d - AK21 South Upland Data Tables - Battelle Final.pdf

Arthur Kill Upland - 2020

Volatiles Action Level Action Level Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

ug/L)

ASI ID # Soil Leachate #20200021 #20200026 #20200026 ug/kg ug/L COMP A Q A COMP A Q A COMP A Q

Chloromethane (Methyl Chloride) 4000 30 12 U 10 U 1.0 U H

Bromomethane 25000 10 12 U 10 U 1.0 U H

Vinyl chloride 700 5 12 U 10 U 1.0 U

Chloroethane 220000 NA 12 U * 10 U * 1.0 U

Methylene chloride (Dichloromethane) 34000 3 12 U 8.0 J 2.8 H B

Acetone 70000000 700 17 J 46 32 J H

Carbon disulfide 7800000 NA 12 U 8.4 J 1.0 U

1,1-Dichloroethene 11000 2 12 U 10 U 1.0 U

1,1-Dichloroethane 8000 50 12 U 10 U 1.0 U

1,2-Dichloroethene (total) 10 24 U 20 U 2.0 U

Chloroform 600 6 12 U 10 U 1.0 U H

1,2-Dichloroethane 900 NA 12 U 10 U 1.0 U H

2-Butanone (MEK) 3100000 300 12 U 87 5.0 H

1,1,1-Trichloroethane 290000 30 12 U 10 U 1.0 U

Carbon tetrachloride 600 2 12 U 10 U 1.0 U H

Bromodichloromethane 1000 1 12 U 10 U 1.0 U H

1,2-Dichloropropane 2000 1 12 U 10 U 1.0 U cis-1,3-Dichloropropene NA NA 12 U 10 U 1.0 U H

Trichloroethene 7000 1 12 U 10 U 1.0 U H

Dibromochloromethane 3000 10 12 U 10 U 1.0 U

1,1,2-Trichloroethane 2000 3 12 U 10 U 1.0 U H

Benzene 2000 1 12 U 10 U 1.0 U H trans-1,3-dichloropropene NA NA 12 U 10 U 1.0 U H

Bromoform 81000 4 12 U 10 U 1.0 U

Tetrachloroethene 2000 1 12 U 10 U 1.0 U

1,1,2,2-Tetrachloroethane 1000 NA 12 U 10 U 1.0 U

Toluene 6300000 1000 12 U 10 U 1.0 U

Chlorobenzene 510000 50 12 U 10 U 1.0 U

Ethyl benzene 7800000 700 12 U 10 U 1.0 U

Styrene 90000 100 12 U 10 U 1.0 U H

Xylenes(Total) 12000000 1000 24 U 20 U 2.0 U

Acrolein 500 240 U 200 U 20 U

Acrylonitrile 900 120 U 100 U 20 U H

1,2-Dibromo-3-chloropropane 80 12 U 10 U 1.0 U

1,2-Dibromoethane 8 12 U 10 U 1.0 U

Dichlorodifluoromethane 490000 12 U 10 U 1.0 U

1,2-Dichloroethene (cis) 230000 12 U 10 U 1.0 U

1,2-Dichloroethene (trans) 300000 12 U 10 U 1.0 U H

Methyl acetate 78000000 61 U 51 U 5.0 U

Methyl tert-butyl ether (MTBE) 110000 12 U 10 U 1.0 U H

Tertiary butyl alcohol (TBA) 1400000 120 U 100 U 40 U

Trichlorofluoromethane 23000000 12 U 10 U 1.0 U H *

Combined 1,3-dichloropropenes (SUM) cis + trans 2000 0.2

1,4-dioxane 2400 U 2000 U 200 U n-propylbenzene 12 U 10 U 1.0 U sec-butylbenzene 12 U 10 U 1.0 U H tert-butylbenzene 12 U 10 U 1.0 U H

1,2,4-trimethylbenzene 12 U 10 U 1.0 U

1,3,5-trimethylbenzene 12 U 10 U 1.0 U n‐Butylbenzene 12 U 10 U 1.0 U H

Arthur Kill Upland - Comp A - Sediment Semivolatiles

Semivolatiles Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200021 #20200026 #20200026 ug/kg ug/kg mg/L mg/L COMP A Q A COMP A Q A COMP A Q

Phenol 18000000 660 4 0.01 800 U 170 U 0.00098 U bis(2-Chloroethyl)ether 400 660 0.01 0.01 160 U 34 U 0.00019 U

2-Chlorophenol 310000 660 0.005 0.01 800 U 170 U 0.00098 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 12 U 10 U 0.001 U H

1,4-Dichlorobenzene 5000 660 0.075 0.01 12 U 10 U 0.001 U H

1,2-Dichlorobenzene 5300000 660 0.6 0.01 12 U 10 U 0.001 U

2-Methylphenol (o-cresol) 310000 660 NA 0.01 800 U 170 U 0.00098 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 160 U 34 U 0.00019 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 800 U 170 U 0.00098 U

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 160 U 34 U 0.00019 U

Hexachloroethane 35000 660 0.01 0.01 800 U 170 U 0.00098 U

Nitrobenzene 31000 660 0.01 0.01 1600 U 340 U 0.002 U

Isophorone 510000 660 0.1 0.01 800 U 170 U 0.00035 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 800 U 170 U 0.00098 U

2,4-Dichlorophenol 180000 660 0.02 0.01 160 U 34 U 0.00019 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 12 U 10 U 0.001 U

Naphthalene 6000 660 0.3 0.01 55 J 14 J 0.00019 U

Hexachloro-1,3-butadiene 6000 660 NA 0.01 160 U 34 U 0.00019 U

2-Methylnaphthalene 230000 660 NA 0.01 44 J 9.4 J 0.00019 U

Hexachlorocyclopentadiene 45000 660 0.05 0.01 800 U 170 U 0.00098 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 800 U 170 U 0.00098 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 800 U 170 U 0.00098 U

2-Chloronaphthalene NA 660 NA 0.01 160 U 34 U 0.00019 U

2-Nitroaniline 39000 3300 NA 0.05 4100 U 860 U 0.0049 U

Acenaphthylene 300000000 660 NA 0.01 90 J 34 0.00019 U

2,6-Dinitrotoluene 700 660 0.01 0.01 800 U 170 U 0.00098 U

Arthur Kill Upland - Comp A - Sediment Semivolatiles, con't.

Semivolatiles, continued Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200021 #20200026 #20200026 ug/kg ug/kg mg/L mg/L COMP A Q A COMP A Q A COMP A Q

Acenaphthene 3400000 660 0.4 0.01 160 U 34 U 0.00019 U

2,4-Dinitrophenol 120000 3300 0.04 0.05 8000 U 1700 U 0.0098 U

Dibenzofuran NA 660 NA 0.01 800 U 170 U 0.00098 U

2,4-Dinitrotoluene 700 660 0.01 0.01 800 U 170 U 0.00098 U

Diethylphthalate 49000000 660 5 0.01 800 U 170 U 0.00098 U

Fluorene 2300000 660 0.3 0.01 160 U 34 U 0.00019 U

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 4100 U 860 U 0.0049 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 800 U 170 U 0.00098 U

Hexachlorobenzene 300 660 0.01 0.01 160 U 34 U 0.00019 U

Pentachlorophenol 3000 3300 0.001 0.05 4100 U 860 U 0.0049 U

Phenanthrene 300000000 6600 NA 0.01 160 49 0.000067 J

Anthracene 17000000 6600 2 0.01 110 J 30 J 0.000088 J

Carbazole 24000 330 NA 0.01 160 U 34 U 0.00019 U

Di-n-butylphthalate 6100000 330 0.9 0.01 800 U 170 U 0.00098 U

Fluoranthene 2300000 660 0.3 0.01 410 110 0.00019 U

Pyrene 1700000 660 0.2 0.01 480 130 0.000057 J

Butylbenzylphthalate 1200000 660 0.1 0.01 800 U 170 U 0.00098 U

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 800 U 170 U 0.00098 U

Benzo(a)anthracene 600 660 NA 0.01 230 71 0.00019 U

Chrysene 62000 660 NA 0.01 280 89 0.00019 U bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 1200 J 280 J 0.0098 U

DI-n-octylphthalate 2400000 660 0.1 0.01 800 U 170 U 0.00098 U

Benzo(b)fluoranthene 600 660 NA 0.01 420 110 0.00019 U

Benzo(k)fluoranthene 6000 660 NA 0.01 180 40 0.00019 U

Benzo(a)pyrene 200 660 NA 0.01 350 91 0.00019 U

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 250 71 0.00019 U

Dibenzo(a,h)anthracene 200 660 NA 0.01 98 J 18 J 0.00019 U

Benzo(ghi)perylene 30000000 660 NA 0.01 320 99 0.00019 U

Acetophenone 2000 1600 U 340 U 0.00098 U

Atrazine 210000 1600 U 340 U 0.00098 U

Benzaldehyde 6100000 1600 U 340 U 0.00035 J

Benzidine 700 16000 U 3400 U 0.02 U

1,1'-Biphenyl 3100000 800 U 170 U 0.00098 U

Caprolactam 31000000 4100 U 860 U 0.0049 U

1,2-Diphenylhydrazine 700 800 U 170 U 0.00098 U

N-Nitrosodimethylamine 700 800 U 170 U 0.00098 U

Total Cresol

Arthur Kill Upland - Comp A - Pesticides/Aroclors

Pesticides/Aroclors Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200021 #20200026 #20200026 ug/kg ug/kg mg/L mg/L COMP A Q A COMP A Q A COMP A Q alpha-BHC 100 1.9 0.00002 0.00005 0.50 U 0.42 U 0.0000013 U beta-BHC 400 3.3 0.0002 0.00005 0.50 U 0.42 U 0.0000013 U delta-BHC NA 1.7 NA 0.00005 0.50 U 0.42 U 0.0000013 U gamma-BHC (Lindane) 400 2 0.0002 0.00005 0.50 U 0.42 U 0.0000013 U

Heptachlor 100 2.1 0.0004 0.00005 0.50 U 0.42 U 0.0000013 U

Aldrin 40 2 0.00004 0.00005 0.50 U 0.42 U 0.0000013 U

Heptachlor epoxide 70 2.1 0.0002 0.00005 1.2 p 0.88 p 0.0000013 U

Endosulfan I NA 2.1 0.0004 0.00005 0.50 U 0.42 U 0.0000013 U

Dieldrin 40 3.3 0.00003 0.0001 0.50 U 0.42 U 0.0000013 U

4,4'-DDE 2000 4.2 0.0001 0.0001 21 p 17 0.0000013 U

Endrin 23000 3.6 0.002 0.0001 5.6 3.1 0.0000013 U

Endosulfan II NA 3.3 0.0004 0.0001 1.0 p 0.48 p 0.0000013 U

4,4'-DDD 3000 4.2 0.0001 0.0001 25 13 0.0000013 U

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.50 U 0.42 U 0.0000013 U

4,4'-DDT 2000 3.6 0.0001 0.0001 22 6.5 p 0.00000064 J p

Methoxychlor 390000 17 0.04 0.001 0.50 U 0.42 U 0.0000013 U alpha-Chlordane 200 1.7 NA 0.00005 0.50 U 1.5 0.0000013 U gamma-Chlordane 200 1.7 0.0005 0.00005 0.50 U 0.42 U 0.0000013 U

Toxaphene 600 170 0.003 0.005 20 U 17 U 0.0001 U

Mirex 0.50 U 0.42 U 0.0000013 U

Aroclor‐1016 10 U 850 U 0.00001 U

Aroclor‐1221 10 U 850 U 0.00001 U

Aroclor‐1232 10 U 850 U 0.00001 U

Aroclor‐1242 10 U 850 U 0.00001 U

Aroclor‐1248 74 23000 0.00001 U

Aroclor‐1254 10 U 850 U 0.00001 U

Aroclor‐1260 60 130000 0.00001 U

Total Aroclor(SUM)

Arthur Kill Upland - Comp A - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

ug/L)

ASI ID # Soil Leachate #20200021 #20200026 #20200026

COMP A Q A COMP A Q A COMP A Q

2,4,5-TP (Silvex) NA NA NA NA 49 U 40 U 0.98 U

Arthur Kill Upland - Comp A - Metals

Metals Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200021 #20200026 #20200026 mg/kg mg/kg mg/L mg/L COMP A Q A COMP A Q A COMP A Q

Aluminum 78000 40 0.2 0.2 9900 12000 1.2

Antimony 31 12 0.02 0.06 0.78 0.73 0.002 U

Arsenic 19 2 0.008 0.01 14 13 0.0012

Barium 16000 40 2 0.2 82 86 0.037

Beryllium 16 1 0.02 0.005 0.71 0.73 0.001 U

Cadmium 78 1 0.004 0.005 0.81 0.72 0.00031 J

Chromium NA 2 0.1 0.01 43 42 0.002 U

Hexavalent Chromium 120000 0.87 J 0.80 U 0.0044 J F1 F2 B

Trivalent Chromium 20 42 42 0.01 U

Cobalt 1,600 10 NA 0.05 6.4 6.2 0.00066

Copper 590 5 1 0.025 92 70 0.002 U

Lead 400 0.6 0.01 0.003 89 78 0.00066 J B

Manganese 5900 3 0.05 0.015 330 370 0.0026 J

Mercury 23 0.1 0.002 0.0002 1.5 B 1.4 B 0.00054

Nickel 1,600 8 0.1 0.04 20 18 0.0041

Selenium 390 1 0.05 0.015 3.0 2.6 0.005 U

Silver 390 2 NA 0.01 1.5 1.4 0.001 U

Vanadium 78 10 NA 0.05 25 25 0.0055

Zinc 23,000 4 5 0.02 150 180 0.005 U

Cyanide, total 1,600 0.5 0.2 0.01 0.55 J 0.50 J 0.01 U

%Solids NA NA NA NA 41.2 49.4

Arthur Kill Upland - Comp A - Dioxin/Furan

Dioxin/Furan Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP (Units:

pg/L)

ASI ID # Soil Leachate #20200021 #20200026 #20200026 ng/kg pg/L COMP A Q A COMP A Q A COMP A Q

2,3,7,8‐TCDD NA NA NA NA 11 7.1 10 U

1,2,3,7,8‐PeCDD NA NA NA NA 4.9 J B 3.1 J B q 51 U

1,2,3,4,7,8‐HxCDD NA NA NA NA 4.9 J B 3.6 J B 51 U

1,2,3,6,7,8‐HxCDD NA NA NA NA 21 B 15 B 51 U

1,2,3,7,8,9‐HxCDD NA NA NA NA 18 B 12 B 51 U

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 310 B 240 B 1.6 J B q

OCDD NA NA NA NA 5300 E B 3900 B 32 J B

2,3,7,8‐TCDF NA NA NA NA 22 14 10 U

1,2,3,7,8‐PeCDF NA NA NA NA 11 7.1 51 U

2,3,4,7,8‐PeCDF NA NA NA NA 13 9.0 51 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 39 B 24 B 51 U

1,2,3,6,7,8‐HxCDF NA NA NA NA 16 B 9.8 I B 51 U

2,3,4,6,7,8‐HxCDF NA NA NA NA 10 B 6.5 B 51 U

1,2,3,7,8,9‐HxCDF NA NA NA NA 6.0 U 4.9 U 51 U

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 150 B 100 B 51 U

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 13 B 7.8 B 51 U

OCDF NA NA NA NA 240 B 150 B 0.48 J B

Arthur Kill Upland ‐ Comp A ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt) SPLP (Units: pg/L)

ASI ID # #20200021 #20200026 #20200026

Comp X Q A Comp X Q A Comp X Q

2,3,7,8‐TCDD 1 11.00 7.10 10.00 U

1,2,3,7,8‐PeCDD 1 4.90 J B 3.10 J B q 51.00 U

1,2,3,4,7,8‐HxCDD 0.1 0.49 J B 0.36 J B 5.10 U

1,2,3,6,7,8‐HxCDD 0.1 2.10 B 1.50 B 5.10 U

1,2,3,7,8,9‐HxCDD 0.1 1.80 B 1.20 B 5.10 U

1,2,3,4,6,7,8‐HpCDD 0.01 3.10 B 2.40 B 0.02 J B q

1,2,3,4,6,7,8,9‐OCDD 0.0003 1.59 E B 1.17 B 0.01 J B

2,3,7,8‐TCDF 0.1 2.20 1.40 1.00 U

1,2,3,7,8‐PeCDF 0.03 0.33 0.21 1.53 U

2,3,4,7,8‐PeCDF 0.3 3.90 2.70 15.30 U

1,2,3,4,7,8‐HxCDF 0.1 3.90 B 2.40 B 5.10 U

1,2,3,6,7,8‐HxCDF 0.1 1.60 B 0.98 I B 5.10 U

2,3,4,6,7,8‐HxCDF 0.1 1.00 B 0.65 B 5.10 U

1,2,3,7,8,9‐HxCDF 0.1 0.60 U 0.49 U 5.10 U

1,2,3,4,6,7,8‐HpCDF 0.01 1.50 B 1.00 B 0.51 U

1,2,3,4,7,8,9‐HpCDF 0.01 0.13 B 0.08 B 0.51 U

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.07 B 0.05 B 0.00 J B

TOTAL TEF as 2,3,7,8‐TCDD 40.21 26.79 115.58

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

ug/L)

ASI ID # Soil Leachate #20200022 #20200027 #20200027 ug/kg ug/L COMP B Q A COMP B Q A COMP B Q

Chloromethane (Methyl Chloride) 4000 30 14 U 11 U 1.0 U

Bromomethane 25000 10 14 U 11 U 1.0 U

Vinyl chloride 700 5 14 U 11 U 1.0 U

Chloroethane 220000 NA 14 U * 11 U * 1.0 U H

Methylene chloride (Dichloromethane) 34000 3 14 U 11 U 5.2 B

Acetone 70000000 700 31 J 69 130 E B

Carbon disulfide 7800000 NA 14 U 11 U 1.0 U H

1,1-Dichloroethene 11000 2 14 U 11 U 1.0 U

1,1-Dichloroethane 8000 50 14 U 11 U 1.0 U H

1,2-Dichloroethene (total) 10 28 U 23 U 2.0 U

Chloroform 600 6 14 U 11 U 1.0 U H

1,2-Dichloroethane 900 NA 14 U 11 U 1.0 U

2-Butanone (MEK) 3100000 300 14 130 7.0

1,1,1-Trichloroethane 290000 30 14 U 11 U 1.0 U

Carbon tetrachloride 600 2 14 U 11 U 1.0 U

Bromodichloromethane 1000 1 14 U 11 U 1.0 U H

1,2-Dichloropropane 2000 1 14 U 11 U 1.0 U H cis-1,3-Dichloropropene NA NA 14 U 11 U 1.0 U

Trichloroethene 7000 1 14 U 11 U 1.0 U H

Dibromochloromethane 3000 10 14 U 11 U 1.0 U

1,1,2-Trichloroethane 2000 3 14 U 11 U 1.0 U

Benzene 2000 1 14 U 11 U 1.0 U H trans-1,3-dichloropropene NA NA 14 U 11 U 1.0 U H

Bromoform 81000 4 14 U 11 U 1.0 U

Tetrachloroethene 2000 1 14 U 11 U 1.0 U H

1,1,2,2-Tetrachloroethane 1000 NA 14 U 11 U 1.0 U H

Toluene 6300000 1000 14 U 11 U 1.0 U H

Chlorobenzene 510000 50 14 U 11 U 1.0 U

Ethyl benzene 7800000 700 14 U 11 U 1.0 U

Styrene 90000 100 14 U 11 U 1.0 U

Xylenes(Total) 12000000 1000 28 U 23 U 2.0 U

Acrolein 500 280 U 230 U 20 U

Acrylonitrile 900 140 U 110 U 20 U H

1,2-Dibromo-3-chloropropane 80 14 U 11 U 1.0 U H

1,2-Dibromoethane 8 14 U 11 U 1.0 U H

Dichlorodifluoromethane 490000 14 U 11 U 1.0 U H

1,2-Dichloroethene (cis) 230000 14 U 11 U 1.0 U H

1,2-Dichloroethene (trans) 300000 14 U 11 U 1.0 U

Methyl acetate 78000000 69 U 57 U 5.0 U H

Methyl tert-butyl ether (MTBE) 110000 14 U 11 U 1.0 U

Tertiary butyl alcohol (TBA) 1400000 140 U 110 U 40 U

Trichlorofluoromethane 23000000 14 U 11 U 1.0 U H *

Combined 1,3-dichloropropenes (SUM) cis + trans 2000 0.2

1,4-dioxane 2800 U 2300 U 200 U H n-propylbenzene 14 U 11 U 1.0 U H sec-butylbenzene 14 U 11 U 1.0 U H tert-butylbenzene 14 U 11 U 1.0 U

1,2,4-trimethylbenzene 14 U 11 U 1.0 U H

1,3,5-trimethylbenzene 14 U 11 U 1.0 U H n‐Butylbenzene 14 U 11 U 1.0 U

Arthur Kill Upland - Comp B - Sediment Semivolatiles

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200022 #20200027 #20200027 ug/kg ug/kg mg/L mg/L COMP B Q A COMP B Q A COMP B Q

Phenol 18000000 660 4 0.01 910 U 180 U 0.001 U bis(2-Chloroethyl)ether 400 660 0.01 0.01 180 U 37 U 0.00019 U

2-Chlorophenol 310000 660 0.005 0.01 910 U 180 U 0.001 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 14 U 11 U 0.001 U

1,4-Dichlorobenzene 5000 660 0.075 0.01 14 U 11 U 0.001 U H

1,2-Dichlorobenzene 5300000 660 0.6 0.01 14 U 11 U 0.001 U H

2-Methylphenol (o-cresol) 310000 660 NA 0.01 910 U 180 U 0.001 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 180 U 37 U 0.00019 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 910 U 180 U 0.00056 J

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 180 U 37 U 0.00019 U

Hexachloroethane 35000 660 0.01 0.01 910 U 180 U 0.001 U

Nitrobenzene 31000 660 0.01 0.01 1800 U 370 U 0.002 U

Isophorone 510000 660 0.1 0.01 910 U 180 U 0.0005 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 910 U 180 U 0.001

2,4-Dichlorophenol 180000 660 0.02 0.01 180 U 37 U 0.00019 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 14 U 11 U 0.001 U

Naphthalene 6000 660 0.3 0.01 89 J 19 J 0.000069 J

Hexachloro-1,3-butadiene 6000 660 NA 0.01 180 U 37 U 0.00019 U

2-Methylnaphthalene 230000 660 NA 0.01 85 J 14 J 0.00019 U

Hexachlorocyclopentadiene 45000 660 0.05 0.01 910 U 180 U 0.001 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 910 U 180 U 0.001 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 910 U 180 U 0.001 U

2-Chloronaphthalene NA 660 NA 0.01 180 U 37 U 0.00019 U

2-Nitroaniline 39000 3300 NA 0.05 4700 U 950 U 0.005 U

Acenaphthylene 300000000 660 NA 0.01 150 J 47 0.00019 U

2,6-Dinitrotoluene 700 660 0.01 0.01 910 U 180 U 0.001 U

Arthur Kill Upland - Comp B - Sediment Semivolatiles, con't.

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200022 #20200027 #20200027 ug/kg ug/kg mg/L mg/L COMP B Q A COMP B Q A COMP B Q

Acenaphthene 3400000 660 0.4 0.01 98 J 37 U 0.00011 J

2,4-Dinitrophenol 120000 3300 0.04 0.05 9100 U 1800 U 0.01 U

Dibenzofuran NA 660 NA 0.01 910 U 180 U 0.001 U

2,4-Dinitrotoluene 700 660 0.01 0.01 910 U 180 U 0.001 U

Diethylphthalate 49000000 660 5 0.01 910 U 180 U 0.001 U

Fluorene 2300000 660 0.3 0.01 69 J 37 U 0.00019 U

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 4700 U 950 U 0.005 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 910 U 180 U 0.001 U

Hexachlorobenzene 300 660 0.01 0.01 180 U 37 U 0.00019 U

Pentachlorophenol 3000 3300 0.001 0.05 4700 U 950 U 0.005 U

Phenanthrene 300000000 6600 NA 0.01 260 64 0.00013 J

Anthracene 17000000 6600 2 0.01 180 44 0.00014 J

Carbazole 24000 330 NA 0.01 180 U 37 U 0.00019 U

Di-n-butylphthalate 6100000 330 0.9 0.01 910 U 180 U 0.001 U

Fluoranthene 2300000 660 0.3 0.01 700 150 0.00013 J

Pyrene 1700000 660 0.2 0.01 710 160 0.000093 J

Butylbenzylphthalate 1200000 660 0.1 0.01 910 U 180 U 0.001 U

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 910 U 180 U 0.001 U

Benzo(a)anthracene 600 660 NA 0.01 390 97 0.00019 U

Chrysene 62000 660 NA 0.01 430 110 0.00019 U bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 10000 1700 J 0.01 U

DI-n-octylphthalate 2400000 660 0.1 0.01 910 U 180 U 0.001 U

Benzo(b)fluoranthene 600 660 NA 0.01 520 100 0.00019 U

Benzo(k)fluoranthene 6000 660 NA 0.01 140 J 54 0.00019 U

Benzo(a)pyrene 200 660 NA 0.01 360 100 0.00019 U

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 290 83 0.00019 U

Dibenzo(a,h)anthracene 200 660 NA 0.01 130 J 25 J 0.00019 U

Benzo(ghi)perylene 30000000 660 NA 0.01 400 110 0.00019 U

Acetophenone 2000 1800 U 370 U 0.001 U

Atrazine 210000 1800 U 370 U 0.001 U

Benzaldehyde 6100000 1800 U 370 U 0.00055 J

Benzidine 700 18000 U 3700 U 0.02 U

1,1'-Biphenyl 3100000 910 U 180 U 0.001 U

Caprolactam 31000000 4700 U 950 U 0.005 U

1,2-Diphenylhydrazine 700 910 U 180 U 0.001 U

N-Nitrosodimethylamine 700 910 U 180 U 0.001 U

Arthur Kill Upland - Comp B - Pesticides/Aroclors

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200022 #20200027 #20200027 ug/kg ug/kg mg/L mg/L COMP B Q A COMP B Q A COMP B Q alpha-BHC 100 1.9 0.00002 0.00005 0.57 U 0.47 U 0.0000013 U beta-BHC 400 3.3 0.0002 0.00005 0.57 U 0.47 U 0.0000013 U delta-BHC NA 1.7 NA 0.00005 0.57 U 0.47 U 0.0000013 U gamma-BHC (Lindane) 400 2 0.0002 0.00005 3.1 1.4 0.0000013 U

Heptachlor 100 2.1 0.0004 0.00005 0.57 U 0.47 U 0.0000013 U

Aldrin 40 2 0.00004 0.00005 0.57 U 0.47 U 0.0000013 U

Heptachlor epoxide 70 2.1 0.0002 0.00005 5.5 p 2.8 p 0.0000013 U

Endosulfan I NA 2.1 0.0004 0.00005 0.57 U 0.47 U 0.0000013 U

Dieldrin 40 3.3 0.00003 0.0001 1.7 1.8 P 0.0000013 U

4,4'-DDE 2000 4.2 0.0001 0.0001 51 p 39 0.0000013 U

Endrin 23000 3.6 0.002 0.0001 13 7.3 0.0000013 U

Endosulfan II NA 3.3 0.0004 0.0001 3.9 1.3 p 0.0000013 U

4,4'-DDD 3000 4.2 0.0001 0.0001 72 22 0.0000013 U

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.86 p 0.47 U 0.0000013 U

4,4'-DDT 2000 3.6 0.0001 0.0001 7.4 p 21 p 0.0000013 U

Methoxychlor 390000 17 0.04 0.001 0.57 U 0.47 U 0.0000013 U alpha-Chlordane 200 1.7 NA 0.00005 0.57 U 2.3 0.0000013 U gamma-Chlordane 200 1.7 0.0005 0.00005 0.57 U 0.47 U 0.0000013 U

Toxaphene 600 170 0.003 0.005 23 U 19 U 0.0001 U

Mirex 0.57 U 0.47 U 0.0000013 U

Aroclor‐1016 11 U 9.4 U 0.00001 U

Aroclor‐1221 11 U 9.4 U 0.00001 U

Aroclor‐1232 11 U 9.4 U 0.00001 U

Aroclor‐1242 11 U 9.4 U 0.00001 U

Aroclor‐1248 240 9.4 U 0.00001 U

Aroclor‐1254 11 U 9.4 U 0.00001 U

Aroclor‐1260 140 53 0.00001 U

Total Aroclor(SUM)

Arthur Kill Upland - Comp B - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

ug/L)

ASI ID # Soil Leachate #20200022 #20200027 #20200027

COMP B Q A COMP B Q A COMP B Q

2,4,5-TP (Silvex) NA NA NA NA 55 U 45 U 0.97 U

Arthur Kill Upland ‐ Comp B ‐ Metals

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200022 #20200027 #20200027 mg/kg mg/kg mg/L mg/L COMP B Q A COMP B Q A COMP B Q

Aluminum 78000 40 0.2 0.2 13000 15000 1.3

Antimony 31 12 0.02 0.06 1.8 1.3 0.00062 J

Arsenic 19 2 0.008 0.01 27 23 0.0032

Barium 16000 40 2 0.2 170 150 0.027

Beryllium 16 1 0.02 0.005 1.0 0.88 0.001 U

Cadmium 78 1 0.004 0.005 3.0 2.4 0.001 U

Chromium NA 2 0.1 0.01 88 80 0.002 U

Hexavalent Chromium 120000 1.1 U 0.91 U 0.014 B

Trivalent Chromium 20 88 80 0.01 U

Cobalt 1,600 10 NA 0.05 9.0 8.4 0.0007

Copper 590 5 1 0.025 260 210 0.002 U

Lead 400 0.6 0.01 0.003 190 160 0.0011 B

Manganese 5900 3 0.05 0.015 480 470 0.005 U

Mercury 23 0.1 0.002 0.0002 4.4 B 3.5 B 0.00056

Nickel 1,600 8 0.1 0.04 34 29 0.0064

Selenium 390 1 0.05 0.015 5.2 4.4 0.0015 J

Silver 390 2 NA 0.01 4.3 3.3 0.001 U

Vanadium 78 10 NA 0.05 37 37 0.011

Zinc 23,000 4 5 0.02 300 310 0.0036 J

Cyanide, total 1,600 0.5 0.2 0.01 1.2 2.7 0.01 U

%Solids NA NA NA NA 36.2 44.2

Arthur Kill Upland ‐ Comp B ‐ Dioxin/Furan

Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP (Units:

pg/L)

ASI ID # Soil Leachate #20200022 #20200027 #20200027 ng/kg pg/L COMP B Q A COMP B Q A COMP B Q

2,3,7,8‐TCDD NA NA NA NA 26 22 10 U

1,2,3,7,8‐PeCDD NA NA NA NA 9.9 B q 6.9 B q 51 U

1,2,3,4,7,8‐HxCDD NA NA NA NA 9.9 B 7.6 B 51 U

1,2,3,6,7,8‐HxCDD NA NA NA NA 62 B 44 B 51 U

1,2,3,7,8,9‐HxCDD NA NA NA NA 42 B 31 B 51 U

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 590 B 520 B 0.70 J B

OCDD NA NA NA NA 8700 E B 7200 E B 15 J B

2,3,7,8‐TCDF NA NA NA NA 45 32 10 U

1,2,3,7,8‐PeCDF NA NA NA NA 26 17 51 U

2,3,4,7,8‐PeCDF NA NA NA NA 35 23 51 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 110 B 79 B 51 U

1,2,3,6,7,8‐HxCDF NA NA NA NA 40 B 28 I B 51 U

2,3,4,6,7,8‐HxCDF NA NA NA NA 29 B 21 B 51 U

1,2,3,7,8,9‐HxCDF NA NA NA NA 3.6 J B 2.7 J B 51 U

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 390 B 280 B 0.24 J B q

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 40 B 26 B 51 U

OCDF NA NA NA NA 610 B 400 B 100 U

Arthur Kill Upland ‐ Comp B ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt) SPLP (Units: pg/L)

ASI ID # #20200022 #20200027 #20200027

COMP B Q A COMP B Q A COMP B Q

2,3,7,8‐TCDD 1 26.00 22.00 10.00 U

1,2,3,7,8‐PeCDD 1 9.90 B q 6.90 B q 51.00 U

1,2,3,4,7,8‐HxCDD 0.1 0.99 B 0.76 B 5.10 U

1,2,3,6,7,8‐HxCDD 0.1 6.20 B 4.40 B 5.10 U

1,2,3,7,8,9‐HxCDD 0.1 4.20 B 3.10 B 5.10 U

1,2,3,4,6,7,8‐HpCDD 0.01 5.90 B 5.20 B 0.01 J B

1,2,3,4,6,7,8,9‐OCDD 0.0003 2.61 E B 2.16 E B 0.00 J B

2,3,7,8‐TCDF 0.1 4.50 3.20 1.00 U

1,2,3,7,8‐PeCDF 0.03 0.78 0.51 1.53 U

2,3,4,7,8‐PeCDF 0.3 10.50 6.90 15.30 U

1,2,3,4,7,8‐HxCDF 0.1 11.00 B 7.90 B 5.10 U

1,2,3,6,7,8‐HxCDF 0.1 4.00 B 2.80 I B 5.10 U

2,3,4,6,7,8‐HxCDF 0.1 2.90 B 2.10 B 5.10 U

1,2,3,7,8,9‐HxCDF 0.1 0.36 J B 0.27 J B 5.10 U

1,2,3,4,6,7,8‐HpCDF 0.01 3.90 B 2.80 B 0.00 J B q

1,2,3,4,7,8,9‐HpCDF 0.01 0.40 B 0.26 B 0.51 U

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.18 B 0.12 B 0.03 U

TOTAL TEF as 2,3,7,8‐TCDD 94.32 71.38 115.08

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

ug/L)

ASI ID # Soil Leachate #20200023 #20200028 #20200028 ug/kg ug/L COMP C Q A COMP C Q A COMPC Q

Chloromethane (Methyl Chloride) 4000 30 13 U 11 U 1.0 U

Bromomethane 25000 10 13 U 11 U 1.0 U

Vinyl chloride 700 5 13 U 11 U 1.0 U

Chloroethane 220000 NA 13 U * 11 U * 1.0 U

Methylene chloride (Dichloromethane) 34000 3 13 U 11 U 1.3 H B

Acetone 70000000 700 23 J 57 41 J H

Carbon disulfide 7800000 NA 13 U 11 U 1.0 U H

1,1-Dichloroethene 11000 2 13 U 11 U 1.0 U

1,1-Dichloroethane 8000 50 13 U 11 U 1.0 U

1,2-Dichloroethene (total) 10 27 U 22 U 2.0 U

Chloroform 600 6 13 U 11 U 1.0 U

1,2-Dichloroethane 900 NA 13 U 11 U 1.0 U H

2-Butanone (MEK) 3100000 300 13 U 110 9.1

1,1,1-Trichloroethane 290000 30 13 U 11 U 1.0 U

Carbon tetrachloride 600 2 13 U 11 U 1.0 U

Bromodichloromethane 1000 1 13 U 11 U 1.0 U H

1,2-Dichloropropane 2000 1 13 U 11 U 1.0 U H cis-1,3-Dichloropropene NA NA 13 U 11 U 1.0 U H

Trichloroethene 7000 1 13 U 11 U 1.0 U

Dibromochloromethane 3000 10 13 U 11 U 1.0 U H

1,1,2-Trichloroethane 2000 3 13 U 11 U 1.0 U H

Benzene 2000 1 13 U 11 U 1.0 U H trans-1,3-dichloropropene NA NA 13 U 11 U 1.0 U H

Bromoform 81000 4 13 U 11 U 1.0 U

Tetrachloroethene 2000 1 13 U 11 U 1.0 U

1,1,2,2-Tetrachloroethane 1000 NA 13 U 11 U 1.0 U H

Toluene 6300000 1000 13 U 11 U 1.0 U

Chlorobenzene 510000 50 13 U 11 U 1.0 U

Ethyl benzene 7800000 700 13 U 11 U 1.0 U

Styrene 90000 100 13 U 11 U 1.0 U H

Xylenes(Total) 12000000 1000 27 U 22 U 2.0 U H

Acrolein 500 270 U 220 U 20 U H

Acrylonitrile 900 130 U 110 U 20 U

1,2-Dibromo-3-chloropropane 80 13 U 11 U 1.0 U

1,2-Dibromoethane 8 13 U 11 U 1.0 U

Dichlorodifluoromethane 490000 13 U 11 U 1.0 U H

1,2-Dichloroethene (cis) 230000 13 U 11 U 1.0 U

1,2-Dichloroethene (trans) 300000 13 U 11 U 1.0 U H

Methyl acetate 78000000 67 U 56 U 5.0 U

Methyl tert-butyl ether (MTBE) 110000 13 U 11 U 1.0 U

Tertiary butyl alcohol (TBA) 1400000 130 U 110 U 40 U

Trichlorofluoromethane 23000000 13 U 11 U 1.0 U H *

Combined 1,3-dichloropropenes (SUM) cis + trans 2000 0.2

1,4-dioxane 2700 U 2200 U 200 U H n-propylbenzene 13 U 11 U 1.0 U sec-butylbenzene 13 U 11 U 1.0 U tert-butylbenzene 13 U 11 U 1.0 U H

1,2,4-trimethylbenzene 3.9 J 11 U 1.0 U H

1,3,5-trimethylbenzene 13 U 11 U 1.0 U H n‐Butylbenzene 13 U 11 U 1.0 U

Arthur Kill Upland - Comp C - Sediment Semivolatiles

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200023 #20200028 #20200028 ug/kg ug/kg mg/L mg/L COMP C Q A COMP C Q A COMPC Q

Phenol 18000000 660 4 0.01 880 U 180 U 0.00096 U bis(2-Chloroethyl)ether 400 660 0.01 0.01 180 U 37 U 0.00018 U

2-Chlorophenol 310000 660 0.005 0.01 880 U 180 U 0.00096 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 13 U 11 U 0.001 U

1,4-Dichlorobenzene 5000 660 0.075 0.01 13 U 11 U 0.001 U H

1,2-Dichlorobenzene 5300000 660 0.6 0.01 13 U 11 U 0.001 U

2-Methylphenol (o-cresol) 310000 660 NA 0.01 880 U 180 U 0.00096 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 180 U 37 U 0.00018 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 880 U 180 U 0.00058 J

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 180 U 37 U 0.00018 U

Hexachloroethane 35000 660 0.01 0.01 880 U 180 U 0.00096 U

Nitrobenzene 31000 660 0.01 0.01 1800 U 370 U 0.0019 U

Isophorone 510000 660 0.1 0.01 880 U 180 U 0.00053 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 880 U 180 U 0.00081 J

2,4-Dichlorophenol 180000 660 0.02 0.01 180 U 37 U 0.00018 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 13 U 11 U 0.001 U H

Naphthalene 6000 660 0.3 0.01 100 J 18 J 0.00016 J

Hexachloro-1,3-butadiene 6000 660 NA 0.01 180 U 37 U 0.00018 U

2-Methylnaphthalene 230000 660 NA 0.01 100 J 17 J 0.00022

Hexachlorocyclopentadiene 45000 660 0.05 0.01 880 U 180 U 0.00096 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 880 U 180 U 0.00096 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 880 U 180 U 0.00096 U

2-Chloronaphthalene NA 660 NA 0.01 180 U 37 U 0.00018 U

2-Nitroaniline 39000 3300 NA 0.05 4500 U 940 U 0.0048 U

Acenaphthylene 300000000 660 NA 0.01 120 J 40 0.00018 U

2,6-Dinitrotoluene 700 660 0.01 0.01 880 U 180 U 0.00096 U

Arthur Kill Upland - Comp C - Sediment Semivolatiles, con't.

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200023 #20200028 #20200028 ug/kg ug/kg mg/L mg/L COMP C Q A COMP C Q A COMPC Q

Acenaphthene 3400000 660 0.4 0.01 180 U 37 U 0.00018 U

2,4-Dinitrophenol 120000 3300 0.04 0.05 8800 U 1800 U 0.0096 U

Dibenzofuran NA 660 NA 0.01 880 U 180 U 0.00096 U

2,4-Dinitrotoluene 700 660 0.01 0.01 880 U 180 U 0.00096 U

Diethylphthalate 49000000 660 5 0.01 880 U 180 U 0.00096 U

Fluorene 2300000 660 0.3 0.01 87 J 19 J 0.00011 J

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 4500 U 940 U 0.0048 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 880 U 180 U 0.00096 U

Hexachlorobenzene 300 660 0.01 0.01 180 U 37 U 0.00018 U

Pentachlorophenol 3000 3300 0.001 0.05 4500 U 940 U 0.0048 U

Phenanthrene 300000000 6600 NA 0.01 330 76 0.00019

Anthracene 17000000 6600 2 0.01 220 56 0.00015 J

Carbazole 24000 330 NA 0.01 180 U 37 U 0.00018 U

Di-n-butylphthalate 6100000 330 0.9 0.01 880 U 180 U 0.00096 U

Fluoranthene 2300000 660 0.3 0.01 750 180 0.00018 U

Pyrene 1700000 660 0.2 0.01 810 170 0.00018 U

Butylbenzylphthalate 1200000 660 0.1 0.01 880 U 180 U 0.00096 U

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 880 U 180 U 0.00096 U

Benzo(a)anthracene 600 660 NA 0.01 370 100 0.00018 U

Chrysene 62000 660 NA 0.01 430 120 0.00018 U bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 4800 J 1100 J 0.0096 U

DI-n-octylphthalate 2400000 660 0.1 0.01 880 U 180 U 0.00096 U

Benzo(b)fluoranthene 600 660 NA 0.01 640 140 0.00018 U

Benzo(k)fluoranthene 6000 660 NA 0.01 170 J 35 J 0.00018 U

Benzo(a)pyrene 200 660 NA 0.01 440 110 0.00018 U

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 310 74 0.00018 U

Dibenzo(a,h)anthracene 200 660 NA 0.01 160 J 37 U 0.00018 U

Benzo(ghi)perylene 30000000 660 NA 0.01 510 120 0.00018 U

Acetophenone 2000 1800 U 370 U 0.00096 U

Atrazine 210000 1800 U 370 U 0.00096 U

Benzaldehyde 6100000 1800 U 370 U 0.00062 J

Benzidine 700 18000 U 3700 U 0.019 U

1,1'-Biphenyl 3100000 880 U 180 U 0.00096 U

Caprolactam 31000000 4500 U 940 U 0.0048 U

1,2-Diphenylhydrazine 700 880 U 180 U 0.00096 U

N-Nitrosodimethylamine 700 880 U 180 U 0.00096 U

Arthur Kill Upland - Comp C - Pesticides/Aroclors

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200023 #20200028 #20200028 ug/kg ug/kg mg/L mg/L COMP C Q A COMP C Q A COMPC Q alpha-BHC 100 1.9 0.00002 0.00005 0.56 U 0.47 U 0.0000013 U * beta-BHC 400 3.3 0.0002 0.00005 0.56 U 0.47 U 0.0000013 U * delta-BHC NA 1.7 NA 0.00005 0.56 U 0.47 U 0.0000013 U * gamma-BHC (Lindane) 400 2 0.0002 0.00005 0.53 J p 1.3 0.00000097 J *

Heptachlor 100 2.1 0.0004 0.00005 0.56 U 0.47 U 0.0000013 U *

Aldrin 40 2 0.00004 0.00005 0.56 U 0.47 U 0.0000013 U *

Heptachlor epoxide 70 2.1 0.0002 0.00005 4.3 p 2.2 p 0.0000013 U *

Endosulfan I NA 2.1 0.0004 0.00005 0.56 U 0.47 U 0.0000013 U *

Dieldrin 40 3.3 0.00003 0.0001 0.56 U 0.47 U 0.0000013 U

4,4'-DDE 2000 4.2 0.0001 0.0001 52 p 29 p 0.0000013 U

Endrin 23000 3.6 0.002 0.0001 9.7 6.5 0.0000013 U

Endosulfan II NA 3.3 0.0004 0.0001 1.5 p 0.96 p 0.00000085 J

4,4'-DDD 3000 4.2 0.0001 0.0001 60 34 0.0000012 J

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.56 U 0.47 U 0.0000013 U

4,4'-DDT 2000 3.6 0.0001 0.0001 49 52 0.0000013 U

Methoxychlor 390000 17 0.04 0.001 0.56 U 0.47 U 0.0000013 U alpha-Chlordane 200 1.7 NA 0.00005 7.0 1.9 p 0.0000013 U * gamma-Chlordane 200 1.7 0.0005 0.00005 0.56 U 0.47 U 0.0000013 U *

Toxaphene 600 170 0.003 0.005 22 U 19 U 0.0001 U *

Mirex 0.56 U 0.47 U 0.0000013 U

Aroclor‐1016 11 U 9.4 U 0.00001 U

Aroclor‐1221 11 U 9.4 U 0.00001 U

Aroclor‐1232 11 U 9.4 U 0.00001 U

Aroclor‐1242 11 U 9.4 U 0.00001 U

Aroclor‐1248 250 9.4 U 0.00001 U

Aroclor‐1254 11 U 9.4 U 0.00001 U

Aroclor‐1260 160 120 0.00001 U

Total Aroclor(SUM)

Arthur Kill Upland - Comp C - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

ug/L)

ASI ID # Soil Leachate #20200023 #20200028 #20200028

COMP C Q A COMP C Q A COMPC Q

2,4,5-TP (Silvex) NA NA NA NA 53 U 44 U 0.96 U

Arthur Kill Upland ‐ Comp C ‐ Metals

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200023 #20200028 #20200028 mg/kg mg/kg mg/L mg/L COMP C Q A COMP C Q A COMPC Q

Aluminum 78000 40 0.2 0.2 12000 14000 0.83

Antimony 31 12 0.02 0.06 1.8 1.4 0.00039 J

Arsenic 19 2 0.008 0.01 23 20 0.0031

Barium 16000 40 2 0.2 160 150 0.034

Beryllium 16 1 0.02 0.005 0.90 0.88 0.001 U

Cadmium 78 1 0.004 0.005 2.2 1.8 0.001 U

Chromium NA 2 0.1 0.01 74 63 0.002 U

Hexavalent Chromium 120000 1.1 U 0.89 U 0.016 B

Trivalent Chromium 20 74 63 0.01 U

Cobalt 1,600 10 NA 0.05 8.1 7.2 0.00065

Copper 590 5 1 0.025 190 150 0.002 U

Lead 400 0.6 0.01 0.003 160 120 0.0003 J B

Manganese 5900 3 0.05 0.015 450 450 0.005 U

Mercury 23 0.1 0.002 0.0002 3.7 B 3.1 B 0.00094

Nickel 1,600 8 0.1 0.04 28 23 0.0052

Selenium 390 1 0.05 0.015 4.6 3.7 0.005 U

Silver 390 2 NA 0.01 2.8 2.2 0.001 U

Vanadium 78 10 NA 0.05 33 29 0.0068

Zinc 23,000 4 5 0.02 240 270 0.005 U

Cyanide, total 1,600 0.5 0.2 0.01 1.4 3.4 0.0062 J

%Solids NA NA NA NA 37.1 44.8

Arthur Kill Upland ‐ Comp C ‐ Dioxin/Furan

Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP (Units:

pg/L)

ASI ID # Soil Leachate #20200023 #20200028 #20200028 ng/kg pg/L COMP C Q A COMP C Q A COMPC Q

2,3,7,8‐TCDD NA NA NA NA 24 18 9.7 U

1,2,3,7,8‐PeCDD NA NA NA NA 7.3 B 6.6 B 49 U

1,2,3,4,7,8‐HxCDD NA NA NA NA 7.5 B 6.3 B 49 U

1,2,3,6,7,8‐HxCDD NA NA NA NA 37 B 32 B 49 U

1,2,3,7,8,9‐HxCDD NA NA NA NA 29 B 25 B 49 U

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 470 B 410 B 0.56 J B q

OCDD NA NA NA NA 7200 E B 6400 E B 5.5 J B

2,3,7,8‐TCDF NA NA NA NA 36 28 9.7 U

1,2,3,7,8‐PeCDF NA NA NA NA 18 16 49 U

2,3,4,7,8‐PeCDF NA NA NA NA 24 20 49 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 77 B 67 B 49 U

1,2,3,6,7,8‐HxCDF NA NA NA NA 32 B 26 I B 49 U

2,3,4,6,7,8‐HxCDF NA NA NA NA 20 B 17 B 49 U

1,2,3,7,8,9‐HxCDF NA NA NA NA 6.5 U 2.1 J B 49 U

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 290 B 240 B 49 U

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 28 B 22 B 49 U

OCDF NA NA NA NA 460 B 350 B 0.28 J B q

Arthur Kill Upland ‐ Comp C ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt) SPLP (Units: pg/L)

ASI ID # #20200023 #20200028 #20200028

COMP C Q A COMP C Q A COMPC Q

2,3,7,8‐TCDD 1 24.00 18.00 9.70 U

1,2,3,7,8‐PeCDD 1 7.30 B 6.60 B 49.00 U

1,2,3,4,7,8‐HxCDD 0.1 0.75 B 0.63 B 4.90 U

1,2,3,6,7,8‐HxCDD 0.1 3.70 B 3.20 B 4.90 U

1,2,3,7,8,9‐HxCDD 0.1 2.90 B 2.50 B 4.90 U

1,2,3,4,6,7,8‐HpCDD 0.01 4.70 B 4.10 B 0.01 J B q

1,2,3,4,6,7,8,9‐OCDD 0.0003 2.16 E B 1.92 E B 0.00 J B

2,3,7,8‐TCDF 0.1 3.60 2.80 0.97 U

1,2,3,7,8‐PeCDF 0.03 0.54 0.48 1.47 U

2,3,4,7,8‐PeCDF 0.3 7.20 6.00 14.70 U

1,2,3,4,7,8‐HxCDF 0.1 7.70 B 6.70 B 4.90 U

1,2,3,6,7,8‐HxCDF 0.1 3.20 B 2.60 I B 4.90 U

2,3,4,6,7,8‐HxCDF 0.1 2.00 B 1.70 B 4.90 U

1,2,3,7,8,9‐HxCDF 0.1 0.65 U 0.21 J B 4.90 U

1,2,3,4,6,7,8‐HpCDF 0.01 2.90 B 2.40 B 0.49 U

1,2,3,4,7,8,9‐HpCDF 0.01 0.28 B 0.22 B 0.49 U

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.14 B 0.11 B 0.00 J B q

TOTAL TEF as 2,3,7,8‐TCDD 73.72 60.17 111.13

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

ug/L)

ASI ID # Soil Leachate #20200024 #20200029 #20200029 ug/kg ug/L COMP D Q A COMP D Q A COMP D Q

Chloromethane (Methyl Chloride) 4000 30 14 U 11 U 1.0 U H

Bromomethane 25000 10 14 U 11 U * 1.0 U H

Vinyl chloride 700 5 14 U 11 U 1.0 U H

Chloroethane 220000 NA 14 U * 11 U * 1.0 U H

Methylene chloride (Dichloromethane) 34000 3 14 U 11 U 4.0 H B

Acetone 70000000 700 20 J 45 U 42 J H

Carbon disulfide 7800000 NA 14 U 11 U 1.0 U H

1,1-Dichloroethene 11000 2 14 U 11 U 1.0 U H

1,1-Dichloroethane 8000 50 14 U 11 U 1.0 U H

1,2-Dichloroethene (total) 10 29 U 23 U 2.0 U H

Chloroform 600 6 14 U 11 U 1.0 U H

1,2-Dichloroethane 900 NA 14 U 11 U 1.0 U H

2-Butanone (MEK) 3100000 300 18 21 5.6 H

1,1,1-Trichloroethane 290000 30 14 U 11 U 1.0 U H

Carbon tetrachloride 600 2 14 U 11 U 1.0 U H

Bromodichloromethane 1000 1 14 U 11 U 1.0 U H

1,2-Dichloropropane 2000 1 14 U 11 U 1.0 U H cis-1,3-Dichloropropene NA NA 14 U 11 U 1.0 U H

Trichloroethene 7000 1 14 U 11 U 1.0 U H

Dibromochloromethane 3000 10 14 U 11 U 1.0 U H

1,1,2-Trichloroethane 2000 3 14 U 11 U 1.0 U H

Benzene 2000 1 14 U 11 U 1.0 U H trans-1,3-dichloropropene NA NA 14 U 11 U 1.0 U H

Bromoform 81000 4 14 U 11 U 1.0 U H

Tetrachloroethene 2000 1 14 U 11 U 1.0 U H

1,1,2,2-Tetrachloroethane 1000 NA 14 U 11 U 1.0 U H

Toluene 6300000 1000 14 U 11 U 1.0 U H

Chlorobenzene 510000 50 14 U 11 U 1.0 U H

Ethyl benzene 7800000 700 14 U 11 U 1.0 U H

Styrene 90000 100 14 U 11 U 1.0 U H

Xylenes(Total) 12000000 1000 29 U 23 U 2.0 U H

Acrolein 500 290 U 230 U 20 U H

Acrylonitrile 900 140 U 110 U 20 U H

1,2-Dibromo-3-chloropropane 80 14 U 11 U 1.0 U H

1,2-Dibromoethane 8 14 U 11 U 1.0 U H

Dichlorodifluoromethane 490000 14 U 11 U 1.0 U H

1,2-Dichloroethene (cis) 230000 14 U 11 U 1.0 U H

1,2-Dichloroethene (trans) 300000 14 U 11 U 1.0 U H

Methyl acetate 78000000 71 U 57 U 5.0 U H

Methyl tert-butyl ether (MTBE) 110000 14 U 11 U 1.0 U H

Tertiary butyl alcohol (TBA) 1400000 140 U 110 U 17 J H

Trichlorofluoromethane 23000000 14 U 11 U 1.0 U H *

Combined 1,3-dichloropropenes (SUM) cis + trans 2000 0.2

1,4-dioxane 2900 U 2300 U 200 U H n-propylbenzene 14 U 11 U 1.0 U H sec-butylbenzene 14 U 11 U 1.0 U H tert-butylbenzene 14 U 11 U 1.0 U H

1,2,4-trimethylbenzene 14 U 11 U 1.0 U H

1,3,5-trimethylbenzene 14 U 11 U 1.0 U H n‐Butylbenzene 14 U 11 U 1.0 U H

Arthur Kill Upland - Comp D - Sediment Semivolatiles

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200024 #20200029 #20200029 ug/kg ug/kg mg/L mg/L COMP D Q A COMP D Q A COMP D Q

Phenol 18000000 660 4 0.01 1200 U 190 U 0.00051 J bis(2-Chloroethyl)ether 400 660 0.01 0.01 240 U 38 U 0.00019 U

2-Chlorophenol 310000 660 0.005 0.01 1200 U 190 U 0.001 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 14 U 11 U 0.001 U H

1,4-Dichlorobenzene 5000 660 0.075 0.01 14 U 11 U 0.001 U H

1,2-Dichlorobenzene 5300000 660 0.6 0.01 14 U 11 U 0.001 U H

2-Methylphenol (o-cresol) 310000 660 NA 0.01 1200 U 190 U 0.001 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 240 U 38 U 0.00019 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 1200 U 190 U 0.00042 J

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 240 U 38 U 0.00019 U

Hexachloroethane 35000 660 0.01 0.01 1200 U 190 U 0.001 U

Nitrobenzene 31000 660 0.01 0.01 2400 U 380 U 0.002 U

Isophorone 510000 660 0.1 0.01 1200 U 190 U 0.00054 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 1200 U 190 U 0.00033 J

2,4-Dichlorophenol 180000 660 0.02 0.01 240 U 38 U 0.00019 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 14 U 11 U 0.001 U H

Naphthalene 6000 660 0.3 0.01 87 J 22 J 0.00019 U

Hexachloro-1,3-butadiene 6000 660 NA 0.01 240 U 38 U 0.00019 U

2-Methylnaphthalene 230000 660 NA 0.01 240 U 15 J 0.00019 U

Hexachlorocyclopentadiene 45000 660 0.05 0.01 1200 U 190 U 0.001 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 1200 U 190 U 0.001 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 1200 U 190 U 0.001 U

2-Chloronaphthalene NA 660 NA 0.01 240 U 38 U 0.00019 U

2-Nitroaniline 39000 3300 NA 0.05 6000 U 960 U 0.005 U

Acenaphthylene 300000000 660 NA 0.01 140 J 49 0.00019 U

2,6-Dinitrotoluene 700 660 0.01 0.01 1200 U 190 U 0.001 U

Arthur Kill Upland - Comp D - Sediment Semivolatiles, con't.

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200024 #20200029 #20200029 ug/kg ug/kg mg/L mg/L COMP D Q A COMP D Q A COMP D Q

Acenaphthene 3400000 660 0.4 0.01 240 U 14 J 0.00019 U

2,4-Dinitrophenol 120000 3300 0.04 0.05 12000 U 1900 U 0.01 U

Dibenzofuran NA 660 NA 0.01 1200 U 190 U 0.001 U

2,4-Dinitrotoluene 700 660 0.01 0.01 1200 U 190 U 0.001 U

Diethylphthalate 49000000 660 5 0.01 1200 U 190 U 0.0015 B

Fluorene 2300000 660 0.3 0.01 240 U 38 U 0.00019 U

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 6000 U 960 U 0.005 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 1200 U 190 U 0.001 U

Hexachlorobenzene 300 660 0.01 0.01 240 U 38 U 0.00019 U

Pentachlorophenol 3000 3300 0.001 0.05 6000 U 960 U 0.005 U

Phenanthrene 300000000 6600 NA 0.01 240 82 0.00032

Anthracene 17000000 6600 2 0.01 150 J 47 0.00019 U

Carbazole 24000 330 NA 0.01 240 U 13 J 0.00019 U

Di-n-butylphthalate 6100000 330 0.9 0.01 1200 U 190 U 0.0011

Fluoranthene 2300000 660 0.3 0.01 640 210 0.00019 U

Pyrene 1700000 660 0.2 0.01 730 210 0.00019 U

Butylbenzylphthalate 1200000 660 0.1 0.01 1200 U 190 U 0.001 U

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 1200 U 190 U 0.001 U

Benzo(a)anthracene 600 660 NA 0.01 400 140 0.00019 U

Chrysene 62000 660 NA 0.01 470 170 0.00019 U bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 1600 J 460 J 0.01 U

DI-n-octylphthalate 2400000 660 0.1 0.01 1200 U 190 U 0.001 U

Benzo(b)fluoranthene 600 660 NA 0.01 640 200 0.00019 U

Benzo(k)fluoranthene 6000 660 NA 0.01 210 J 57 0.00019 U

Benzo(a)pyrene 200 660 NA 0.01 420 150 0.00019 U

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 400 110 0.00019 U

Dibenzo(a,h)anthracene 200 660 NA 0.01 240 U 35 J 0.00019 U

Benzo(ghi)perylene 30000000 660 NA 0.01 510 150 0.00019 U

Acetophenone 2000 2400 U 380 U 0.001 U

Atrazine 210000 2400 U 380 U 0.001 U

Benzaldehyde 6100000 2400 U 380 U 0.003

Benzidine 700 24000 U 3800 U 0.02 U

1,1'-Biphenyl 3100000 1200 U 190 U 0.001 U

Caprolactam 31000000 6000 U 960 U 0.005 U

1,2-Diphenylhydrazine 700 1200 U 190 U 0.001 U

N-Nitrosodimethylamine 700 1200 U 190 U 0.001 U

Arthur Kill Upland - Comp D - Pesticides/Aroclors

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200024 #20200029 #20200029 ug/kg ug/kg mg/L mg/L COMP D Q A COMP D Q A COMP D Q alpha-BHC 100 1.9 0.00002 0.00005 0.59 U 0.47 U 0.0000013 U beta-BHC 400 3.3 0.0002 0.00005 0.59 U 0.47 U 0.0000013 U delta-BHC NA 1.7 NA 0.00005 0.59 U 0.47 U 0.0000013 U gamma-BHC (Lindane) 400 2 0.0002 0.00005 0.59 U 0.47 U 0.0000013 U

Heptachlor 100 2.1 0.0004 0.00005 0.59 U 0.47 U 0.0000013 U

Aldrin 40 2 0.00004 0.00005 0.59 U 0.47 U 0.0000013 U

Heptachlor epoxide 70 2.1 0.0002 0.00005 1.7 p 1.9 p 0.0000013 U

Endosulfan I NA 2.1 0.0004 0.00005 0.59 U 0.47 U 0.0000013 U

Dieldrin 40 3.3 0.00003 0.0001 0.59 U 0.47 U 0.0000013 U

4,4'-DDE 2000 4.2 0.0001 0.0001 50 36 0.0000015

Endrin 23000 3.6 0.002 0.0001 7.0 4.9 0.0000013 U

Endosulfan II NA 3.3 0.0004 0.0001 0.89 p 1.2 0.00000059 J

4,4'-DDD 3000 4.2 0.0001 0.0001 57 41 0.0000013 U

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.59 U 0.47 U 0.0000013 U

4,4'-DDT 2000 3.6 0.0001 0.0001 160 130 0.0000013 U

Methoxychlor 390000 17 0.04 0.001 0.59 U 0.47 U 0.0000013 U alpha-Chlordane 200 1.7 NA 0.00005 4.2 2.7 0.0000013 U gamma-Chlordane 200 1.7 0.0005 0.00005 0.59 U 0.47 U 0.0000013 U

Toxaphene 600 170 0.003 0.005 24 U 19 U 0.0001 U

Mirex 0.59 U 0.47 U 0.0000013 U

Aroclor‐1016 12 U 9.4 U 0.00001 U

Aroclor‐1221 12 U 9.4 U 0.00001 U

Aroclor‐1232 12 U 9.4 U 0.00001 U

Aroclor‐1242 12 U 9.4 U 0.00001 U

Aroclor‐1248 120 200 0.00001 U

Aroclor‐1254 12 U 9.4 U 0.00001 U

Aroclor‐1260 110 110 0.00001 U

Total Aroclor(SUM)

Arthur Kill Upland - Comp D - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

ug/L)

ASI ID # Soil Leachate #20200024 #20200029 #20200029

COMP D Q A COMP D Q A COMP D Q

2,4,5-TP (Silvex) NA NA NA NA 57 U 45 U 1.0 U

Arthur Kill Upland ‐ Comp D ‐ Metals

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200024 #20200029 #20200029 mg/kg mg/kg mg/L mg/L COMP D Q A COMP D Q A COMP D Q

Aluminum 78000 40 0.2 0.2 12000 15000 1.6

Antimony 31 12 0.02 0.06 1.1 1.1 0.00062 J

Arsenic 19 2 0.008 0.01 17 16 0.0026

Barium 16000 40 2 0.2 140 140 0.031

Beryllium 16 1 0.02 0.005 0.92 0.87 0.00032 J

Cadmium 78 1 0.004 0.005 1.0 0.86 0.00022 J

Chromium NA 2 0.1 0.01 60 56 0.002 U

Hexavalent Chromium 120000 1.1 U 0.91 U 0.01 U

Trivalent Chromium 20 60 56 0.01 U

Cobalt 1,600 10 NA 0.05 7.9 7.5 0.0022

Copper 590 5 1 0.025 140 110 0.15

Lead 400 0.6 0.01 0.003 130 100 0.00031 J B

Manganese 5900 3 0.05 0.015 470 480 0.0015 J

Mercury 23 0.1 0.002 0.0002 2.5 B 3.1 B 0.0002 U

Nickel 1,600 8 0.1 0.04 26 23 0.032

Selenium 390 1 0.05 0.015 3.7 3.1 0.0034 J

Silver 390 2 NA 0.01 2.1 1.7 0.001 U

Vanadium 78 10 NA 0.05 30 29 0.01

Zinc 23,000 4 5 0.02 200 240 0.005 U

Cyanide, total 1,600 0.5 0.2 0.01 0.81 1.5 0.01 U

%Solids NA NA NA NA 35 44.2

Arthur Kill Upland ‐ Comp D ‐ Dioxin/Furan

Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP (Units:

pg/L)

ASI ID # Soil Leachate #20200024 #20200029 #20200029 ng/kg pg/L COMP D Q A COMP D Q A COMP D Q

2,3,7,8‐TCDD NA NA NA NA 15 q 11 9.7 U

1,2,3,7,8‐PeCDD NA NA NA NA 5.9 J B q 4.8 J B 49 U

1,2,3,4,7,8‐HxCDD NA NA NA NA 7.0 B 5.0 J B 49 U

1,2,3,6,7,8‐HxCDD NA NA NA NA 27 B 21 B 49 U

1,2,3,7,8,9‐HxCDD NA NA NA NA 23 B 18 B 49 U

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 430 B 370 B 0.77 J q B

OCDD NA NA NA NA 7000 E B 5700 E B 12 J B

2,3,7,8‐TCDF NA NA NA NA 27 20 9.7 U

1,2,3,7,8‐PeCDF NA NA NA NA 13 10 49 U

2,3,4,7,8‐PeCDF NA NA NA NA 18 13 49 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 53 B 44 B 49 U

1,2,3,6,7,8‐HxCDF NA NA NA NA 24 B 18 I B 49 U

2,3,4,6,7,8‐HxCDF NA NA NA NA 13 B 10 B 49 U

1,2,3,7,8,9‐HxCDF NA NA NA NA 6.9 U 5.5 U 49 U

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 220 B 200 B 49 U

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 18 B 13 B 49 U

OCDF NA NA NA NA 360 B 310 B 0.94 J q B

Arthur Kill Upland ‐ Comp D ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt) SPLP (Units: pg/L)

ASI ID # #20200024 #20200029 #20200029

COMP D Q A COMP D Q A COMP D Q

2,3,7,8‐TCDD 1 15.00 q 11.00 9.70 U

1,2,3,7,8‐PeCDD 1 5.90 J B q 4.80 J B 49.00 U

1,2,3,4,7,8‐HxCDD 0.1 0.70 B 0.50 J B 4.90 U

1,2,3,6,7,8‐HxCDD 0.1 2.70 B 2.10 B 4.90 U

1,2,3,7,8,9‐HxCDD 0.1 2.30 B 1.80 B 4.90 U

1,2,3,4,6,7,8‐HpCDD 0.01 4.30 B 3.70 B 0.01 J q B

1,2,3,4,6,7,8,9‐OCDD 0.0003 2.10 E B 1.71 E B 0.00 J B

2,3,7,8‐TCDF 0.1 2.70 2.00 0.97 U

1,2,3,7,8‐PeCDF 0.03 0.39 0.30 1.47 U

2,3,4,7,8‐PeCDF 0.3 5.40 3.90 14.70 U

1,2,3,4,7,8‐HxCDF 0.1 5.30 B 4.40 B 4.90 U

1,2,3,6,7,8‐HxCDF 0.1 2.40 B 1.80 I B 4.90 U

2,3,4,6,7,8‐HxCDF 0.1 1.30 B 1.00 B 4.90 U

1,2,3,7,8,9‐HxCDF 0.1 0.69 U 0.55 U 4.90 U

1,2,3,4,6,7,8‐HpCDF 0.01 2.20 B 2.00 B 0.49 U

1,2,3,4,7,8,9‐HpCDF 0.01 0.18 B 0.13 B 0.49 U

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.11 B 0.09 B 0.00 J q B

TOTAL TEF as 2,3,7,8‐TCDD 53.67 41.78 111.13

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

ug/L)

ASI ID # Soil Leachate #20200015 #20200030 #20200030 ug/kg ug/L COMP E Q A COMP E Q A COMP E Q

Chloromethane (Methyl Chloride) 4000 30 14 U 11 U 1.0 U H

Bromomethane 25000 10 14 U 11 U * 1.0 U H

Vinyl chloride 700 5 14 U 11 U 1.0 U H

Chloroethane 220000 NA 14 U * 11 U * 1.0 U H

Methylene chloride (Dichloromethane) 34000 3 14 U 11 U 3.6 H B

Acetone 70000000 700 42 J 62 28 J H

Carbon disulfide 7800000 NA 14 U 11 U 1.0 U H

1,1-Dichloroethene 11000 2 14 U 11 U 1.0 U H

1,1-Dichloroethane 8000 50 14 U 11 U 1.0 U H

1,2-Dichloroethene (total) 10 28 U 23 U 2.0 U H

Chloroform 600 6 14 U 11 U 1.0 U H

1,2-Dichloroethane 900 NA 14 U 11 U 1.0 U H

2-Butanone (MEK) 3100000 300 22 17 5.7 H

1,1,1-Trichloroethane 290000 30 14 U 11 U 1.0 U H

Carbon tetrachloride 600 2 14 U 11 U 1.0 U H

Bromodichloromethane 1000 1 14 U 11 U 1.0 U H

1,2-Dichloropropane 2000 1 14 U 11 U 1.0 U H cis-1,3-Dichloropropene NA NA 14 U 11 U 1.0 U H

Trichloroethene 7000 1 14 U 11 U 1.0 U H

Dibromochloromethane 3000 10 14 U 11 U 1.0 U H

1,1,2-Trichloroethane 2000 3 14 U 11 U 1.0 U H

Benzene 2000 1 14 U 11 U 1.0 U H trans-1,3-dichloropropene NA NA 14 U 11 U 1.0 U H

Bromoform 81000 4 14 U 11 U 1.0 U H

Tetrachloroethene 2000 1 14 U 11 U 1.0 U H

1,1,2,2-Tetrachloroethane 1000 NA 14 U 11 U 1.0 U H

Toluene 6300000 1000 14 U 11 U 1.0 U H

Chlorobenzene 510000 50 14 U 11 U 1.0 U H

Ethyl benzene 7800000 700 14 U 11 U 1.0 U H

Styrene 90000 100 14 U 11 U 1.0 U H

Xylenes(Total) 12000000 1000 28 U 23 U 2.0 U H

Acrolein 500 280 U 230 U 20 U H

Acrylonitrile 900 140 U 110 U 20 U H

1,2-Dibromo-3-chloropropane 80 14 U 11 U 1.0 U H

1,2-Dibromoethane 8 14 U 11 U 1.0 U H

Dichlorodifluoromethane 490000 14 U 11 U 1.0 U H

1,2-Dichloroethene (cis) 230000 14 U 11 U 1.0 U H

1,2-Dichloroethene (trans) 300000 14 U 11 U 1.0 U H

Methyl acetate 78000000 70 U 57 U 5.0 U H

Methyl tert-butyl ether (MTBE) 110000 14 U 11 U 1.0 U H

Tertiary butyl alcohol (TBA) 1400000 140 U 110 U 40 U H

Trichlorofluoromethane 23000000 14 U 11 U 1.0 U H *

Combined 1,3-dichloropropenes (SUM) cis + trans 2000 0.2

1,4-dioxane 2800 U 2300 U 200 U H n-propylbenzene 14 U 11 U 1.0 U H sec-butylbenzene 14 U 11 U 1.0 U H tert-butylbenzene 14 U 11 U 1.0 U H

1,2,4-trimethylbenzene 14 U 11 U 1.0 U H

1,3,5-trimethylbenzene 14 U 11 U 1.0 U H n‐Butylbenzene 14 U 11 U 1.0 U H

Arthur Kill Upland - Comp E - Sediment Semivolatiles

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200015 #20200030 #20200030 ug/kg ug/kg mg/L mg/L COMP E Q A COMP E Q A COMP E Q

Phenol 18000000 660 4 0.01 1200 U 190 U 0.00079 J bis(2-Chloroethyl)ether 400 660 0.01 0.01 230 U 38 U 0.00018 U

2-Chlorophenol 310000 660 0.005 0.01 1200 U 190 U 0.00096 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 14 U 11 U 0.001 U H

1,4-Dichlorobenzene 5000 660 0.075 0.01 14 U 11 U 0.001 U H

1,2-Dichlorobenzene 5300000 660 0.6 0.01 14 U 11 U 0.001 U H

2-Methylphenol (o-cresol) 310000 660 NA 0.01 1200 U 190 U 0.00096 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 230 U 38 U 0.00018 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 1200 U 190 U 0.0011

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 230 U 38 U 0.00018 U

Hexachloroethane 35000 660 0.01 0.01 1200 U 190 U 0.00096 U

Nitrobenzene 31000 660 0.01 0.01 2300 U 380 U 0.0019 U

Isophorone 510000 660 0.1 0.01 1200 U 190 U 0.00064 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 1200 U 190 U 0.0028

2,4-Dichlorophenol 180000 660 0.02 0.01 230 U 38 U 0.00018 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 14 U 11 U 0.001 U H

Naphthalene 6000 660 0.3 0.01 94 J 38 U 0.000097 J

Hexachloro-1,3-butadiene 6000 660 NA 0.01 230 U 38 U 0.00018 U

2-Methylnaphthalene 230000 660 NA 0.01 86 J 11 J 0.00018 U

Hexachlorocyclopentadiene 45000 660 0.05 0.01 1200 U 190 U 0.00096 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 1200 U 190 U 0.00096 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 1200 U 190 U 0.00096 U

2-Chloronaphthalene NA 660 NA 0.01 230 U 38 U 0.00018 U

2-Nitroaniline 39000 3300 NA 0.05 5900 U 960 U 0.0048 U

Acenaphthylene 300000000 660 NA 0.01 180 J 31 J 0.00018 U

2,6-Dinitrotoluene 700 660 0.01 0.01 1200 U 190 U 0.00096 U

Arthur Kill Upland - Comp E - Sediment Semivolatiles, con't.

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200015 #20200030 #20200030 ug/kg ug/kg mg/L mg/L COMP E Q A COMP E Q A COMP E Q

Acenaphthene 3400000 660 0.4 0.01 230 U 38 U 0.00018 U

2,4-Dinitrophenol 120000 3300 0.04 0.05 12000 U 1900 U 0.0096 U

Dibenzofuran NA 660 NA 0.01 1200 U 190 U 0.00096 U

2,4-Dinitrotoluene 700 660 0.01 0.01 1200 U 190 U 0.00096 U

Diethylphthalate 49000000 660 5 0.01 1200 U 190 U 0.0036 B

Fluorene 2300000 660 0.3 0.01 110 J 38 U 0.00018 U

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 5900 U 960 U 0.0048 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 1200 U 190 U 0.00096 U

Hexachlorobenzene 300 660 0.01 0.01 230 U 38 U 0.00018 U

Pentachlorophenol 3000 3300 0.001 0.05 5900…