071714 ECO Lab-MIKROKLENE SDS.PDF

SAFETY DATA SHEET

MIKROKLENE

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : MIKROKLENE

Other means of identification : Not applicable

Recommended use : Sanitizer

Restrictions on use : Reserved for industrial and professional use.

Product dilution information : No dilution information provided.

Company : Ecolab S. de RL. De CV

AVENUE INDUSTRIALES 28

SUBURB: INDUSTRIAL CUAMATLA,

MPIO: CUAUTITLAN IZCALLI,

EDO DE MEXICO, Mexico

CP. 54700

(55) 5864 1800

Emergency telephone : 800 837 2998 Please request assistance in Spanish language

Issuing date : 15.02.2023

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification Corrosive to Metals, Category 1 H290 Acute toxicity (Inhalation), Category 4 H332 Skin corrosion, Sub-category 1A H314 Serious eye damage, Category 1 H318 Short-term (acute) aquatic hazard, Category 3 H402

GHS label elements Hazard pictograms :

Signal Word : Danger

Hazard Statements : H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

H332 Harmful if inhaled.

H402 Harmful to aquatic life.

Precautionary Statements : Prevention:

P234 Keep only in original container.

P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.

P264 Wash skin thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response:

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

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P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.

P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Immediately call a POISON CENTER or doctor/ physician.

P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER or doctor/ physician.

P363 Wash contaminated clothing before reuse.

P390 Absorb spillage to prevent material damage.

Storage:

P405 Store locked up.

Disposal:

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards : Do not mix with bleach or other chlorinated products – will cause chlorine gas.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical name CAS-No. Concentration (%) Alkylethoxy-propoxylates 9038-95-3 10 - 20 Phosphoric acid 7664-38-2 5 - 10 iodine 7553-56-2 1 - 5 2-butoxyethanol 111-76-2 1 - 5

No hazardous ingredients

SECTION 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. Get medical attention immediately.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.

If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention.

Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal protective equipment.

Notes to physician : Treat symptomatically.

Most important symptoms and effects, both acute and delayed

: See Section 11 for more detailed information on health effects and symptoms.

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Product AT USE DILUTION In case of eye contact : Rinse with plenty of water.

In case of skin contact : Rinse with plenty of water.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

: None known.

Specific hazards during fire fighting

: Not flammable or combustible.

Hazardous combustion products

: Decomposition products may include the following materials:

Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus

Special protective equipment for fire-fighters

: Use personal protective equipment.

Specific extinguishing methods

: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes.

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for containment and cleaning up

: Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.

Personal precautions, protective equipment and emergency procedures

: Refer to protective measures listed.

Environmental precautions : No special environmental precautions required.

Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non-

929422-03 4 / 10 15.02.2023 containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Use only with adequate ventilation. Wash hands thoroughly after handling. Do not mix with bleach or other chlorinated products – will cause chlorine gas. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment (PPE).

Conditions for safe storage : Keep away from strong bases. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers.

Storage temperature : 0 °C to 40 °C

Product AT USE DILUTION Advice on safe handling : Wash hands after handling. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment (PPE). For personal protection see section 8.

Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Form of exposure

Permissible concentration

Basis

Phosphoric acid 7664-38-2 VLE-PPT 1 mg/m3 NOM-010-

STPS-2014

VLE-CT 3 mg/m3 NOM-010-

STPS-2014

Phosphoric acid 7664-38-2 TWA 1 mg/m3 ACGIH

STEL 3 mg/m3 ACGIH

TWA 1 mg/m3 NIOSH REL

ST 3 mg/m3 NIOSH REL

TWA 1 mg/m3 OSHA Z-1

TWA 1 mg/m3 OSHA P0

STEL 3 mg/m3 OSHA P0

PEL 1 mg/m3 CAL PEL

STEL 3 mg/m3 CAL PEL iodine 7553-56-2 VLE-PPT (Inhalable fraction and vapour)

0,01 ppm NOM-010-

STPS-2014

VLE-CT

(Vapour and aerosol)

0,1 ppm NOM-010-

STPS-2014

iodine 7553-56-2 TWA (Inhalable fraction and vapor)

0,01 ppm ACGIH

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C 0,1 ppm 1 mg/m3

NIOSH REL

C 0,1 ppm 1 mg/m3

OSHA Z-1

STEL (Vapor) 0,1 ppm ACGIH

C 0,1 ppm 1 mg/m3

OSHA P0

C 0,1 ppm 1 mg/m3

CAL PEL

2-butoxyethanol 111-76-2 VLE-PPT 20 ppm NOM-010-

STPS-2014

2-butoxyethanol 111-76-2 TWA 20 ppm ACGIH

TWA 5 ppm 24 mg/m3

NIOSH REL

TWA 50 ppm 240 mg/m3

OSHA Z-1

TWA 25 ppm 120 mg/m3

OSHA P0

PEL 20 ppm 97 mg/m3

CAL PEL

sodium iodide 7681-82-5 TWA (Inhalable fraction and vapor)

0,01 ppm (iodine) ACGIH

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.

Personal protective equipment

Eye protection : Safety goggles

Face-shield

Hand protection : Wear the following personal protective equipment:

Standard glove type.

Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing

Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after handling.

Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.

Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Personal protective equipment

Eye protection : No special protective equipment required.

Hand protection : No special protective equipment required.

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Skin protection : No special protective equipment required.

Respiratory protection : No personal respiratory protective equipment normally required.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : dark brown

Odor : slight pH : 1,75, (100 %)

Flash point : closed cupNot applicable

Odor Threshold : No data available

Melting point/freezing point : No data available

Initial boiling point and boiling range

: No data available

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapor pressure : No data available

Relative vapor density : No data available

Relative density : 1,077

Water solubility : No data available

Solubility in other solvents : No data available

Partition coefficient: n-octanol/water

: No data available

Autoignition temperature : No data available

Thermal decomposition : No data available

Viscosity, kinematic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Molecular weight : No data available

VOC : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reactions

: Do not mix with bleach or other chlorinated products – will cause chlorine gas.

Conditions to avoid : None known.

Incompatible materials : Bases

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Metals Organic materials

Hazardous decomposition products

: In case of fire hazardous decomposition products may be produced such as:

Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

: Inhalation, Eye contact, Skin contact

Potential Health Effects

Eyes : Causes serious eye damage.

Skin : Causes severe skin burns.

Ingestion : Causes digestive tract burns.

Inhalation : Harmful if inhaled. May cause nose, throat, and lung irritation.

Chronic Exposure : Health injuries are not known or expected under normal use.

Product AT USE DILUTION Eyes : Health injuries are not known or expected under normal use.

Skin : Health injuries are not known or expected under normal use.

Ingestion : Health injuries are not known or expected under normal use.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact : Redness, Pain, Corrosion

Skin contact : Redness, Pain, Corrosion

Ingestion : Corrosion, Abdominal pain

Inhalation : Respiratory irritation, Cough

Product AT USE DILUTION Eye contact : No symptoms known or expected.

Skin contact : No symptoms known or expected.

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Toxicity

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Product

Acute oral toxicity : Acute toxicity estimate : > 5.000 mg/kg

Acute inhalation toxicity : 4 h Acute toxicity estimate : 4,38 mg/l Test atmosphere: dust/mist

Acute dermal toxicity : Acute toxicity estimate : > 5.000 mg/kg

Skin corrosion/irritation : Corrosive

Serious eye damage/eye irritation

: No data available

Respiratory or skin sensitization

: No data available

Carcinogenicity : No data available

Reproductive effects : No data available

Germ cell mutagenicity : No data available

Teratogenicity : No data available

STOT-single exposure : No data available

STOT-repeated exposure : No data available

Aspiration toxicity : No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Environmental Effects : Harmful to aquatic life.

Environmental Effects : This product has no known ecotoxicological effects.

Product

Toxicity to fish : No data available

Toxicity to daphnia and other aquatic invertebrates

: 48 h LC50 Daphnia magna (Water flea): 22 mg/l

Toxicity to algae : No data available

Components

Toxicity to fish : iodine 96 h LC50 Oncorhynchus mykiss (rainbow trout): 1,67 mg/l

2-butoxyethanol 96 h LC50 Fish: > 100 mg/l

Components

Toxicity to algae : Phosphoric acid 72 h EC50 Desmodesmus subspicatus (green algae): > 100 mg/l iodine 72 h EC50 Desmodesmus subspicatus (green algae): 0,13 mg/l

2-butoxyethanol 72 h EC50 Aquatic Plant: 911 mg/l

Persistence and degradability

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Not applicable - Biocide

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Do not contaminate storm water drains, natural waterways or soil with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Dispose of in accordance with local, state, and federal regulations.

Disposal methods : Diluted product can be flushed to sanitary sewer.

Disposal considerations : Dispose of in accordance with local, state, and federal regulations.

SECTION 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.

Land transport: generally applicable for transport in Mexico.

UN number : 1805

Description of the goods : PHOSPHORIC ACID, LIQUID

Class : 8

Packing group : III

Hazchem Code : E1

Environmentally hazardous : yes

Air transport (IATA)

Contact Regulatory for air freight eligibility

Sea transport (IMDG/IMO)

UN number : 1805 Proper shipping name : PHOSPHORIC ACID SOLUTION Class : 8 Packing group : III Marine pollutant : no

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SECTION 15. REGULATORY INFORMATION

Mexico: Our SDS meets the requirements established by the Official Mexican Regulation NOM-018- STPS-2015, Harmonized System for the identification and communication of hazards and risks by dangerous chemical substances in work centers.

SECTION 16. OTHER INFORMATION

Revision Date : 15.02.2023 Version : 1.2 Prepared by : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the MSDS.

The information provided in this Material Safety Data Sheet is considered correct but is not thorough and is intended for guidance only, which is based on current knowledge of the substance or mixture and is applicable to the appropriate safety precautions for the product.