C05_Stabrom 909 SDS_1232SA26R0048.pdf

SAFETY DATA SHEET

STABROM® 909 Biocide Preparation Date : 24-Apr-2015 Revision Date: 07-Jan-2019 Revision Number 4.01

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product Identifier Product Name STABROM® 909 Biocide

Other means of identification Chemical Family Stabilized bromine biocide, aqueous solution CAS-No Mixture

Recommended use of the chemical and restrictions on use General function Water treatment chemical.

Uses advised against No information available

Details of the supplier of the safety data sheet Company Albemarle Corporation

451 Florida Street Baton Rouge, LA 70801

For Non-Emergency 800-535-3030

'Competent Body for SDS' HSE@Albemarle.com

Emergency telephone number Emergency Telephone Numbers In case of emergency, call Albemarle emergency response at +1 225 344 7147

2. HAZARDS IDENTIFICATION

Classification

Skin Corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Acute aquatic toxicity Category 2

Label elements

Emergency Overview

Corrosive to metals Category 1

Danger

Hazard Statements Causes severe skin burns and eye damage Toxic to aquatic life May be corrosive to metals

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FIN00246 - STABROM® 909 Biocide Revision Date: 07-Jan-2019

Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid release to the environment Keep only in original container

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove person to fresh air and keep comfortable for breathing Immediately call a POISON CENTER or doctor/physician IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Absorb spillage to prevent material damage

Storage Store locked up Store in corrosive resistant container with a resistant inner liner

Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Not applicable Other Information May be harmful if swallowed. May be harmful in contact with skin.

4. FIRST AID MEASURES

First aid measures Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison control center or doctor for treatment advice.

Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician.

Inhalation IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.

Immediately call a POISON CENTER or doctor/physician.

Ingestion IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Most important symptoms and effects, both acute and delayed Symptoms Causes severe skin burns and eye damage.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture Mixture

Component CAS-No Weight % Water 7732-18-5 60-70

Halogenated Complex Proprietary. 18-20 Sodium hydroxide 1310-73-2 <10

Note: The exact concentrations of the above listed chemicals are being withheld as a trade secret.

Physical state Liquid Color Yellow. Orange. Odor Mild.

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Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Extinguishing media Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media No information available.

Specific Hazards Arising from the Chemical Combustion/explosion hazards No information available.

Hazardous Combustion Products

Bromine, Chlorine.

Explosion Data Sensitivity to mechanical impact None.

Sensitivity to static discharge None.

Protective Equipment and Precautions for Firefighters In the event of fire and/or explosion do not breathe fumes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Do not breathe dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling Use personal protective equipment. Keep only in original container

Environmental Precautions Environmental precautions Contain any spill with dikes or absorbents to prevent migration and entry into sewers or streams. Large spills should be collected mechanically (remove by pumping) for disposal.

May require excavation of contaminated soil. Take up small spills by first diluting with water and then using a dehalogenating agent such as sodium thiosulfate solution.

Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, universal binder, sawdust)

7. HANDLING AND STORAGE

Precautions for safe handling Handling Avoid contact with skin, eyes and clothing. Do not breathe dust/fume/gas/mist/vapors/spray

Wash face, hands and any exposed skin thoroughly after handling Use personal protective equipment as required

Conditions for safe storage, including any incompatibilities Storage Avoid freezing, excessive heat or exposure to light, especially direct sunlight. If heating is necessary to prevent freezing, care must be taken to prevent overheating. Precautions should be taken to ensure that the average product temperature is maintained below 43 °C. Temperature monitoring is recommended. At elevated temperatures, self-heating can lead to vigorous gas generation and over-pressurization of storage containers if appropriate controls are not in place. Avoid exposure of this product to incompatible materials/chemicals (see Stability and Reactivity section). Use of incompatible materials can promote the exothermic decomposition of the product. In extreme cases, this could result in vigorous gas formation and over-pressurization of the storage container. STORAGE CONTAINER: Vented and opaque containers: As the product ages, activity is gradually lost and pressure can build-up in the headspace

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(nitrogen); therefore, the product should be stored in vented containers. Product should also be stored in opaque containers to prevent exposure to light. To maximize product shelf life, store the product in an opaque container, in a cool, dry, well-ventilated area. Store locked up. Store in corrosive resistant container with a resistant inner liner.

Incompatible Materials This product is strongly basic and an oxidizing agent. Avoid contact with alcohols, aldehydes, strong reducing agents, strong oxidizers, acids, ammonia-containing products, and common metals such as steel, aluminum, iron and copper. Use of incompatible materials can promote the exothermic decomposition of the product.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .

Component CAS-No ACGIH TLV (TWA) OSHA PEL (TWA) NIOSH IDLH Water 7732-18-5 - - -

Halogenated Complex - - - - Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 TWA: 2 mg/m3

(vacated) Ceiling: 2 mg/m3

IDLH: 10 mg/m3

Ceiling: 2 mg/m3

Component CAS-No Alberta British Columbia Ontario Quebec Water 7732-18-5 - - - -

Halogenated Complex - - - - - Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 Ceiling: 2 mg/m3 CEV: 2 mg/m3 Ceiling: 2 mg/m3

Other information Wear suitable protective clothing.

Appropriate engineering controls Engineering Controls Use only in well-ventilated areas.

Individual protection measures, such as personal protective equipment Eye/face Protection Chemical goggles or face shield with safety glasses.

Skin Protection Wear protective gloves/clothing.

Hand protection Gloves resistant to chemical permeation.

Respiratory protection None under normal conditions.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state Liquid Color Yellow. Orange.

Odor Mild.

Odor Threshold No data available

Molecular Weight No data available pH 12.4 - 14.0 Melting point/freezing point ca 0 °C / 32 - °F Boiling Point/Range ca 106 °C / 223 - °F Flash Point No data available.

Evaporation Rate No data available.

Flammability (solid, gas) No data available Flammability Limit in Air

Upper flammability limit: No data available Lower flammability limit: No data available

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Vapor Pressure 19 mm Hg (25°C) Vapor Density No data available Density 1.29 - 1.37 (25°C) Solubility(ies)

Water Solubility Miscible.

Solubility in other solvents No data available

Partition coefficient No data available Autoignition temperature No data available Decomposition temperature No data available Viscosity, kinematic 2 cSt (25°C) Dynamic viscosity No data available

Explosive Properties None Oxidizing Properties None

10. STABILITY AND REACTIVITY

Reactivity Hazard No data available.

Stability No information available

Hazardous Reactions No hazardous reaction expected under normal handling.

Hazardous Polymerization None under normal processing.

Conditions to Avoid Extremes of temperature and direct sunlight. Keep away from heat. Freezing.

Materials to avoid This product is strongly basic and an oxidizing agent. Avoid contact with alcohols, aldehydes, strong reducing agents, strong oxidizers, acids, ammonia-containing products, and common metals such as steel, aluminum, iron and copper. Use of incompatible materials can promote the exothermic decomposition of the product.

Hazardous decomposition products Bromine, Chlorine.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation Not expected to be acutely toxic.

Eye contact Causes severe burns.

Skin contact Causes severe burns.

Ingestion May be harmful if swallowed.

Potential Health Effects Acute Effects Skin Corrosion/irritation Data obtained from tests on used product. Skin irritation. (rabbit). (4 hr): Causes severe burns.

Serious eye damage/eye irritation Causes severe eye damage.

Respiratory irritation No data available

Sensitization: Data obtained from tests on used product: Buehler Test. (guinea pig): Not sensitizing.

STOT - single exposure No information available.

Chronic Effects Mutagenic Effects No information available.

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Carcinogenicity There are no known carcinogenic chemicals in this product.

Component CAS-No ACGIH

Carcinogens

IARC NTP OSHA

Carcinogens Water 7732-18-5 - - - - Halogenated Complex - - - - - Sodium hydroxide 1310-73-2 - - - -

Reproductive Effects No information available.

STOT - repeated exposure No information available.

Chronic Effects No information available

Aspiration hazard No information available.

Numerical measures of toxicity Product Information Data obtained from tests on used product:

LD50 Oral: Rat Oral LD50: 2491 mg/kg LD50 Dermal: Rat Dermal LD50: > 2000 mg/kg Inhalation LC50: Rat Inhalation LC50: > 20.37 mg/L (4h) (aerosol)

Component Information No information available

12. ECOLOGICAL INFORMATION

Ecotoxicity

Toxic to aquatic life.

LC50/96h/fish: 3.8 mg whole material/L ( Bluegill sunfish ) EC50/48h/Daphnia : 4.8 mg whole material/L ( Waterflea Daphnia magna ) IC50/96-hour: 2.6 mg whole material/L ( Unicellular Green Alga, Selenastrum capricornutum )

Persistence/Degradability Inorganic substance.

Bioaccumulation/ Accumulation Not likely to bioaccumulate.

Mobility in Environmental Media No information available.

Other adverse effects No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods Waste Disposal Method Dispose in a safe manner in accordance with local/national regulations.

Contaminated Packaging Do not reuse container.

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15. REGULATORY INFORMATION

(X) Complies (-) Does not Comply

THIS MATERIAL IS EXEMPT FROM THE TOXIC SUBSTANCES CONTROL ACT (15 USC 2601-2629)

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

Reportable and Threshold Planning Quantities The following components have RQs and/or TPQs under SARA and/or CERCLA

Component CERCLA RQ, lbs SARA 302 RQ, lbs SARA 302 TPQ, lbs Sodium hydroxide (CAS #: 1310-73-2) 1000 lb - -

14. TRANSPORT INFORMATION

DOT

Proper Shipping Name Corrosive Liquids, Basic, Inorganic, N.O.S. (Halogenated Complex, Sodium Hydroxide) Hazard Class 8 UN No. 3266 Packing Group III Description UN 3266 Corrosive liquid, Basic, Inorganic, N.O.S. (Halogenated complex, Sodium hydroxide), 8, III

TDG This material is considered as Dangerous Goods per regulations of Transport Canada. The use of the above US DOT information from US 49 CDR regulations is allowed for shipments that originate in the United States.

IMDG/IMO

IMO Class 8 Packing Group III UN-No 3266 IMO Labelling and Marking 8 Proper Shipping Name Corrosive liquid, Basic, Inorganic, N.O.S. (Halogenated complex, Sodium hydroxide) EmS F-A, S-B Marpol - Annex II Not determined Marpol - Annex III Unregulated Transport Description UN 3266 Corrosive liquid, Basic, Inorganic, N.O.S. (Halogenated complex, Sodium hydroxide), 8, III

IATA/ICAO

IATA/ICAO Class 8 Packing Group III UN-No 3266 IATA/ICAO Labelling/Marking 8 Passenger Aircraft Forbidden (Product is shipped in containers with vented caps) Cargo aircraft only Forbidden (Product is shipped in containers with vented caps) Proper shipping name Corrosive liquid, Basic, Inorganic, N.O.S. (Halogenated complex, Sodium hydroxide) Transport Description UN 3266 Corrosive liquid, Basic, Inorganic, N.O.S. (Halogenated complex, Sodium hydroxide), 8, III

International Inventories TSCA DSL NDSL AICS EINECS ENCS KECL PICCS IECSC NZIoC TCSI STABROM® 909 Biocide - - - X - - X X X X -

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State Right-to-Know This product contains the following chemicals regulated in the states listed below.

Component California Prop.

New Jersey Massachusetts Pennsylvania

Sodium hydroxide (CAS #: 1310-73-2) - X X X

16. OTHER INFORMATION

Prepared By Health & Environment DepartmentAlbemarle Corporation

FOR ADDITIONAL NONEMERGENCY PRODUCT INFORMATION, CONTACT:

HEALTH AND ENVIRONMENT DEPARTMENT

ALBEMARLE CORPORATION

451 FLORIDA ST.

BATON ROUGE, LA. 70801

(800) 535-3030

Preparation Date : 24-Apr-2015 Revision Date: 07-Jan-2019 Disclaimer:

The information contained herein is accurate to the best of our knowledge. The Company makes no warranty of any kind, express or implied, concerning the safe use of this material in your process or in combination with other substances.

End of Safety Data Sheet

NFPA Health 3 Flammability 0 Instability 0 Physical Hazards - HMIS Health 3 Flammability 0 Physical Hazards 0

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