09 Attachment 5 Virkon S MSDS.pdf
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- Attached to
- Fish Treatment Chemicals
- Solicitation number
- 6100054186
- Issued by
- Centre County, Terre Hill Borough, Pennsylvania
About this file
This document is a Safety Data Sheet (SDS) for the disinfectant product Virkon S, which is regulated by the U.S. Environmental Protection Agency (EPA). Virkon S is a powder disinfectant with active ingredients including potassium peroxymonosulfate, sodium chloride, and other substances. The SDS provides detailed information on the product's hazards, first aid measures, handling and storage, exposure controls, physical and chemical properties, toxicological information, ecological information, disposal considerations, and regulatory information.
The SDS indicates that Virkon S is classified as causing skin and eye irritation, as well as respiratory tract irritation. Precautions are required when handling the concentrated product, including the use of personal protective equipment. The product is registered with the EPA under registration number 39967-137. The SDS also includes information on toxicity to aquatic organisms and provides guidance on proper disposal of the product.
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Virkon(TM) S
SAFETY DATA SHEET
Product identifier
In case of emergency
Section 1. Identification
Identified uses Disinfectant, Cleaning agents
Material Number : 57818065
EPA Registration Number: :
Supplier/Manufacturer :
39967-137
LANXESS Corporation Product Safety & Regulatory Affairs 111 RIDC Park West Drive Pittsburgh, PA 15275-1112
For Information: US/Canada (800) LANXESS) International: +1 412 809 1000
CHEMTREC (800) 424 9300
International (703) 527 3887 Lanxess Emergency Phone: (866) 673 6350
Section 2. Hazards identification
SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Classification of the substance or mixture
Signal word : Danger
Hazard statements : Causes serious eye damage. Causes skin irritation. May cause respiratory irritation.
Hazard pictograms :
Precautionary statements
Prevention : Wear protective gloves and eye/face protection. Use only in a well-ventilated area.
Avoid breathing dust. Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.
HAZCOM Standard Status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Supplemental label elements
: Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink.
Physical state : Powder.
Color : Yellow
Hazard Not Otherwise Classified (HNOC)
: None known.
Virkon(TM) S 1/1357818065 1Version
Section 3. Composition/information on ingredients
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Pentapotassium bis(peroxymonosulphate) bis(sulphate) 25 - 50 70693-62-8 Sodium Dodecylbenzene Sulfonate 10 - ≤25 25155-30-0 Butanedioic acid, 2-hydroxy- ≤10 6915-15-7 sulphamic acid ≤5 5329-14-6 Potassium hydrogen sulphate ≤5 7646-93-7 Sodium chloride ≤5 7647-14-5 dipotassium peroxodisulphate ≤5 7727-21-1 Dipotassium disulphate ≤5 7790-62-7 dipentene <1 138-86-3
Get medical attention immediately. Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. In case of contact with eyes, flush eyes with plenty of water for at least 30 minutes. Chemical burns must be treated promptly by a physician.
In case of contact, flush skin with plenty of water for at least 30 minutes. Get medical attention immediately. Immediately remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. If not breathing, if breathing is irregulor or respiratory arrest occurs, provide artifical respiration, or oxygen by a trained professional, using a pocket type respirator.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
Description of first aid measures
Inhalation : May cause respiratory irritation.
May cause burns to mouth, throat and stomach.:Ingestion
Skin contact : Causes skin irritation.
Causes serious eye damage. May cause mechanical irritation (abrasion).:Eye contact
Over-exposure signs/symptoms
Potential acute health effects
Virkon(TM) S 2/1357818065 1Version
Section 4. First aid measures
Protection of first-aiders : If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. No specific treatment.
Skin contact
Ingestion
Inhalation May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose.
Corrosive with symptoms of coughing, burning, ulceration, and pain.
Corrosive with symptoms of reddening, itching, swelling, burning and possible permanent damage.
Causes irritation with symptoms of reddening, itching, and swelling.
Eye contact : Corrosive with symptoms of reddening, tearing, swelling, burning and possible permanent damage.
See toxicological information (Section 11)
Potential chronic health effects
Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:
carbon dioxide carbon monoxide nitrogen oxides sulfur oxides phosphorus oxides halogenated compounds metal oxide/oxides
Toxic and irritating gases/fumes may be given off during burning or thermal decomposition. Water runoff from fire fighting may be corrosive.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire. In case of fire, use water spray (fog), foam or dry chemical.
Extinguishing media
Carbon dioxide (CO₂).
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe dust. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Virkon(TM) S 3/1357818065 1Version
Section 6. Accidental release measures Move containers from spill area. Approach release from upwind. Avoid dust generation.
Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Avoid creating dusty conditions and prevent wind dispersal. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Prevent entry into sewers, water courses, basements or confined areas.
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Conditions for safe storage Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Empty containers retain product residue and can be hazardous. Do not reuse container.
Protective measures Do not get in eyes or on skin or clothing. Do not breathe dust. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Remove contaminated clothing and protective equipment before entering eating areas. Workers should wash hands and face before eating, drinking and smoking. Put on appropriate personal protection equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed.
Precautions for safe handling
Pentapotassium bis(peroxymonosulphate) bis(sulphate) None Sodium Dodecylbenzene Sulfonate None Butanedioic acid, 2-hydroxy- None sulphamic acid None Potassium hydrogen sulphate None Sodium chloride None dipotassium peroxodisulphate ACGIH TLV (United States, 3/2016).
TWA: 0.1 mg/m³, (as persulfate) 8 hours.
Dipotassium disulphate None dipentene None
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Occupational exposure limits
Appropriate engineering controls
: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Personal protection
Virkon(TM) S 4/1357818065 1Version
Section 8. Exposure controls/personal protection Although no exposure limit has been established for this product, the OSHA PEL for Particulates Not Otherwise Regulated (PNOR) of 15 mg/m3 - total dust, 5 mg/m3 -respirable fraction is recommended. In addition, the ACGIH recommends 3 mg/m3 -respirable particles and 10 mg/m3 - inhalable particles for Particles (insoluble or poorly soluble) Not Otherwise Specified (PNOS). The following respirator is recommended if airborne concentrations exceed the appropriate standard/guideline. NIOSH approved, air-purifying particulate respirator with N-95 filters.
Respiratory protection :
Skin protection : Wear suitable protective clothing and gloves. Suitable protective footwear.
Eye/face protection : chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. If contact with product is possible, wear safety glasses with side shields.
Medical Surveillance Not available.:
Section 9. Physical and chemical properties Physical state
Melting point
Vapor pressure
Vapor density
Solid. [Powder.]
Not available.
Not available.
Not available.
Pleasant. Sweet.Odor pH
Yellow Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Not available.
Not available.
2.2 to 2.7 [Conc. (% w/w): 1%]
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-octanol/water
Boiling point : Not available.
Decomposition temperature : Not available.
Explosion limits : Not available.
Specific gravity (Relative density)
1.07:
Solubility in water : 65 g/l
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid Protect from moisture.
Sulfur dioxide, Chlorine
The product is stable.Chemical stability
Strong bases, Combustible material., Acids, Oxidizers, brass, Copper, halogenated compounds, cyanides, heavy metal compounds
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Virkon(TM) S 5/1357818065 1Version
Section 11. Toxicological information
Acute toxicity
Irritation/Corrosion
Information on toxicological effects
Information on the likely routes of exposure
Inhalation : May cause respiratory irritation.
May cause burns to mouth, throat and stomach.:Ingestion
Skin contact : Causes skin irritation.
Causes serious eye damage. May cause mechanical irritation (abrasion).:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose.
Corrosive with symptoms of coughing, burning, ulceration, and pain.
Corrosive with symptoms of reddening, itching, swelling, burning and possible permanent damage.
Causes irritation with symptoms of reddening, itching, and swelling.
Eye contact : Corrosive with symptoms of reddening, tearing, swelling, burning and possible permanent damage.
: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Potential chronic health effects
Potential immediate effects
: Not available.
Short term exposure
Long term exposure
Potential delayed effects : Not available.
Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Product/ingredient name Result Species Dose Exposure
Virkon(TM) S LD50 Oral Rat - Male, Female
4123 mg/kg - OECD 401 Acute Oral Toxicity
Virkon(TM) S LD50 Dermal Rat - Male, Female
2200 mg/kg Extrapolation according to Regulation (EC) No. 440/2008
Virkon(TM) S LC50 Inhalation Dusts and mists
Rat - Male, Female
3.7 mg/l the particle size measurements of the product indicate that it is not respirable and therefore not bioavailable by the inhalation route.
4 hours -
Test
Virkon(TM) S 6/1357818065 1Version
Mutagenicity
Pentapotassium bis (peroxymonosulphate) bis (sulphate)
OECD 476 In vitro Mammalian Cell Gene Mutation Test
Experiment: In vitro Subject: Mammalian-Animal Cell: Somatic Metabolic activation: +/-
Positive
OECD 473 In vitro Mammalian Chromosomal Aberration Test
Experiment: In vitro Subject: Mammalian-Human Cell: Somatic Metabolic activation: +/-
Positive
OECD 471 Bacterial Reverse Mutation Test
Experiment: In vitro Subject: Bacteria Metabolic activation: +/-
Negative
OECD 474 Mammalian Erythrocyte Micronucleus Test
Experiment: In vivo Subject: Mammalian-Animal
Negative sulphamic acid OECD 471 Bacterial Reverse Mutation Test
Experiment: In vitro Subject: Bacteria Metabolic activation: With and Without
Negative
OECD 471 Bacterial Reverse Mutation Test
Experiment: In vitro Subject: Bacteria Metabolic activation: With and
Negative
Product/ingredient name Test Experiment Result sulphamic acid Eyes - Cornea opacity Rabbit 2 - 4 hours Fully reversible
Eyes - Redness of the conjunctivae
Rabbit 1.5 - 7 days Fully reversible
Eyes - Edema of the conjunctivae
Rabbit 1.5 - 7 days Fully reversible in more than 7 days
Product/ingredient name
Result Score Exposure Observation
Conclusion/Summary
Skin : Irritating to skin. Moderate irritant
Eyes : Risk of serious damage to eyes.
Sensitization
Virkon(TM) S skin Guinea pig Not sensitizing Respiratory Mammal - species unspecified Not sensitizing
Product/ingredient name Route of exposure
Species Result
Skin : Not sensitizing
Respiratory : Not sensitizing
Species
Chronic toxicity
Pentapotassium bis (peroxymonosulphate) bis (sulphate)
Sub-acute NOEL Oral Rat - Male, Female
>1000 mg/kg bw/ day
28 days
Sub-chronic LOAEL Oral Rat - Male, Female
600 mg/kg bw/ day
90 days; 7 days per week daily
Sodium Dodecylbenzene Sulfonate
Chronic NOAEL Oral Rat 220 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary : Butanedioic acid, 2-hydroxy-:No known significant effects or critical hazards.
Reversibility
Virkon(TM) S 7/1357818065 1Version
Carcinogenicity
Without OECD 476 In vitro Mammalian Cell Gene Mutation Test
Experiment: In vitro Subject: Mammalian-Animal Metabolic activation: With and Without
Negative
OECD 476 In vitro Mammalian Cell Gene Mutation Test
Experiment: In vitro Subject: Mammalian-Animal Metabolic activation: With and Without
Negative
OECD 487 In vitro Micronucleus Test
Experiment: In vitro Subject: Mammalian-Human Metabolic activation: with and without
Negative
Conclusion/Summary : dipotassium peroxodisulphate:Not mutagenic in a standard battery of genetic toxicological tests.
Reproductive toxicity
Conclusion/Summary : Butanedioic acid, 2-hydroxy-:No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Pentapotassium bis(peroxymonosulphate) bis(sulphate) Category 3 Not applicable. Respiratory tract irritation
Butanedioic acid, 2-hydroxy- Category 3 Not applicable. Respiratory tract irritation sulphamic acid Category 3 Not applicable. Respiratory tract irritation
Potassium hydrogen sulphate Category 3 Not applicable. Respiratory tract irritation
Sodium chloride Category 3 Not applicable. Respiratory tract irritation dipotassium peroxodisulphate Category 3 Not applicable. Respiratory tract irritation
Name Category
Not available.
Route ATE value (Acute Toxicity Estimates)
Acute toxicity estimates
Route of exposure
Target organs
Product/ingredient name IARC NTP OSHACAS #
Pentapotassium bis (peroxymonosulphate) bis(sulphate)
70693-62-8 Not classified. Not classified. Not classified.
Sodium Dodecylbenzene Sulfonate 25155-30-0 Not classified. Not classified. None Butanedioic acid, 2-hydroxy- 6915-15-7 Not classified. Not classified. Not classified.
sulphamic acid 5329-14-6 Not classified. Not classified. Not classified.
Potassium hydrogen sulphate 7646-93-7 Not classified. Not classified. Not classified.
Sodium chloride 7647-14-5 Not classified. Not classified. Not classified.
dipotassium peroxodisulphate 7727-21-1 Not classified. Not classified. Not classified.
Dipotassium disulphate 7790-62-7 Not classified. Not classified. Not classified.
dipentene 138-86-3 Not classified. Not classified. Not classified.
Virkon(TM) S 8/1357818065 1Version
Section 12. Ecological information Toxicity
Product/ingredient name SpeciesResult Exposure
Pentapotassium bis (peroxymonosulphate) bis (sulphate)
OECD 201 Alga, Growth Inhibition Test
Acute EC50 >1 mg/l Fresh water Algae - Pseudokirchneriella subcapitata
72 hours
OECD 202 Daphnia
sp. Acute Immobilization Test
Acute EC50 3.5 mg/l Fresh water
Daphnia - Daphnia magna
48 hours
OECD 203 Fish, Acute Toxicity Test
Acute LC50 53 mg/l Fresh water Fish - Oncorhynchus mykiss
96 hours
OECD 201 Alga, Growth Inhibition Test
Chronic NOEC 0.5 mg/l Fresh water
Algae - Pseudokirchneriella subcapitata
72 hours
Sodium Dodecylbenzene Sulfonate
- Chronic NOEC 4 mg/l Daphnia - Daphnia magna
7 days
- Chronic NOEC 3.1 mg/l Fish - Oncorhynchus kisutch
3 days
Butanedioic acid, 2-hydroxy- OECD 201 Alga, Growth Inhibition Test
Acute EC50 >100 mg/l Fresh water
Algae - Daphnia magna
72 hours
OECD 202 Daphnia
sp. Acute Immobilization Test
Acute EC50 240 mg/l Fresh water
Daphnia - Daphnia magna
48 hours
OECD 203 Fish, Acute Toxicity Test
Acute LC50 >100 mg/l Fresh water
Fish - Danio rerio 96 hours
OECD 201 Alga, Growth Inhibition Test
Chronic NOEC 100 mg/l Fresh water
Algae - Daphnia magna
72 hours sulphamic acid OECD 201 Alga, Growth Inhibition Test
Acute EC50 48 mg/l Fresh water Algae - Desmodesmus subspicatus
72 hours
OECD 202 Daphnia
sp. Acute Immobilization Test
Acute EC50 71.6 mg/l Fresh water
Daphnia - Daphnia magna
48 hours
OECD 209 Activated Sludge, Respiration Inhibition Test
Acute EC50 >200 mg/l Fresh water
Micro-organism 3 hours
OECD 203 Fish, Acute Toxicity Test
Acute LC50 70.3 mg/l Fresh water
Fish - Pimephales promelas
96 hours
OECD 201 Alga, Growth Inhibition Test
Chronic EC10 29.5 mg/l Fresh water
Algae - Desmodesmus subspicatus
72 hours
OECD 201 Alga, Growth Inhibition Test
Chronic NOEC 18 mg/l Fresh water
Algae - Desmodesmus subspicatus
72 hours
Sodium chloride - Acute EC50 402.6 mg/l Daphnia 48 hours
- Acute LC50 7400 mg/l Fish 96 hours dipotassium peroxodisulphate
OECD 201 Alga, Growth Inhibition Test
Acute EC50 83.7 mg/l Algae - Pseudokirchneriella subcapitata
72 hours
- Acute EC50 120 mg/l Daphnia - Daphnia magna
48 hours
- Acute LC50 76.3 mg/l Fish - Oncorhynchus mykiss
96 hours
Dipotassium disulphate - Acute EC10 656 mg/l Read-across from CAS # 7778-80-5 Fresh water
Algae - Pseudokirchneriella subcapitata
96 hours
Test
Virkon(TM) S 9/1357818065 1Version
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
: No known significant effects or critical hazards.
Product/ingredient name
Pentapotassium bis (peroxymonosulphate) bis (sulphate)
<0.3 - low
Sodium Dodecylbenzene Sulfonate
0.45 220 low
Butanedioic acid, 2-hydroxy- -1.26 - low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Butanedioic acid, 2-hydroxy- - - Readily Sodium chloride - - Readily dipentene - - Not readily
Conclusion/Summary : Not available.
Persistence and degradability
Butanedioic acid, 2-hydroxy- OECD 301B Ready Biodegradability - CO₂ Evolution Test
67.5 % - Readily - 28 days - -
Product/ingredient name Test DoseResult Inoculum
Conclusion/Summary : Not available.
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Other adverse effects
- Acute EC50 1492 mg/l Read-across from CAS # 7778-80-5 Fresh water
Algae - Pseudokirchneriella subcapitata
96 hours
- Acute EC50 720 mg/l Read-across from CAS # 7778-80-5 Fresh water
Daphnia - Daphnia magna
48 hours
- Acute LC50 680 mg/l Read-across from CAS # 7778-80-5 Fresh water
Fish - Pimephales promelas
96 hours
- Chronic NOEC 790 mg/l Read-across from CAS # 7757-82-6 Fresh water
Daphnia - Daphnia dubia (water flea)
7 days
- Chronic NOEC >595 mg/l Read-across from CAS # 7757-82-6 Fresh water
Fish - Pimephales promelas
7 days dipentene - Acute EC50 0.421 mg/l Fresh water
Daphnia - Daphnia magna
48 hours
- Acute LC50 0.702 mg/l Fresh water
Fish - Pimephales promelas
96 hours
Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal should be in accordance with existing federal state, provincial and or local environmental controls laws.
:Disposal methods
Virkon(TM) S 10/1357818065 1Version
Section 13. Disposal considerations RCRA classification : : If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40
CFR 261.20-24)
Section 14. Transport information
9 8, 146, 335, A112, B54, B120, IB8, IP3,
N20, N91, T1, TP33
When in individual containers of less than the Product RQ, this material ships as non-regulated.
DOT Classification Environmentally hazardous substance, solid, n.o.s. (SODIUM
DODECYLBENZENE
SULFONATE)
III
IMDG Class
IATA-DGR Class
Regulatory information
UN number Proper shipping name
Classes PG* Label Additional information
UN3077
PG* : Packing group
7310 lbsRQ :
-- Not regulated.
Not regulated.
Section 15. Regulatory information
State regulations The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections on the SDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropraite agency in your state.
Sodium Metaphosphate 10124-56-8 MA - S, PA - RTK HS 10 - ≤25 Sodium Dodecylbenzene Sulfonate 25155-30-0 MA - S, NJ - HS, PA - RTK HS 10 - ≤25 dipotassium peroxodisulphate 7727-21-1 MA - S, NJ - HS, PA - RTK HS ≤5 sulphamic acid 5329-14-6 NJ - HS ≤5 Potassium hydrogen sulphate 7646-93-7 NJ - HS ≤5 Pentapotassium bis (peroxymonosulphate) bis(sulphate)
70693-62-8 25 - 50
Butanedioic acid, 2-hydroxy- 6915-15-7 ≤10
Ingredient name CAS number State Code Concentration
SARA Title III Section 313 Toxic Chemicals
SARA 311/312 :
SARA Title III Section 302 Extremely Hazardous Substances
Immediate (acute) health hazard
US EPA CERCLA
Hazardous Subtances (40
CFR 302.4)
CAS numberIngredient name RQ
Sodium Metaphosphate 10124-56-8 5000 lbs. (2270 kg)
Sodium Dodecylbenzene Sulfonate 25155-30-0 1000 lbs. (454 kg)
None
None
Virkon(TM) S 11/1357818065 1Version
Section 15. Regulatory information
U.S. Toxic Substances Control Act
: This product is excluded from TSCA Regulation under FIFRA Section 3 (2)(B)(ii) when used as a pesticide.
WARNING: This product contains a chemical known to the State of California to cause cancer.
California Prop. 65
Ingredient name Cancer ReproductiveCAS # Concentration (%)
7-methyl-3-methyleneocta-1, 6-diene
123-35-3 ≤0.1 Yes
Massachusetts Substances: MA - S Massachusetts Extraordinary Hazardous Substances: MA - Extra HS New Jersey Hazardous Substances: NJ - HS Pennsylvania RTK Hazardous Substances: PA - RTK HS Pennsylvania Special Hazardous Substances: PA - Special HS
FIFRA
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.
Signal word : DANGER
Hazard statements : Danger. Powder is corrosive. Causes irreversible eye damage and skin burns. Harmful if swallowed or absorbed through skin. Corrosive statement does not refer to 1% in-use solution.
FIFRA Registered Composition:
Active Ingredients:
Potassium peroxymonosulfate (CAS# 10058-23-8) 21.41% Sodium chloride (CAS# 7647-14-5) 1.5% Other Ingredients 77.09% Total: 100%
39967-137EPA Registration Number :
Section 16. Other information Hazardous Material Information System
National Fire Protection Association (U.S.A.)
The customer is responsible for determining the PPE code for this material. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
0= Minimal 1=Slight 2=Moderate 3=Serious 4=Severe
0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme *=Chronic
No.
3Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Virkon(TM) S 12/1357818065 1Version
Section 16. Other information
Notice to reader
Date of issue
Date of previous issue
Version :
Our method of hazard communication is comprised of Product Labels and Safety Data Sheets. HMIS and NFPA ratings are provided as a customer service.
Indicates information that has changed from previously issued version.
08-14-2017
No previous validation
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Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
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