Amd 0003 DLA SD Fertilizer_Triple Pro 15-15-15 SDS.pdf

Best Triple Pro 15-15-15 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

06/08/2017 EN (English) Page 1

SECTION 1: Identification

1.1. Identification

Product form : Mixture Product name : Best Triple Pro 15-15-15 Product code : M74102

1.2. Relevant identified uses of the substance or mixture and uses advised against No additional information available

1.3. Details of the supplier of the safety data sheet

JR Simplot Company P.O. Box 70013 Boise, ID 83707 T 1-208-336-2110

1.4. Emergency telephone number

Emergency number : CHEMTREC 1-800-424-9300

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture

GHS-US classification Serious eye damage/eye irritation, Category 2B

H320

Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation

H335

Full text of H statements : see section 16

2.2. Label elements

GHS-US labelling Hazard pictograms (GHS-US) :

GHS07

Signal word (GHS-US) : Warning Contains : ammonium sulfate; Monoammonium Phosphate; urea; Sand Hazard statements (GHS-US) : H320 - Causes eye irritation

H335 - May cause respiratory irritation Precautionary statements (GHS-US) : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray

P264 - Wash hands, forearms and face thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a poison center/doctor/… if you feel unwell P337+P313 - If eye irritation persists: Get medical attention P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to ... in accordance with local, regional, and national regulations

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity (GHS US)

Not applicable according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

06/08/2017 EN (English) 2/8

SECTION 3: Composition/information on ingredients

3.1. Substance

Not applicable

3.2. Mixture

Name Product identifier % GHS-US classification ammonium sulfate (CAS No) 7783-20-2 Eye Irrit. 2B, H320

STOT SE 3, H335

potassium chloride (CAS No) 7447-40-7 Not classified

Monoammonium Phosphate (CAS No) 7722-76-1 Eye Irrit. 2B, H320

STOT SE 3, H335

urea (CAS No) 57-13-6 Skin Irrit. 2, H315 Eye Irrit. 2B, H320

STOT SE 3, H335

wax (paraffins- petroleum) (CAS No) 64771-72-8 Not classified

Sand STOT SE 3, H335

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a

POISON CENTER or doctor/physician if you feel unwell. Allow breathing of fresh air. Allow the victim to rest.

First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.

First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist.

First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use.

Symptoms/injuries after inhalation : May cause respiratory irritation.

Symptoms/injuries after eye contact : Causes eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.

Emergency procedures : Ventilate area.

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

06/08/2017 EN (English) 3/8

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials.

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area.

7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed. Keep container closed when not in use.

Incompatible products : Strong bases. Strong acids.

Incompatible materials : Sources of ignition. Direct sunlight.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

ammonium sulfate (7783-20-2) Not applicable

Monoammonium Phosphate (7722-76-1) Not applicable potassium chloride (7447-40-7) Not applicable urea (57-13-6) Not applicable wax (paraffins- petroleum) (64771-72-8) Not applicable

Sand Not applicable

8.2. Exposure controls

Personal protective equipment : Avoid all unnecessary exposure.

Hand protection : Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.

Respiratory protection : Wear appropriate mask.

Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Solid

Appearance : Granules.

Colour : Light green

Odour : characteristic

Odour threshold : No data available pH : 6 - 7 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

06/08/2017 EN (English) 4/8

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Relative evaporation rate (butylacetate=1) : No data available

Flammability (solid, gas) : No data available

Explosive limits : No data available

Explosive properties : No data available

Oxidising properties : No data available

Vapour pressure : No data available

Relative density : No data available

Relative vapour density at 20 °C : No data available

Solubility : Soluble.

Water: Solubility in water of component(s) of the mixture :

• ammonium sulfate: 77 g/100ml • Monoammonium Phosphate: 38 g/100ml • potassium chloride: 34 g/100ml • urea: 100 g/100ml • wax (paraffins- petroleum): insoluble

Log Pow : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity

No additional information available

10.2. Chemical stability

Not established.

10.3. Possibility of hazardous reactions

Not established.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials

Strong acids. Strong bases.

10.6. Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified ammonium sulfate (7783-20-2) LD50 oral rat 2840 mg/kg (Rat) LD50 dermal rat > 2000 mg/kg ATE US (oral) 2840.000 mg/kg bodyweight

Monoammonium Phosphate (7722-76-1) LD50 oral rat 5750 mg/kg (Rat) LD50 dermal rat > mg/kg LD50 dermal rabbit > 7940 mg/kg (Rabbit) ATE US (oral) 5750.000 mg/kg bodyweight according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

06/08/2017 EN (English) 5/8 potassium chloride (7447-40-7) LD50 oral rat 2600 mg/kg (Rat) ATE US (oral) 2600.000 mg/kg bodyweight urea (57-13-6) LD50 oral rat 8471 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Literature study; 14300 mg/kg bodyweight;

Rat; Experimental value) LD50 dermal rat > 3200 mg/kg (Rat; Literature study) LD50 dermal rabbit > 21000 mg/kg (Rabbit; Literature study) ATE US (oral) 8471.000 mg/kg bodyweight wax (paraffins- petroleum) (64771-72-8) LD50 oral rat > 5000 mg/kg (Rat) LD50 dermal rabbit > 2000 mg/kg (Rabbit)

Skin corrosion/irritation : Not classified pH: 6 - 7

Serious eye damage/irritation : Causes eye irritation.

pH: 6 - 7

Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified

Based on available data, the classification criteria are not met Carcinogenicity : Not classified

Reproductive toxicity : Not classified Based on available data, the classification criteria are not met

Specific target organ toxicity (single exposure) : May cause respiratory irritation.

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard : Not classified

Potential adverse human health effects and symptoms

: Based on available data, the classification criteria are not met.

Symptoms/injuries after inhalation : May cause respiratory irritation.

Symptoms/injuries after eye contact : Causes eye irritation.

SECTION 12: Ecological information

12.1. Toxicity

ammonium sulfate (7783-20-2) LC50 fish 1 126 mg/l (96 h; Poecilia reticulata) EC50 Daphnia 1 202 mg/l (96 h; Daphnia magna) LC50 fish 2 250 - 480 mg/l (96 h; Brachydanio rerio) EC50 Daphnia 2 433 mg/l (50 h; Daphnia magna) TLM fish 1 1290 ppm (96 h; Gambusia affinis)

Monoammonium Phosphate (7722-76-1) LC50 fish 1 155 ppm (96 h; Pimephales promelas) potassium chloride (7447-40-7) LC50 fish 1 920 mg/l (96 h; Gambusia affinis; Static system) EC50 Daphnia 1 630 mg/l (48 h; Ceriodaphnia dubia) LC50 fish 2 2010 mg/l (96 h; Lepomis macrochirus; Static system) EC50 Daphnia 2 660 mg/l (48 h; Daphnia magna) Threshold limit algae 1 850 mg/l (72 h; Scenedesmus subspicatus) Threshold limit algae 2 > 100 mg/l (72 h; Scenedesmus subspicatus; GLP) according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

06/08/2017 EN (English) 6/8 urea (57-13-6) LC50 fish 1 > 6810 mg/l (96 h; Leuciscus idus; Nominal concentration) EC50 Daphnia 1 > 10000 mg/l (48 h; Daphnia magna; Nominal concentration) LC50 fish 2 17500 mg/l (96 h; Poecilia reticulata) EC50 Daphnia 2 > 10000 mg/l (24 h; Daphnia magna) TLM fish 1 17500 ppm (96 h; Poecilia reticulata) Threshold limit other aquatic organisms 1 120000 mg/l (16 h; Bacteria; Toxicity test) Threshold limit other aquatic organisms 2 > 10000 mg/l (Pseudomonas putida) Threshold limit algae 1 > 10000 mg/l (168 h; Scenedesmus quadricauda; Growth rate) Threshold limit algae 2 47 mg/l (192 h; Microcystis aeruginosa; Growth rate)

12.2. Persistence and degradability

Best Triple Pro 15-15-15 Persistence and degradability Not established.

ammonium sulfate (7783-20-2) Persistence and degradability Biodegradability in water: no data available. Not established.

Monoammonium Phosphate (7722-76-1) Persistence and degradability Biodegradability in water: no data available. Not established.

potassium chloride (7447-40-7) Persistence and degradability Biodegradability: not applicable. Not established.

Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable BOD (% of ThOD) Not applicable urea (57-13-6) Persistence and degradability Inherently biodegradable. Hydrolysis in water. Not established.

ThOD 0.27 g O₂/g substance wax (paraffins- petroleum) (64771-72-8) Persistence and degradability Readily biodegradable in water.

Sand Persistence and degradability Not established.

12.3. Bioaccumulative potential

Best Triple Pro 15-15-15 Bioaccumulative potential Not established.

ammonium sulfate (7783-20-2) Log Pow -5.1 Bioaccumulative potential Bioaccumulation: not applicable. Not established.

Monoammonium Phosphate (7722-76-1) Bioaccumulative potential Not bioaccumulative. Not established.

potassium chloride (7447-40-7) Log Pow -0.46 (Estimated value) Bioaccumulative potential Bioaccumulation: not applicable. Not established.

urea (57-13-6) BCF fish 1 1 (72 h; Brachydanio rerio; Fresh water) BCF other aquatic organisms 1 11700 (Chlorella sp.)

Log Pow < -1.73 (Experimental value; EU Method A.8: Partition Coefficient) Bioaccumulative potential Bioaccumulation: not applicable. Not established.

wax (paraffins- petroleum) (64771-72-8) Bioaccumulative potential No bioaccumulation data available.

Sand Bioaccumulative potential Not established.

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

06/08/2017 EN (English) 7/8

12.4. Mobility in soil

No additional information available

12.5. Other adverse effects

Effect on the global warming : No known ecological damage caused by this product.

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.

Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

Department of Transportation (DOT) In accordance with DOT Not regulated for transport

TDG

No additional information available

Transport by sea No additional information available

Air transport No additional information available

SECTION 15: Regulatory information

15.1. US Federal regulations

ammonium sulfate (7783-20-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory

Monoammonium Phosphate (7722-76-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory potassium chloride (7447-40-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory urea (57-13-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory

Sand Not listed on the United States TSCA (Toxic Substances Control Act) inventory

15.2. International regulations

CANADA

No additional information available

EU-Regulations No additional information available

National regulations No additional information available

15.3. US State regulations

No additional information available according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

06/08/2017 EN (English) 8/8

SECTION 16: Other information Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE

COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.

Other information : None.

Full text of H-statements:

------ H315 Causes skin irritation ------ H320 Causes eye irritation ------ H335 May cause respiratory irritation

SDS US (GHS HazCom 2012)

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