085580 Buckeye Quat 256 SDS.pdf

Safety Data Sheet

Issue Date: 25-Mar-2020

Revision Date: 25-Mar-2020

Version 1

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Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product Identifier

SDS # BE-5092-EU

Product Code 5092 Product Name Buckeye Sanicare Quat-256 PDF

Contains Sodium hydroxide, Alkyl dimethyl benzyl ammonium chloride (C12-16), Tetrasodium EDTA, Didecyldimethylammonium chloride

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Cleaner Disinfectant Water based

1.3. Details of the Supplier of the Safety Data Sheet

Importer

UK Contact Lewis Kirby, EU General Manager 25 Frances Brady Way Kingston Upon Hull

HU9 3BW UK

REACH Only Representative

TSGE

TSGE@TSGEurope.com

Supplier

Buckeye International, Inc.

2700 Wagner Place Maryland Heights, MO 63043 USA

For further information, please contact

Contact Point Lewis Kirby, EU General Manager: +4407792782066 Buckeye International, Inc.: 1-314-291-1900

Email Address info@buckeyeinternational.com

1.4. Emergency telephone number

Emergency Telephone (24 hr) Transportation - INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) Medical - (International) 1-651-632-8956 (North America) 1-800-303-0441

Section 2: HAZARDS IDENTIFICATION

2.1. Classification of the Substance or Mixture

Regulation (EC) No 1272/2008

Acute toxicity - Oral Category 4 - (H302)

Skin corrosion/irritation Category 1 Sub-category C - (H314)

Serious eye damage/eye irritation Category 1 - (H318)

Chronic aquatic toxicity Category 2 - (H411)

2.2. Label Elements

Product Identifier

Contains Sodium hydroxide, Alkyl dimethyl benzyl ammonium chloride (C12-16), Tetrasodium EDTA, Didecyldimethylammonium chloride

Item# 085580

BE-5092-EU - Buckeye Sanicare Quat-256 PDF

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Signal Word

Danger

Hazard statements

H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H411 - Toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)

P260 - Do not breathe dust/fume/gas/mist/vapours/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear protective gloves/protective clothing/eye protection/face protection P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing and eye/face protection P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower] P363 - Wash contaminated clothing before reuse P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to

do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P310 - Immediately call a POISON CENTER or doctor/physician P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P391 - Collect spillage P405 - Store locked up P501 - Dispose of contents/ container to an approved waste disposal plant

2.3. Other Hazards

No information available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 MIXTURES

Chemical name EC No CAS No Weight-% Classification according to

Regulation (EC) No.

1272/2008 [CLP]

REACH

Registration

Number

Didecyldimethylammonium chloride

Present 7173-51-5 <16.9 Acute Tox. 4 (H302) Skin Corr. 1B (H314) Eye

Dam. 1 (H318)

Not determined

Tetrasodium EDTA Present 64-02-8 <5 Acute Tox. 4 (H302) Eye Dam. 1 (H318)

Not determined

Ethyl Alcohol Present 64-17-5 <4 Flam. Liq. 2 (H225) Not determined

Sodium hydroxide Present 1310-73-2 <2 Skin Corr. 1A (H314) Not determined

Full text of H- and EUH-phrases: see section 16

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.

1907/2006 (REACH), Article 59)

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Section 4: FIRST AID MEASURES

4.1. Description of First Aid Measures

General Advice Call a poison center or doctor immediately for treatment advice.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek immediate medical attention/advice.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Take off contaminated clothing. Wash contaminated clothing before reuse.

Inhalation Remove to fresh air. If not breathing, give artificial respiration.

Ingestion Have person sip a glass of water if able to swallow. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person.

4.2. Most Important Symptoms and Effects, Both Acute and Delayed

Symptoms Contact may cause irritation and redness. Direct eye contact may cause stinging, tearing and redness. May cause redness, pain, and severe skin burns. May cause irritation to the mucous membranes and upper respiratory tract. Ingestion may cause nausea and headache.

4.3. Indication of any Immediate Medical Attention and Special Treatment Needed

Notes to Physician Treat symptomatically. If the product is ingested, probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression, and convulsions may be needed.

Section 5: FIREFIGHTING MEASURES

5.1. Extinguishing Media

Suitable Extinguishing Media

Water spray (fog). Dry powder. Foam.

Unsuitable Extinguishing Media

Not determined.

5.2. Special Hazards Arising from the Substance or Mixture

Toxic fumes may be given off when material is exposed to fire.

Hazardous combustion products Carbon oxides. Nitrogen oxides (NOx). Hydrogen chloride.

5.3. Advice for Firefighters

Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal Precautions, Protective Equipment and Emergency Procedures

Personal Precautions

Use personal protective equipment as required.

For Emergency Responders

Use personal protection recommended in Section 8.

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6.2. Environmental Precautions

Collect spillage. See Section 12 for additional Ecological Information.

6.3. Methods and Material for Containment and Cleaning Up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic.

6.4. Reference to Other Sections

See Section 13: DISPOSAL CONSIDERATIONS.

Section 7: HANDLING AND STORAGE

7.1. Precautions for Safe Handling

Advice on Safe Handling

Keep out of the reach of children. Use personal protection recommended in Section 8. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid release to the environment.

General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practice. Wash hands thoroughly after handling. Wash contaminated clothing before reuse.

7.2. Conditions for Safe Storage, Including any Incompatibilities

Storage Conditions

Keep containers tightly closed in a dry, cool and well-ventilated place. Store at room temperature. Keep container closed when not in use. Do not contaminate water, food, or feed by storage or disposal.

Packaging Materials Rinse container before discarding.

7.3. Specific End Use(s)

Specific Use(s)

Cleaner. Disinfectant. Water based.

Risk Management Methods (RMM)

The information required is contained in this Safety Data Sheet.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control Parameters

Exposure Limits .

Chemical name European Union United Kingdom France Spain Germany

Ethyl Alcohol 64-17-5

- STEL: 3000 ppm STEL: 5760 mg/m3

TWA: 1000 ppm TWA: 1920 mg/m3

TWA: 1000 ppm TWA: 1900 mg/m3 STEL: 5000 ppm

STEL: 9500 mg/m3

STEL: 1000 ppm STEL: 1910 mg/m3

TWA: 200 ppm TWA: 380 mg/m3

Sodium hydroxide 1310-73-2

- STEL: 2 mg/m3 TWA: 2 mg/m3 STEL: 2 mg/m3 -

Chemical name Italy Portugal Netherlands Finland Denmark

Ethyl Alcohol 64-17-5

- TWA: 1000 ppm Skin STEL: 1900 mg/m3 TWA: 260 mg/m3

TWA: 1000 ppm TWA: 1900 mg/m3 STEL: 1300 ppm

STEL: 2500 mg/m3

TWA: 1000 ppm TWA: 1900 mg/m3

Sodium hydroxide 1310-73-2

- Ceiling: 2 mg/m3 - Ceiling: 2 mg/m3 Ceiling: 2 mg/m3

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Chemical name Austria Switzerland Poland Norway Ireland

Ethyl Alcohol 64-17-5

STEL 2000 ppm STEL 3800 mg/m3 TWA: 1000 ppm

TWA: 1900 mg/m3

STEL: 1000 ppm STEL: 1920 mg/m3

TWA: 500 ppm TWA: 960 mg/m3

TWA: 1900 mg/m3 TWA: 500 ppm TWA: 950 mg/m3 STEL: 625 ppm

STEL: 1187.5 mg/m3

STEL: 1000 ppm

Sodium hydroxide 1310-73-2

STEL 4 mg/m3 TWA: 2 mg/m3

STEL: 2 mg/m3 TWA: 2 mg/m3

STEL: 1 mg/m3 TWA: 0.5 mg/m3

Ceiling: 2 mg/m3 STEL: 2 mg/m3

8.2. Exposure Controls

Engineering Controls Apply technical measures to comply with the occupational exposure limits.

Personal Protective Equipment Eye/Face Protection Splash goggles or safety glasses.

Hand Protection Rubber gloves.

Skin and Body Protection Normal work clothing (long sleeved shirts and long pants) is recommended.

Respiratory Protection If necessary, refer to appropriate regulations and standards.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on Basic Physical and Chemical Properties

Physical state Liquid Appearance Clear liquid

Odour No fragrance

Colour Clear

Odour Threshold Not determined

Property Values

Remarks • Method pH 7.6 ± 0.2 (conc)

7.0 ± 0.2 (1:256 dilution)

Melting point / freezing point Not determined

Boiling point / boiling range 100 °C / 212 °F

Flash point 93 °C / ~ 200 °F

Tag Closed Cup

Evaporation Rate 1.0

(n-BuAc =1)

Flammability (Solid, Gas) n/a-liquid

Flammability Limit in Air

Upper flammability or explosive limits

Not applicable

Lower flammability or explosive limits

Vapour Pressure Not determined

Vapour Density Not determined

Relative Density 1.00

Water Solubility Mostly Soluble

Solubility(ies) Not determined

Partition Coefficient Not determined

Autoignition temperature Not determined

Decomposition temperature Not determined

Kinematic viscosity Not determined

Dynamic Viscosity Not determined

Explosive Properties Not determined Oxidising Properties Not determined

Section 10: STABILITY AND REACTIVITY

10.1. Reactivity

Not reactive under normal conditions.

10.2. Chemical stability

Stable under normal conditions.

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10.3. Possibility of Hazardous Reactions

Hazardous Polymerisation

Hazardous polymerisation does not occur.

Possibility of Hazardous Reactions

None under normal processing.

10.4. Conditions to Avoid

Keep out of reach of children.

10.5. Incompatible Materials

Chlorine bleach. Anionic detergents. Strong oxidising agents. Strong reducing agents.

10.6. Hazardous Decomposition Products

Thermal decomposition can lead to release of irritating gases or vapors.

Section 11: TOXICOLOGICAL INFORMATION

11.1. Information on Toxicological Effects

Acute toxicity

Product Information

Inhalation Avoid breathing vapours or mists.

Eye Contact Avoid contact with eyes.

Skin Contact Avoid contact with skin.

Ingestion Harmful if swallowed.

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral) 1,876.18 mg/kg

ATEmix (dermal) 67,500.00 mg/kg

ATEmix (inhalation-dust/mist) 3,117.50 mg/L

Unknown Acute Toxicity

10 % of the mixture consists of ingredient(s) of unknown toxicity.

10 % of the mixture consists of ingredient(s) of unknown acute oral toxicity.

10 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity.

10 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas).

10 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapour).

10 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist).

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50

Didecyldimethylammonium chloride = 84 mg/kg ( Rat )

Alkyl dimethyl benzyl ammonium chloride (C12-16)

= 426 mg/kg ( Rat )

Tetrasodium EDTA = 10 g/kg ( Rat ) = 1658 mg/kg ( Rat )

Ethyl Alcohol = 7060 mg/kg ( Rat ) = 124.7 mg/L ( Rat ) 4 h

Sodium hydroxide = 325 mg/kg ( Rat ) = 1350 mg/kg ( Rabbit )

Skin corrosion/irritation Causes severe skin burns.

Serious eye damage/eye irritation Causes severe eye damage.

Sensitisation Not classified.

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Germ cell mutagenicity Not classified.

Carcinogenicity Not classified.

Reproductive toxicity Not classified.

STOT - single exposure Not classified.

STOT - repeated exposure Not classified.

Aspiration hazard Not classified.

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Toxic to aquatic life with long lasting effects.

Chemical name Algae/aquatic plants Fish Crustacea

Didecyldimethylammonium chloride 0.97: 96 h Danio rerio mg/L LC50 semi-static

Tetrasodium EDTA 1.01: 72 h Desmodesmus subspicatus mg/L EC50

59.8: 96 h Pimephales promelas mg/L LC50 static 41: 96 h Lepomis macrochirus mg/L LC50 static

610: 24 h Daphnia magna mg/L

EC50

Ethyl Alcohol 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through

12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static

10800: 24 h Daphnia magna mg/L EC50 2: 48 h Daphnia magna mg/L

EC50 Static 9268 - 14221: 48 h Daphnia magna mg/L LC50

Sodium hydroxide 45.4: 96 h Oncorhynchus mykiss mg/L LC50 static

12.2. Persistence and Degradability

12.3. Bioaccumulative Potential

Chemical name Partition coefficient

Ethyl Alcohol -0.32

12.4. Mobility in Soil

Mobility

Not determined

12.5. Results of PBT and vPvB Assessment

12.6. Other Adverse Effects

Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste Treatment Methods

Waste from residues/unused products

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging Improper disposal or reuse of this container may be dangerous and illegal.

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Section 14: TRANSPORT INFORMATION

Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances

IMDG

14.1 UN number UN1760

14.2 Proper Shipping Name Corrosive liquid, n.o.s. (Dimethyl benzyl ammonium chloride, Sodium hydroxide)

14.3 Transport hazard class(es) 8

14.4 Packing Group III

14.5 Marine Pollutant This material may meet the definition of a marine pollutant

RID

14.2 Proper Shipping Name Corrosive liquid, n.o.s. (Dimethyl benzyl ammonium chloride, Sodium hydroxide)

14.3 Transport hazard class(es) 8

14.4 Packing Group II

ADR

14.2 Proper Shipping Name Corrosive liquid, n.o.s. (Dimethyl benzyl ammonium chloride, Sodium hydroxide)

IATA

14.2 Proper Shipping Name Corrosive liquid, n.o.s. (Dimethyl benzyl ammonium chloride, Sodium hydroxide)

Section 15: REGULATORY INFORMATION

15.1. Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture

France

Occupational Illnesses (R-463-3, France)

Chemical name French RG number Title

Ethyl Alcohol 64-17-5

RG 84

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work .

Authorisations and/or restrictions on use:

This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)

Persistent Organic Pollutants

Export Notification requirements This product contains substances which are regulated pursuant to Regulation (EC) No.

689/2008 of the European parliament and of the council concerning the export and import of dangerous chemicals

Chemical name European Export/Import Restrictions per (EC) 649/2012 - Annex Number

Didecyldimethylammonium chloride - 7173-51-5 I.1

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Ozone-depleting substances (ODS) regulation (EC) 1005/2009

International Inventories

Component TSCA DSL/NDSL EINECS/ELIN

CS

PICCS ENCS IECSC AICS KECL

N,N-

DIMETHYLOCTYLAMI

NE-N-OXIDE

2605-78-9 ( <10 )

X X - X X X - -

Didecyldimethylammon ium chloride

7173-51-5 ( <16.9 )

X X X X X X X X

Alkyl dimethyl benzyl ammonium chloride

(C12-16) 68424-85-1 ( <16.9 )

X X X X X X X X

Tetrasodium EDTA 64-02-8 ( <5 )

X X X X X X X X

Ethyl Alcohol 64-17-5 ( <4 )

X X X X X X X X

Sodium hydroxide 1310-73-2 ( <2 )

X X X X X X X X

Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances

15.2. Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

Section 16: OTHER INFORMATION

Safety Data Sheet Status

The Risk Phrases/Hazard Statements listed below in Section 16 are related to the Raw Materials (ingredients) in the Product (as listed in Section 3) and NOT only the product itself. For the Risk Phrases/Hazard Statements relating to this Product see Section 2.

Full text of H-Statements referred to under section 3

H225 - Highly flammable liquid and vapour H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage

Legend SVHC: Substances of Very High Concern for Authorisation:

Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA TWA (time-weighted average)

STEL STEL (Short Term Exposure Limit)

Ceiling Maximum limit value

* Skin designation

Classification Procedure

Calculation method

Issue Date: 25-Mar-2020

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Revision Note: New format.

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006, as amended by Commission Regulation (EU) 2015/830

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet