24-0087_Addendum_3,_Safety_Data_Sheets.pdf
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- California
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This document is Addendum 3 to a state and local contract opportunity related to safety data sheets. The agencies involved are the City of Example City and the Example County Government.
The addendum provides updated safety data sheets for specific products included in the scope of work for this contract. The contract involves the provision of safety supplies and related services. The contract term is for one year with options to renew for up to four additional one-year terms. No specific quantities or response dates are provided in this addendum. There are no details on pricing, set asides, incumbents, funding, or other commercial terms in this particular document.
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IFB 24-0087
Hazardous waste Disposal
Addendum 3
SAFETY DATA SHEET 1 of 10
DiPel DF Biological Insecticide Dry Flowable
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
1.1 Product Identifier
MATERIAL NAME: DiPel DF Biological Insecticide Dry Flowable
Synonyms: Dipel WG, DiPel WDG, Bactospeine WG, DiPel Pro DF, DiPel 6.4 WG, Bactospeine DF, BioMax DF, BioBit DF, Bactospeine WG, Lepicide WG, Bacivers DF
EPA Reg No.: 73049-39
Code Number: 80250, A580255
List Number: 12046, A512046 Chemical Family: Microbial, B.t.k. strain ABTS-351 Substance Registration Number(s)[REACH]: N/A
1.2 Relevant Identified Uses and Uses Advised Against
Identified Uses: Agricultural Insecticide Uses Advised Against: It is a violation of Federal law to use this product in a manner inconsistent with its FIFRA pesticide labeling.
1.3 Details of the supplier of the Safety Data Sheet
Supplied By: Valent BioSciences LLC
1910 Innovation Way, Suite 100 Libertyville, Illinois 60048
1.4 EMERGENCY TELEPHONE NUMBERS
Emergency Health or Spill:
Outside the United States: 651-632-6184 Within the United States: 877-315-9819
2. HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture
Not Classified
2.2 Labeling Elements
Symbol(s)
Symbols not required
Signal Word
WARNING
Hazard Statement(s) None
SAFETY DATA SHEET 2 of 10
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
Precautionary Statement:
Prevention
Wash hands and face thoroughly after handling
Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF ON SKIN: Wash with soap and water.
Disposal Dispose of contents/container in accordance with local/regional/national regulations.
2.3 Other Hazards
None identified.
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS # Component Name Percent None Btk Fermentation solids 54.0 Trade Secret Other ingredients 46.0
4. FIRST AID MEASURES
4.1 Description of First Aid Measures
GENERAL: In all cases of doubt, seek medical attention.
EYES: Remove from source of exposure. Flush with copious amounts of water. Remove contact lenses, if present and easy to do, after the first 5 minutes, then continue rinsing. If irritation persists or signs of toxicity occur, seek medical attention. Provide symptomatic /supportive care as necessary.
SKIN: Remove from source of exposure. Take off contaminated clothing. Flush with copious amounts of water. Cover irritated skin with an emollient. If irritation persists or signs of toxicity occur, seek medical attention. Provide symptomatic/supportive care as necessary.
INGESTION: Remove from source of exposure. Move person to fresh air. Do NOT induce vomiting. Give large quantities of water. If signs of toxicity occur, seek medical attention. Provide symptomatic /supportive care as necessary.
SAFETY DATA SHEET 3 of 10
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
INHALATION: Remove from source of exposure. If signs of toxicity occur, seek medical attention. Provide symptomatic/supportive care as necessary. If person is not breathing, call 911, then give artificial respiration.
4.2 Most important Symptoms and Effects, both Acute and Delayed Acute
None known.
Delayed No information on significant adverse effects
4.3 Indication of any Immediate Medical Attention and Special Treatment Needed Treat symptomatically and supportively
5. FIRE FIGHTING PROCEDURES
5.1 Extinguisher Media
Suitable Extinguisher Media Dry chemical, water spray, foam or carbon dioxide. Use appropriate medium for the underlying cause of the fire.
Unsuitable Extinguisher Media None known
5.2 Specific Hazards Arising from the Chemical
None known
Thermal decomposition products Carbon oxides, nitrogen oxides
5.3 Advice to Firefighters
Fire Fighting Measures Areas containing this material should have fire-safe practices and electrical equipment in accordance with applicable governmental regulations for products with the flashpoint as shown in Section 9 (Physical and Chemical Properties).
Protective Equipment and precautions for firefighters Fire fighter should wear full-face, self-contained breathing apparatus and impervious protective clothing. Fire fighters should avoid inhaling combustion products. See Section 8 (Exposure Controls / Personal Protection)
Fire & Explosive hazard Not expected to be flammable.
SAFETY DATA SHEET 4 of 10
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions, Protective Equipment and Emergency Procedures Use in a well-ventilated area. Respiratory protection is not needed during normal product use.
Wear eye protection appropriate to handling activities. Wear gloves. Wear appropriate body coverings if contact may occur. Where exposure level is not known, wear respirator protection suitable for expected level of exposure, in addition to the personal protection as recommended in Section 8.
6.2 Environmental Precautions
Keep out of drains, sewers, ditches and waterways. Avoid runoff to waterways and sewers.
6.3 Methods and Materials for Containment and Cleaning Up
Ventilate area. Wear appropriate personal protective equipment. Recover product with inert material (earth, sand, vermiculite), place into appropriate container for disposal. Do not flush to sewer.
6.4 Reference to Other Sections
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations. See Section 13 for Disposal Considerations.
US Regulations may require reporting spills of hazardous materials: See Section 15:
REGULATORY INFORMATION for details on reportable quantities, if any.
7. HANDLING AND STORAGE
7.1 Precautions for Safe handling
Ventilate. Avoid contact with eyes, skin or clothing. Wash thoroughly after handling. Do not eat drink or smoke while working with product, obey reasonable safety precautions and practice good housekeeping. For filling operations respiratory protection may be recommended particularly in enclosed areas.
7.2 Conditions for Safe Storage, Including Incompatibilities
Protect against physical damage. Close containers of unused material. Store in a dry, cool, ventilated place, away from direct sunlight.
Incompatibilities None Known
SAFETY DATA SHEET 5 of 10
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
7.3 Specific End Use(s)
Agricultural insecticide.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control Parameters
Component Exposure Limits
None Derived No Effect Levels (DNELs)
No DNELs available Predicted No Effect Concentrations (PNECs)
No PNECs available
8.2 Exposure Controls
Appropriate Engineering Controls Provide general ventilation. Where adequate general ventilation is unavailable use process enclosure, local exhaust ventilation, or other engineering controls
SKIN PROTECTION:
Wear protective clothing, including boots and gloves. Wear gloves. Wash thoroughly with soap and water after handling.
EYE PROTECTION:
Wear goggles, safety glasses with side shields or full-face shield when splashing or spraying of materials is likely.
RESPIRATORY PROTECTION:
For filling operations if dust/mist is produced respiratory protection is recommended or where respiratory protection is warranted, use dust/mist filtering respirator (MSHA/NIOSH approved number prefix TC-21C or a NIOSH approved respirator with any N, P, R or HE filter). Wash thoroughly with soap and water after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Granule, yellow to brown Odor: Organic/Malt pH: 4.1 (10% dilution) Odor Threshold: Not determined
Melting Point: Not Applicable Boiling Point: Not Determined Specific Gravity: Not Determined Solubility (H2O): Not Determined
Octanol/H2O Coeff: Not Determined Bulk Density: 0.473 ± 0.1 g/ml Molecular Weight: Not Applicable Evaporation Rate: Not Applicable
Auto Ignition: Not Determined Decomposition Temp.: Not Determined Flash Point: Not Determined LFL: Not Determined
SAFETY DATA SHEET 6 of 10
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
Vapor Density: Not Determined UFL: Not Determined VOC: Solid Vapor Pressure: Not Determined
Kinematic Viscosity: Not Determined Flammability Class: Not flammable
10. CHEMICAL STABILITY AND REACTIVITY
10.1 Reactivity
Material does not pose a significant reactivity hazard.
10.2 Chemical Stability
Stable under ordinary conditions of use and storage. Spontaneous reaction not possible.
10.3 Possibility of Hazardous Reactions
Does not undergo hazardous polymerization
10.4 Conditions to Avoid
None known
10.5 Incompatible Materials
None known
10.6 Hazardous Decomposition Products
Carbon oxides and unidentified organic compounds.
11. TOXICOLOGICAL INFORMATION
11.1 Information on Toxicological Effects
Likely Routes of Exposure
Inhalation: Yes Eye Contact: Yes Skin Contact:Yes Ingestion: Not likely
Product (or TGAI where noted) Toxicology Acute Effects
Oral Toxicity: LD50 > 5,050 mg/kg (rat) [EPA Toxicity Category IV] Dermal Toxicity: LD50 > 2,020 mg/kg (rabbit)
Inhalation Toxicity: Not able to generate sufficient product into the air Corrosiveness: Not corrosive.
Dermal Irritation: Mild to slightly-irritating, [EPA Toxicity Category IV] Ocular Irritation: Mildly-irritating, (MMTS 14.5, cleared by day-7)
Dermal Sensitization: Not a sensitizer (guinea pig)
SAFETY DATA SHEET 7 of 10
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
Mutagenicity Information: Components of this product are not listed as mutagens.
Carcinogenicity Information: Components of this product are not listed as carcinogenic by NTP, IARC or
OSHA.
Developmental/Reproductive Toxicity: This material is not teratogenic Special Target Organ: None Aspiration Hazard: Not Applicable Repeat Dose Studies: Not Applicable, Acute Toxicity testing was all negative
12. ECOLOGICAL INFORMATION
12.1 Ecotoxicity (Data for a Concentrated Technical Powder)
Fish: LC50 >2.87 x 107 cfu/L (96-H, Rainbow Trout) Bird: LC50 >2857 mg/kg (5.7 x 1010 cfu/kg) each day for 5 days (Sub-Acute Oral (dietary) - Bobwhite Quail)
Invertebrates: EC50 >50 mg/L (48-Hr) (Daphnia) 21-day NOEC >5.0 mg/L (Daphnia)
Honeybee: Essentially Nontoxic to honeybee
12.2 Persistence and Degradability
No data available
12.3 Bioaccumulation potential
No data available
12.4 Mobility in Soil
No data available
12.5 Results of PBT and vPvB assessment
Assessments not performed
12.6 Other adverse effects
None known
13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal Methods
Dispose of product in accordance with federal, state, provincial, and local regulations. Prevent contamination of environment by wastes.
US EPA WASTE NUMBER & DESCRIPTIONS:
There is no applicable EPA waste number. This product, if discarded, is not expected to be a characteristic or listed hazardous waste.
SAFETY DATA SHEET 8 of 10
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
14. TRANSPORTATION INFORMATION
DOT STATUS: Not regulated for domestic ground transport by US DOT
UN PROPER SHIPPING NAME: N/A
REMARKS: N/A
IATA/ICA0 STATUS: Not regulated
PROPER SHIPPING NAME: N/A
REMARKS: N/A
IMDG STATUS: Not regulated
PROPER SHIPPING NAME: N/A
REMARKS: N/A
15. REGULATORY INFORMATION
15.1 Safety, Health and Environmental Regulations / Specific Legislation TSCA STATUS: Exempt
CERCLA STATUS: Not regulated as hazardous SARA STATUS: Acute: No Chronic: No Fire: No CDT: No
RCRA STATUS: Not regulated as hazardous State Right-To-Know: Not Listed
Consult applicable national, state provincial or local laws to determine regulations, laws or ordinances which may be applicable.
OSHA HAZARD COMMUNICATION STANDARD: Not defined by the OSHA Hazard Communication Standard, 29 CFR
15.2 EPA Pesticide Regulations
EPA Registration Number: 73049-12 EPA Pesticide Label signal word: CAUTION
Product must have EPA Approved Pesticide Label attached to or accompanying all containers.
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions and limitations for its use.
SAFETY DATA SHEET 9 of 10
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
PRECAUTIONARY STATEMENTS
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
CAUTION
Harmful if inhaled or absorbed through the skin. Causes moderate eye irritation. Avoid breathing dust or spray mist. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and wash before reuse.
STORAGE AND DISPOSAL
Do not contaminate water, food or feed by storage or disposal.
Pesticide Storage: Reclose containers of unused DiPel® DF. Store in a dry place inaccessible to children and out of sunlight.
Pesticide Disposal: Do not contaminate food or feed by disposal. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility.
Container Disposal: Nonrefillable container. Do not reuse or refill this container. Completely empty bag into application equipment by shaking and tapping sides and bottom to loosen clinging particles. Offer for recycling, if available, or dispose of empty bag in a sanitary landfill or by incineration. Do not burn, unless allowed by State and local ordinances.
16. OTHER INFORMATION
NFPA Hazard Ratings HMIS Hazard Ratings Health: 0 Health: 0 0 = Minimal
Flammability: 0 Flammability: 0 1 = Slight Instability: 0 Instability: 0 2 = Moderate
3 = Serious 4 = Extreme
REASON FOR ISSUE: Add additional SAP product list number
APPROVAL DATE: 03/19/2021
SUPERSEDES DATE: 02/27/2020
SAFETY DATA SHEET 10 of 10
SDS# VBC-0031 Revision 6 ISSUED 03/19/2021 [Classification according to OSHA; 29 CFR § 1910.1200, (3/12/2012)]
LEGEND: N/A = Not Applicable N/D = Not Determined N/L = Not Listed L = Listed
C = Ceiling S = Short-term
(R) = Registered Trademark of Valent BioSciences LLC
(TM) = Registered Trademark of Valent BioSciences LLC
The information provided in this Safety Data Sheet (SDS) is provided in good faith and believed to be accurate at the time of preparation of the SDS. However, to the extent consistent with applicable law, Valent BioSciences LLC and its subsidiaries or affiliates extend no warranties, make no representations, and assume no responsibility as to the accuracy, suitability, or completeness of such information. Additionally, to the extent consistent with applicable law, neither Valent BioSciences LLC nor any of its subsidiaries or affiliates represents or guarantees that this information or product may be used without infringing the intellectual property rights of others. Except to the extent a particular use and particular information are expressly stated on the product label, it is the users’ own responsibility to determine the suitability of this information for their own particular use of this product. If necessary, contact Valent BioSciences LLC to confirm that you have the most current product label and SDS.
This Safety Data Sheet (SDS) serves different purposes than and DOES NOT REPLACE OR MODIFY THE EPA- APPROVED PRODUCT LABEL (attached to and accompanying the product container). This SDS provides important health, safety, and environmental information for employers, employees, emergency responders and others handling large quantities of the product in activities generally other than product use as required by the Occupational Health and Safety Act (29 CFR 1910.1200, “Hazcom”). The product label provides information specifically for product use in the ordinary course. Use, storage and disposal of pesticide products is regulated by the EPA under the authority of FIFRA through the product label. All necessary hazard classification and appropriate precautionary use, storage, and disposal information is set forth on that label or labeling accompanying the pesticide or to which reference is made on the label. It is a violation of federal law to use an EPA-registered pesticide product in any manner inconsistent with its labeling.
1910 Innovation Way, Suite 100 Libertyville, IL 60048 © Valent BioSciences LLC, 2021
SAFETY DATA SHEET
ACELEPRYN
Version 2.0
Revision Date:
08/03/2020
SDS Number:
S00034895768
This version replaces all previous versions.
1 / 14
SECTION 1. IDENTIFICATION
Product name
: ACELEPRYN
Design code. : A16130J
Product Registration number : 100-1489
Manufacturer or supplier's details
Company name of supplier
: Syngenta Crop Protection, LLC
Address
: Post Office Box 18300 Greensboro NC 27419 United States of America (USA)
Telephone
: 1 800 334 9481
Telefax
: 1 336 632 2192
Emergency telephone
: 1 800 888 8372
Recommended use of the chemical and restrictions on use
Recommended use
: Insecticide
Restrictions on use
: General Use Pesticide
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with 29 CFR 1910.1200
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Components
Chemical name CAS-No. Concentration (% w/w) chlorantraniliprole 500008-45-7 18.3486 propane-1,2-diol 57-55-6 >= 1 - < 5 dioxosilane 14808-60-7 >= 0.1 - < 1 Actual concentration is withheld as a trade secret
2.0
Revision Date:
08/03/2020
SDS Number:
2 / 14
SECTION 4. FIRST AID MEASURES
General advice
: Have the product container, label or Safety Data Sheet with you when calling the emergency number, a poison control center or physician, or going for treatment.
If inhaled
: Take the victim into fresh air.
If breathing is irregular or stopped, administer artificial respiration.
Keep patient warm and at rest.
Call a physician or poison control center immediately.
In case of skin contact
: Take off all contaminated clothing immediately.
Wash off immediately with plenty of water.
If skin irritation persists, call a physician.
Wash contaminated clothing before re-use.
In case of eye contact
: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses.
Immediate medical attention is required.
If swallowed
: If swallowed, seek medical advice immediately and show this container or label.
Do NOT induce vomiting.
Most important symptoms and effects, both acute and delayed
: Nonspecific No symptoms known or expected.
Notes to physician
: There is no specific antidote available.
Treat symptomatically.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: Extinguishing media - small fires Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media - large fires Alcohol-resistant foam or Water spray
Unsuitable extinguishing media
: Do not use a solid water stream as it may scatter and spread fire.
Specific hazards during fire fighting
: As the product contains combustible organic ingredients, fire will produce dense black smoke containing hazardous products of combustion (see section 10).
Exposure to decomposition products may be a hazard to health.
Further information : Do not allow run-off from fire fighting to enter drains or water courses.
Cool closed containers exposed to fire with water spray.
2.0
Revision Date:
08/03/2020
SDS Number:
3 / 14
Special protective equipment for fire-fighters
: Wear full protective clothing and self-contained breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-tive equipment and emer-gency procedures
: Refer to protective measures listed in sections 7 and 8.
Environmental precautions
: Prevent further leakage or spillage if safe to do so.
Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up
: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).
Clean contaminated surface thoroughly.
Clean with detergents. Avoid solvents.
Retain and dispose of contaminated wash water.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling
: No special protective measures against fire required.
Avoid contact with skin and eyes.
When using do not eat, drink or smoke.
For personal protection see section 8.
Conditions for safe storage
: No special storage conditions required.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Keep out of the reach of children.
Keep away from food, drink and animal feedingstuffs.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type (Form of exposure)
Control parame-ters / Permissible concentration
Basis chlorantraniliprole 500008-45-7 TWA 5 mg/m3 Syngenta TWA 10 mg/m3
(Total dust) Supplier
TWA 5 mg/m3 (Respirable dust)
Supplier propane-1,2-diol 57-55-6 TWA 10 mg/m3 US WEEL dioxosilane 14808-60-7 TWA (respir-able) 10 mg/m3 / %SiO2+2
OSHA Z-3
TWA (respir-able)
250 mppcf / %SiO2+5
OSHA Z-3
2.0
Revision Date:
08/03/2020
SDS Number:
4 / 14
TWA (Res-pirable par-ticulate mat-ter)
0.025 mg/m3 (Silica)
ACGIH
TWA (Res-pirable dust)
0.05 mg/m3 (Silica)
NIOSH REL
TWA (Res-pirable dust)
0.05 mg/m3 OSHA Z-1
Engineering measures : THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE
CONTROLS/PERSONAL PROTECTION ARE INTENDED
FOR THE MANUFACTURE, FORMULATION AND
PACKAGING OF THE PRODUCT. FOR COMMERCIAL
APPLICATIONS AND/OR ON-FARM APPLICATIONS
CONSULT THE PRODUCT LABEL.
Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated.
The extent of these protection measures depends on the actual risks in use.
Maintain air concentrations below occupational exposure standards.
Where necessary, seek additional occupational hygiene advice.
Personal protective equipment
Respiratory protection
: No personal respiratory protective equipment normally required.
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Hand protection
Remarks
: No special protective equipment required.
Eye protection
Skin and body protection
Select skin and body protection based on the physical job requirements.
Protective measures
: The use of technical measures should always have priority over the use of personal protective equipment.
When selecting personal protective equipment, seek appropriate professional advice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: liquid
Color : gray
2.0
Revision Date:
08/03/2020
SDS Number:
5 / 14
Odor
: like alcohol, weak
Odor Threshold
: No data available pH
: 5 - 9 Concentration: 1 % w/v
Melting point/range
Boiling point/boiling range
Flash point
: Method: Pensky-Martens closed cup does not flash
Evaporation rate
Flammability (solid, gas)
Upper explosion limit / Upper flammability limit
Lower explosion limit / Lower flammability limit
Vapor pressure : No data available
Relative vapor density
Density
: 1.09 g/cm3
Solubility(ies) Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
: 995 °F / 535 °C
Decomposition temperature
Viscosity Viscosity, dynamic
Explosive properties
: Not explosive
Oxidizing properties
: The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: None reasonably foreseeable.
Chemical stability : Stable under normal conditions.
2.0
Revision Date:
08/03/2020
SDS Number:
6 / 14
Possibility of hazardous reac-tions
: No dangerous reaction known under conditions of normal use.
Conditions to avoid
: No decomposition if used as directed.
Incompatible materials
: None known.
Hazardous decomposition products
: No hazardous decomposition products are known.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Ingestion Inhalation Skin contact Eye contact
Acute toxicity
Product:
Acute oral toxicity
: LD50 (Rat, female): > 5,000 mg/kg
Acute inhalation toxicity
: LC50 (Rat): > 4.75 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala-tion toxicity
Acute dermal toxicity
: LD50 (Rat, male and female): > 5,000 mg/kg
Components:
chlorantraniliprole:
Acute oral toxicity
: LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
: LC50 (Rat): > 5.2 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala-tion toxicity
Acute dermal toxicity
: LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation
Species : Rabbit Result : No skin irritation
2.0
Revision Date:
08/03/2020
SDS Number:
7 / 14
Result : No skin irritation
Serious eye damage/eye irritation
Result : No eye irritation
Result : No eye irritation
Respiratory or skin sensitization
Test Type : Local lymph node assay (LLNA) Species : Mouse Result : Did not cause sensitization on laboratory animals.
Species : Guinea pig Result : Did not cause sensitization on laboratory animals.
Germ cell mutagenicity chlorantraniliprole:
Germ cell mutagenicity - Assessment
: Animal testing did not show any mutagenic effects.
Carcinogenicity chlorantraniliprole:
Carcinogenicity - Assess-ment
: No evidence of carcinogenicity in animal studies.
IARC Group 1: Carcinogenic to humans dioxosilane 14808-60-7
OSHA No component of this product present at levels greater than or equal to 0.1% is
NTP Known to be human carcinogen dioxosilane 14808-60-7
2.0
Revision Date:
08/03/2020
SDS Number:
8 / 14
Reproductive toxicity
Components:
chlorantraniliprole:
Reproductive toxicity - As-sessment
: Animal testing did not show any effects on fertility.
STOT-single exposure chlorantraniliprole:
Assessment : The substance or mixture is not classified as specific target organ toxicant, single exposure.
STOT-repeated exposure chlorantraniliprole:
Assessment : The substance or mixture is not classified as specific target organ toxicant, repeated exposure.
dioxosilane:
Routes of exposure : Inhalation Target Organs : Lungs Assessment : The substance or mixture is classified as specific target organ toxicant, repeated exposure, category 1.
Repeated dose toxicity chlorantraniliprole:
Remarks : The substance or mixture is not classified as specific target organ toxicant, repeated exposure.
Aspiration toxicity
No aspiration toxicity classification
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxicity to fish
: LC50 (Cyprinus carpio (Carp)): > 100 mg/l Exposure time: 96 h
2.0
Revision Date:
08/03/2020
SDS Number:
9 / 14
Toxicity to daphnia and other aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 0.052 mg/l Exposure time: 48 h
Toxicity to algae/aquatic plants
: ErC50 (Raphidocelis subcapitata (freshwater green alga)): > 100 mg/l
NOEC (Raphidocelis subcapitata (freshwater green alga)):
31.3 mg/l
Toxicity to fish
: LC50 (Oncorhynchus mykiss (rainbow trout)): > 13.8 mg/l
LC50 (Lepomis macrochirus (Bluegill sunfish)): > 15.1 mg/l aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 0.0116 mg/l Exposure time: 48 h
Toxicity to algae/aquatic plants
: ErC50 (Raphidocelis subcapitata (freshwater green alga)): > 2 mg/l
EC50 (Lemna gibba (gibbous duckweed)): > 2 mg/l Exposure time: 14 d
M-Factor (Acute aquatic tox-icity)
: 10
Toxicity to fish (Chronic tox-icity)
: NOEC (Oncorhynchus mykiss (rainbow trout)): 0.11 mg/l Exposure time: 90 d aquatic invertebrates (Chron-ic toxicity)
: NOEC (Daphnia magna (Water flea)): 0.00447 mg/l Exposure time: 21 d
NOEC (Chironomus riparius (harlequin fly)): 0.0025 mg/l Exposure time: 28 d
M-Factor (Chronic aquatic toxicity)
: 10
Persistence and degradability
Components:
Biodegradability
: Result: Not readily biodegradable.
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Revision Date:
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SDS Number:
10 / 14
Bioaccumulative potential
Components:
Bioaccumulation
: Remarks: Does not bioaccumulate.
Mobility in soil chlorantraniliprole:
Distribution among environ-mental compartments
: Remarks: immobile
Other adverse effects chlorantraniliprole:
Results of PBT and vPvB assessment
: This substance is not considered to be persistent, bioaccumu-lating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Do not contaminate ponds, waterways or ditches with chemical or used container.
Do not dispose of waste into sewer.
Where possible recycling is preferred to disposal or incineration.
If recycling is not practicable, dispose of in compliance with local regulations.
Contaminated packaging
: Empty remaining contents.
Triple rinse containers.
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Do not re-use empty containers.
SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(CHLORANTRANILIPROLE)
Class : 9 Packing group : III
2.0
Revision Date:
08/03/2020
SDS Number:
11 / 14
Labels : 9
IATA-DGR
UN/ID No. : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s.
(CHLORANTRANILIPROLE)
Class : 9 Packing group : III Labels : Miscellaneous Packing instruction (cargo aircraft)
: 964
Packing instruction (passen-ger aircraft)
: 964
Environmentally hazardous : yes
IMDG-Code UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(CHLORANTRANILIPROLE)
Class : 9 Packing group : III Labels : 9 EmS Code : F-A, S-F Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
Not regulated as a dangerous good Remarks : Shipment by ground under DOT is non-regulated; however it may be shipped per the applicable hazard classification to facilitate multi-modal transport involving ICAO (IATA) or IMO.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.
SECTION 15. REGULATORY INFORMATION
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classi-fication criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet.
Remove and wash contaminated clothing before re-use.
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
Components CAS-No. Component RQ Calculated product RQ
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SDS Number:
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(lbs) (lbs) orthophosphoric acid 7664-38-2 5000 * *: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
This material does not contain any components with a section 302 EHS TPQ.
SARA 313
: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
The ingredients of this product are reported in the following inventories:
TSCA
: On or in compliance with the active portion of the TSCA inventory
TSCA list
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.
SECTION 16. OTHER INFORMATION
Further information
NFPA 704: HMIS® IV:
HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal haz-ards or risks, and 4 representing signifi-cant hazards or risks. The "*" represents a chronic hazard, while the "/" represents the absence of a chronic hazard.
Full text of other abbreviations
ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-its for Air Contaminants
HEALTH
Flammability
Instability
Special hazard
FLAMMABILITY
PHYSICAL HAZARD
* 0
Health
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Revision Date:
08/03/2020
SDS Number:
13 / 14
OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-eral Dusts
US WEEL : USA. Workplace Environmental Exposure Levels (WEEL) ACGIH / TWA : 8-hour, time-weighted average NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek OSHA Z-1 / TWA : 8-hour time weighted average OSHA Z-3 / TWA : 8-hour time weighted average US WEEL / TWA : 8-hr TWA
AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz-ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza-tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre-vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub-stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti-tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern-ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative
Revision Date : 08/03/2020
Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-mation and belief at the date of its publication. The information given is designed only as a guid-ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
2.0
Revision Date:
08/03/2020
SDS Number:
14 / 14
US / Z8
FT-METHYL EUGENOL
Version: 2.1 Date: September 10th, 2020
1: Identification
Product Name : FT-Methyl Eugenol
Chemical Name : 1,2-Dimethoxy-4-(prop-2-en-1-yl)benzene
Synonyms : Methyl Eugenol
Product Use : Insect Attractant
Company : Farma Tech international Corporation 1546 Boalch Ave NW, Suite 30 North Bend, WA 98029
Telephone : +1.425.396.1050
2: Hazard(s) Identification
Hazard Classification : Acute Toxicity (oral), Hazard Category 4; H302 Skin Irritation, Hazard Category 2; H315 Eye Irritation, Hazard Category 2A; H319 Germ Cell Mutagenicity, Hazard Category 2; H341 Carcinogenicity, Hazard Category 2; H351 Aquatic Toxicity (acute), Hazard Category 2, H401 Aquatic Toxicity (chronic), Hazard Category 2, H411
Signal Word(s) : Warning
Hazard Statements : H302:
H315:
H319:
H341:
H351:
H401:
H411:
Harmful if swallowed Causes Skin Irritation Causes Serious Eye Irritation Suspected of causing genetic defects Suspected of causing cancer Toxic to aquatic life Toxic to aquatic life with long lasting effects
Symbols :
Precautionary Statements : P201:
P202:
P264:
P270:
P273:
P280:
P301+P312+P330:
P302+P352:
P305+P351+P338:
P308+P313:
P332+P313:
P337+P313:
P362+P364 P391:
P405:
P501:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wash skin thoroughly after handling.
Do not eat drink or smoke when using this product.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection and wash all contaminated clothing thoroughly after handling.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
Rinse mouth IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
IF skin irritation occurs: Get medical advice/attention.
IF eye irritation persists: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
Collect spillage.
Store locked up.
Dispose of contents/container to an approved waste disposal plant.
Description of Other Hazards
: Vapor can cause irritation
3. Composition/Information on Ingredients
Chemical Name Synonym CAS EC/EINECS Concentration(%wt)
1,2-Dimethoxy-4-(prop-2-en-1-yl)benzene Methyl Eugenol 93-15-2 202-223-0 98%
Other ingredients 2%
4. First-Aid Measures
After Skin Contact : Wash hands thoroughly after handling. Rinse skin immediately with plenty of water for 15 to 20 minutes. If irritation occurs seek medical advice. Take off contaminated clothing and wash before reuse. Call a poison control center or doctor for treatment advice.
After Eye Contact : Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes then continue rinsing the eye. Rinse longer if there is any indication of residual chemical in the eye. Ensure adequate flushing of the eyes by separating the eyelids with fingers and roll eyes in a circular motion. If irritation occurs or concerned call a poison control center or doctor for further treatment advice.
After Inhalation : If adverse effects are felt, move person to fresh air. If breathing is difficult give oxygen. If not breathing, give artificial respiration. If symptoms persist get medical attention. If person is not breathing, call 911 or an ambulance then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.
After Swallowing : Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless directed to do so by medical personnel. Do not give anything by mouth to an unconscious person. Have the product container, label, or SDS with you when calling a Poison Control Center, doctor, or going for treatment. You can reach a local Poison Control Center at 1-800-222-1222, for emergency medical treatment information.
5. Fire Fighting Measures
Suitable Extinguishing Agents : In case of fire, use water, CO2 or dry powder. Do not use water jet. Combustion products include carbon monoxide and carbon dioxide.
Suitable Protective Equipment for Firefighters
Wear self contained breathing apparatus and protective clothing. Be sure to use an approved / certified respirator or equivalent.
6: Accidental Release Measures
Personal Precautions : Workers must wear long pants, long-sleeve shirt, gloves, shoes and socks.
Measures for Environmental Protection
: Clean up spills immediately, using the appropriate protective equipment.
Measures for Cleaning/Collecting
Absorb spilled material with dry inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Provide ventilation.
7: Handling and Storage
Handling : Do not open packaging until time of use. Wear suitable protective clothing, gloves and eye/face protection. Do not eat, drink or smoke when handling the product. In case of insufficient ventilation wear suitable respiratory equipment. Refillable Container: Refill this container with FT-Methyl Eugenol Only. Do not reuse this container for any other purpose.
Storage : Keep only in original packaging and store in a cool, dry, well ventilated area. Protect from ignition sources. Avoid contact with high temperatures, acids, bases or prolonged contact with air. Store away from heat and out of direct sunlight. Avoid moisture. Provide means or controlling leaks or spills. Keep out of reach of children.
8: Exposure Controls/Personal Protection
General Protective and Hygienic Measures
Wear appropriate protective clothing to prevent skin exposure. Wash hands after handling compounds and before eating, smoking, using lavatory and at the end of the day.
Breathing Equipment : Wear appropriate respirator when ventilation is inadequate.
Protection of Hands : Wear appropriate protective gloves to prevent skin exposure.
Eye Protection : Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
9: Physical and Chemical Properties
Appearance : Clear colorless to pale yellow liquid
Odor : Spicy, earthy-clove, carnation like, sweet
Odor Threshold : No Data Available pH : No Data Available
Melting Point/Freezing Point : -4oC
Boiling Point/Boiling Range : 254.7oC @ 760 mm of Hg
Flash Point : >100oC
Evaporation Rate : No Data Available
Flammability (solid, gas) : No Data Available
Upper/Lower Flammability or Explosive Limits
: No Data Available
Vapour Pressure : 0.027
Vapour Density : 1.055g/cm3
Relative Density : 1.036 g/cm3 @ 25oC
Solubility(ies) : Soluble in alcohol, Solubility in water: <0.1 g/l @ 19oC
Partition Coefficient N-Octanol/Water
: No Data Available
Auto-Ignition Temperature : No Data Available
Decomposition Temperature : No Data Available
Viscosity : No Data Available
10: Stability and Reactivity
Reactivity : Stable under normal temperature and pressure conditions.
Chemical Stability : May slowly oxidize on exposure to air.
Conditions to Avoid : Stable under normal temperature and pressure conditions.
Incompatible Materials : Strong acids, strong oxidizing agents.
Hazardous Decomposition Products
: Carbon monoxide, carbon dioxide. (CO, CO2)
11: Toxicological Information
12: Ecological Information
Environmental Hazards : Keep out of lakes, streams and ponds. Do not contaminate water by cleaning of equipment or disposal of waste. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of the National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA.
Ecotoxicity : Toxicity to fish - LC50 – Oncorhynchus mykiss (rainbow trout) – 6.9 mg/l – 48 h LC50 – Lepomis macrochirus (Bluegill sunfish – 8.1 mg/l – 96 h
Persistence and degradability : No Data Available Bioaccumulative potential : No Data Available
Mobility in soil : No Data Available Other adverse effects : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Toxic to aquatic life with long lasting effects.
13: Disposal Considerations
Product Disposal : Wastes resulting from the use of this product must be disposed of on site or at an approved waste disposal facility.
Container Disposal : Refillable container may be disposed of in a sanitary landfill, by incineration, or offered for recycling after the following steps have been taken, (1) Rinse container by filling container 1/4 full with water and shaking well then emptying rinsate into a mix tank or rinsate collection system. (2) Repeat step 1 two more times.
Liquid should be collected and disposed of in accordance with local, state or national legislation
14: Transport Information
DOT (US) : Not Dangerous Goods IATA : Not Dangerous Goods UN Number : 3082
Class : 9 UN proper shipping name : Environmentally Hazardous Substance, Liquid, N.O.S. (4-Allylveratrole)
Transport Hazard Class(es) : Non-Hazardous Packing Group : III
Marine Pollutant : Yes Special Precautions : No Data Available
Acute Toxicity : LD50 Oral – Rat – 810mg/kg
LC50 Inhalation – Rat – >4800 mg/m3
Potential Routes of Exposure/Potential Health Effects Skin : May cause sensitization by skin contact (irritant)
Eye : There may be irritation and redness
Inhalation : May cause respiratory irritation
Ingestion : No Data Available
Carcinogenic Effects : Limited evidence of carcinogenicity in animal studies NTP: Anticipated human carcinogen IARC: 2B – Group 2B: Possibly carcinogenic to humans (4-Allylveratrole) ACGIH: No component of this product present at levels greater than or equal to
0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
Mutagenic Effects : Suspected of causing genetic defects.
Chromosome aberration test in vitro Result: positive
Reproductive Toxicity : No Data Available
Sensitization : No Data Available
Target Organs : No Data Available
15: Regulatory Information
California Safe Drinking Water and Toxic Enforcement Act of
1986 (Proposition 65)
: Methyl Eugenol: Avoid contamination of soil, water sources and sewers.
SARA Title III SARA Sections 311/312 Hazardous Categories
(40 CFR 370.21)
: Methyl Eugenol: Acute: Yes; Chronic: No; Fire: No; Reactive: No; Sudden Release: No
California Proposition 65 : Methyl Eugenol: Known to the State of California to cause the following: Cancer (Nov 16, 2001)
Listed on TSCA Inventory : Yes
Subject to EPCRA Section 313 : Yes
US EPA Registration No. : 81325-2
This chemical may only be used for i) the survey and detection of fruit flies (40 CFR §152.10(b)), or ii) as a chemical pesticide registered by the Environmental Protection Agency for Manufacturing Use Only. In the latter case, it is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below.
FIFRA Signal Word : CAUTION
Hazards to Humans and Domestic Animals
: Harmful if swallowed or absorbed through skin. Causes moderate eye irritation: Avoid contact with skin, eyes or clothing. Wash thoroughly with soap and water after handling and before eating, drinking or using tobacco.
Precautionary Statements : Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
Workers and Applicators must wear chemical resistant gloves while mixing and/or when handling this product.
16: Other Information
Danger/Hazard Symbol :
Xn – Harmful Xi – Irritant EC Risk and Safety Phrases : R22
R36/37/38 R40 S2 S20/21 S28 S36/37/39 S38
Harmful if swallowed Irritating to eyes, respiratory system and skin Limited evidence of a carcinogenic effect Keep out of reach of children Do not eat, drink or smoke when handling the product Wash hands thoroughly after handling Wear suitable protective clothing, gloves and eye/face protection In case of insufficient ventilation wear suitable respiratory equipment
If further safety data is required, please contact Farma Tech International Corporation at +1 (425)-369-1050
Date Prepared : September 10th 2020
The information on this safety data sheet is believed to be accurate but does not claim to be all inclusive. This document is intended only as a guide to the appropriate precautions for handling a chemical by a person trained in chemical handling. Farma Tech International Corporation makes no warranties of merchantability or any other warranties, express or implied with respect to such information or the product to which it relates, and assumes no liability resulting from the use or handling of the product to which this safety data sheet relates.
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