SAMPLE OF

SITE DESIGN

BY

PROFESSIONAL

ENGINEER

Matthew Schenecker Cross-Out

Schappacher

Engineering, LLC

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DATE: DEC. 2024

SCALE: AS NOTED

DESIGNED DRAWN CHECKED

Signature Date

Professional Engineer #

CKD BY

3604 53rd AVENUE EAST, BRADENTON, FL 34203

PHONE: (941) 251-7613

WWW.SCHAPPACHERENG.COM

SARASOTA COUNTY BREEZE TRANSIT

BUS STOP / SHELTER MODIFICATIONS

RICHARD SCHAPPACHER, P.E.

51501

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Work Assignment #23

LOCKWOOD RIDGE ROAD and 61st STREET

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DATE: DEC. 2024

SCALE: AS NOTED

DESIGNED DRAWN CHECKED

Signature Date

Professional Engineer #

CKD BY

3604 53rd AVENUE EAST, BRADENTON, FL 34203

PHONE: (941) 251-7613

WWW.SCHAPPACHERENG.COM

SARASOTA COUNTY BREEZE TRANSIT

BUS STOP / SHELTER MODIFICATIONS

RICHARD SCHAPPACHER, P.E.

51501

SE MM RS

SITE CONSTRUCTION PLAN

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North

Work Assignment #23

LOCKWOOD RIDGE ROAD and 61st STREET

DESCRIPTIONREV DWN BYDATE

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DATE: DEC. 2024

SCALE: AS NOTED

DESIGNED DRAWN CHECKED

Signature Date

Professional Engineer #

CKD BY

3604 53rd AVENUE EAST, BRADENTON, FL 34203

PHONE: (941) 251-7613

WWW.SCHAPPACHERENG.COM

SARASOTA COUNTY BREEZE TRANSIT

BUS STOP / SHELTER MODIFICATIONS

RICHARD SCHAPPACHER, P.E.

51501

SE MM RS

SITE CONSTRUCTION PLAN

C

A

North

Work Assignment #23

LOCKWOOD RIDGE ROAD and 61st STREET

DESCRIPTIONREV DWN BYDATE

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DATE: DEC. 2024

SCALE: AS NOTED

DESIGNED DRAWN CHECKED

Signature Date

Professional Engineer #

CKD BY

3604 53rd AVENUE EAST, BRADENTON, FL 34203

PHONE: (941) 251-7613

WWW.SCHAPPACHERENG.COM

SARASOTA COUNTY BREEZE TRANSIT

BUS STOP / SHELTER MODIFICATIONS

RICHARD SCHAPPACHER, P.E.

51501

SE MM RS

CONSTRUCTION NOTES

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(Work Assignment - #23)

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DATE: DEC. 2024

SCALE: AS NOTED

DESIGNED DRAWN CHECKED

Signature Date

Professional Engineer #

CKD BY

3604 53rd AVENUE EAST, BRADENTON, FL 34203

PHONE: (941) 251-7613

WWW.SCHAPPACHERENG.COM

SARASOTA COUNTY BREEZE TRANSIT

BUS STOP / SHELTER MODIFICATIONS

RICHARD SCHAPPACHER, P.E.

51501

SE MM RS

CONSTRUCTION DETAILS

BREEZE STANDARDS (STOPS)

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DATE: DEC. 2024

SCALE: AS NOTED

DESIGNED DRAWN CHECKED

Signature Date

Professional Engineer #

CKD BY

3604 53rd AVENUE EAST, BRADENTON, FL 34203

PHONE: (941) 251-7613

WWW.SCHAPPACHERENG.COM

SARASOTA COUNTY BREEZE TRANSIT

BUS STOP / SHELTER MODIFICATIONS

RICHARD SCHAPPACHER, P.E.

51501

SE MM RS

CONSTRUCTION DETAILS

BREEZE STANDARDS (STOPS)

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DATE: DEC. 2024

SCALE: AS NOTED

DESIGNED DRAWN CHECKED

Signature Date

Professional Engineer #

CKD BY

3604 53rd AVENUE EAST, BRADENTON, FL 34203

PHONE: (941) 251-7613

WWW.SCHAPPACHERENG.COM

SARASOTA COUNTY BREEZE TRANSIT

BUS STOP / SHELTER MODIFICATIONS

RICHARD SCHAPPACHER, P.E.

51501

SE MM RS

EROSION AND SEDIMENT

CONTROL DETAILS

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DATE: DEC. 2024

SCALE: AS NOTED

DESIGNED DRAWN CHECKED

Signature Date

Professional Engineer #

CKD BY

3604 53rd AVENUE EAST, BRADENTON, FL 34203

PHONE: (941) 251-7613

WWW.SCHAPPACHERENG.COM

SARASOTA COUNTY BREEZE TRANSIT

BUS STOP / SHELTER MODIFICATIONS

RICHARD SCHAPPACHER, P.E.

51501

SE MM RS

MAINTENANCE OF TRAFFIC PLAN

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BREEZE

TRANSIT

SHELTER

ASSEMBLY

BREEZE TRANSIT SHELTER ASSEMBLY

All the Columns will receive a Welded Anchor Boot. Secure with a 1/2-13 x 4 inch Hex Head Stainless Bolt, washers, and nut.

The Rooftop comes from the supplier as one assembled piece as shown.

Tip the Rooftop on edge as shown and insert the 'back right' Column and secure with (2) 3/8-16 x 1 inch Stainless Hex Head Bolts.

Secure the Center Columns with (2) 3/8-16 x 1 inch Stainless Hex Head Bolts for each Column as shown.

insert the 'Back Left' Column and scure with (2) 3/8-16 x 1 inch Stainless Hex Head Bolts.

Safely tilt the shelter onto the 4 Coulmns that were attached to the roof structure.

Insert the 'Front Left' Column as the shelter is being tilted. Insert the 'Front Right' Column and secure both front Coumns with (2) 3/8-16 x 1 Stainless Hex Head Bolts each.

The Perforated Aluminum Panels are inserted between the Columns.

The Lower Sill Beam is installed using screws or pop rivets.

The Left and Right Vertical Sashes are installed by tapping on them with a rubber mallet.

The Lower Sash is then installed with a rubber mallet.

These sashes clip into place.

The Perforated Aluminum Panels are now held secure and the Columns are secured as well.

The shelter is then manually pushed into postion. The center of the Columns are 12 inches from the back of the concrete shelter pad.

The shelter is then spotted 12 inches either to the right or the left edge of the concrete shelter pad per instruction from the Breeze Project Manager.

Secure each Column with (4) 1/2 x 5 inch concrete anchor bolts.

Set the Bench with 2 inches of clearance tot he back wall and 3 inches away fromt he side wall. The number of bolts required varies by the size of the Bench

Set one Inverted Bike Rack 2 feet from the shelter and secure with 3/8 x 3 inch concrete anchor bolts

BRASCO

ASSEMBLY

DRAWINGS

AND

COMPONENTS

BRASCO INTERNATIONAL, INC.

32400 INDUSTRIAL DR.

MADISON HEIGHTS, MICHIGAN 48071

1-800-893-3665 WWW.BRASCO.COM

CUSTOMER: DESIGNER:

DATE:

THIS DRAWING IS CONFIDENTIAL AND IS FOR THE SOLE USE OF

OUR CUSTOMERS AND MAY NOT BE REPRODUCED OR COPIED

WITHOUT WRITTEN PERMISSION FROM BRASCO INTERNATIONAL.

PROJECT:

MODEL: SHEET:JOB #

BRASCO INTERNATIONAL

CURVELINE SERIES BENCH ASSEMBLY

BE-CL-6-P-1-4-0 XXXX

CMP

10-13-21

CHECKER:

DATE:

REVISION:

SJT

10-13-21

A

24.250"

REF,

18.465"

15.250"

REF.

23.500"

TYP.

72.000"

REF.

QUANTITY (X) BENCHES THUS

SPECIFICATIONS:

- 6' CURVELINE SERIES ALUMINUM BENCH WITH PERFORATED SEATING

AND FOUR ARMRESTS

- POWDER COAT PAINTED FINISH- RAL TBD

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BREEZE TRANSIT

PAINTING

SPECIFICATIONS

PRESSURE WASH AND ENAMEL PAINT

Painting a Bus Shelter involves a multistep process. The main items selected from the UPC will be the following.

• Preparation for painting semi-gloss Sherwin Williams Direct-To Metal Alkyd Enamel per specification by Sherwin Williams Commercial Paint 125.01.

• Mask the solar panel, LED light bulbs, concrete flooring, walls of adjoining walls, buildings or vehicles will be required.

• Pressure wash the entire bus shelter. Inclusive of the roof panels, benches, waste bins bicycle racks and the solar light fixture if it is applicable.

• Apply 5.0 to 10.0 wet mils of Sherwin Williams Pro Industrial Pro-Cryl Primer per the attached Safety Data Sheet, and Production Data Sheets.

• Apply 7.0-13.0 mils of B55-100 Series Alkyd Enamel Semi-Gloss paint per the attached Safety Data Sheet, and Production Data Sheets.

ENVIRONMENTAL DATA SHEET

(Certified Product Data Sheet)

46 00 [1045] Date of Preparation

Apr 14, 2025

PRODUCT NUMBER

B55T104

PRODUCT NAME

Direct-to-Metal Alkyd Enamel, Ultradeep Base

MANUFACTURER'S NAME

THE SHERWIN-WILLIAMS COMPANY

101 W. Prospect Avenue Cleveland, OH 44115

This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).

All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided, or the upper limit reported by our supplier. Additionally, the suppliers’ information may include amounts present in the product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made during production.

Hazard Category (for SARA 311.312) B55T104 = | Acute | Chronic | Fire |

Product Weight

8.93 lb/gal

Specific Gravity 1.07

FLASH POINT

101 °F PMCC

Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA HAPS 112 % by Weight % by Volume Light Aliphatic Hydrocarbon

64742-47-8 N N N 33 46

Ethylbenzene 100-41-4 N Y Y 0.2 0.2

Light Aromatic Hydrocarbons 64742-95-6 N N N 3 3

Cumene 98-82-8 N Y Y 0.2 0.2

Trimethylbenzene 25551-13-7 N N N 1 2

Methyl Isobutyl Ketone 108-10-1 N Y Y 0.1 0.1

Regulated Compounds SARA 302 EHS CERCLA HAPS 112 % by Weight % by Volume

Zinc (as Zn) N Y N 1 Cobalt Compound N N Y 0.2

B55T104

Volatile Organic Compounds - U.S. EPA / Canada

B55T104 LB/Gal g/L

Coating Density 8.93 1070 By wt By vol

Total Volatiles 41.4% 56.6% Federally exempt solvents

Water 0.1% 0.1% Organic Volatiles 41.3% 56.4% Percent Non-Volatile 58.6% 43.4% VOC Content LB/Gal g/L

Total 3.68 441 Less exempt solvents 3.69 442 Of solids 8.48 1017 Of solids 0.70 lb/lb 0.70 kg/kg

By wt By wt LVP-VOC 41.3%

Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.82

Volatile Organic Compounds - California

B55T104 LB/Gal g/L

Coating Density 8.93 1070 By wt By vol

Total Volatiles 41.4% 56.6% Exempt solvents

Water 0.1% 0.1% Organic Volatiles 41.3% 56.4% Percent Non-Volatile 58.6% 43.4% VOC Content LB/Gal g/L

Total 3.68 441 Less exempt solvents 3.69 442 Of solids 8.48 1017 Of solids 0.70 lb/lb 0.70 kg/kg

By wt By wt LVP-VOC 41.3%

Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.76

Volatile Organic Compounds - South Coast Air Quality Management District, California, US

B55T104 LB/Gal g/L

Coating Density 8.93 1070 By wt By vol

Total Volatiles 41.4% 56.6% Exempt solvents

Water 0.1% 0.1% Organic Volatiles 41.3% 56.4% Percent Non-Volatile 58.6% 43.4% VOC Content LB/Gal g/L

Total 3.68 441 Less exempt solvents 3.69 442 Of solids 8.48 1017 Of solids 0.70 lb/lb 0.70 kg/kg

Volatile Organic Compounds - EU Directive 2004/42/EC

B55T104 By wt By vol

Total Volatiles 41.4% 56.6% VOC Content LB/Gal g/L

Total 3.68 441

Volatile Organic Compounds - EU Directive 2010/75/EU

B55T104 By wt By vol

Total Volatiles 41.4% 56.6% VOC Content LB/Gal g/L

Total 3.68 441

Volatile Organic Compounds - Mexico

B55T104 LB/Gal g/L

Coating Density 8.93 1070 By wt By vol

Total Volatiles 41.4% 56.6% Exempt solvents

Water 0.1% 0.1% Organic Volatiles 41.3% 56.4% Percent Non-Volatile 58.6% 43.4% VOC Content LB/Gal g/L

Total 3.68 441 Less exempt solvents 3.69 442 Of solids 8.48 1017 Of solids 0.70 lb/lb 0.70 kg/kg

Hazardous Air Pollutants (Clean Air Act, Section 112(b))

B55T104 LB/Gal kg/L

Volatile HAPS 0.04 0.004 Of solids 0.09 0.011 Of solids 0.00 lb/lb 0.00 kg/kg

Air Quality Data

Density of Organic Solvent Blend

6.53 lb/gal

Photochemically Reactive Yes

Waste Disposal

Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.

Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.

The addition of any material to this product can change the composition, hazards and risks of the product and may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.

Direct-to-Metal Alkyd Enamel Ultradeep Base

Not available.

Liquid.

US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Emergency telephone number of the company

Section 1. Identification

Manufacturer : THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Paint or paint related material.

B55T104

B55T104Product code :

Product Information Telephone Number

: US / Canada: (800) 524-5979 Mexico: Not Available

Transportation Emergency Telephone Number

: US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 3 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 1A TOXIC TO REPRODUCTION - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 ASPIRATION HAZARD - Category 1

Classification of the substance or mixture

Signal word : Danger

Hazard pictograms :

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 41.7% (oral), 43.1% (dermal), 41.7% (inhalation)

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Date of issue/Date of revision : 7/30/2025 Date of previous issue : 4/14/2025 Version : 38 1/28

B55T104 Direct-to-Metal Alkyd Enamel

SHW-85-NA-GHS-US

Section 2. Hazards identification

Precautionary statements

Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing, eye protection, face protection, or hearing protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.

Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. If skin irritation or rash occurs: Get medical advice or attention.

Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed.

Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

: DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations.

Flammable liquid and vapor.

May be fatal if swallowed and enters airways.

May cause an allergic skin reaction.

May cause drowsiness or dizziness.

May cause cancer.

May damage fertility or the unborn child.

Causes damage to organs through prolonged or repeated exposure. (lungs)

:Hazard statements

Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.

Supplemental label elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:

This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.

Section 3. Composition/information on ingredients

Light Aliphatic Hydrocarbon ≥25 - ≤50 64742-47-8 Kaolin ≤10 1332-58-7 Talc ≤10 14807-96-6 Light Aromatic Hydrocarbons ≤3 64742-95-6 trimethylbenzene ≤3 25551-13-7 Xylene, mixed isomers <1 1330-20-7 1-Methyl-2-Pyrrolidone <1 872-50-4 1,3,5-Trimethylbenzene <1 108-67-8 1,2,4-Trimethylbenzene <1 95-63-6 Hydrotreated Heavy Petroleum Naphtha ≤1 64742-48-9 Methyl Ethyl Ketoxime <1 96-29-7 Ethylbenzene ≤0.3 100-41-4

Ingredient name Identifiers% by weight

Other means of identification

: Not available.

Substance/mixture

CAS number/other identifiers

: Mixture

Date of issue/Date of revision : 7/30/2025 Date of previous issue : 4/14/2025 Version : 38 2/28

B55T104 Direct-to-Metal Alkyd Enamel

Section 3. Composition/information on ingredients Cobalt 2-Ethylhexanoate ≤0.3 136-52-7 Cumene ≤0.3 98-82-8 1,2,3-Trimethylbenzene ≤0.3 526-73-8 Crystalline Silica, respirable powder ≤0.3 14808-60-7 Zirconium 2-Ethylhexanoate ≤0.3 22464-99-9 Calcium 2-Ethylhexanoate ≤0.3 136-51-6 Methyl Isobutyl Ketone ≤0.3 108-10-1 2-(2-Methoxyethoxy)-ethanol ≤0.3 111-77-3

Occupational exposure limits, if available, are listed in Section 8.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.

:Ingestion

Skin contact : May cause an allergic skin reaction.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Eye contact : No specific data.

Potential acute health effects

Date of issue/Date of revision : 7/30/2025 Date of previous issue : 4/14/2025 Version : 38 3/28

B55T104 Direct-to-Metal Alkyd Enamel

Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:

nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following:

nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following:

irritation redness reduced fetal weight increase in fetal deaths skeletal malformations

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon dioxide carbon monoxide phosphorus oxides metal oxide/oxides

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.

Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Date of issue/Date of revision : 7/30/2025 Date of previous issue : 4/14/2025 Version : 38 4/28

B55T104 Direct-to-Metal Alkyd Enamel

Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Flammable liquid.Remark :

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Dispose of via a licensed waste disposal contractor.

Contaminated absorbent material may pose the same hazard as the spilled product.

Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations.

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.

Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

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Section 7. Handling and storage Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area.

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2024) [Kerosene] A3. Absorbed through skin.

TWA 8 hours: 200 mg/m³ (as total hydrocarbon vapor).

Kaolin 1332-58-7 ACGIH TLV (United States, 1/2024) A4.

TWA 8 hours: 2 mg/m³. Form: Respirable fraction.

NIOSH REL (United States, 10/2020) TWA 10 hours: 10 mg/m³. Form: Total.

TWA 10 hours: 5 mg/m³. Form: Respirable fraction.

OSHA PEL (United States, 5/2018) TWA 8 hours: 15 mg/m³. Form: Total dust.

TWA 8 hours: 5 mg/m³. Form: Respirable fraction.

Talc 14807-96-6 ACGIH TLV (United States, 1/2024) A4.

TWA 8 hours: 2 mg/m³. Form: Respirable fraction.

NIOSH REL (United States, 10/2020) TWA 10 hours: 2 mg/m³. Form: Respirable fraction.

Light Aromatic Hydrocarbons 64742-95-6 None.

trimethylbenzene 25551-13-7 ACGIH TLV (United States, 1/2024)

[trimethyl benzene, isomers] TWA 8 hours: 10 ppm.

Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2024) [p-xylene and mixtures containing p-xylene] A4. Ototoxicant.

TWA 8 hours: 20 ppm.

OSHA PEL (United States, 5/2018) [Xylenes] TWA 8 hours: 100 ppm.

TWA 8 hours: 435 mg/m³.

1-Methyl-2-Pyrrolidone 872-50-4 OARS WEEL (United States, 9/2024) Absorbed through skin.

TWA 8 hours: 15 ppm.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Control parameters

CAS #

Occupational exposure limits(OSHA United States)

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Section 8. Exposure controls/personal protection STEL 15 minutes: 120 mg/m³.

STEL 15 minutes: 30 ppm.

TWA 8 hours: 60 mg/m³.

1,3,5-Trimethylbenzene 108-67-8 ACGIH TLV (United States, 1/2024) [trimethyl benzene, isomers] TWA 8 hours: 10 ppm.

NIOSH REL (United States, 10/2020) TWA 10 hours: 25 ppm.

TWA 10 hours: 125 mg/m³.

1,2,4-Trimethylbenzene 95-63-6 ACGIH TLV (United States, 1/2024) A4.

TWA 8 hours: 10 ppm.

NIOSH REL (United States, 10/2020) TWA 10 hours: 25 ppm.

TWA 10 hours: 125 mg/m³.

Hydrotreated Heavy Petroleum Naphtha 64742-48-9 None.

Methyl Ethyl Ketoxime 96-29-7 OARS WEEL (United States, 9/2024) Skin sensitizer.

TWA 8 hours: 10 ppm.

Ethylbenzene 100-41-4 ACGIH TLV (United States, 1/2024) A3.

Ototoxicant.

TWA 8 hours: 20 ppm.

NIOSH REL (United States, 10/2020) TWA 10 hours: 100 ppm.

TWA 10 hours: 435 mg/m³.

STEL 15 minutes: 125 ppm.

STEL 15 minutes: 545 mg/m³.

OSHA PEL (United States, 5/2018) TWA 8 hours: 100 ppm.

TWA 8 hours: 435 mg/m³.

Cobalt 2-Ethylhexanoate 136-52-7 ACGIH TLV (United States, 1/2024) [cobalt and inorganic compounds] A3. Skin sensitizer , Inhalation sensitizer.

TWA 8 hours: 0.02 mg/m³ (as Co).

Cumene 98-82-8 ACGIH TLV (United States, 1/2024) A3.

TWA 8 hours: 5 ppm.

NIOSH REL (United States, 10/2020) Absorbed through skin.

TWA 10 hours: 50 ppm.

TWA 10 hours: 245 mg/m³.

OSHA PEL (United States, 5/2018) Absorbed through skin.

TWA 8 hours: 50 ppm.

TWA 8 hours: 245 mg/m³.

1,2,3-Trimethylbenzene 526-73-8 ACGIH TLV (United States, 1/2024) [trimethyl benzene, isomers] TWA 8 hours: 10 ppm.

NIOSH REL (United States, 10/2020) TWA 10 hours: 25 ppm.

TWA 10 hours: 125 mg/m³.

Crystalline Silica, respirable powder 14808-60-7 ACGIH TLV (United States, 1/2024) [Silica, crystalline] A2.

TWA 8 hours: 0.025 mg/m³. Form:

Respirable fraction.

NIOSH REL (United States, 10/2020)

[SILICA, CRYSTALLINE] NIA.

TWA 10 hours: 0.05 mg/m³. Form:

respirable dust.

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OSHA PEL (United States, 5/2018) [Silica, crystalline] TWA 8 hours: 50 µg/m³. Form: Respirable dust.

OSHA PEL Z3 (United States, 6/2016) TWA 8 hours: 250 / (%SiO₂+5) mppcf.

Form: Respirable.

TWA 8 hours: 10 / (%SiO₂+2) mg/m³. Form:

Respirable.

Zirconium 2-Ethylhexanoate 22464-99-9 ACGIH TLV (United States, 1/2024) [Zirconium and compounds] A4.

TWA 8 hours: 5 mg/m³ (as Zr).

STEL 15 minutes: 10 mg/m³ (as Zr).

NIOSH REL (United States, 10/2020) [zirconium compounds] TWA 10 hours: 5 mg/m³ (as Zr).

STEL 15 minutes: 10 mg/m³ (as Zr).

OSHA PEL (United States, 5/2018) [Zirconium compounds] TWA 8 hours: 5 mg/m³ (as Zr).

Calcium 2-Ethylhexanoate 136-51-6 None.

Methyl Isobutyl Ketone 108-10-1 ACGIH TLV (United States, 1/2024) A3.

TWA 8 hours: 20 ppm.

STEL 15 minutes: 75 ppm.

NIOSH REL (United States, 10/2020) TWA 10 hours: 50 ppm.

TWA 10 hours: 205 mg/m³.

STEL 15 minutes: 75 ppm.

STEL 15 minutes: 300 mg/m³.

OSHA PEL (United States, 5/2018) TWA 8 hours: 100 ppm.

TWA 8 hours: 410 mg/m³.

2-(2-Methoxyethoxy)-ethanol 111-77-3 None.

Petroleum refining, hydrotreated light distillate 64742-47-8 CA British Columbia Provincial (Canada, 9/2024) [kerosene/jet fuels] Absorbed through skin.

TWA 8 hours: 200 mg/m³ (as total hydrocarbon vapour). Notes: Application restricted to conditions in which there are negligible aerosol exposures.

CA Ontario Provincial (Canada, 6/2019) Absorbed through skin.

TWA 8 hours: 200 mg/m³ (as total hydrocarbon vapour).

CA Quebec Provincial (Canada, 2/2024) [kerosene] C3. Absorbed through skin.

TWAEV 8 hours: 200 mg/m³.

CA Alberta Provincial (Canada, 3/2023) [Kerosene/Jet fuels] Absorbed through skin.

OEL 8 hours: 200 mg/m³ (as total hydrocarbon vapour).

Kaolin 1332-58-7 CA Saskatchewan Provincial (Canada, 4/2021)

Ingredient name Exposure limits

Occupational exposure limits (Canada)

CAS #

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STEL 15 minutes: 4 mg/m³. Form:

respirable fraction.

TWA 8 hours: 2 mg/m³. Form: respirable fraction.

CA British Columbia Provincial (Canada, 9/2024) TWA 8 hours: 2 mg/m³. Form: Respirable.

Notes: the value is for particulate matter containing no asbestos and less than 1% crystalline silica.

CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 2 mg/m³. Form: Respirable particulate matter..

CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 2 mg/m³. Form: respirable aerosol fraction.

CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 2 mg/m³. Form: Respirable.

talc (none asbestiform) 14807-96-6 CA Saskatchewan Provincial (Canada, 4/2021) TWA 8 hours: 2 mg/m³. Form: respirable fraction.

CA British Columbia Provincial (Canada, 9/2024) TWA 8 hours: 2 mg/m³. Form: Respirable.

Notes: the value is for particulate matter containing no asbestos and less than 1% crystalline silica.

CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 2 mg/m³. Form: Respirable particulate matter..

TWA 8 hours: 2 fibers/cm³.

CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 2 mg/m³. Form: respirable aerosol fraction.

CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 2 mg/m³. Form: Respirable particulate.

Trimethylbenzene 25551-13-7 CA Saskatchewan Provincial (Canada, 4/2021) [Trimethyl benzene] STEL 15 minutes: 30 ppm.

TWA 8 hours: 25 ppm.

CA British Columbia Provincial (Canada, 9/2024) [trimethyl benzene (mixed isomers)] TWA 8 hours: 25 ppm.

CA Ontario Provincial (Canada, 6/2019) [Trimethyl benzene (mixed isomers)] TWA 8 hours: 25 ppm.

CA Quebec Provincial (Canada, 2/2024) [Trimethyl benzene] Sensitizer.

TWAEV 8 hours: 25 ppm.

CA Alberta Provincial (Canada, 3/2023) [Trimethyl benzene] OEL 8 hours: 123 mg/m³.

OEL 8 hours: 25 ppm.

Xylene 1330-20-7 CA Saskatchewan Provincial (Canada, Date of issue/Date of revision : 7/30/2025 Date of previous issue : 4/14/2025 Version : 38 9/28

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4/2021) [Xylene] STEL 15 minutes: 150 ppm.

TWA 8 hours: 100 ppm.

CA British Columbia Provincial (Canada, 9/2024) [xylene (o, m & p isomers)] TWA 8 hours: 100 ppm.

STEL 15 minutes: 150 ppm.

CA Ontario Provincial (Canada, 6/2019) [Xylene (o-, m-, p-isomers)] STEL 15 minutes: 150 ppm.

TWA 8 hours: 100 ppm.

CA Quebec Provincial (Canada, 2/2024) [Xylene] TWAEV 8 hours: 100 ppm.

TWAEV 8 hours: 434 mg/m³.

STEV 15 minutes: 150 ppm.

STEV 15 minutes: 651 mg/m³.

CA Alberta Provincial (Canada, 3/2023) [Dimethylbenzene] OEL 8 hours: 100 ppm.

OEL 15 minutes: 651 mg/m³.

OEL 15 minutes: 150 ppm.

OEL 8 hours: 434 mg/m³.

N-Methyl pyrrolidone 872-50-4 CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 400 mg/m³.

Methyl Ethyl Ketoxime 96-29-7 OARS WEEL (United States, 9/2024) Skin sensitizer.

TWA 8 hours: 10 ppm.

Ethylbenzene 100-41-4 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 125 ppm.

TWA 8 hours: 100 ppm.

CA British Columbia Provincial (Canada, 9/2024) Carc 2B.

TWA 8 hours: 20 ppm.

CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 20 ppm.

CA Quebec Provincial (Canada, 2/2024) C3.

TWAEV 8 hours: 20 ppm.

CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 100 ppm.

OEL 8 hours: 434 mg/m³.

OEL 15 minutes: 543 mg/m³.

OEL 15 minutes: 125 ppm.

Cobalt 2-Ethylhexanoate 136-52-7 CA Saskatchewan Provincial (Canada, 4/2021) [Cobalt and inorganic compounds] STEL 15 minutes: 0.06 mg/m³ (measured as Co).

TWA 8 hours: 0.02 mg/m³ (measured as Co).

CA British Columbia Provincial (Canada, 9/2024) [cobalt and inorganic compounds] Carc 2B. Skin sensitizer.

TWA 8 hours: 0.02 mg/m³ (as Co). Form:

Inhalable.

CA Ontario Provincial (Canada, 6/2019)

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[Cobalt and inorganic compounds] TWA 8 hours: 0.02 mg/m³ (as Co).

CA Quebec Provincial (Canada, 2/2024) [Cobalt elemental, and inorganic compounds] C3. Skin sensitizer , Inhalation sensitizer.

TWAEV 8 hours: 0.02 mg/m³ (as Co). Form:

inhalable aerosol fraction.

Cumene 98-82-8 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 74 ppm.

TWA 8 hours: 50 ppm.

CA British Columbia Provincial (Canada, 9/2024) Carc 2B.

TWA 8 hours: 25 ppm.

STEL 15 minutes: 75 ppm.

CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 50 ppm.

CA Quebec Provincial (Canada, 2/2024) C3.

TWAEV 8 hours: 5 ppm.

CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 50 ppm.

OEL 8 hours: 246 mg/m³.

Quartz 14808-60-7 CA Saskatchewan Provincial (Canada, 4/2021) TWA 8 hours: 0.05 mg/m³. Form: respirable fraction.

CA British Columbia Provincial (Canada, 9/2024) [silica, crystalline - alpha quartz and cristobalite] Carc 2A, Carc 1.

TWA 8 hours: 0.025 mg/m³. Form:

Respirable.

CA Ontario Provincial (Canada, 6/2019) [Silica, Crystalline (Quartz/Tripoli)] TWA 8 hours: 0.1 mg/m³. Form: Respirable particulate matter..

CA Quebec Provincial (Canada, 2/2024) [Silica Crystalline -Quartz] C2.

TWAEV 8 hours: 0.1 mg/m³. Form:

respirable aerosol fraction.

CA Alberta Provincial (Canada, 3/2023) A2.

OEL 8 hours: 0.025 mg/m³. Form:

Respirable particulate.

Zirconium 2-Ethylhexanoate 22464-99-9 CA British Columbia Provincial (Canada, 9/2024) [zirconium and compounds] TWA 8 hours: 5 mg/m³ (as Zr).

STEL 15 minutes: 10 mg/m³ (as Zr).

CA Ontario Provincial (Canada, 6/2019) [Zirconium and compounds] STEL 15 minutes: 10 mg/m³ (as Zr).

TWA 8 hours: 5 mg/m³ (as Zr).

CA Quebec Provincial (Canada, 2/2024) [Zirconium and compounds] TWAEV 8 hours: 5 mg/m³ (as Zr).

STEV 15 minutes: 10 mg/m³ (as Zr).

CA Alberta Provincial (Canada, 3/2023)

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[Zirconium and compounds] OEL 8 hours: 5 mg/m³ (as Zr).

OEL 15 minutes: 10 mg/m³ (as Zr).

Methyl isobutyl ketone 108-10-1 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 75 ppm.

TWA 8 hours: 50 ppm.

CA British Columbia Provincial (Canada, 9/2024) Carc 2B.

TWA 8 hours: 20 ppm.

STEL 15 minutes: 75 ppm.

CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 20 ppm.

STEL 15 minutes: 75 ppm.

CA Quebec Provincial (Canada, 2/2024) C3.

TWAEV 8 hours: 20 ppm.

STEV 15 minutes: 75 ppm.

CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 205 mg/m³.

OEL 8 hours: 50 ppm.

OEL 15 minutes: 75 ppm.

OEL 15 minutes: 307 mg/m³.

Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2024) [Kerosene] A3. Absorbed through skin.

TWA 8 hours: 200 mg/m³ (as total hydrocarbon vapor).

trimethylbenzene 25551-13-7 NOM-010-STPS-2014 (Mexico, 4/2016) [Trimetil benceno, mezcla de Isómeros] TWA 8 hours: 25 ppm.

Cobalt 2-Ethylhexanoate 136-52-7 NOM-010-STPS-2014 (Mexico, 4/2016) [Cobalto y compuestos inorgánicos] A3.

TWA 8 hours: 0.02 mg/m³ (as Co).

Cumene 98-82-8 NOM-010-STPS-2014 (Mexico, 4/2016) TWA 8 hours: 50 ppm.

Zirconium 2-Ethylhexanoate 22464-99-9 NOM-010-STPS-2014 (Mexico, 4/2016) [Circonio y compuestos] A4.

TWA 8 hours: 5 mg/m³ (as Zr).

STEL 15 minutes: 10 mg/m³ (as Zr).

Methyl Isobutyl Ketone 108-10-1 NOM-010-STPS-2014 (Mexico, 4/2016) A3.

TWA 8 hours: 50 ppm.

STEL 15 minutes: 75 ppm.

Ingredient name Exposure limits

Occupational exposure limits (Mexico)

CAS #

Biological exposure indices

Xylene, mixed isomers ACGIH BEI (United States, 1/2024) [xylenes (technical or commercial grades)] BEI: 0.3 g/g creatinine, methylhippuric acids [in urine]. Sampling time: end of shift.

1-Methyl-2-Pyrrolidone ACGIH BEI (United States, 1/2024) BEI: 100 mg/l, 5-hydroxy-N-methyl- 2-pyrrolidone [in urine]. Sampling time: end of

Ingredient name Exposure indices

(United States)

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Ethylbenzene ACGIH BEI (United States, 1/2024) BEI: 150 mg/g creatinine, sum of mandelic acid and phenylglyoxylic acid [in urine].

Sampling time: end of shift.

Cobalt 2-Ethylhexanoate ACGIH BEI (United States, 1/2024) [cobalt and inorganic compounds including cobalt oxides] BEI: 15 μg/l, not combined with tungsten carbide - cobalt [in urine]. Sampling time: end of shift at end of workweek.

BEI: Nonquantitative: Biological monitoring should be considered for this compound based on the review; however, a specific BEI® could not be determined due to insufficient data., cobalt with tungsten carbide - cobalt [in urine]. Sampling time: end of shift at end of workweek.

Methyl Isobutyl Ketone ACGIH BEI (United States, 1/2024) BEI: 1 mg/l, methyl isobutyl ketone [in urine].

Sampling time: end of shift.

Biological exposure indices (Canada)

Biological exposure indices (Mexico)

No exposure indices known.

1-Methyl-2-Pyrrolidone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 100 mg/L, 5-hydroxy-n-methyl- 2-pyrrolidone [in urine]. Sampling time: at the end of the work shift.

Cobalt 2-Ethylhexanoate Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) [cobalto] BEI: 1 µg/l [Basal level.The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu; semi-quantitative.The biological determinant is an indicator of chemical exposure, but the quantitative interpretation of the measure is ambiguous. These biological determinants should be used as a screening test if a quantitative test is not possible.], cobalt [in blood]. Sampling time: at the end of

Ingredient name Exposure indices

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Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Eye/face protection

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls the shift at the end of the work week.

BEI: 15 µg/l [Basal level.The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu], cobalt [in urine]. Sampling time: at the end of the shift at the end of the work week.

Methyl Isobutyl Ketone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 2 mg/L, MIBK [in urine]. Sampling time:

at the end of the work shift.

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Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Respiratory protection :

Section 9. Physical and chemical properties

Physical state

Melting point/freezing point

Vapor pressure

Relative density

Liquid.

Not available.

1.07

4.1 [Air = 1]

Not available.Odor pH

Clear.Color

Evaporation rate 0.23 (butyl acetate = 1)

Auto-ignition temperature

Flash point

Not available.

Closed cup: 38°C (100.4°F) [Pensky-Martens Closed Cup]

Not applicable.

Not applicable.

Viscosity Dynamic (room temperature): Not available.

Kinematic (room temperature): Not available.

Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt)

Not available.Odor threshold

Partition coefficient: n-octanol/water

Appearance

: 148°C (298.4°F)

: Flammable liquid.

: Lower: 0.7% Upper: 7%

Decomposition temperature : Not available.

Heat of combustion : 17.541 kJ/g

: Not applicable.

Boiling point or initial boiling point and boiling range

Flammability

Lower and upper explosion limit/flammability limit

Relative vapor density

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

0.51 kPa (3.8 mm Hg)

Solubility(ies) :

Media Result cold water Not soluble

Density : 1.07 g/cm³

Particle characteristics

Median particle size : Not applicable.

Molecular weight

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Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Reactive or incompatible with the following materials:

oxidizing materials

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

Information on toxicological effects

Light Aromatic Hydrocarbons Rat - Oral - LD50 8400 mg/kg Toxic effects: Behavioral - Somnolence (general depressed activity) Behavioral - Tremor Lung, Thorax, or Respiration - Other changes trimethylbenzene Rat - Oral - LD50 8970 mg/kg

Xylene, mixed isomers Rat - Oral - LD50 4300 mg/kg Toxic effects: Liver - Other changes Kidney, Ureter, and Bladder - Other changes Rat - Inhalation - LC50 Gas.

6700 ppm [4 hours] Toxic effects: Behavioral - Somnolence (general depressed activity)

1-Methyl-2-Pyrrolidone Rat - Oral - LD50 3914 mg/kg Rabbit - Dermal - LD50 8 g/kg

1,3,5-Trimethylbenzene Rat - Oral - LD50 5000 mg/kg Rat - Inhalation - LC50 Vapor 24000 mg/m³ [4 hours]

1,2,4-Trimethylbenzene Rat - Oral - LD50 5 g/kg Rat - Inhalation - LC50 Vapor 18000 mg/m³ [4 hours]

Hydrotreated Heavy Petroleum Naphtha Rat - Oral - LD50 >6 g/kg Rat - Inhalation - LC50 Vapor 8500 mg/m³ [4 hours] Toxic effects: Lung, Thorax, or Respiration - Other changes

Product/ingredient name Result

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Section 11. Toxicological information Methyl Ethyl Ketoxime Rat - Oral - LD50

930 mg/kg Ethylbenzene Rat - Oral - LD50

3500 mg/kg Toxic effects: Liver - Other changes Kidney, Ureter, and Bladder - Other changes Rabbit - Dermal - LD50 >5000 mg/kg

Cobalt 2-Ethylhexanoate Rabbit - Dermal - LD50 >5 g/kg Toxic effects: Skin After topical exposure - Primary irritation Rat - Oral - LD50

1.22 g/kg Toxic effects: Behavioral - Ataxia Behavioral - Coma

Cumene Rat - Oral - LD50 1400 mg/kg Toxic effects: Gastrointestinal - Gastritis Rat - Inhalation - LC50 Vapor 39000 mg/m³ [4 hours]

Zirconium 2-Ethylhexanoate Rabbit - Dermal - LD50 >5 g/kg Rat - Oral - LD50 >5 g/kg Toxic effects: Behavioral - Somnolence (general depressed activity)

Methyl Isobutyl Ketone Rat - Oral - LD50 2080 mg/kg

Conclusion/Summary [Product] : Not available.

Skin corrosion/irritation

Talc Human - Skin - Mild irritant Duration of treatment/exposure: 72 hours Amount/concentration applied: 300 ug I trimethylbenzene Rabbit - Skin - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 500 mg

Xylene, mixed isomers Rat - Skin - Mild irritant Duration of treatment/exposure: 8 hours Amount/concentration applied: 60 uL Rabbit - Skin - Moderate irritant Duration of…