05 Attachment 1 Hydrogen Peroxide 35% MSDS.pdf

Hercules Pro-Poxy SDS US SDS # 7375E Version #: 01 Revision date: Issue date: 11-May-2015 Page 1 of 7

SAFETY DATA SHEET

1. Identification

Product identifier Hercules Propoxy® 20

Other means of identification

Product code 7375E

Synonyms Part Numbers: 25515

Recommended use Epoxy based sealant.

Recommended restrictions None known.

Manufacturer/Importer/Supplier/Distributor information

Company Name HCC Holdings, Inc. an Oatey Affiliate

Address 4700 West 160th Street

Cleveland, OH 44135

Telephone 216-267-7100

E-mail info@oatey.com

Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)

Emergency First Aid 1-877-740-5015

Contact person MSDS Coordinator

2. Hazard(s) identification

Physical hazards Not Classified.

Health hazards Skin corrosion/irritation Cat 2B

Serious eye damage/eye irritation Cat 2B

Skin sensitization Cat 1

OSHA defined hazards Not Classified

Label elements

Signal word Warning!

Hazard statement Causes skin and eye irritation.

May cause an allergic skin reaction.

Precautionary statement

Prevention Wear protective gloves. Wear eye or face protection. Avoid breathing dust. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.

Response IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage Not applicable.

Disposal Dispose of contents and container in accordance with all local, regional, national and International regulations.

Hazard(s) not otherwise classified (HNOC)

None known.

SDS # 7375E Version #: 01 Revision date: Issue date: 11-May-2015 Page 2 of 7

3. Composition/information on ingredients

Mixtures

Chemical name CAS number % reaction product: bisphenol-A-(epichlorhydrin); epoxy resin 25068-38-6 10 – 30

2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 1 – 5 crystalline silica non-respirable 14808-60-7 0.1 - 1

*Designates that a specific chemical identity and or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Skin contact Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.

Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Ingestion Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Irritating to mouth, throat and stomach.

Indication of immediate medical attention and special treatment

Needed

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

General information None

5. Fire-fighting measures

Suitable extinguishing media Use an existing agent suitable for surrounding fire.

Unsuitable extinguishing media None known.

Specific hazards arising from the chemical

No specific fire or explosion hazard.

Special protective equipment and precautions for firefighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Fire-fighting equipment/instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Specific methods None

General fire hazards None

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Methods and materials for Large Spills: Move containers from spill area. Approach release from upwind. Prevent entry into

SDS # 7375E Version #: 01 Revision date: Issue date: 11-May-2015 Page 3 of 7 containment and cleaning up sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep.

Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Small Spills: Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container.

Dispose of via a licensed waste disposal contractor.

Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

7. Handling and storage

Precautions for safe handling Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use.

Empty containers retain product residue and can be hazardous. Do not reuse container.

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

Do not store above the following temperature: 35°C (95°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Use appropriate containment to avoid environmental contamination.

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value crystalline silica non-respirable (CAS 14808-60-7) PEL 10 mg/M3

US. ACGIH Threshold Limit Values crystalline silica non-respirable (CAS 14808-60-7) Ceiling 0.025 mg/m^3

US. NIOSH: Pocket Guide to Chemical Hazards crystalline silica non-respirable (CAS 14808-60-7) Ceiling 0.05 mg.m^3

Biological limit values No Biological limits.

Appropriate engineering controls

Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Individual protection measures, such as personal protective equipment

Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Skin protection

Hand Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be

SDS # 7375E Version #: 01 Revision date: Issue date: 11-May-2015 Page 4 of 7 accurately estimated.

Other Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Thermal hazards None.

General hygiene considerations

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

9. Physical and chemical properties

Appearance Physical state Solid.

Form Rod Color Black/White Odor Sulfurous Odor threshold Not available.

pH Not Applicable Melting point/freezing point Not available.

Initial boiling point and boiling range

Not determined

Flash point Not Applicable Upper/lower flammability or explosive limits Flammability limit – lower (%) Not Available Flammability limit – upper (%) Not Available Explosive limit - lower (%) Not Available Explosive limit - upper (%) Not Available Vapor pressure Not Available Vapor density Not Available Relative density 1.95 Solubility(ies) Insoluble in the following materials: cold water and hot water.

Solubility (water) Not applicable Partition coefficient (n-octanol/water) Not Available Auto-ignition temperature Not Available Decomposition temperature >150°C (>302°F) Viscosity Not Available Other information VOC (Weight %) < 0.1% by weight

10. Stability and reactivity

Reactivity No specific test data related to reactivity available for this product or its ingredients.

Chemical stability The product is stable.

Possibility of hazardous reaction

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid No specific data.

Incompatible materials No specific data.

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

11. Toxicological information

Information on likely routes of exposure Inhalation Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Skin contact Causes skin irritation. May cause an allergic skin reaction.

Eye contact Causes serious eye irritation.

Ingestion Irritating to mouth, throat and stomach.

Symptoms related to the Irritation, pain or redness

SDS # 7375E Version #: 01 Revision date: Issue date: 11-May-2015 Page 5 of 7 physical, chemical and toxicological characteristics

Information on likely routes of exposure Acute Toxicity

Components Species Results

2,4,6-tris (dimethylaminomethyl)phenol LD50 Dermal Rat 1280 mg/kg

LD50 Oral Rat 1200 mg/kg

Skin corrosion/irritation Prolonged skin contact may cause temporary irritation

Serious eye damage/eye irritation

Direct contact in the eye may cause temporary irritation

Respiratory or skin sensitization Respiratory sensitization Not considered a respiratory irritant

Skin sensitization This product is not expected to cause skin irritation.

Germ cell mutagenicity No specific data

Carcinogenicity No known significant effects or critical hazards.

Reproductive toxicity No known significant effects or critical hazards.

Specific target organ toxicity

Single exposure Repeated exposure

Not Classified.

Not Classified.

Aspiration Hazard Not an aspiration hazard.

Chronic effects Not Classified.

Further information Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

12. Ecological information

Ecotoxicity No Specific Data.

Persistence and degradability No Specific Data.

Bio accumulative potential

Product/ingredient name LogPow BCF Potential reaction product: bisphenol-A-(epichlorhydrin); epoxy resin

2.64 – 3.78 31 low

2,4,6-tris(dimethylaminomethyl)phenol .219 - low

Mobility in soil Not available

Other adverse effects No known significant effects or critical hazards.

13. Disposal considerations

Disposal instructions Local disposal regulations Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Hazardous waste code Not available

Waste from residues / unused products

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Contaminated packaging Waste packaging should be recylcled.

14. Transportation information

DOT

UN number Not Regulated

UN Proper Shipping Name -

Transportation Hazard classes

Packing group - IATA Not Regulated

UN number -

SDS # 7375E Version #: 01 Revision date: Issue date: 11-May-2015 Page 6 of 7

UN Proper Shipping Name -

Transportation Hazard classes

Packing group -

IMDG

UN number Not regulated

UN Proper Shipping Name -

Transportation Hazard classes

Packing group - Environmental hazards Marine polluntant

15. Regulatory information

U.S. Federal regulations TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me, reaction products with silica

TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted.

Clean Water Act (CWA) 307: zinc sulphide

Clean Air Act Section 112 Not Listed

(b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Not Listed Class I Substances Clean Air Act Section 602 Not Listed Class II Substances

SARA 302/304

Composition/information on ingredients

No products were found.

SARA 304 RQ Not applicable.

SARA 311/312

Classification Immediate (acute) health hazard

Name wt %

Fire Hazard

Sudden release of pressure

Reactive

Immediate (acute) health hazard

Delayed (Chronic) health hazard reaction product: bisphenol-A-(epichlorhydrin);

epoxy resin

10 – 30 No No No Yes No

2,4,6-tris(dimethylaminomethyl)phenol 1 – 5 No No No Yes No crystalline silica non-respirable 0.1 - 1 No No No No Yes

Sara 313

Product Name CAS Number Wt%

Form R- Reporting requirements

Zinc sulphide 1314-98-3 1-5

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

US state regulations Massachusetts The following components are listed: soapstone, mineral wool fiber

New York None of the components are listed

New Jersey The following components are listed: soapstone; silica quartz, quartz (SiO2); zinc compounds

Pennsylvania The following components are listed: soapstone dust; quartz (SiO2); zinc compounds

SDS # 7375E Version #: 01 Revision date: Issue date: 11-May-2015 Page 7 of 7

California Prop 65 This product contains a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm. (Talc, not containing asbestiform fibers and crystalline silica, non-repirable)

International regulations

Country(s) or region Inventory Name On inventory list (yes/no)*

Canada Domestic Substance List (DSL) Yes

Australia Australian Inventory of Chemical Substances (AICS) Yes

China Inventory of Existing Chemical Substances in China (IECSC) Yes

United States & Puerto Rico Toxic Substances Control Act (TSCA) Yes

16. Other information, including date of preparation or last revision

Issue Date 11-May-2015

Revision Date -

Version # 01

HMIS Rating Health:

Flammability:

Physical Hazards:

Disclaimer HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.