13. Tree Marking Paint MSDS.pdf

Safety Data Sheet

USFS Tree Mark Paint

SDS Revision Date: 12/09/2014

1. Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product Identity USFS Tree Mark Paint

Alternate Names Specification: 2400-400b, Type A, Orange EF LHB Part No/Pkg: 00R4-320/Quarts, 00R4-321/Gallons National Stock No.: 8010-01-441-6078, 8010-01-441-6079 CAGE Code: 0FTT5 Contract Number: AG-3187-C-09-0026

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use See product label.

Application Method See product label.

1.3. Details of the supplier of the safety data sheet

Company Name LHB Industries

8833 Fleischer Place

Berkeley, MO 63134

Emergency

24 hour Emergency Telephone No. (800) 633-8253 (PERS)

Customer Service: LHB Industries (314) 423-4333

2. Hazard identification of the product

2.1. Classification of the substance or mixture

STOT RE 2;H373

May cause damage to organs through prolonged or repeated exposure.

Specific Target Organs: (central nervous system )

2.2. Label elements

Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.

Warning

H373 May cause damage to organs through prolonged or repeated exposure.

[Prevention]:

P260 Do not breathe mist / vapors / spray.

P262 Do not get in eyes, on skin, or on clothing.

[Response]:

P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician.

P314 Get Medical advice / attention if you feel unwell.

P331 Do NOT induce vomiting.

[Storage]:

No GHS storage statements

[Disposal]:

No GHS disposal statements

3. Composition/information on ingredients

This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations.

Ingredient/Chemical Designations Weight % GHS Classification Notes

Propylene Glycol CAS Number: 0000057-55-6

25 - 50 Not Classifed [1]

Stoddard solvent CAS Number: 0008052-41-3

1.0 - 10 STOT RE 1;H372

Asp. Tox. 1;H304

[1][2]

Titanium dioxide CAS Number: 0013463-67-7

1.0 - 10 Not Classified [1][2]

Cobalt neodecanoate CAS Number: 0027253-31-2

0.10 - 1.0 Acute Tox. 4;H302, Skin Sens. 1;H317, Flam. Liq. 3;H226, Aquatic Chronic 3;H412 Repr. 2;H361

[1]

[1] Substance classified with a health or environmental hazard.

[2] Substance with a workplace exposure limit.

[3] PBT-substance or vPvB-substance.

*The full texts of the phrases are shown in Section 16.

4. First aid measures

4.1. Description of first aid measures

General In all cases of doubt, or when symptoms persist, seek medical attention.

Never give anything by mouth to an unconscious person.

Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth.

Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention.

Skin Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin cleanser.

Ingestion If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.

4.2. Most important symptoms and effects, both acute and delayed

Overview INHALATION: May be irritating to upper respiratory tract.

SKIN: Low potential of causing irritation following exposure. Not absorbed topically. Some reddening of the skin may occur with lengthy exposure.

EYE CONTACT: May cause mild irritation.

INGESTION: No significant signs or symptoms indicative of any adverse health hazard are expected to occur as a result of ingestion. Large amounts may cause gastric disturbances.

Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage. See section 2 for further details.

5. Fire-fighting measures

5.1. Extinguishing media

Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray.

Do not use; water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition: Oxides of carbon and sulfur, formaldehyde gas and thiols.

Do not breathe mist / vapors / spray.

Do not get in eyes, on skin, or on clothing.

5.3. Advice for fire-fighters

Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter drains or water ways.

ERG Guide No. ----

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a major spill or spillage in a confined space evacuate the area and check that solvent vapor levels are below the Lower Explosive Limit before re-entering.

6.2. Environmental precautions

Do not allow spills to enter drains or waterways.

Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.

6.3. Methods and material for containment and cleaning up

Ventilate the area and avoid breathing vapors. Take the personal protective measures listed in section 8.

Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed containers outside buildings and dispose of according to the Waste Regulations. (See section 13).

Clean, preferably with a detergent. Do not use solvents.

Do not allow spills to enter drains or watercourses.

If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be informed.

7. Handling and storage

7.1. Precautions for safe handling

See section 2 for further details. - [Prevention]:

7.2. Conditions for safe storage, including any incompatibilities

Handle containers carefully to prevent damage and spillage.

Store this product below 120°F, in a cool, dry, well ventilated area away from heat, sparks, flame, oxidizers and out of direct sunlight.

Incompatible materials: Strong oxidizers and alkali metals.

See section 2 for further details. - [Storage]:

7.3. Specific end use(s)

No data available.

8. Exposure controls and personal protection

8.1. Control parameters

Exposure

CAS No. Ingredient Source Value

0000057-55-6 Propylene Glycol OSHA No Established Limit

ACGIH No Established Limit

NIOSH No Established Limit

Supplier 10 mg/m3 TWA (listed as AIHA WEEL)

0008052-41-3 Stoddard solvent OSHA TWA 500 ppm (2900 mg/m3)

ACGIH TWA: 290 mg/m3STEL: 580 mg/m3

NIOSH TWA 350 mg/m3 C 1800 mg/m3 [15-minute]

Supplier No Established Limit

0013463-67-7 Titanium dioxide OSHA TWA 15 mg/m3

ACGIH TWA: 10 mg/m32B, Revised 2006, NIOSH Footnote ca

Supplier No Established Limit

0027253-31-2 Cobalt neodecanoate OSHA No Established Limit

ACGIH No Established Limit

NIOSH No Established Limit

Supplier No Established Limit

Carcinogen Data

CAS No. Ingredient Source Value

0000057-55-6 Propylene Glycol OSHA Select Carcinogen: No

NTP Known: No; Suspected: No

IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;

0008052-41-3 Stoddard solvent OSHA Select Carcinogen: No

NTP Known: No; Suspected: No

IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;

0013463-67-7 Titanium dioxide OSHA Select Carcinogen: No

NTP Known: No; Suspected: No

IARC Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No;

0027253-31-2 Cobalt neodecanoate OSHA Select Carcinogen: No

NTP Known: No; Suspected: No

IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;

8.2. Exposure controls

Respiratory If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators.

Eyes Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.

Skin Overalls which cover the body, arms and legs should be worn. Skin should not be exposed.

All parts of the body should be washed after contact.

Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn.

Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.

See section 2 for further details. - [Prevention]:

9. Physical and chemical properties

Appearance Orange Liquid

Odor Solvent Odor

Odor threshold Not Measured pH Not Measured

Melting point / freezing point Not Measured

Initial boiling point and boiling range 316-370 F

Flash Point 205 F (96 C) SETAFLASH

Evaporation rate (Ether = 1) Slower than ether

Flammability (solid, gas) Not Applicable

Upper/lower flammability or explosive limits Lower Explosive Limit: 1.0

Upper Explosive Limit: 17.4

Vapor pressure (Pa) Not Measured

Vapor Density Heavier than Air

Specific Gravity 1.07

Solubility in Water Not Measured

Partition coefficient n-octanol/water (Log Kow) Not Measured

Auto-ignition temperature Not Measured

Decomposition temperature Not Measured

Viscosity (cSt) Not Measured

VOC Content 5.52 lbs/gal

Maximum Incremental Reactivity Not Measured

HAPS (lbs/gal) 0.0

HAPS (lbs/gal of Solids) 0.0

HAPS (lbs/lb of Solids) 0.0

% Volatile (by volume) Not Measured

9.2. Other information

No other relevant information.

10. Stability and reactivity

10.1. Reactivity

Hazardous Polymerization will not occur.

10.2. Chemical stability

Stable under normal circumstances.

10.3. Possibility of hazardous reactions

No data available.

10.4. Conditions to avoid

Temperatures above 160 C

10.5. Incompatible materials

Strong oxidizers and alkali metals.

10.6. Hazardous decomposition products

Oxides of carbon and sulfur, formaldehyde gas and thiols.

11. Toxicological information

Acute toxicity

Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin.

Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.

Ingredient Oral LD50, mg/kg

Skin LD50, mg/kg

Inhalation Vapor LD50, mg/L/4hr

Inhalation Dust/Mist LD50, mg/L/4hr

Inhalation Gas LD50, ppm

Propylene Glycol - (57-55-6) 20,000.00, Rat - Category: NA

20,800.00, Rabbit -

Category: NA

105.00, Rat - Category: NA

No data available

No data available

Stoddard solvent - (8052-41-3) No data available

No data available

No data available

No data available

No data available

Titanium dioxide - (13463-67-7) 10,000.00, Rat - Category: NA

10,000.00, Rabbit -

Category: NA

No data available

6.82, Rat - Category: NA

No data available

Cobalt neodecanoate - (27253-31-2) 900.00, Rat - Category: 4

No data available

No data available

No data available

No data available

Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate).

Classification Category Hazard Description

Acute toxicity (oral) --- Not Applicable

Acute toxicity (dermal) --- Not Applicable

Acute toxicity (inhalation) --- Not Applicable

Skin corrosion/irritation --- Not Applicable

Serious eye damage/irritation --- Not Applicable

Respiratory sensitization --- Not Applicable

Skin sensitization --- Not Applicable

Germ cell mutagenicity --- Not Applicable

Carcinogenicity --- Not Applicable

Reproductive toxicity --- Not Applicable

STOT-single exposure --- Not Applicable

STOT-repeated exposure 2 May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard --- Not Applicable

12. Ecological information

12.1. Toxicity

No additional information provided for this product. See Section 3 for chemical specific data.

Aquatic Ecotoxicity

Ingredient 96 hr LC50 fish, mg/l 48 hr EC50 crustacea, mg/l ErC50 algae, mg/l

Propylene Glycol - (57-55-6) 710.00, Pimephales promelas

10,000.00, Daphnia magna

Not Available

Stoddard solvent - (8052-41-3) Not Available Not Available Not Available

Titanium dioxide - (13463-67-7) 1,000.00, Fundulus heteroclitus

5.50, Daphnia magna 5.83 (72 hr), Pseudokirchneriella subcapitata

Cobalt neodecanoate - (27253-31-2) Not Available Not Available Not Available

12.2. Persistence and degradability

There is no data available on the preparation itself.

12.3. Bioaccumulative potential

Not Measured

12.4. Mobility in soil

No data available.

12.5. Results of PBT and vPvB assessment

This product contains no PBT/vPvB chemicals.

12.6. Other adverse effects

No data available.

13. Disposal considerations

13.1. Waste treatment methods

Observe all federal, state and local regulations when disposing of this substance.

14. Transport information

DOT (Domestic Surface Transportation)

IMO / IMDG (Ocean Transportation)

ICAO/IATA

14.1. UN number Not Applicable Not Regulated Not Regulated

14.2. UN proper shipping

name

Not Regulated Not Regulated Not Regulated

14.3. Transport hazard

class(es)

DOT Hazard Class: Not Applicable DOT Label: None

IMDG: Not Applicable Sub Class: Not Applicable

Air Class: Not Applicable

14.4. Packing group Not Applicable Not Applicable Not Applicable

14.5. Environmental hazards

IMDG Marine Pollutant: No

14.6. Special precautions for user

No further information

15. Regulatory information

Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented.

Toxic Substance Control Act ( TSCA)

All components of this material are either listed or exempt from listing on the TSCA Inventory.

WHMIS Classification D2B

US EPA Tier II Hazards Fire: No

Sudden Release of Pressure: No

Reactive: No

Immediate (Acute): No

Delayed (Chronic): Yes

EPCRA 311/312 Chemicals and RQs:

(No Product Ingredients Listed)

EPCRA 302 Extremely Hazardous :

(No Product Ingredients Listed)

EPCRA 313 Toxic Chemicals:

Cobalt neodecanoate

Proposition 65 - Carcinogens (>0.0%):

(No Product Ingredients Listed)

Proposition 65 - Developmental Toxins (>0.0%):

(No Product Ingredients Listed)

Proposition 65 - Female Repro Toxins (>0.0%):

(No Product Ingredients Listed)

Proposition 65 - Male Repro Toxins (>0.0%):

(No Product Ingredients Listed)

N.J. RTK Substances (>1%):

Propylene Glycol

Stoddard solvent

Titanium dioxide

Penn RTK Substances (>1%):

Propylene Glycol

Stoddard solvent

Titanium dioxide

16. Other information

The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.

We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.

The full text of the phrases appearing in section 3 is:

H226 Flammable liquid and vapor.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H361 Suspected of damaging fertility or the unborn child.

H372 Causes damage to organs through prolonged or repeated exposure.

H412 Harmful to aquatic life with long lasting effects.

This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable.

IMPORTANT NOTE: This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or any process. Final determination of suitability of any material is the sole responsibility of the user.

End of Document