victim at rest. Call for prompt medical attention.

Estimated % by Wt.

0-30

CAS# /

EINECS#

0-40

0-50

20-55

Tile products are mixtures of predominately Clays, Silica Sand and other naturally-occurring minerals, that have been mixed with water and fired in a high temperature kiln.

Under normal conditions these products do not release hazardous materials after installation and are not considered hazardous waste should disposal be necessary.

Date SDS Prepared: May 31, 2015 Page 3 of 5

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE

Do not store near acids. If tiles contact some acids, damage/discoloration to the surface may occur.

Shelf life is unlimited.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Exposure Table

Composition

NIOSH

IDLH

Units

Crystalline silica as quartz 0.05 mg/m3

-respirable fraction

-total dust N.E. mg/m3

Clays

-respirable fraction N.E. mg/m3

-total dust** N.E. mg/m3

Nepheline syenite

-respirable fraction** N.E. mg/m3

-total dust** N.E. mg/m3

Talc

-respirable fraction 2 mg/m3

-total dust** 10 mg/m3

Feldspar

-respirable fraction N.E. mg/m3

-total dust** N.E. mg/m3

Biotite

-respirable fraction** 15 mg/m3

-total dust** N.E. mg/m3

* 2006 Edition, respirable fraction to be determined as per Appendix D of ACGIH TLV.

** Covered as particles not otherwise regulated per OSHA and particles not otherwise classified per ACGIH.

N.D. - Not determined

N.E. - Not established

8.2 EXPOSURE CONTROLS/PERSONAL PROTECTION

N.E.

15 N.E.

15 10

N.E N.E.

15 N.E.

2 2

ACGIH

TLV*

Avoid creating excessive dust. Clean up dust with a vacuum system with a High-efficiency particulate (HEPA) air filter vacuum or damp sweeping. See Section 8 of this SDS concerning PPE information for clean-up.

When cutting, grinding or removing, use equipment with integral dust collection and/or use local exhaust ventilation. Use wet cutting methods to reduce generation of dust. Use respiratory protection in the absence of effective engineering controls.

OSHA

PEL

5 N.E.

%SiO2+2

%SiO2+2

0.025

N.E.

Ventilation: Use adequate ventilation to keep exposure to dust below recommended exposure levels. Avoid inhalation of dust. The highest probability of silica exposure occurs during installation using dry cutting methods or during removal of installed tile. Wet cutting methods are recommended.

Respiratory Protection: Use of a properly fitted NIOSH/MSHA approved particulate respirator is recommended when cutting tiles for installation or during the removal of installed tile.

Eye Protection: Use dust-proof goggles or safety glasses with side shields. Contact lenses may absorb irritants. Do not wear contact lenses in work areas.

Skin Protection: Cotton or leather work gloves should be worn when cutting this product to minimize skin exposure to dust and/or cuts. Wash hands prior to eating, drinking, or smoking, and at the end of the work shift, after cutting operations are conducted.

NOTE: Personal protection information in Section 8 is based on general information for normal uses and conditions. Where special or unusual uses or conditions exist, it is suggested that the assistance of an industrial hygienist or other qualified professional be obtained.

Date SDS Prepared: May 31, 2015 Page 4 of 5

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Brittle solid; color may vary

Odor: Odorless

Melting Point: Not Available (>2200 F)

Boiling Point: Not applicable

Vapor Pressure: Not applicable

Vapor Density (Air = 1): Not applicable

Solubility in Water: Insoluble

Specific Gravity (H2) = 1): 1.6 to 2.1

Percent Volatile by Volume: Not applicable

Evaporation Rate (Ethyl Ether = 1): Not applicable

Viscosity: Not applicable

Volatility: 0 g/L Volatile Organic Compounds (VOCs)

10. STABILITY AND REACTIVITY

Stability: Stable in current form.

Conditions to Avoid: Avoid contact with acids (e.g., acetic, hydrofluoric, etc.)

Incompatibility (Materials to Avoid): Avoid contact with acids (e.g., acetic, hydrofluoric, etc.)

Hazardous Polymerization: Will not occur.

Hazardous Decomposition Products: None.

11. TOXICOLOGICAL INFORMATION

Potential Health Effects

Primary Routes of Exposure

Acute Effects

Chronic Effects

Potential Adverse Interactions

Carcinogen Status

Overview of Animal Testing

Oral (silica) Lethality

LD50 Rat oral >22,500 mg/kg

LD50 Mouse oral >15,000 mg/kg

LC50 Carp >10,000 mg/l (per 72 hr.)

No acute effects from exposure to intact tile are known. Working with broken or cut tile produces a potential for cuts to the hands and exposed body parts. Acute effects such as eye irritation may occur if associated with high dust operations such as dry cutting tile or during the removal of installed tile. In very rare cases, symptoms of acute silicosis, a form of silicosis (a nodular pulmonary fibrosis) associated with exposure to respirable crystalline silica, may develop following acute exposure to extremely dusty environments caused by generation of tile dust. Signs such as labored breathing and early fatigue may indicate silicosis; however, these same symptoms can arise from many other causes.

No chronic effects are known for exposure to intact tile. Long-term, continual exposure to respirable crystalline silica at or above established permissible occupational exposure limits may lead to the development of silicosis, a nodular pulmonary fibrosis (NPF). NPFs are also associated with pulmonary tuberculosis, bronchitis, emphysema, and other airway diseases. This type of chronic exposure to silica dust may also result in the development of autoimmune disorders, chronic renal disease, and other adverse health effects.

Recent epidemiologic studies demonstrate that workers exposed to elevated silica concentrations have a significant risk of developing chronic silicosis. Signs such as labored breathing and early fatigue may indicate silicosis; however, these same symptoms can also arise from many other causes.

Silicosis may be complicated by severe mycobacterial or fungal infections and result in tuberculosis (TB). Epidemiologic studies have established that silicosis is a risk factor for developing TB. Any existing respiratory or pulmonary diseases may be complicated by exposure to respirable crystalline silica. Smoking may increase the risk of adverse effects if done in conjunction with occupational exposure to silica dust at or above permissible exposure limits.

Respirable crystalline silica is classified by the International Agency for Research on Cancer (IRAC) as a Group I Carcinogen

(carcinogenic to humans). The National Toxicology Program (9th Report) lists respirable crystalline silica as “Known to be a Human

Carcinogen”. USDOL/OSHA and NIOSH have recommended that crystalline silica be considered a potential occupational carcinogen.

Short term experimental studies of rats have found that intratracheal instillation of quartz particles leads to the formation of discrete silicotic nodules in rats, mice and hamsters.

None for intact tile. Inhalation and potential exposure to eyes, hands, or other body parts if contact is made with broken tile, and/or during procedures involving the cutting of tiles, and/or for operations involving the removal of installed tiles.

Date SDS Prepared: May 31, 2015 Page 5 of 5

12. ECOLOGICAL INFORMATION

No information available at this time.

13. DISPOSAL CONSIDERATIONS

14. TRANSPORTATION INFORMATION

D.O.T Shipping Name: Not applicable

Hazard Class: Non-regulated (for disposal purposes material is non-hazardous Class III regulated material)

ID Number: Not applicable

Marking: Not applicable

Label: None

Placard: None

Hazardous Substance/RQ: Not applicable

Shipping Description: Porcelain/Ceramic Tiles

Packaging References: None

15. REGULATORY INFORMATION

Combustible Liquid Flammable Aerosol Oxidizer

Compressed Gas Explosive Pyrophoric

Flammable Gas X Health Hazard (Sections 3 & 11) Unstable

Flammable Liquid Organic Peroxide Water Reactive

Flammable Solid

16. ADDITIONAL INFORMATION

Global Harmonization Identification System

GHIS: Health: 3 Fire: 4 Reactivity: 4

Hazardous Material Identification System

HMIS: Health: 0 Fire: 0 Reactivity: 0

National Fire Protection Association

NFPA: Health: 0 Fire: 0 Reactivity: 0

Note: The information in this data sheet provides information related to the potential hazards associated with dusts which may be produced during cutting or otherwise changing the shape of the tile during installation and/or removal.

Based on information presently available, this product does not meet any of the hazard definitions of 29 CFR Section 1910.1200.

Waste should be disposed of in a landfill certified to accept such materials in accordance with federal, state, and local regulations.

Title 22 Division 2, California Code of Regulation Chapter 3 (Proposition 65): This product contains a chemical or chemicals known to the State of California to cause cancer and/or birth defects or other reproductive harm.

This product and/or its components have been previously introduced into U.S. commerce and is listed in the Toxic Substances Control

Act (TSCA) Inventory of Chemicals in Commerce. Hence, it is subject to all applicable provisions and restrictions under TSCA 40 CFR

Section 721 and 723.250.

This tile contains <1 percent by weight each of the following elements, which are SARA 313 Recordable: Antimony, Arsenic, Barium, Beryllium, Cadmium, Cobalt, Chromium, Copper, Manganese, Mercury, Nickel, Lead, Silver, Thallium, Tin, Titanium, Vanadium, and

Zinc.

This product or its components meets the following hazard definition(s) as defined by the Occupational Safety and Health Hazard

Communication Standard (29 CFR Section 1910.1200):