Drewplex OX Safety Data Sheet.pdf

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Boiler Maintenance Chemicals for CGC Polar Star
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This document is a Safety Data Sheet (SDS) for DREWPLEX OX, a chemical product manufactured by Drew Marine. The product is classified as a Combustible Liquid Category 4, containing diethylhydroxylamine, with a proper shipping name of "Combustible liquid, n.o.s." Key safety precautions include keeping the product away from heat and ignition sources, wearing protective gloves and clothing, and storing in a well-ventilated, cool place. The product has a flash point of 62.7°C and a pH of 8.3, with emergency contact numbers provided for Drew Marine and Chemwatch Emergency Response.

The SDS details potential hazards, first aid measures, and handling instructions, noting the product is harmful to aquatic organisms and may cause long-term adverse effects in the aquatic environment. Toxicological information indicates the substance has low bioaccumulation potential and low mobility in soil. The product is regulated under various national inventories, including the US Toxic Substances Control Act (TSCA), and is listed as active in multiple international chemical substance inventories. Transportation is classified as a combustible liquid under DOT regulations, with specific packaging and handling guidelines.

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DREWPLEX OX

Drew Marine Version No: 3.1

Safety Data Sheet according to OSHA HazCom Standard (2024) requirements

Initial Date: 14/02/2023

Revision Date: 27/10/2023

Print Date: 01/10/2025

S.GHS.USA.EN

SECTION 1 Identification

Product Identifier

Product name DREWPLEX OX

Chemical Name Not Applicable

Proper shipping name Combustible liquid, n.o.s. (contains diethylhydroxylamine)

Chemical formula Not Applicable

Other means of identification

UFI: KFGQ-W21M-6M0A-2F5R

Recommended use of the chemical and restrictions on use

Relevant identified uses Use according to manufacturer's directions.

Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party

Registered company name Drew Marine

Address 400 Captain Neville Drive, Waterbury CT 06705 United States

Telephone +1-973-526-5700

Fax Not Available

Website

Email info@drew-marine.com

Emergency phone number

Association / Organisation Drew Marine CHEMWATCH EMERGENCY RESPONSE (24/7)

Emergency telephone number(s)

The numbers below are for EMERGENCY USE ONLY. Use the corporate number above for all other calls.

+1 855-237-5573 (ID#: 5575-39)

Other emergency telephone number(s)

CHEMWATCH: +613 9573 3188 +61 3 9573 3188

SECTION 2 Hazard(s) identification

Classification of the substance or mixture

Classification Flammable Liquids Category 4

Label elements

Hazard pictogram(s) Not Applicable

Signal word Warning

Hazard statement(s)

H227 Combustible liquid.

www.drew-marine.com

Page 1 continued...

Hazard(s) not otherwise classified

Not Applicable

Supplementary statement(s)

Not Applicable

Precautionary statement(s) Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P280 Wear protective gloves and protective clothing.

Precautionary statement(s) Response

P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish.

Precautionary statement(s) Storage

P403+P235 Store in a well-ventilated place. Keep cool.

Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

No further product hazard information.

SECTION 3 Composition / information on ingredients

Substances

See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name

3710-84-7 10-30

SECTION 4 First-aid measures

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes:

Wash out immediately with fresh running water.

Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.

Seek medical attention without delay; if pain persists or recurs seek medical attention.

Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:

Immediately remove all contaminated clothing, including footwear.

Flush skin and hair with running water (and soap if available).

Seek medical attention in event of irritation.

Inhalation If fumes, aerosols or combustion products are inhaled remove from contaminated area.

Other measures are usually unnecessary.

Ingestion Immediately give a glass of water.

First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Most important symptoms and effects, both acute and delayed

See Section 11

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 Fire-fighting measures

Extinguishing media

Foam.

Dry chemical powder.

BCF (where regulations permit).

Carbon dioxide.

diethylhydroxylamine

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Revision Date: 27/10/2023

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Continued...

Water spray or fog - Large fires only.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Special protective equipment and precautions for fire-fighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard.

Wear full body protective clothing with breathing apparatus.

Prevent, by any means available, spillage from entering drains or water course.

Use water delivered as a fine spray to control fire and cool adjacent area.

Avoid spraying water onto liquid pools.

DO NOT approach containers suspected to be hot.

Cool fire exposed containers with water spray from a protected location.

If safe to do so, remove containers from path of fire.

Fire/Explosion Hazard

Combustible.

Slight fire hazard when exposed to heat or flame.

Heating may cause expansion or decomposition leading to violent rupture of containers.

On combustion, may emit toxic fumes of carbon monoxide (CO).

May emit acrid smoke.

Mists containing combustible materials may be explosive.

Combustion products include:

carbon dioxide (CO2) nitrogen oxides (NOx) phosphorus oxides (POx) other pyrolysis products typical of burning organic material.

May emit poisonous fumes.

May emit corrosive fumes.

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions

See section 12

Methods and material for containment and cleaning up

Minor Spills

Remove all ignition sources.

Clean up all spills immediately.

Avoid breathing vapours and contact with skin and eyes.

Control personal contact with the substance, by using protective equipment.

Contain and absorb spill with sand, earth, inert material or vermiculite.

Wipe up.

Place in a suitable, labelled container for waste disposal.

Major Spills

Moderate hazard.

Clear area of personnel and move upwind.

Alert Fire Brigade and tell them location and nature of hazard.

Wear breathing apparatus plus protective gloves.

Prevent, by any means available, spillage from entering drains or water course.

No smoking, naked lights or ignition sources.

Increase ventilation.

Stop leak if safe to do so.

Contain spill with sand, earth or vermiculite.

Collect recoverable product into labelled containers for recycling.

Absorb remaining product with sand, earth or vermiculite.

Collect solid residues and seal in labelled drums for disposal.

Wash area and prevent runoff into drains.

If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

Safe handling DO NOT USE brass or copper containers / stirrers

DO NOT allow clothing wet with material to stay in contact with skin

Avoid all personal contact, including inhalation.

Wear protective clothing when risk of exposure occurs.

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Use in a well-ventilated area.

Prevent concentration in hollows and sumps.

DO NOT enter confined spaces until atmosphere has been checked.

Avoid smoking, naked lights or ignition sources.

Avoid contact with incompatible materials.

When handling, DO NOT eat, drink or smoke.

Keep containers securely sealed when not in use.

Avoid physical damage to containers.

Always wash hands with soap and water after handling.

Work clothes should be laundered separately.

Use good occupational work practice.

Observe manufacturer's storage and handling recommendations contained within this SDS.

Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.

Other information

Store in original containers.

Keep containers securely sealed.

No smoking, naked lights or ignition sources.

Store in a cool, dry, well-ventilated area.

Store away from incompatible materials and foodstuff containers.

Protect containers against physical damage and check regularly for leaks.

Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities

Suitable container

Metal can or drum

Packaging as recommended by manufacturer.

Check all containers are clearly labelled and free from leaks.

Storage incompatibility Avoid strong acids, bases.

Avoid reaction with oxidising agents

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Not Available

Emergency Limits

Ingredient TEEL-1 TEEL-2 TEEL-3

DREWPLEX OX Not Available Not Available Not Available

Ingredient Original IDLH Revised IDLH diethylhydroxylamine Not Available Not Available

Exposure controls

Appropriate engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.

The basic types of engineering controls are:

Process controls which involve changing the way a job activity or process is done to reduce the risk.

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.

Employers may need to use multiple types of controls to prevent employee overexposure.

General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection.

Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.

Type of Contaminant: Air Speed:

solvent, vapours, degreasing etc., evaporating from tank (in still air).

0.25-0.5 m/s (50-

100 f/min) aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation)

0.5-1 m/s (100-

200 f/min.)

direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion)

1-2.5 m/s (200-

500 f/min.)

grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity 2.5-10 m/s (500-

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Initial Date: 14/02/2023

Revision Date: 27/10/2023 into zone of very high rapid air motion). 2000 f/min.)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range

1: Room air currents minimal or favourable to capture 1: Disturbing room air currents

2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity

3: Intermittent, low production. 3: High production, heavy use

4: Large hood or large air mass in motion 4: Small hood-local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used.

Individual protection measures, such as personal protective equipment

Eye and face protection

Safety glasses with side shields.

Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]

Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.

Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

Skin protection See Hand protection below

Hands/feet protection

Wear chemical protective gloves, e.g. PVC.

Wear safety footwear or safety gumboots, e.g. Rubber

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.

The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when making a final choice.

Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.

Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:

· frequency and duration of contact,

· chemical resistance of glove material,

· glove thickness and

· dexterity

Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).

· When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.

· When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.

· Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-term use.

· Contaminated gloves should be replaced.

As defined in ASTM F-739-96 in any application, gloves are rated as:

· Excellent when breakthrough time > 480 min

· Good when breakthrough time > 20 min

· Fair when breakthrough time < 20 min

· Poor when glove material degrades

For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended.

It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based on consideration of the task requirements and knowledge of breakthrough times.

Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers technical data should always be taken into account to ensure selection of the most appropriate glove for the task.

Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example:

· Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves are only likely to give short duration protection and would normally be just for single use applications, then disposed of.

· Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasion or puncture potential

Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.

Body protection See Other protection below

Other protection Overalls.

P.V.C apron.

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DREWPLEX OX

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Barrier cream.

Skin cleansing cream.

Eye wash unit.

Respiratory protection

Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection

Factors (defined as the ratio of contaminant outside and inside the mask) may also be important.

Required minimum protection factor

Maximum gas/vapour concentration present in air p.p.m. (by volume)

Half-face

Respirator

Full-Face

Respirator up to 10 1000 AK-AUS / Class1 P2 -up to 50 1000 - AK-AUS / Class 1 P2 up to 50 5000 Airline * -up to 100 5000 - AK-2 P2 up to 100 10000 - AK-3 P2

100+ Airline**

* - Continuous Flow ** - Continuous-flow or positive pressure demand

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content.

The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask is not functioning properly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use of cartridge respirators is considered appropriate.

Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determined that the humidity is less than

75%, in which case, cartridges can be used for 4 hr. Used cartridges should be discarded daily, regardless of the length of time used

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

Appearance Clear pale yellow to dark brown liquid.

Physical state Liquid Relative density (Water =

1) 1.005

Odour Not Available Partition coefficient n-octanol / water Not Available

Odour threshold Not Available Auto-ignition temperature

(°C) Not Available pH (as supplied) 8.3 Decomposition temperature (°C) Not Available

Melting point / freezing point (°C) Not Applicable Viscosity (cSt) Not Available

Initial boiling point and boiling range (°C) Not Available Molecular weight (g/mol) Not Applicable

Flash point (°C) 62.7 Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Combustible. Oxidising properties Not Available

Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm or mN/m) Not Available

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Not Available pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available

Heat of Combustion (kJ/g) Not Available Ignition Distance (cm) Not Available

Flame Height (cm) Not Available Flame Duration (s) Not Available

Enclosed Space Ignition

Time Equivalent (s/m3) Not Available

Enclosed Space Ignition

Deflagration Density

(g/m3)

Not Available

Nanoform Solubility Not Available Nanoform Particle

Characteristics Not Available

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Particle Size Not Available

SECTION 10 Stability and reactivity

Reactivity See section 7

Chemical stability

Unstable in the presence of incompatible materials.

Product is considered stable.

Hazardous polymerisation will not occur.

Possibility of hazardous reactions See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decomposition products See section 5

SECTION 11 Toxicological information

Information on toxicological effects

a) Acute Toxicity Based on available data, the classification criteria are not met.

b) Skin Irritation/Corrosion Based on available data, the classification criteria are not met.

c) Serious Eye

Damage/Irritation Based on available data, the classification criteria are not met.

d) Respiratory or Skin sensitisation Based on available data, the classification criteria are not met.

e) Mutagenicity Based on available data, the classification criteria are not met.

f) Carcinogenicity Based on available data, the classification criteria are not met.

g) Reproductivity Based on available data, the classification criteria are not met.

h) STOT - Single Exposure Based on available data, the classification criteria are not met.

i) STOT - Repeated

Exposure Based on available data, the classification criteria are not met.

j) Aspiration Hazard Based on available data, the classification criteria are not met.

Inhaled

The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been produced following exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.

Ingestion Accidental ingestion of the material may be damaging to the health of the individual.

Skin Contact

Open cuts, abraded or irritated skin should not be exposed to this material

Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.

Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Skin contact with the material may be harmful; systemic effects may result following absorption.

This material can cause inflammation of the skin on contact in some persons.

Eye This material causes serious eye irritation.

Chronic Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.

DREWPLEX OX

TOXICITY IRRITATION

Not Available Not Available diethylhydroxylamine

TOXICITY IRRITATION

Dermal (Guinea Pig) LD50: 90 mg/kg[2] Eye (Rodent - rabbit): 0.1mL - Mild

Inhalation (Rat) LC50: 2620 ppm4h[1] Eye: no adverse effect observed (not irritating)[1]

Oral (Mouse) LD50; 2150 mg/kg[1] Skin (Rodent - rabbit): 0.5mL

Skin: adverse effect observed (irritating)[1]

Skin: no adverse effect observed (not irritating)[1]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.

Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

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Legend: – Data either not available or does not fill the criteria for classification

– Data available to make classification

DIETHYLHYDROXYLAMINE

Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible airflow pattern on lung function tests, moderate to severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal lymphocytic inflammation, without eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance. On the other hand, industrial bronchitis is a disorder that occurs as a result of exposure due to high concentrations of irritating substance (often particles) and is completely reversible after exposure ceases. The disorder is characterized by difficulty breathing, cough and mucus production.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye

Damage/Irritation STOT - Single Exposure

Respiratory or Skin sensitisation STOT - Repeated Exposure

Mutagenicity Aspiration Hazard

SECTION 12 Ecological information

Toxicity

DREWPLEX OX

Endpoint Test Duration (hr) Species Value Source

Not

Available Not Available Not Available

Not

Available

Not

Available diethylhydroxylamine

Endpoint Test Duration (hr) Species Value Source

EC50 72h Algae or other aquatic plants >101mg/l 2

EC50 48h Crustacea 8.2mg/l 2

NOEC(ECx) 48h Crustacea 2.5mg/l 2

LC50 96h Fish >134mg/l 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity

4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -

Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air diethylhydroxylamine LOW LOW

Bioaccumulative potential

Ingredient Bioaccumulation diethylhydroxylamine LOW (LogKOW = -0.17)

Mobility in soil

Ingredient Mobility diethylhydroxylamine LOW (Log KOC = 73.83)

Other adverse effects

No evidence of ozone depleting properties were found in the current literature.

SECTION 13 Disposal considerations

Waste treatment methods

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14.1. UN number or ID

number

14.2. UN proper shipping

name

14.3. Transport hazard

class(es)

14.4. Packing group

14.5. Environmental

hazard

14.6. Special precautions

for user

Product / Packaging disposal

DO NOT allow wash water from cleaning or process equipment to enter drains.

It may be necessary to collect all wash water for treatment before disposal.

In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.

Where in doubt contact the responsible authority.

Recycle wherever possible or consult manufacturer for recycling options.

Consult State Land Waste Authority for disposal.

Bury or incinerate residue at an approved site.

Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 Transport information

Labels Required

Marine Pollutant NO

Land transport (DOT)

NA1993

Combustible liquid, n.o.s. (contains diethylhydroxylamine)

Class Comb liq

Subsidiary Hazard Not Applicable

III

Not Applicable

Hazard Label Not Applicable

Special provisions 148, IB3, T1, TP1

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.7. Maritime transport in bulk according to IMO instruments

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code

Product name Group diethylhydroxylamine Not Available

14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type diethylhydroxylamine Not Available

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture diethylhydroxylamine is found on the following regulatory lists

US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory

Additional Regulatory Information

Not Applicable

Federal Regulations

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Section 311/312 hazard categories

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Flammable (Gases, Aerosols, Liquids, or Solids) Yes

Gas under pressure No

Explosive No

Self-heating No

Pyrophoric (Liquid or Solid) No

Pyrophoric Gas No

Corrosive to metal No

Oxidizer (Liquid, Solid or

Gas) No

Organic Peroxide No

Self-reactive No

In contact with water emits flammable gas No

Combustible Dust No

Carcinogenicity No

Acute toxicity (any route of exposure) No

Reproductive toxicity No

Skin Corrosion or Irritation No

Respiratory or Skin

Sensitization No

Serious eye damage or eye irritation No

Specific target organ toxicity

(single or repeated exposure)

No

Aspiration Hazard No

Germ cell mutagenicity No

Simple Asphyxiant No

Hazards Not Otherwise

Classified No

US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4)

None Reported

US. EPCRA Section 313 Toxic Release Inventory (TRI) (40 CFR 372)

None Reported

Additional Federal Regulatory Information

Not Applicable

State Regulations

US. California Proposition 65

None Reported

Not Applicable

National Inventory Status

National Inventory Status

Australia - AIIC / Australia

Non-Industrial Use Yes

Canada - DSL Yes

Canada - NDSL No (diethylhydroxylamine)

China - IECSC Yes

Europe - EINEC / ELINCS /

NLP

Yes

Japan - ENCS Yes

Korea - KECI Yes

New Zealand - NZIoC Yes

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National Inventory Status

Philippines - PICCS Yes

USA - TSCA All chemical substances in this product have been designated as TSCA Inventory ‘Active'

Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - FBEPH Yes

UAE - Control List

(Banned/Restricted

Substances)

No (diethylhydroxylamine)

Legend:

Yes = All CAS declared ingredients are on the inventory

No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require registration.

SECTION 16 Other information

Revision Date 27/10/2023

Initial Date 14/02/2023

Other information

Classification of the preparation and its individual components has drawn on official and authoritative sources using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC-TWA: Permissible Concentration-Time Weighted Average

PC-STEL: Permissible Concentration-Short Term Exposure Limit

IARC: International Agency for Research on Cancer

ACGIH: American Conference of Governmental Industrial Hygienists

STEL: Short Term Exposure Limit

TEEL: Temporary Emergency Exposure Limit。 IDLH: Immediately Dangerous to Life or Health Concentrations

ES: Exposure Standard

OSF: Odour Safety Factor

NOAEL: No Observed Adverse Effect Level

LOAEL: Lowest Observed Adverse Effect Level

TLV: Threshold Limit Value

LOD: Limit Of Detection

OTV: Odour Threshold Value

BCF: BioConcentration Factors

BEI: Biological Exposure Index

DNEL: Derived No-Effect Level

PNEC: Predicted no-effect concentration

MARPOL: International Convention for the Prevention of Pollution from Ships

IMSBC: International Maritime Solid Bulk Cargoes Code

IGC: International Gas Carrier Code

IBC: International Bulk Chemical Code

AIIC: Australian Inventory of Industrial Chemicals

DSL: Domestic Substances List

NDSL: Non-Domestic Substances List

IECSC: Inventory of Existing Chemical Substance in China

EINECS: European INventory of Existing Commercial chemical Substances

ELINCS: European List of Notified Chemical Substances

NLP: No-Longer Polymers

ENCS: Existing and New Chemical Substances Inventory

KECI: Korea Existing Chemicals Inventory

NZIoC: New Zealand Inventory of Chemicals

PICCS: Philippine Inventory of Chemicals and Chemical Substances

TSCA: Toxic Substances Control Act

TCSI: Taiwan Chemical Substance Inventory

INSQ: Inventario Nacional de Sustancias Químicas

NCI: National Chemical Inventory

FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

Version No: 3.1 Page 11 of 12

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Initial Date: 14/02/2023

Revision Date: 27/10/2023

Disclaimer: This SDS was prepared by a third party for product identification purposes only and is not endorsed by or affiliated with the original brand owner.

Version No: 3.1 Page 12 of 12

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Initial Date: 14/02/2023

Revision Date: 27/10/2023 end of SDS

File details come from the government source that posted it. Updated .