ATTACHMENT E SAFETY DATA SHEETS.pdf
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- Z2QA--FY25: Epoxy Coating of Chiller Condensers
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About this file
This document contains two Safety Data Sheets (SDS) for Nalco chemical products: NALCO® 3DTS68 and NALCO® 7346 TAB.
The NALCO® 3DTS68 is a cooling water treatment product for high hardness waters, classified as non-hazardous. It is a solid, light yellow substance with no specific health hazards under normal use. The product is completely water-soluble and has a relative density of 1.38. The NALCO® 7346 TAB is a biocide classified as an oxidizing solid with corrosive properties. It contains multiple hydantoin compounds and is characterized as harmful if swallowed or inhaled, causing potential skin burns and eye damage. The product is very toxic to aquatic life and requires careful handling with personal protective equipment. Both products are manufactured by Nalco Company in Naperville, Illinois, and are regulated under various chemical control laws internationally.
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| File | Type | Posted |
|---|---|---|
| 36C24825Q0454 0003.docx | DOCX document | |
| REPOST ATTACHMENT C GOVERNMENT RESPONSE TO VENDORS QUESTIONS.pdf | ||
| ATTACHMENT F VIERA HEALTHCARE CENTER CHILLER DESIGN BUILD.pdf | ||
| ATTACHMENT G REVISED PWS A0002.docx | DOCX document | |
| ATTACHMENT D COOLING UNIT GRAPH OVER NINETY DAYS.pdf | ||
| 36C24825Q0454 0002.docx | DOCX document | |
| ATTACHMENT C GOVERNMENT RESPONSE TO VENDORS QUESTIONS.docx | DOCX document | |
| 36C24825Q0454 0001.docx | DOCX document | |
| 36C24825Q0454_1.docx | DOCX document | |
| ATTACHMENT B - CONTRACTOR QUESTIONS.docx | DOCX document | |
| ATTACHMENT A - ATTACHMENT A - PICTURES DISPLAYING CHILLERS CURRENT CONDITIONS.docx | DOCX document |
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SAFETY DATA SHEET
NALCO® 3DTS68
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : NALCO® 3DTS68
Other means of identification : Not applicable.
Recommended use : Cooling Water Treatment for High Hardness Waters
Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits.
Company : Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198
USA
TEL: (630)305-1000
Emergency telephone number
: (800) 424-9300 (24 Hours) CHEMTREC
Issuing date : 06/27/2014
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Not a hazardous substance or mixture.
GHS Label element
Precautionary Statements : Prevention:
Wash hands thoroughly after handling.
Response:
Specific measures: consult MSDS Section 4.
Storage:
Store in accordance with local regulations.
Other hazards : None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Non-hazardous ingredients
SECTION 4. FIRST AID MEASURES
In case of eye contact : Rinse with plenty of water. Get medical attention if symptoms occur.
In case of skin contact : Wash off with soap and plenty of water. Get medical attention if symptoms occur.
If swallowed : Rinse mouth. Get medical attention if symptoms occur.
If inhaled : Get medical attention if symptoms occur.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders.Use personal protective equipment as required.
2 / 8
Notes to physician : No specific measures identified.
See toxicological information (Section 11)
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
: None known.
Specific hazards during firefighting
: Not flammable or combustible.
Hazardous combustion products
: Carbon oxides
Special protective equipment for firefighters
: Use personal protective equipment.
Specific extinguishing methods
: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Environmental precautions : No special environmental precautions required.
Methods and materials for containment and cleaning up
: Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : For personal protection see section 8. Wash hands after handling.
Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers.
Suitable material : The following compatibility data is suggested based on similar product data and/or industry experience: Shipping and long term storage compatibility with construction materials can vary; we therefore recommend that compatibility is tested prior to use.
Unsuitable material : not determinednot determined
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
3 / 8
This product does not contain any substance that has an established exposure limit.
Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Personal protective equipment
Eye protection : Safety glasses
Hand protection : Wear protective gloves.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Wear suitable protective clothing.
Respiratory protection : No personal respiratory protective equipment normally required.
Hygiene measures : Wash hands before breaks and immediately after handling the product.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Solid
Colour : Light yellow
Odour : None
Flash point : > 93.3 °C pH : no data available
Odour Threshold : no data available
Melting point/freezing point : no data available
Initial boiling point and boiling range
: no data available
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : 1.38
Density : no data available
Water solubility : completely soluble
Solubility in other solvents : no data available
Partition coefficient: n-octanol/water
: no data available
Auto-ignition temperature : no data available
Thermal decomposition : Carbon oxides
Viscosity, dynamic : no data available
4 / 8
Viscosity, kinematic : no data available
VOC : no data available
SECTION 10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal conditions.
Possibility of hazardous reactions
: No dangerous reaction known under conditions of normal use.
Conditions to avoid : None known.
Incompatible materials : Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.
Contains Sulfite.
Hazardous decomposition
: Oxides of carbon Oxides of nitrogen Oxides of phosphorus
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
: Eye contact, Skin contact
Potential Health Effects
Eyes : Health injuries are not known or expected under normal use.
Skin : Health injuries are not known or expected under normal use.
Ingestion : Health injuries are not known or expected under normal use.
Inhalation : Health injuries are not known or expected under normal use.
Chronic Exposure : Health injuries are not known or expected under normal use.
Experience with human exposure
Eye contact : No symptoms known or expected.
Skin contact : No symptoms known or expected.
Ingestion : No symptoms known or expected.
Inhalation : No symptoms known or expected.
Toxicity
Product
Acute oral toxicity : no data available
Acute inhalation toxicity : no data available
Acute dermal toxicity : no data available
5 / 8
Skin corrosion/irritation : no data available
Serious eye damage/eye irritation
: no data available
Respiratory or skin sensitization
: no data available
Carcinogenicity
IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive effects : no data available
Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : no data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : Harmful to aquatic life with long lasting effects.
Toxicity to fish : LC50 Oncorhynchus mykiss (rainbow trout): 4,891 mg/l Exposure time: 96 h Test substance: 5% Aqueous Solution of Product
Toxicity to daphnia and other aquatic invertebrates
: LC50 Ceriodaphnia dubia: 4,317 mg/l Exposure time: 48 h Test substance: 5% Aqueous Solution of Product
Toxicity to algae : no data available
Persistence and degradability no data available
Mobility
6 / 8
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages;
Air : <5% Water : 30 - 50% Soil : 50 - 70%
The portion in water is expected to be soluble or dispersible.
Bioaccumulative potential
This preparation or material is not expected to bioaccumulate.
Other information
SECTION 13. DISPOSAL CONSIDERATIONS
If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.
Disposal methods : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
SECTION 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport (DOT)
Proper shipping name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
Air transport (IATA)
Sea Transport (IMDG/IMO)
7 / 8
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302
: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
: SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
INTERNATIONAL CHEMICAL CONTROL LAWS :
TOXIC SUBSTANCES CONTROL ACT (TSCA)
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40
CFR 710)
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA)
The substance(s) in this preparation are included in or exempted from the Domestic Substance List
(DSL).
SECTION 16. OTHER INFORMATION
NFPA: HMIS III:
Revision Date : 06/27/2014 Version Number : 1.0 Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a
Flammability
H e a lt h
In s ta b ility
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
Special hazard.
0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
8 / 8 guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
For additional copies of an MSDS visit www.nalco.com and request access.
NALCO® 7346 TAB
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Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : NALCO® 7346 TAB
Other means of identification : Not applicable.
Recommended use : BIOCIDE
Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits.
Company : Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198
USA
TEL: (630) 305-1000
Emergency telephone number
: (800) 424-9300 (24 Hours) CHEMTREC
Issuing date : 12/09/2021
Section: 2. HAZARDS IDENTIFICATION
GHS Classification
Oxidizing solids : Category 1 Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 4 Skin corrosion : Category 1B Serious eye damage : Category 1 Skin sensitization : Category 1
GHS Label element
Hazard pictograms :
Signal Word : Danger
Hazard Statements : May cause fire or explosion; strong oxidiser.
Harmful if swallowed or if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Precautionary Statements : Prevention:
Keep away from heat. Keep/Store away from clothing and other combustible materials. Do not breathe dusts or mists. Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response:
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove
2 / 11 person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/ physician. IF ON CLOTHING:
rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.
Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Concentration: (%)
1-Bromo-3-Chloro-5,5-Dimethyl-Hydantoin 16079-88-2 54.2 1,3-Dichloro-5,5-Dimethylhydantoin 118-52-5 28.9 1,3-Dichloro-5-Ethyl-5-Methylhydantoin 89415-87-2 15.9 Sodium Chloride 7647-14-5 1 - 5
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention immediately.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms and effects, both acute and delayed
: See Section 11 for more detailed information on health effects and symptoms.
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
: None known.
Specific hazards during : Oxidizer. Contact with other material may cause fire.
3 / 11 firefighting
Hazardous combustion products
: Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx)
Special protective equipment for firefighters
: Use personal protective equipment.
Specific extinguishing methods
: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
: Ensure adequate ventilation. Keep people away from and upwind of spill/leak.
Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only.
Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for containment and cleaning up
: Sweep up and shovel into suitable containers for disposal.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation.
Conditions for safe storage : Keep in a cool, well-ventilated place. Keep away from reducing agents. Keep away from combustible material. Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers.
Suitable material : The following compatibility data is suggested based on similar product data and/or industry experience: Shipping and long term storage compatibility with construction materials can vary; we therefore recommend that compatibility is tested prior to use.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Form of exposure Permissible concentration
Basis
1,3-Dichloro-5,5- Dimethylhydantoin
118-52-5 TWA 0.2 mg/m3 ACGIH
STEL 0.4 mg/m3 ACGIH
TWA 0.2 mg/m3 NIOSH REL
4 / 11
STEL 0.4 mg/m3 NIOSH REL
TWA 0.2 mg/m3 OSHA Z1
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.
Personal protective equipment
Eye protection : Safety goggles
Face-shield
Hand protection : Wear impervious chemical-resistant gloves when handling this product.
The following glove types are recommended based on our review of glove manufacturer information and/or other available sources.
Nitrile rubber Other glove types may be used for short term, incidental contact if determined by testing to provide adequate worker protection.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Flame retardant protective clothing
Respiratory protection : Use local exhaust ventilation or other engineering controls as necessary to control airborne mist and vapor.
Where concentrations in air may exceed the limits given in this section or when significant mists, vapors, aerosols are generated, an approved air purifying respirator equipped with suitable filter cartridges is recommended.
Use a particulate pre-filter where operations generate significant mists or aerosols.
Recommended gas and vapour cartridge:
A particulate cartridge may be used.
with a Particulate pre-filter.
In event of emergency or planned entry into unknown concentrations, a positive pressure, full-facepiece SCBA or supplied-air respirator should be used.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.
The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith based on typical expected conditions of use. PPE selection should always be completed in conjunction with a proper risk assessment and in accordance with a PPE management program.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Briquettes
Colour : off-white
Odour : Pungent
Flash point : 142 °C, Method: ASTM D 92, Cleveland open cup pH : 3.6,(1 %), Method: ASTM E 70
Odour Threshold : no data available
5 / 11
Melting point/freezing point : MELTING POINT: 120 - 148 °C, ASTM D-2117
Initial boiling point and boiling range
: no data available
Evaporation rate : < 1
Flammability (solid, gas) : no data available
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : no data available
Density : no data available
Water solubility : 5.4 g/l (25 °C)
Solubility in other solvents : no data available
Partition coefficient: n-octanol/water
: no data available
Auto-ignition temperature : no data available
Thermal decomposition : no data available
Viscosity, dynamic : no data available
Viscosity, kinematic : no data available
Molecular weight : no data available
VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reactions
: No dangerous reaction known under conditions of normal use.
Conditions to avoid : None known.
Incompatible materials : Strong acids
Strong Bases Contact with organic materials (e.g. rags, sawdust, hydrocarbon oils or solvents) and avoid reducing agents (e.g. hydrazine, sulfites, sulfide, aluminum or magnesium dust) which can generate heat, fires, explosions and the release of toxic fumes.
Organic materials and reducing agents Oxidizing agents Combustible materials
Hazardous decomposition
: In case of fire, hazardous decomposition products may be produced such as:
Carbon oxides
6 / 11 nitrogen oxides (NOx)
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
: Eye contact, Skin contact
Potential Health Effects
Eyes : Causes serious eye damage.
Skin : Causes severe skin burns. May cause allergic skin reaction.
Ingestion : Harmful if swallowed. Causes digestive tract burns.
Inhalation : Harmful if inhaled. May cause nose, throat, and lung irritation.
Chronic Exposure : Health injuries are not known or expected under normal use.
Experience with human exposure
Eye contact : Redness, Pain, Corrosion
Skin contact : Redness, Pain, Irritation, Corrosion, Allergic reactions
Ingestion : Corrosion, Abdominal pain
Inhalation : Respiratory irritation, Cough
Toxicity
Product
Acute oral toxicity : LD50 rat: 468 - 477 mg/kg Test substance: Product
Acute inhalation toxicity : Acute toxicity estimate: 1.59 mg/l Exposure time: 4 h Test atmosphere: dust/mist
Acute dermal toxicity : LD50 rabbit: > 2,000 mg/kg Test substance: Active Substance
Skin corrosion/irritation : no data available
Serious eye damage/eye irritation
: no data available
Respiratory or skin sensitization
: no data available
Carcinogenicity : no data available
Reproductive effects : no data available
Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available
7 / 11
STOT - repeated exposure : no data available
Aspiration toxicity : no data available
Section: 12. ECOLOGICAL INFORMATION
Toxicity
Environmental Effects : Very toxic to aquatic life.
Toxicity to fish : LC50 Oncorhynchus mykiss (rainbow trout): 0.5 mg/l Exposure time: 96 hrs Test substance: Product
LC50 Lepomis macrochirus (Bluegill sunfish): 1.2 mg/l
LC50 Cyprinodon variegatus (sheepshead minnow): 1.4 mg/l
Test substance: value expressed as Br2
LC50 Pimephales promelas (fathead minnow): 0.71 mg/l
: LC50 Mysid Shrimp (Mysidopsis bahia): 0.93 mg/l
LC50 American Oyster: 0.84 mg/l
Test substance: value expressed as Br2
EC50 Daphnia magna (Water flea): 1.1 mg/l Exposure time: 48 hrs
LC50 Daphnia magna (Water flea): 1.1 mg/l
NOEC Daphnia magna (Water flea): 0.63 mg/l
Toxicity to algae : LC50 Green Algae (Pseudokirchneriella subcapitata, previously Selenastrum capricornutum): 0.12 mg/l Exposure time: 72 hrs Test substance: Active Substance
Toxicity to fish (Chronic toxicity)
: EC25 / IC25: 0.60 mg/l Exposure time: 7 d
8 / 11
Species: Fathead Minnow
LOEC: 1.0 mg/l
NOEC: 0.50 mg/l
(Chronic toxicity)
: EC25 / IC25: 0.45 mg/l Exposure time: 7 d Species: Ceriodaphnia dubia
LOEC: 0.50 mg/l
NOEC: 0.25 mg/l
Toxicity to terrestrial organisms
: LC50 Bobwhite Quail: > 5,620 mg/kg Test substance: Similar active ingredients
LC50 Mallard Duck: > 5,620 mg/kg Test substance: Similar active ingredients
Persistence and degradability
The product is hydrolyzed in water to hypobromous acid, hypochlorous acid and 5,5-dimethylhydantoin.
Chemical Oxygen Demand (COD): 140,000 mg/l
Biochemical Oxygen Demand (BOD):
Incubation Period Value Test Descriptor 150 mg/l
Mobility
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages;
Air : <5%
9 / 11
Water : 50 - 70% Soil : 30 - 50%
The portion in water is expected to be soluble or dispersible.
Bioaccumulative potential
This preparation or material is not expected to bioaccumulate.
Other information
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : Do not contaminate storm water drains, natural waterways or soil with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations.
Dispose of wastes in an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport (DOT)
Proper shipping name : OXIDIZING SOLID, CORROSIVE, N.O.S.
Technical name(s) : 1-BROMO-3-CHLORO-5,5,-DIMETHYLHYDANTOIN UN/ID No. : UN 3085 Transport hazard class(es) : 5.1, 8 Packing group : III
Air transport (IATA)
Proper shipping name : OXIDIZING SOLID, CORROSIVE, N.O.S.
Technical name(s) : 1-BROMO-3-CHLORO-5,5,-DIMETHYLHYDANTOIN UN/ID No. : UN 3085 Transport hazard class(es) : 5.1, 8 Packing group : III
Sea transport (IMDG/IMO)
Proper shipping name : OXIDIZING SOLID, CORROSIVE, N.O.S.
Technical name(s) : 1-BROMO-3-CHLORO-5,5,-DIMETHYLHYDANTOIN UN/ID No. : UN 3085 Transport hazard class(es) : 5.1, 8 Packing group : III
*Marine pollutant : BROMOCHLORO-5,5-DIMETHYLHYDANTOIN
10 / 11
* Note: This product is regulated as a Marine Pollutant when shipped by Rail or Highway (in bulk quantities), and when shipped by water in all quantities.
Section: 15. REGULATORY INFORMATION
TSCA list : No substances are subject to a Significant New Use Rule.
The following substance(s) is/are subject to TSCA 12(b) export notification requirements: 1-Bromo-3-Chloro-5,5-Dimethyl-Hydantoin
EPA Reg. No. : 6836-115-1706
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This product does not contain a RQ substance, or this product contains a substance with a RQ, however the calculated RQ exceeds the reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Oxidiser (liquid, solid or gas)
Acute toxicity (any route of exposure) Respiratory or skin sensitisation Skin corrosion or irritation Serious eye damage or eye irritation
SARA 302 : This material does not contain any components with a section 302
EHS TPQ.
SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
INTERNATIONAL CHEMICAL CONTROL LAWS :
United States TSCA Inventory This product is exempted under TSCA and regulated under FIFRA. The inerts are on the Inventory List.
Australia. Australian Industrial Chemicals Introduction Scheme (AICIS) All substances in this product comply with the Australian Industrial Chemicals Introduction Scheme (AICIS)
Canadian Domestic Substances List (DSL) Substances regulated under the Pest Control Products Act are exempt from CEPA New Substance Notification requirements.
Japan. ENCS - Existing and New Chemical Substances Inventory All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).
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Korea. Korean Existing Chemicals Inventory (KECI) All substances in this product comply with the Chemical Control Act (CCA) and are listed on the Existing Chemicals List (ECL)
Philippines Inventory of Chemicals and Chemical Substances (PICCS) All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS).
China Inventory of Existing Chemical Substances All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).
New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals.
Taiwan Chemical Substance Inventory All substances in this product comply with the Taiwan Existing Chemical Substances Inventory (ECSI).
Section: 16. OTHER INFORMATION
NFPA: HMIS III:
Revision Date : 12/09/2021 Version Number : 1.6 Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
For additional copies of an SDS visit www.nalco.com and request access.
Flammability
H e a lt h
In s ta b ility
OX
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3*
Special hazard. 0 = not significant, 1 = Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
| 3DTS68 |
| 7346 TAB |
File details come from the government source that posted it. Updated .