d - AK21 North Upland Data Tables - Battelle Final.pdf

Arthur Kill North Channel Upland - 2020

Arthur Kill North Channel Upland - COMP F - Sediment Volatiles

Volatiles Action Level Action Level Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200450 #20200483 #20200483 ug/kg ug/L COMP F Q A COMP F Q A COMP F Q

Chloromethane (Methyl Chloride) 4000 30 11 U 9.5 U 1.0 U

Bromomethane 25000 10 11 U 9.5 U 1.0 U

Vinyl chloride 700 5 11 U 9.5 U 1.0 U

Chloroethane 220000 NA 11 U 9.5 U 1.0 U

Methylene chloride (Dichloromethane) 34000 3 11 U 9.5 U 1.0 U

Acetone 70000000 700 43 U 17 J 20 F1

Carbon disulfide 7800000 NA 7.9 J 6.8 J 1.0 U

1,1-Dichloroethene 11000 2 11 U 9.5 U 1.0 U

1,1-Dichloroethane 8000 50 11 U 9.5 U 1.0 U

1,2-Dichloroethene (total) 10 22 U 19 U 2.0 U

Chloroform 600 6 11 U 9.5 U 1.0 U

1,2-Dichloroethane 900 NA 11 U 9.5 U 1.0 U

2-Butanone (MEK) 3100000 300 10 J 37 5.0 U

1,1,1-Trichloroethane 290000 30 11 U 9.5 U 1.0 U

Carbon tetrachloride 600 2 11 U 9.5 U 1.0 U

Bromodichloromethane 1000 1 11 U 9.5 U 1.0 U

1,2-Dichloropropane 2000 1 11 U 9.5 U 1.0 U cis-1,3-Dichloropropene NA NA 11 U 9.5 U 1.0 U

Trichloroethene 7000 1 11 U 9.5 U 1.0 U

Dibromochloromethane 3000 10 11 U 9.5 U 1.0 U

1,1,2-Trichloroethane 2000 3 11 U 9.5 U 1.0 U

Benzene 2000 1 11 U 9.5 U 1.0 U trans-1,3-dichloropropene NA NA 11 U 9.5 U 1.0 U

Bromoform 81000 4 11 U 9.5 U 1.0 U

Tetrachloroethene 2000 1 11 U 9.5 U 1.0 U

1,1,2,2-Tetrachloroethane 1000 NA 11 U 9.5 U 1.0 U

Toluene 6300000 1000 11 U 9.5 U 1.0 U

Chlorobenzene 510000 50 11 U * 9.5 U * 1.0 U

Ethyl benzene 7800000 700 11 U 9.5 U 1.0 U

Styrene 90000 100 11 U * 9.5 U * 1.0 U

Xylenes(Total) 12000000 1000 22 U 19 U 2.0 U

Acrolein 500 220 U 190 U 20 U F1 *

Acrylonitrile 900 110 U 95 U 20 U

1,2-Dibromo-3-chloropropane 80 11 U 9.5 U 1.0 U

1,2-Dibromoethane 8 11 U 9.5 U 1.0 U

Dichlorodifluoromethane 490000 11 U 9.5 U 1.0 U

1,2-Dichloroethene (cis) 230000 11 U 9.5 U 1.0 U

1,2-Dichloroethene (trans) 300000 11 U 9.5 U 1.0 U

Methyl acetate 78000000 54 U 48 U 5.0 U

Methyl tert-butyl ether (MTBE) 110000 11 U 9.5 U 1.0 U

Tertiary butyl alcohol (TBA) 1400000 110 U 95 U 40 U *3

Trichlorofluoromethane 23000000 11 U 9.5 U 1.0 U

1,4-dioxane 2200 U 1900 U 200 U n-propylbenzene 11 U 9.5 U 1.0 U *3 sec-butylbenzene 11 U 9.5 U 1.0 U tert-butylbenzene 11 U 9.5 U 1.0 U

1,2,4-trimethylbenzene 11 U 9.5 U 1.0 U *3

1,3,5-trimethylbenzene 11 U 9.5 U 1.0 U *3 n‐Butylbenzene 11 U 9.5 U 1.0 U *3

Arthur Kill North Channel Upland - COMP F - Sediment Semivolatiles

Semivolatiles Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200450 #20200483 #20200483 ug/kg ug/kg mg/L mg/L COMP F Q A COMP F Q A COMP F Q

Phenol 18000000 660 4 0.01 350 U 310 U 0.00097 U bis(2-Chloroethyl)ether 400 660 0.01 0.01 71 U 63 U 0.00018 U

2-Chlorophenol 310000 660 0.005 0.01 350 U 310 U 0.00097 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 11 U * 9.5 U * 0.001 U

1,4-Dichlorobenzene 5000 660 0.075 0.01 11 U * 9.5 U * 0.001 U

1,2-Dichlorobenzene 5300000 660 0.6 0.01 11 U * 9.5 U * 0.001 U *3

2-Methylphenol (o-cresol) 310000 660 NA 0.01 350 U 310 U 0.00097 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 71 U 63 U 0.00018 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 350 U 140 J 0.0017

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 71 U 63 U 0.00018 U

Hexachloroethane 35000 660 0.01 0.01 350 U 310 U 0.00097 U

Nitrobenzene 31000 660 0.01 0.01 710 U 630 U 0.0019 U Isophorone 510000 660 0.1 0.01 350 U 310 U 0.00027 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 350 U 200 J 0.0032

2,4-Dichlorophenol 180000 660 0.02 0.01 71 U 63 U 0.00018 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 11 U 9.5 U 0.001 U *3

Naphthalene 6000 660 0.3 0.01 80 67 0.0003

Hexachloro-1,3-butadiene 6000 660 NA 0.01 71 U 63 U 0.00018 U

2-Methylnaphthalene 230000 660 NA 0.01 62 J 48 J 0.0001 J

Hexachlorocyclopentadiene 45000 660 0.05 0.01 350 U 310 U 0.00097 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 350 U 310 U 0.00097 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 350 U 310 U 0.00097 U

2-Chloronaphthalene NA 660 NA 0.01 71 U 63 U 0.00018 U

2-Nitroaniline 39000 3300 NA 0.05 1800 U 1600 U 0.0049 U

Acenaphthylene 300000000 660 NA 0.01 130 92 0.00018 U

2,6-Dinitrotoluene 700 660 0.01 0.01 350 U 310 U 0.00097 U

Arthur Kill North Channel Upland - COMP F - Sediment Semivolatiles, con't.

Semivolatiles, continued Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200450 #20200483 #20200483 ug/kg ug/kg mg/L mg/L COMP F Q A COMP F Q A COMP F Q

Acenaphthene 3400000 660 0.4 0.01 44 J 47 J 0.000087 J

2,4-Dinitrophenol 120000 3300 0.04 0.05 3500 U 3100 U 0.0097 U

Dibenzofuran NA 660 NA 0.01 35 J 26 J 0.00097 U

2,4-Dinitrotoluene 700 660 0.01 0.01 350 U 310 U 0.00097 U

Diethylphthalate 49000000 660 5 0.01 350 U 310 U 0.00097 U

Fluorene 2300000 660 0.3 0.01 69 J 47 J 0.0001 J

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 1800 U 1600 U 0.0049 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 350 U 310 U 0.00097 U

Hexachlorobenzene 300 660 0.01 0.01 71 U 63 U 0.00018 U

Pentachlorophenol 3000 3300 0.001 0.05 1800 U 1600 U 0.0049 U

Phenanthrene 300000000 6600 NA 0.01 210 160 0.00011 J

Anthracene 17000000 6600 2 0.01 200 160 0.00009 J

Carbazole 24000 330 NA 0.01 41 J 63 U 0.000055 J

Di-n-butylphthalate 6100000 330 0.9 0.01 350 U 310 U 0.00097 U

Fluoranthene 2300000 660 0.3 0.01 620 410 0.000099 J

Pyrene 1700000 660 0.2 0.01 960 640 0.00014 J

Butylbenzylphthalate 1200000 660 0.1 0.01 350 U 310 U 0.00097 U

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 350 U 310 U 0.00097 U

Benzo(a)anthracene 600 660 NA 0.01 350 240 0.00018 U

Chrysene 62000 660 NA 0.01 350 260 0.00018 U bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 3400 J 2100 J 0.0097 U

DI-n-octylphthalate 2400000 660 0.1 0.01 350 U 310 U 0.00097 U

Benzo(b)fluoranthene 600 660 NA 0.01 530 330 0.00018 U

Benzo(k)fluoranthene 6000 660 NA 0.01 170 120 0.00018 U

Benzo(a)pyrene 200 660 NA 0.01 420 300 0.00018 U

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 260 180 0.00018 U

Dibenzo(a,h)anthracene 200 660 NA 0.01 130 120 0.00018 U

Benzo(ghi)perylene 30000000 660 NA 0.01 370 270 0.00018 U

Acetophenone 2000 710 U 630 U 0.00018 J

Atrazine 210000 710 U 630 U 0.00097 U

Benzaldehyde 6100000 85 J 630 U 0.00056 J

Benzidine 700 7100 U 6300 U 0.019 U

1,1'-Biphenyl 3100000 350 U 310 U 0.00097 U

Caprolactam 31000000 1800 U 1600 U 0.00047 J

1,2-Diphenylhydrazine 700 350 U 310 U 0.00097 U

N-Nitrosodimethylamine 700 350 U 310 U 0.00097 U

Arthur Kill North Channel Upland - COMP F - Pesticides/Aroclors

Pesticides/Aroclors Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200450 #20200483 #20200483 ug/kg ug/kg mg/L mg/L COMP F Q A COMP F Q A COMP F Q alpha-BHC 100 1.9 0.00002 0.00005 0.45 U 0.39 U 0.0000022 p beta-BHC 400 3.3 0.0002 0.00005 0.45 U F1 0.39 U 0.0000012 U delta-BHC NA 1.7 NA 0.00005 0.45 U F1 0.39 U 0.0000012 U gamma-BHC (Lindane) 400 2 0.0002 0.00005 0.45 U 0.39 U 0.0000012 U

Heptachlor 100 2.1 0.0004 0.00005 0.45 U 0.39 U 0.0000012 U

Aldrin 40 2 0.00004 0.00005 0.45 U F1 0.39 U 0.0000012 U

Heptachlor epoxide 70 2.1 0.0002 0.00005 5.9 p 4.9 p 0.0000012 U

Endosulfan I NA 2.1 0.0004 0.00005 0.45 U 0.39 U 0.0000012 U

Dieldrin 40 3.3 0.00003 0.0001 0.45 U F1 0.39 U 0.0000012 U

4,4'-DDE 2000 4.2 0.0001 0.0001 42 p 31 p 0.0000012 U

Endrin 23000 3.6 0.002 0.0001 13 9.7 0.0000012 U

Endosulfan II NA 3.3 0.0004 0.0001 2.5 2.2 0.0000012 U

4,4'-DDD 3000 4.2 0.0001 0.0001 33 27 0.0000012 U

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.45 U F1 0.39 U 0.0000012 U

4,4'-DDT 2000 3.6 0.0001 0.0001 9.9 F2 F1 p9.4 p 0.0000018

Methoxychlor 390000 17 0.04 0.001 0.45 U F2 F10.39 U 0.0000012 U alpha-Chlordane 200 1.7 NA 0.00005 4.2 p 4.4 0.0000012 U gamma-Chlordane 200 1.7 0.0005 0.00005 0.45 U F1 0.39 U 0.00009

Toxaphene 600 170 0.003 0.005 18 U 16 U 0.000095 U

Mirex 0.45 U 0.39 U 0.0000012 U

Aroclor‐1016 4.4 U 7.9 U 0.0000095 U

Aroclor‐1221 4.4 U 7.9 U 0.0000095 U

Aroclor‐1232 4.4 U 7.9 U 0.0000095 U

Aroclor‐1242 4.4 U 7.9 U 0.0000095 U

Aroclor‐1248 280 280 0.0000095 U

Aroclor‐1254 4.4 U 7.9 U 0.0000095 U

Aroclor‐1260 83 70 0.0000095 U

Total Aroclor(SUM)

Arthur Kill North Channel Upland - COMP F - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200450 #20200483 #20200483

COMP F Q A COMP F Q A COMP F Q

2,4,5-TP (Silvex) NA NA NA NA 43 U 38 U 0.97 U

Arthur Kill North Channel Upland ‐ COMP F ‐ Metals

Metals Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200450 #20200483 #20200483 mg/kg mg/kg mg/L mg/L COMP F Q A COMP F Q A COMP F Q

Aluminum 78000 40 0.2 0.2 3200 14000 1.4 B

Antimony 31 12 0.02 0.06 2.1 F1 1.9 0.0018 J

Arsenic 19 2 0.008 0.01 31 28 0.0043

Barium 16000 40 2 0.2 130 140 0.12 B

Beryllium 16 1 0.02 0.005 0.87 0.91 0.001 U

Cadmium 78 1 0.004 0.005 2.7 2.3 0.0003 J

Chromium NA 2 0.1 0.01 100 B 140 B 0.002 U

Hexavalent Chromium 120000 0.85 U 0.76 U 0.010 U F1

Trivalent Chromium 20 100 140 0.01 U

Cobalt 1,600 10 NA 0.05 9.4 9.2 0.00074

Copper 590 5 1 0.025 240 210 0.00076 J

Lead 400 0.6 0.01 0.003 150 130 0.00067 J

Manganese 5900 3 0.05 0.015 240 280 0.005 U

Mercury 23 0.1 0.002 0.0002 3.6 3.3 0.02 U

Nickel 1,600 8 0.1 0.04 34 41 0.034

Selenium 390 1 0.05 0.015 2.3 2.0 0.005 U

Silver 390 2 NA 0.01 2.6 2.2 0.001 U

Vanadium 78 10 NA 0.05 40 54 0.017

Zinc 23,000 4 5 0.02 270 250 0.01

Cyanide, total 1,600 0.5 0.2 0.01 2.4 2.0 0.0056 J

%Solids NA NA NA NA 46.4 52.4

Arthur Kill North Channel Upland ‐ COMP F ‐ Dioxin/Furan

Dioxin/Furan Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP

(Units: pg/L)

ASI ID # Soil Leachate #20200450 #20200483 #20200483 ng/kg pg/L COMP F Q A COMP F Q A COMP F Q

2,3,7,8‐TCDD NA NA NA NA 24 20 9.7 U

1,2,3,7,8‐PeCDD NA NA NA NA 5.2 J q B 4.7 B 48 U

1,2,3,4,7,8‐HxCDD NA NA NA NA 7.0 B 5.8 B 1.4 J B q

1,2,3,6,7,8‐HxCDD NA NA NA NA 34 B 31 B 48 U

1,2,3,7,8,9‐HxCDD NA NA NA NA 28 B 22 B 48 U

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 400 B 560 B 1.6 J B q

OCDD NA NA NA NA 5900 E B 7000 E B 7.7 J B

2,3,7,8‐TCDF NA NA NA NA 31 B 24 B 9.7 U

1,2,3,7,8‐PeCDF NA NA NA NA 36 16 48 U

2,3,4,7,8‐PeCDF NA NA NA NA 23 17 48 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 120 I 57 I 1.1 J B q

1,2,3,6,7,8‐HxCDF NA NA NA NA 64 20 0.74 J B q

2,3,4,6,7,8‐HxCDF NA NA NA NA 31 B 15 B 48 U

1,2,3,7,8,9‐HxCDF NA NA NA NA 13 B 2.1 J B 1.1 J B q

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 560 B 210 B 1.2 J B q

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 110 B 18 B 1.3 J B

OCDF NA NA NA NA 1100 B 370 B 3.7 J B q

Arthur Kill North Channel Upland ‐ COMP F ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt)

SPLP

(Units: pg/L)

ASI ID # #20200450 #20200483 #20200483

COMP F Q A COMP F Q A COMP F Q

2,3,7,8‐TCDD 1 24.00 20.00 9.70 U

1,2,3,7,8‐PeCDD 1 5.20 J q B 4.70 B 48.00 U

1,2,3,4,7,8‐HxCDD 0.1 0.70 B 0.58 B 0.14 J B q

1,2,3,6,7,8‐HxCDD 0.1 3.40 B 3.10 B 4.80 U

1,2,3,7,8,9‐HxCDD 0.1 2.80 B 2.20 B 4.80 U

1,2,3,4,6,7,8‐HpCDD 0.01 4.00 B 5.60 B 0.02 J B q

1,2,3,4,6,7,8,9‐OCDD 0.0003 1.77 E B 2.10 E B 0.00 J B

2,3,7,8‐TCDF 0.1 3.10 B 2.40 B 0.97 U

1,2,3,7,8‐PeCDF 0.03 1.08 0.48 1.44 U

2,3,4,7,8‐PeCDF 0.3 6.90 5.10 14.40 U

1,2,3,4,7,8‐HxCDF 0.1 12.00 I 5.70 I 0.11 J B q

1,2,3,6,7,8‐HxCDF 0.1 6.40 2.00 0.07 J B q

2,3,4,6,7,8‐HxCDF 0.1 3.10 B 1.50 B 4.80 U

1,2,3,7,8,9‐HxCDF 0.1 1.30 B 0.21 J B 0.11 J B q

1,2,3,4,6,7,8‐HpCDF 0.01 5.60 B 2.10 B 0.01 J B q

1,2,3,4,7,8,9‐HpCDF 0.01 1.10 B 0.18 B 0.01 J B

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.33 B 0.11 B 0.00 J B q

TOTAL TEF as 2,3,7,8‐TCDD 82.78 58.06 89.39

Arthur Kill North Channel Upland - COMP H - Sediment Volatiles

Volatiles Action Level Action Level Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200475 #20200484 #20200484 ug/kg ug/L COMP H Q A COMP H Q A COMP H Q

Chloromethane (Methyl Chloride) 4000 30 10 U 9.7 U 1.0 U

Bromomethane 25000 10 10 U 9.7 U 1.0 U

Vinyl chloride 700 5 10 U 9.7 U 1.0 U

Chloroethane 220000 NA 10 U 9.7 U 1.0 U

Methylene chloride (Dichloromethane) 34000 3 10 U 9.7 U 1.0 U

Acetone 70000000 700 42 U 21 J 18

Carbon disulfide 7800000 NA 6.6 J 8.9 J 0.97 J

1,1-Dichloroethene 11000 2 10 U 9.7 U 1.0 U

1,1-Dichloroethane 8000 50 10 U 9.7 U 1.0 U

1,2-Dichloroethene (total) 10 21 U 19 U 2.0 U

Chloroform 600 6 10 U 9.7 U 1.0 U

1,2-Dichloroethane 900 NA 10 U 9.7 U 1.0 U

2-Butanone (MEK) 3100000 300 8.3 J 19 3.4 J

1,1,1-Trichloroethane 290000 30 10 U 9.7 U 1.0 U

Carbon tetrachloride 600 2 10 U 9.7 U 1.0 U

Bromodichloromethane 1000 1 10 U 9.7 U 1.0 U

1,2-Dichloropropane 2000 1 10 U 9.7 U 1.0 U cis-1,3-Dichloropropene NA NA 10 U 9.7 U 1.0 U

Trichloroethene 7000 1 10 U 9.7 U 1.0 U

Dibromochloromethane 3000 10 10 U 9.7 U 1.0 U

1,1,2-Trichloroethane 2000 3 10 U 9.7 U 1.0 U

Benzene 2000 1 10 U 9.7 U 1.0 U trans-1,3-dichloropropene NA NA 10 U 9.7 U 1.0 U

Bromoform 81000 4 10 U 9.7 U 1.0 U

Tetrachloroethene 2000 1 10 U 9.7 U 1.0 U

1,1,2,2-Tetrachloroethane 1000 NA 10 U 9.7 U 1.0 U

Toluene 6300000 1000 10 U 9.7 U 1.0 U

Chlorobenzene 510000 50 10 U * 9.7 U * 1.0 U

Ethyl benzene 7800000 700 10 U 9.7 U 1.0 U

Styrene 90000 100 10 U * 9.7 U * 1.0 U

Xylenes(Total) 12000000 1000 21 U 19 U 2.0 U

Acrolein 500 210 U 190 U 20 U *

Acrylonitrile 900 100 U 97 U 20 U

1,2-Dibromo-3-chloropropane 80 10 U 9.7 U 1.0 U

1,2-Dibromoethane 8 10 U 9.7 U 1.0 U

Dichlorodifluoromethane 490000 10 U 9.7 U 1.0 U

1,2-Dichloroethene (cis) 230000 10 U 9.7 U 1.0 U

1,2-Dichloroethene (trans) 300000 10 U 9.7 U 1.0 U

Methyl acetate 78000000 52 U 49 U 5.0 U

Methyl tert-butyl ether (MTBE) 110000 10 U 9.7 U 1.0 U

Tertiary butyl alcohol (TBA) 1400000 100 U 97 U 40 U

Trichlorofluoromethane 23000000 10 U 9.7 U 1.0 U

1,4-dioxane 2100 U 1900 U 200 U n-propylbenzene 10 U 9.7 U 1.0 U sec-butylbenzene 10 U 9.7 U 1.0 U tert-butylbenzene 10 U 9.7 U 1.0 U

1,2,4-trimethylbenzene 10 U 9.7 U 1.0 U

1,3,5-trimethylbenzene 10 U 9.7 U 1.0 U n‐Butylbenzene 10 U 9.7 U 1.0 U

Arthur Kill North Channel Upland - COMP H - Sediment Semivolatiles

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200475 #20200484 #20200484 ug/kg ug/kg mg/L mg/L COMP H Q A COMP H Q A COMP H Q

Phenol 18000000 660 4 0.01 340 U 160 U 0.001 U bis(2-Chloroethyl)ether 400 660 0.01 0.01 70 U 32 U 0.00019 U

2-Chlorophenol 310000 660 0.005 0.01 340 U F1 160 U 0.001 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 10 U * 9.7 U * 0.001 U

1,4-Dichlorobenzene 5000 660 0.075 0.01 10 U * 9.7 U * 0.001 U

1,2-Dichlorobenzene 5300000 660 0.6 0.01 10 U * 9.7 U * 0.001 U

2-Methylphenol (o-cresol) 310000 660 NA 0.01 340 U 160 U 0.001 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 70 U 32 U 0.00019 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 340 U 160 U 0.00048 J

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 70 U 32 U 0.00019 U

Hexachloroethane 35000 660 0.01 0.01 340 U F1 160 U 0.001 U

Nitrobenzene 31000 660 0.01 0.01 690 U 320 U 0.002 U Isophorone 510000 660 0.1 0.01 340 U 160 U 0.00041 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 340 U 160 U 0.00082 J

2,4-Dichlorophenol 180000 660 0.02 0.01 70 U 32 U 0.00019 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 10 U 9.7 U 0.001 U

Naphthalene 6000 660 0.3 0.01 53 J 20 J 0.00024

Hexachloro-1,3-butadiene 6000 660 NA 0.01 70 U 32 U 0.00019 U

2-Methylnaphthalene 230000 660 NA 0.01 35 J 13 J 0.000068 J

Hexachlorocyclopentadiene 45000 660 0.05 0.01 340 U F1 160 U 0.001 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 340 U 160 U 0.001 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 340 U 160 U 0.001 U

2-Chloronaphthalene NA 660 NA 0.01 70 U 32 U 0.00019 U

2-Nitroaniline 39000 3300 NA 0.05 1800 U 810 U 0.005 U

Acenaphthylene 300000000 660 NA 0.01 77 30 J 0.00019 U

2,6-Dinitrotoluene 700 660 0.01 0.01 340 U 160 U 0.001 U

Arthur Kill North Channel Upland - COMP H - Sediment Semivolatiles, con't.

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200475 #20200484 #20200484 ug/kg ug/kg mg/L mg/L COMP H Q A COMP H Q A COMP H Q

Acenaphthene 3400000 660 0.4 0.01 25 J 11 J 0.000073 J

2,4-Dinitrophenol 120000 3300 0.04 0.05 3400 U F1 1600 U 0.01 U

Dibenzofuran NA 660 NA 0.01 24 J 160 U 0.001 U

2,4-Dinitrotoluene 700 660 0.01 0.01 340 U F1 160 U 0.001 U

Diethylphthalate 49000000 660 5 0.01 340 U 160 U 0.001 U

Fluorene 2300000 660 0.3 0.01 40 J 12 J 0.00019 U

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 1800 U F1 810 U 0.005 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 340 U 160 U 0.001 U

Hexachlorobenzene 300 660 0.01 0.01 70 U 32 U 0.00019 U

Pentachlorophenol 3000 3300 0.001 0.05 1800 U F1 810 U 0.005 U

Phenanthrene 300000000 6600 NA 0.01 150 65 0.000099 J

Anthracene 17000000 6600 2 0.01 100 40 0.00019 U

Carbazole 24000 330 NA 0.01 26 J 8.8 J 0.00019 U

Di-n-butylphthalate 6100000 330 0.9 0.01 340 U 160 U 0.001 U

Fluoranthene 2300000 660 0.3 0.01 440 F1 190 0.000085 J

Pyrene 1700000 660 0.2 0.01 570 200 0.0001 J

Butylbenzylphthalate 1200000 660 0.1 0.01 340 U 160 U 0.001 U

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 340 U 160 U 0.001 U

Benzo(a)anthracene 600 660 NA 0.01 220 100 0.00019 U

Chrysene 62000 660 NA 0.01 240 110 0.00019 U bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 3500 F1 980 J 0.01 U

DI-n-octylphthalate 2400000 660 0.1 0.01 340 U 160 U 0.001 U

Benzo(b)fluoranthene 600 660 NA 0.01 410 F1 130 0.00019 U

Benzo(k)fluoranthene 6000 660 NA 0.01 100 50 0.00019 U

Benzo(a)pyrene 200 660 NA 0.01 280 110 0.00019 U

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 190 73 0.00019 U

Dibenzo(a,h)anthracene 200 660 NA 0.01 120 49 0.00019 U

Benzo(ghi)perylene 30000000 660 NA 0.01 260 94 0.00019 U

Acetophenone 2000 22 J 320 U 0.00023 J

Atrazine 210000 700 U 320 U 0.001 U

Benzaldehyde 6100000 51 J F1 320 U 0.00086 J

Benzidine 700 7000 U 3200 U 0.02 U

1,1'-Biphenyl 3100000 23 J 7.4 J 0.001 U

Caprolactam 31000000 1800 U 810 U 0.005 U

1,2-Diphenylhydrazine 700 340 U 160 U 0.001 U

N-Nitrosodimethylamine 700 340 U 160 U 0.001 U

Arthur Kill North Channel Upland - COMP H - Pesticides/Aroclors

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200475 #20200484 #20200484 ug/kg ug/kg mg/L mg/L COMP H Q A COMP H Q A COMP H Q alpha-BHC 100 1.9 0.00002 0.00005 0.43 U 0.40 U 0.0000013 U beta-BHC 400 3.3 0.0002 0.00005 0.43 U 0.40 U 0.0000013 U delta-BHC NA 1.7 NA 0.00005 0.43 U 0.40 U 0.0000013 U gamma-BHC (Lindane) 400 2 0.0002 0.00005 0.43 U 0.40 U 0.0000013 U

Heptachlor 100 2.1 0.0004 0.00005 0.43 U 0.40 U 0.0000013 U

Aldrin 40 2 0.00004 0.00005 0.43 U 0.40 U 0.0000013 U

Heptachlor epoxide 70 2.1 0.0002 0.00005 2.7 p 1.6 p 0.0000013 U

Endosulfan I NA 2.1 0.0004 0.00005 0.43 U 0.40 U 0.0000013 U

Dieldrin 40 3.3 0.00003 0.0001 0.43 U 0.40 U 0.0000013 U

4,4'-DDE 2000 4.2 0.0001 0.0001 28 p 19 p 0.0000029

Endrin 23000 3.6 0.002 0.0001 6.9 4.5 0.0000013 U

Endosulfan II NA 3.3 0.0004 0.0001 1.9 1.3 0.0000013 U

4,4'-DDD 3000 4.2 0.0001 0.0001 32 20 0.0000013 U

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.43 U 0.40 U 0.0000013 U

4,4'-DDT 2000 3.6 0.0001 0.0001 33 38 0.0000013 U

Methoxychlor 390000 17 0.04 0.001 0.43 U 0.40 U 0.0000013 U alpha-Chlordane 200 1.7 NA 0.00005 2.1 p 1.1 p 0.0000013 U gamma-Chlordane 200 1.7 0.0005 0.00005 0.43 U 0.40 U 0.00015

Toxaphene 600 170 0.003 0.005 17 U 16 U 0.000096 U

Mirex 0.43 U 0.40 U 0.0000013 U

Aroclor‐1016 8.5 U 0.81 U 0.0000096 U

Aroclor‐1221 8.5 U 0.81 U 0.0000096 U

Aroclor‐1232 8.5 U 0.81 U 0.0000096 U

Aroclor‐1242 8.5 U 0.81 U 0.0000096 U

Aroclor‐1248 250 63 0.0000096 U

Aroclor‐1254 8.5 U 28 0.0000096 U

Aroclor‐1260 110 38 0.0000096 U

Total Aroclor(SUM)

Arthur Kill North Channel Upland - COMP H - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200475 #20200484 #20200484

COMP H Q A COMP H Q A COMP H Q

2,4,5-TP (Silvex) NA NA NA NA 42 U 39 U 0.96 U

Arthur Kill North Channel Upland - COMP H - Metals

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200475 #20200484 #20200484 mg/kg mg/kg mg/L mg/L COMP H Q A COMP H Q A COMP H Q

Aluminum 78000 40 0.2 0.2 14000 3800 1.1 B

Antimony 31 12 0.02 0.06 1.3 1.1 0.00051 J

Arsenic 19 2 0.008 0.01 20 17 0.0014

Barium 16000 40 2 0.2 160 140 0.39 B

Beryllium 16 1 0.02 0.005 1.3 1.2 0.001 U

Cadmium 78 1 0.004 0.005 1.9 1.8 0.001 U

Chromium NA 2 0.1 0.01 94 B 100 B 0.002 U

Hexavalent Chromium 120000 0.82 U 0.78 U 0.010 U

Trivalent Chromium 20 94 100 0.01 U

Cobalt 1,600 10 NA 0.05 14 12 0.00083

Copper 590 5 1 0.025 200 170 0.0018 J

Lead 400 0.6 0.01 0.003 140 130 0.0011

Manganese 5900 3 0.05 0.015 320 300 0.005 U

Mercury 23 0.1 0.002 0.0002 2.7 2.4 0.00061

Nickel 1,600 8 0.1 0.04 40 37 0.04

Selenium 390 1 0.05 0.015 1.6 1.1 0.005 U

Silver 390 2 NA 0.01 2.5 2.2 0.001 U

Vanadium 78 10 NA 0.05 44 43 0.0088

Zinc 23,000 4 5 0.02 240 220 0.085

Cyanide, total 1,600 0.5 0.2 0.01 0.89 1.1 0.01 U

%Solids NA NA NA NA 48.1 51.5

Arthur Kill North Channel Upland - COMP H - Dioxin/Furan

Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP

(Units: pg/L)

ASI ID # Soil Leachate #20200475 #20200484 #20200484 ng/kg pg/L COMP H Q A COMP H Q A COMP H Q

2,3,7,8‐TCDD NA NA NA NA 14 13 9.5 U

1,2,3,7,8‐PeCDD NA NA NA NA 4.2 J q B 3.8 J B 1.2 J B

1,2,3,4,7,8‐HxCDD NA NA NA NA 5.5 B 5.1 B 1.2 J B

1,2,3,6,7,8‐HxCDD NA NA NA NA 24 B 23 B 0.78 J B

1,2,3,7,8,9‐HxCDD NA NA NA NA 20 B 18 B 1.0 J B

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 350 B 370 B 1.2 J B q

OCDD NA NA NA NA 5000 E B 5300 E B 7.5 J B

2,3,7,8‐TCDF NA NA NA NA 21 B 17 B 9.5 U

1,2,3,7,8‐PeCDF NA NA NA NA 17 13 48 U

2,3,4,7,8‐PeCDF NA NA NA NA 18 15 48 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 77 I 53 I 48 U

1,2,3,6,7,8‐HxCDF NA NA NA NA 31 I 19 48 U

2,3,4,6,7,8‐HxCDF NA NA NA NA 18 B 13 B 48 U

1,2,3,7,8,9‐HxCDF NA NA NA NA 5.3 B 1.5 J B 48 U

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 360 B 210 B 0.84 J B q

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 76 B 16 B 0.60 J B q

OCDF NA NA NA NA 1000 B 320 B 2.5 J B q

Arthur Kill North Channel Upland ‐ COMP H ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt)

SPLP

(Units: pg/L)

ASI ID # #20200475 #20200484 #20200484

COMP H Q A COMP H Q A COMP H Q

2,3,7,8‐TCDD 1 14.00 13.00 9.50 U

1,2,3,7,8‐PeCDD 1 4.20 J q B 3.80 J B 1.20 J B

1,2,3,4,7,8‐HxCDD 0.1 0.55 B 0.51 B 0.12 J B

1,2,3,6,7,8‐HxCDD 0.1 2.40 B 2.30 B 0.08 J B

1,2,3,7,8,9‐HxCDD 0.1 2.00 B 1.80 B 0.10 J B

1,2,3,4,6,7,8‐HpCDD 0.01 3.50 B 3.70 B 0.01 J B q

1,2,3,4,6,7,8,9‐OCDD 0.0003 1.50 E B 1.59 E B 0.00 J B

2,3,7,8‐TCDF 0.1 2.10 B 1.70 B 0.95 U

1,2,3,7,8‐PeCDF 0.03 0.51 0.39 1.44 U

2,3,4,7,8‐PeCDF 0.3 5.40 4.50 14.40 U

1,2,3,4,7,8‐HxCDF 0.1 7.70 I 5.30 I 4.80 U

1,2,3,6,7,8‐HxCDF 0.1 3.10 I 1.90 4.80 U

2,3,4,6,7,8‐HxCDF 0.1 1.80 B 1.30 B 4.80 U

1,2,3,7,8,9‐HxCDF 0.1 0.53 B 0.15 J B 4.80 U

1,2,3,4,6,7,8‐HpCDF 0.01 3.60 B 2.10 B 0.01 J B q

1,2,3,4,7,8,9‐HpCDF 0.01 0.76 B 0.16 B 0.01 J B q

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.30 B 0.10 B 0.00 J B q

TOTAL TEF as 2,3,7,8‐TCDD 53.95 44.30 47.02

Arthur Kill North Channel Upland - COMP I - Sediment Volatiles

Volatiles Action Level Action Level Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200476 #20200485 #20200485 ug/kg ug/L COMP I Q A COMP I Q A COMP I Q

Chloromethane (Methyl Chloride) 4000 30 11 U 10 U 1.0 U

Bromomethane 25000 10 11 U 10 U 1.0 U

Vinyl chloride 700 5 11 U 10 U 1.0 U

Chloroethane 220000 NA 11 U 10 U 1.0 U

Methylene chloride (Dichloromethane) 34000 3 11 U 10 U 1.0 U

Acetone 70000000 700 45 U 81 31

Carbon disulfide 7800000 NA 11 U 8.1 J 2.7

1,1-Dichloroethene 11000 2 11 U 10 U 1.0 U

1,1-Dichloroethane 8000 50 11 U 10 U 1.0 U

1,2-Dichloroethene (total) 10 23 U 20 U 2.0 U

Chloroform 600 6 11 U 10 U 1.0 U

1,2-Dichloroethane 900 NA 11 U 10 U 1.0 U

2-Butanone (MEK) 3100000 300 9.6 J 69 6.0

1,1,1-Trichloroethane 290000 30 11 U 10 U 1.0 U

Carbon tetrachloride 600 2 11 U 10 U 1.0 U

Bromodichloromethane 1000 1 11 U 10 U 1.0 U

1,2-Dichloropropane 2000 1 11 U 10 U 1.0 U cis-1,3-Dichloropropene NA NA 11 U 10 U 1.0 U

Trichloroethene 7000 1 11 U 10 U 1.0 U

Dibromochloromethane 3000 10 11 U 10 U 1.0 U

1,1,2-Trichloroethane 2000 3 11 U 10 U 1.0 U

Benzene 2000 1 11 U 10 U 1.0 U trans-1,3-dichloropropene NA NA 11 U 10 U 1.0 U

Bromoform 81000 4 11 U 10 U 1.0 U

Tetrachloroethene 2000 1 11 U 10 U 1.0 U

1,1,2,2-Tetrachloroethane 1000 NA 11 U 10 U 1.0 U

Toluene 6300000 1000 11 U 10 U 1.0 U

Chlorobenzene 510000 50 11 U * 10 U * 1.0 U

Ethyl benzene 7800000 700 11 U 10 U 1.0 U

Styrene 90000 100 11 U * 10 U * 1.0 U

Xylenes(Total) 12000000 1000 23 U 20 U 2.0 U

Acrolein 500 230 U 200 U 20 U *

Acrylonitrile 900 110 U 100 U 20 U

1,2-Dibromo-3-chloropropane 80 11 U 10 U 1.0 U

1,2-Dibromoethane 8 11 U 10 U 1.0 U

Dichlorodifluoromethane 490000 11 U 10 U 1.0 U

1,2-Dichloroethene (cis) 230000 11 U 10 U 1.0 U

1,2-Dichloroethene (trans) 300000 11 U 10 U 1.0 U

Methyl acetate 78000000 57 U 51 U 5.0 U

Methyl tert-butyl ether (MTBE) 110000 11 U 10 U 1.0 U

Tertiary butyl alcohol (TBA) 1400000 110 U 100 U 40 U

Trichlorofluoromethane 23000000 11 U 10 U 1.0 U

1,4-dioxane 2300 U 2000 U 200 U n-propylbenzene 11 U 10 U 1.0 U sec-butylbenzene 11 U 10 U 1.0 U tert-butylbenzene 11 U 10 U 1.0 U

1,2,4-trimethylbenzene 11 U 10 U 1.0 U

1,3,5-trimethylbenzene 11 U 10 U 1.0 U n‐Butylbenzene 11 U 10 U 1.0 U

Arthur Kill North Channel Upland - COMP I - Sediment Semivolatiles

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200476 #20200485 #20200485 ug/kg ug/kg mg/L mg/L COMP I Q A COMP I Q A COMP I Q

Phenol 18000000 660 4 0.01 920 U 830 U 0.00068 J bis(2-Chloroethyl)ether 400 660 0.01 0.01 190 U 170 U 0.00018 U

2-Chlorophenol 310000 660 0.005 0.01 920 U 830 U 0.00097 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 11 U * 10 U * 0.001 U

1,4-Dichlorobenzene 5000 660 0.075 0.01 11 U * 10 U * 0.001 U

1,2-Dichlorobenzene 5300000 660 0.6 0.01 11 U * 10 U * 0.001 U

2-Methylphenol (o-cresol) 310000 660 NA 0.01 920 U 830 U 0.00097 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 190 U 170 U 0.00018 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 920 U 830 U 0.0015

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 190 U 170 U 0.00018 U

Hexachloroethane 35000 660 0.01 0.01 920 U 830 U 0.00097 U

Nitrobenzene 31000 660 0.01 0.01 1900 U 1700 U 0.0019 U Isophorone 510000 660 0.1 0.01 920 U 830 U 0.00071 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 920 U 830 U 0.0025

2,4-Dichlorophenol 180000 660 0.02 0.01 190 U 170 U 0.00018 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 11 U 10 U 0.001 U

Naphthalene 6000 660 0.3 0.01 540 300 0.0017

Hexachloro-1,3-butadiene 6000 660 NA 0.01 190 U 170 U 0.00018 U

2-Methylnaphthalene 230000 660 NA 0.01 180 J 130 J 0.00038

Hexachlorocyclopentadiene 45000 660 0.05 0.01 920 U 830 U 0.00097 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 920 U 830 U 0.00097 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 920 U 830 U 0.00097 U

2-Chloronaphthalene NA 660 NA 0.01 190 U 170 U 0.00018 U

2-Nitroaniline 39000 3300 NA 0.05 4700 U 4300 U 0.0049 U

Acenaphthylene 300000000 660 NA 0.01 260 170 0.00018 U

2,6-Dinitrotoluene 700 660 0.01 0.01 920 U 830 U 0.00097 U

Arthur Kill North Channel Upland - COMP I - Sediment Semivolatiles, con't.

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200476 #20200485 #20200485 ug/kg ug/kg mg/L mg/L COMP I Q A COMP I Q A COMP I Q

Acenaphthene 3400000 660 0.4 0.01 200 130 J 0.00046

2,4-Dinitrophenol 120000 3300 0.04 0.05 9200 U 8300 U 0.0097 U

Dibenzofuran NA 660 NA 0.01 140 J 830 U 0.00097 U

2,4-Dinitrotoluene 700 660 0.01 0.01 920 U 830 U 0.00097 U

Diethylphthalate 49000000 660 5 0.01 920 U 830 U 0.00097 U

Fluorene 2300000 660 0.3 0.01 280 170 0.00034

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 4700 U 4300 U 0.0049 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 920 U 830 U 0.00097 U

Hexachlorobenzene 300 660 0.01 0.01 190 U 170 U 0.00018 U

Pentachlorophenol 3000 3300 0.001 0.05 4700 U 4300 U 0.0049 U

Phenanthrene 300000000 6600 NA 0.01 860 530 0.00044

Anthracene 17000000 6600 2 0.01 700 380 0.00017 J

Carbazole 24000 330 NA 0.01 150 J 63 J 0.00018 U

Di-n-butylphthalate 6100000 330 0.9 0.01 920 U 830 U 0.00097 U

Fluoranthene 2300000 660 0.3 0.01 1500 920 0.00015 J

Pyrene 1700000 660 0.2 0.01 1600 1000 0.00013 J

Butylbenzylphthalate 1200000 660 0.1 0.01 920 U 830 U 0.00097 U

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 920 U 830 U 0.00097 U

Benzo(a)anthracene 600 660 NA 0.01 770 500 0.00018 U

Chrysene 62000 660 NA 0.01 870 590 0.00018 U bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 12000 5900 J 0.0097 U

DI-n-octylphthalate 2400000 660 0.1 0.01 920 U 830 U 0.00097 U

Benzo(b)fluoranthene 600 660 NA 0.01 910 620 0.00018 U

Benzo(k)fluoranthene 6000 660 NA 0.01 280 200 0.00018 U

Benzo(a)pyrene 200 660 NA 0.01 670 440 0.00018 U

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 460 300 0.00018 U

Dibenzo(a,h)anthracene 200 660 NA 0.01 290 220 0.00018 U

Benzo(ghi)perylene 30000000 660 NA 0.01 580 430 0.00018 U

Acetophenone 2000 1900 U 1700 U 0.00037 J

Atrazine 210000 1900 U 1700 U 0.00097 U

Benzaldehyde 6100000 1900 U 1700 U 0.0012

Benzidine 700 19000 U 17000 U 0.019 U

1,1'-Biphenyl 3100000 54 J 830 U 0.00097 U

Caprolactam 31000000 4700 U 4300 U 0.0049 U

1,2-Diphenylhydrazine 700 920 U 830 U 0.00097 U

N-Nitrosodimethylamine 700 920 U 830 U 0.00097 U

Arthur Kill North Channel Upland - COMP I - Pesticides/Aroclors

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200476 #20200485 #20200485 ug/kg ug/kg mg/L mg/L COMP I Q A COMP I Q A COMP I Q alpha-BHC 100 1.9 0.00002 0.00005 0.47 U 0.42 U 0.0000013 U beta-BHC 400 3.3 0.0002 0.00005 0.47 U 0.42 U 0.0000033 p delta-BHC NA 1.7 NA 0.00005 0.47 U 0.42 U 0.0000013 U gamma-BHC (Lindane) 400 2 0.0002 0.00005 2.0 0.42 U 0.0000013 U

Heptachlor 100 2.1 0.0004 0.00005 0.47 U 0.42 U 0.0000013 U

Aldrin 40 2 0.00004 0.00005 0.47 U 0.42 U 0.0000013 U

Heptachlor epoxide 70 2.1 0.0002 0.00005 7.4 p 6.1 p 0.0000013 U

Endosulfan I NA 2.1 0.0004 0.00005 0.47 U 0.42 U 0.0000013 U

Dieldrin 40 3.3 0.00003 0.0001 0.47 U 0.42 U 0.0000013 U

4,4'-DDE 2000 4.2 0.0001 0.0001 62 p 48 p 0.0000013 U

Endrin 23000 3.6 0.002 0.0001 13 12 0.0000013 U

Endosulfan II NA 3.3 0.0004 0.0001 3.6 4.1 0.0000013 U

4,4'-DDD 3000 4.2 0.0001 0.0001 95 77 0.0000013 U

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.47 U 0.42 U 0.0000013 U

4,4'-DDT 2000 3.6 0.0001 0.0001 170 160 0.0000013 U

Methoxychlor 390000 17 0.04 0.001 0.47 U 0.42 U 0.0000013 U alpha-Chlordane 200 1.7 NA 0.00005 6.6 p 5.6 p 0.0000013 U gamma-Chlordane 200 1.7 0.0005 0.00005 25 0.42 U 0.00016

Toxaphene 600 170 0.003 0.005 19 U 17 U 0.000099 U

Mirex 0.47 U 0.42 U 0.0000013 U

Aroclor‐1016 9.4 U 8.4 U 0.0000099 U

Aroclor‐1221 9.4 U 8.4 U 0.0000099 U

Aroclor‐1232 9.4 U 8.4 U 0.0000099 U

Aroclor‐1242 9.4 U 8.4 U 0.0000099 U

Aroclor‐1248 650 350 0.0000099 U

Aroclor‐1254 9.4 U 8.4 U 0.0000099 U

Aroclor‐1260 180 95 0.0000099 U

Total Aroclor(SUM)

Arthur Kill North Channel Upland - COMP I - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200476 #20200485 #20200485

COMP I Q A COMP I Q A COMP I Q

2,4,5-TP (Silvex) NA NA NA NA 45 U 41 U 0.96 U

Arthur Kill North Channel Upland - COMP I - Metals

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200476 #20200485 #20200485 mg/kg mg/kg mg/L mg/L COMP I Q A COMP I Q A COMP I Q

Aluminum 78000 40 0.2 0.2 5700 14000 0.82 B

Antimony 31 12 0.02 0.06 3.1 3.0 0.00064 J

Arsenic 19 2 0.008 0.01 36 31 0.003

Barium 16000 40 2 0.2 250 210 0.17 B

Beryllium 16 1 0.02 0.005 1.1 1.1 0.001 U

Cadmium 78 1 0.004 0.005 4.2 3.5 0.001 U

Chromium NA 2 0.1 0.01 130 B 150 B 0.002 U

Hexavalent Chromium 120000 0.62 J 0.82 U 0.010 U

Trivalent Chromium 20 130 150 0.01 U

Cobalt 1,600 10 NA 0.05 12 11 0.0011

Copper 590 5 1 0.025 380 290 0.002 U

Lead 400 0.6 0.01 0.003 210 170 0.0003 J

Manganese 5900 3 0.05 0.015 390 380 0.005 U

Mercury 23 0.1 0.002 0.0002 5.3 4.3 0.0012

Nickel 1,600 8 0.1 0.04 49 49 0.048

Selenium 390 1 0.05 0.015 3.0 2.7 0.005 U

Silver 390 2 NA 0.01 3.2 2.6 0.001 U

Vanadium 78 10 NA 0.05 46 55 0.0062

Zinc 23,000 4 5 0.02 390 330 0.0078

Cyanide, total 1,600 0.5 0.2 0.01 3.1 2.7 0.01 U

%Solids NA NA NA NA 44.1 49.3

Arthur Kill North Channel Upland - COMP I - Dioxin/Furan

Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP

(Units: pg/L)

ASI ID # Soil Leachate #20200476 #20200485 #20200485 ng/kg pg/L COMP I Q A COMP I Q A COMP I Q

2,3,7,8‐TCDD NA NA NA NA 30 21 9.7 U

1,2,3,7,8‐PeCDD NA NA NA NA 6.9 q B 6.2 B 49 U

1,2,3,4,7,8‐HxCDD NA NA NA NA 11 B 9.8 B 1.3 J B

1,2,3,6,7,8‐HxCDD NA NA NA NA 46 B 33 B 1.1 J B q

1,2,3,7,8,9‐HxCDD NA NA NA NA 38 B 32 B 1.2 J B q

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 610 B 550 B 9.9 J B q

OCDD NA NA NA NA 8200 E B 6900 E B 110 B

2,3,7,8‐TCDF NA NA NA NA 46 B 31 B 9.7 U

1,2,3,7,8‐PeCDF NA NA NA NA 31 21 49 U

2,3,4,7,8‐PeCDF NA NA NA NA 42 29 49 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 150 I 110 I 2.4 J B

1,2,3,6,7,8‐HxCDF NA NA NA NA 53 41 I 0.88 J B q

2,3,4,6,7,8‐HxCDF NA NA NA NA 42 B 30 B 0.99 J B q

1,2,3,7,8,9‐HxCDF NA NA NA NA 5.4 J B 3.2 J q B 49 U

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 520 B 350 B 6.8 J B

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 58 B 34 B 1.3 J B

OCDF NA NA NA NA 930 B 490 B 12 J B

Arthur Kill North Channel Upland ‐ COMP I ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt)

SPLP

(Units: pg/L)

ASI ID # #20200476 #20200485 #20200485

COMP I Q A COMP I Q A COMP I Q

2,3,7,8‐TCDD 1 30.00 21.00 9.70 U

1,2,3,7,8‐PeCDD 1 6.90 q B 6.20 B 49.00 U

1,2,3,4,7,8‐HxCDD 0.1 1.10 B 0.98 B 0.13 J B

1,2,3,6,7,8‐HxCDD 0.1 4.60 B 3.30 B 0.11 J B q

1,2,3,7,8,9‐HxCDD 0.1 3.80 B 3.20 B 0.12 J B q

1,2,3,4,6,7,8‐HpCDD 0.01 6.10 B 5.50 B 0.10 J B q

1,2,3,4,6,7,8,9‐OCDD 0.0003 2.46 E B 2.07 E B 0.03 B

2,3,7,8‐TCDF 0.1 4.60 B 3.10 B 0.97 U

1,2,3,7,8‐PeCDF 0.03 0.93 0.63 1.47 U

2,3,4,7,8‐PeCDF 0.3 12.60 8.70 14.70 U

1,2,3,4,7,8‐HxCDF 0.1 15.00 I 11.00 I 0.24 J B

1,2,3,6,7,8‐HxCDF 0.1 5.30 4.10 I 0.09 J B q

2,3,4,6,7,8‐HxCDF 0.1 4.20 B 3.00 B 0.10 J B q

1,2,3,7,8,9‐HxCDF 0.1 0.54 J B 0.32 J q B 4.90 U

1,2,3,4,6,7,8‐HpCDF 0.01 5.20 B 3.50 B 0.07 J B

1,2,3,4,7,8,9‐HpCDF 0.01 0.58 B 0.34 B 0.01 J B

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.28 B 0.15 B 0.00 J B

TOTAL TEF as 2,3,7,8‐TCDD 104.19 77.09 81.74

Arthur Kill North Channel Upland - COMP J - Sediment Volatiles

Volatiles Action Level Action Level Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200477 #20200486 #20200486 ug/kg ug/L COMP J Q A COMP J Q A COMP J Q

Chloromethane (Methyl Chloride) 4000 30 13 U 11 U 5.0 U

Bromomethane 25000 10 13 U 11 U 5.0 U

Vinyl chloride 700 5 13 U 11 U 5.0 U

Chloroethane 220000 NA 13 U 11 U 5.0 U

Methylene chloride (Dichloromethane) 34000 3 13 U 11 U 5.0 U

Acetone 70000000 700 53 U 61 110 E

Carbon disulfide 7800000 NA 13 U 11 U 5.0 U

1,1-Dichloroethene 11000 2 13 U 11 U 5.0 U

1,1-Dichloroethane 8000 50 13 U 11 U 5.0 U

1,2-Dichloroethene (total) 10 26 U 22 U 2.0 U

Chloroform 600 6 13 U 11 U 5.0 U

1,2-Dichloroethane 900 NA 13 U 11 U 1.0 U

2-Butanone (MEK) 3100000 300 13 U 80 15

1,1,1-Trichloroethane 290000 30 13 U 11 U 5.0 U

Carbon tetrachloride 600 2 13 U 11 U 5.0 U

Bromodichloromethane 1000 1 13 U 11 U 5.0 U

1,2-Dichloropropane 2000 1 13 U 11 U 1.0 U cis-1,3-Dichloropropene NA NA 13 U 11 U 1.0 U

Trichloroethene 7000 1 13 U 11 U 1.0 U

Dibromochloromethane 3000 10 13 U 11 U 1.0 U

1,1,2-Trichloroethane 2000 3 13 U 11 U 5.0 U

Benzene 2000 1 13 U 11 U 5.0 U trans-1,3-dichloropropene NA NA 13 U 11 U 1.0 U

Bromoform 81000 4 13 U 11 U 1.0 U

Tetrachloroethene 2000 1 13 U 11 U 1.0 U

1,1,2,2-Tetrachloroethane 1000 NA 13 U 11 U 5.0 U

Toluene 6300000 1000 13 U 11 U 3.1

Chlorobenzene 510000 50 13 U 11 U 5.0 U

Ethyl benzene 7800000 700 13 U 11 U 5.0 U

Styrene 90000 100 13 U 11 U 1.0 U

Xylenes(Total) 12000000 1000 26 U 22 U 2.0 U

Acrolein 500 260 U 220 U 20 U

Acrylonitrile 900 130 U 110 U 20 U

1,2-Dibromo-3-chloropropane 80 13 U 11 U 5.0 U

1,2-Dibromoethane 8 13 U 11 U 1.0 U

Dichlorodifluoromethane 490000 13 U 11 U 1.0 U

1,2-Dichloroethene (cis) 230000 13 U 11 U 1.0 U

1,2-Dichloroethene (trans) 300000 13 U 11 U 1.0 U

Methyl acetate 78000000 66 U 55 U 25 U

Methyl tert-butyl ether (MTBE) 110000 13 U 11 U 1.0 U

Tertiary butyl alcohol (TBA) 1400000 130 U 110 U 40 U

Trichlorofluoromethane 23000000 13 U 11 U 1.0 U

1,4-dioxane 2600 U 2200 U 200 U n-propylbenzene 13 U 11 U 5.0 U sec-butylbenzene 13 U 11 U 5.0 U tert-butylbenzene 13 U 11 U 1.0 U

1,2,4-trimethylbenzene 13 U 11 U 1.0 U

1,3,5-trimethylbenzene 13 U 11 U 1.0 U n‐Butylbenzene 13 U 11 U 5.0 U

Arthur Kill North Channel Upland - COMP J - Sediment Semivolatiles

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200477 #20200486 #20200486 ug/kg ug/kg mg/L mg/L COMP J Q A COMP J Q A COMP J Q

Phenol 18000000 660 4 0.01 1100 U 900 U 0.00077 J bis(2-Chloroethyl)ether 400 660 0.01 0.01 220 U 180 U 0.00018 U

2-Chlorophenol 310000 660 0.005 0.01 1100 U 900 U 0.00093 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 13 U 11 U 0.001 U

1,4-Dichlorobenzene 5000 660 0.075 0.01 13 U 11 U 0.005 U

1,2-Dichlorobenzene 5300000 660 0.6 0.01 13 U 11 U 0.001 U

2-Methylphenol (o-cresol) 310000 660 NA 0.01 1100 U 900 U 0.00093 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 220 U 180 U 0.00018 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 1100 U 900 U 0.0018

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 220 U 180 U 0.00018 U

Hexachloroethane 35000 660 0.01 0.01 1100 U 900 U 0.00093 U

Nitrobenzene 31000 660 0.01 0.01 2100 U 1800 U 0.0019 U Isophorone 510000 660 0.1 0.01 1100 U 49 J 0.0003 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 1100 U 900 U 0.0013

2,4-Dichlorophenol 180000 660 0.02 0.01 220 U 180 U 0.00018 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 13 U 11 U 0.001 U

Naphthalene 6000 660 0.3 0.01 160 J 130 J 0.00048

Hexachloro-1,3-butadiene 6000 660 NA 0.01 220 U 180 U 0.00018 U

2-Methylnaphthalene 230000 660 NA 0.01 94 J 82 J 0.0003

Hexachlorocyclopentadiene 45000 660 0.05 0.01 1100 U 900 U 0.00093 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 1100 U 900 U 0.00093 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 1100 U 900 U 0.00093 U

2-Chloronaphthalene NA 660 NA 0.01 220 U 180 U 0.00018 U

2-Nitroaniline 39000 3300 NA 0.05 5500 U 4600 U 0.0046 U

Acenaphthylene 300000000 660 NA 0.01 280 260 0.00018 U

2,6-Dinitrotoluene 700 660 0.01 0.01 1100 U 900 U 0.00093 U

Arthur Kill North Channel Upland - COMP J - Sediment Semivolatiles, con't.

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200477 #20200486 #20200486 ug/kg ug/kg mg/L mg/L COMP J Q A COMP J Q A COMP J Q

Acenaphthene 3400000 660 0.4 0.01 220 U 63 J 0.0005

2,4-Dinitrophenol 120000 3300 0.04 0.05 11000 U 9000 U 0.0093 U

Dibenzofuran NA 660 NA 0.01 1100 U 50 J 0.0003 J

2,4-Dinitrotoluene 700 660 0.01 0.01 1100 U 900 U 0.00093 U

Diethylphthalate 49000000 660 5 0.01 1100 U 900 U 0.00093 U

Fluorene 2300000 660 0.3 0.01 97 J 180 U 0.00041

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 5500 U 4600 U 0.0046 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 1100 U 900 U 0.00093 U

Hexachlorobenzene 300 660 0.01 0.01 220 U 180 U 0.00018 U

Pentachlorophenol 3000 3300 0.001 0.05 5500 U 4600 U 0.0046 U

Phenanthrene 300000000 6600 NA 0.01 480 380 0.00062

Anthracene 17000000 6600 2 0.01 320 280 0.00025

Carbazole 24000 330 NA 0.01 85 J 75 J 0.000069 J

Di-n-butylphthalate 6100000 330 0.9 0.01 1100 U 900 U 0.00093 U

Fluoranthene 2300000 660 0.3 0.01 1500 1100 0.00014 J

Pyrene 1700000 660 0.2 0.01 1800 1200 0.00022

Butylbenzylphthalate 1200000 660 0.1 0.01 1100 U 900 U 0.00088 J

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 1100 U 900 U 0.00093 U

Benzo(a)anthracene 600 660 NA 0.01 840 600 0.00011 J

Chrysene 62000 660 NA 0.01 940 730 0.00014 J bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 4800 J 3200 J 0.0093 U

DI-n-octylphthalate 2400000 660 0.1 0.01 1100 U 900 U 0.00093 U

Benzo(b)fluoranthene 600 660 NA 0.01 1300 930 0.00013 J

Benzo(k)fluoranthene 6000 660 NA 0.01 480 300 0.00014 J

Benzo(a)pyrene 200 660 NA 0.01 1000 730 0.000055 J

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 710 520 0.00012 J

Dibenzo(a,h)anthracene 200 660 NA 0.01 370 260 0.00014 J

Benzo(ghi)perylene 30000000 660 NA 0.01 920 690 0.00012 J

Acetophenone 2000 2200 U 1800 U 0.0005 J B

Atrazine 210000 2200 U 1800 U 0.00093 U

Benzaldehyde 6100000 150 J 150 J 0.00057 J

Benzidine 700 22000 U 18000 U 0.019 U

1,1'-Biphenyl 3100000 50 J 41 J 0.00093 U

Caprolactam 31000000 5500 U 4600 U 0.0046 U

1,2-Diphenylhydrazine 700 1100 U 900 U 0.00093 U

N-Nitrosodimethylamine 700 1100 U 900 U 0.00093 U

Arthur Kill North Channel Upland - COMP J - Pesticides/Aroclors

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200477 #20200486 #20200486 ug/kg ug/kg mg/L mg/L COMP J Q A COMP J Q A COMP J Q alpha-BHC 100 1.9 0.00002 0.00005 0.54 U 0.45 U 0.0000049 p beta-BHC 400 3.3 0.0002 0.00005 0.54 U 0.45 U 0.0000012 U delta-BHC NA 1.7 NA 0.00005 0.54 U 0.45 U 0.0000012 U gamma-BHC (Lindane) 400 2 0.0002 0.00005 0.28 J p 0.45 U 0.0000012 U

Heptachlor 100 2.1 0.0004 0.00005 0.54 U 0.45 U 0.0000012 U

Aldrin 40 2 0.00004 0.00005 0.54 U 0.45 U 0.0000012 U

Heptachlor epoxide 70 2.1 0.0002 0.00005 2.3 p 1.0 p 0.0000012 U

Endosulfan I NA 2.1 0.0004 0.00005 0.54 U 0.45 U 0.0000012 U

Dieldrin 40 3.3 0.00003 0.0001 0.54 U 0.45 U 0.0000012 U

4,4'-DDE 2000 4.2 0.0001 0.0001 51 p 25 p 0.0000012 U

Endrin 23000 3.6 0.002 0.0001 8.0 4.6 0.0000012 U

Endosulfan II NA 3.3 0.0004 0.0001 1.9 1.2 0.0000012 U

4,4'-DDD 3000 4.2 0.0001 0.0001 93 48 0.0000012 U

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.54 U 0.45 U 0.0000012 U

4,4'-DDT 2000 3.6 0.0001 0.0001 340 93 0.0000012 U

Methoxychlor 390000 17 0.04 0.001 0.54 U 0.45 U 0.0000012 U alpha-Chlordane 200 1.7 NA 0.00005 2.7 p 1.4 p 0.0000012 U gamma-Chlordane 200 1.7 0.0005 0.00005 0.54 U 6.6 0.0000012 U

Toxaphene 600 170 0.003 0.005 22 U 18 U 0.000094 U

Mirex 0.54 U 0.45 U 0.0000012 U

Aroclor‐1016 1.1 U 0.92 U 0.0000094 U

Aroclor‐1221 1.1 U 0.92 U 0.0000094 U

Aroclor‐1232 1.1 U 0.92 U 0.0000094 U

Aroclor‐1242 1.1 U 0.92 U 0.0000094 U

Aroclor‐1248 130 75 0.0000094 U

Aroclor‐1254 1.1 U 0.92 U 0.0000094 U

Aroclor‐1260 93 52 0.0000094 U

Total Aroclor(SUM)

Arthur Kill North Channel Upland - COMP J - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200477 #20200486 #20200486

COMP J Q A COMP J Q A COMP J Q

2,4,5-TP (Silvex) NA NA NA NA 53 U 44 U 0.95 U

Arthur Kill North Channel Upland - COMP J - Metals

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200477 #20200486 #20200486 mg/kg mg/kg mg/L mg/L COMP J Q A COMP J Q A COMP J Q

Aluminum 78000 40 0.2 0.2 15000 15000 1.1

Antimony 31 12 0.02 0.06 1.7 1.3 0.00088 J

Arsenic 19 2 0.008 0.01 22 B 20 B 0.0028

Barium 16000 40 2 0.2 260 220 0.097

Beryllium 16 1 0.02 0.005 0.95 0.74 0.001 U

Cadmium 78 1 0.004 0.005 1.7 1.2 0.001 U

Chromium NA 2 0.1 0.01 100 110 0.002 U

Hexavalent Chromium 120000 1.1 U 0.89 U 0.010 U F1

Trivalent Chromium 20 100 110 0.01 U

Cobalt 1,600 10 NA 0.05 11 B 10 B 0.00061

Copper 590 5 1 0.025 240 160 0.002 U

Lead 400 0.6 0.01 0.003 200 150 0.00017 J

Manganese 5900 3 0.05 0.015 450 430 0.005 U

Mercury 23 0.1 0.002 0.0002 3.9 3.2 0.00073

Nickel 1,600 8 0.1 0.04 39 38 0.015

Selenium 390 1 0.05 0.015 2.2 1.5 0.005 U

Silver 390 2 NA 0.01 2.8 2.3 0.001 U

Vanadium 78 10 NA 0.05 44 46 0.0074

Zinc 23,000 4 5 0.02 290 250 0.01

Cyanide, total 1,600 0.5 0.2 0.01 1.0 B 1.9 B 0.01 U ^

%Solids NA NA NA NA 37.8 45.5

Arthur Kill North Channel Upland - COMP J - Dioxin/Furan

Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP

(Units: pg/L)

ASI ID # Soil Leachate #20200477 #20200486 #20200486 ng/kg pg/L COMP J Q A COMP J Q A COMP J Q

2,3,7,8‐TCDD NA NA NA NA 22 30 10 U

1,2,3,7,8‐PeCDD NA NA NA NA 6.6 q 5.2 J q 52 U

1,2,3,4,7,8‐HxCDD NA NA NA NA 7.2 B 5.7 B 1.2 J q B

1,2,3,6,7,8‐HxCDD NA NA NA NA 29 B 24 B 52 U

1,2,3,7,8,9‐HxCDD NA NA NA NA 24 B 19 B 52 U

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 470 410 52 U

OCDD NA NA NA NA 6300 E B 5500 E B 4.0 J B

2,3,7,8‐TCDF NA NA NA NA 32 23 10 U

1,2,3,7,8‐PeCDF NA NA NA NA 16 11 52 U

2,3,4,7,8‐PeCDF NA NA NA NA 21 16 52 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 63 49 52 U

1,2,3,6,7,8‐HxCDF NA NA NA NA 26 I 24 I 52 U

2,3,4,6,7,8‐HxCDF NA NA NA NA 16 13 52 U

1,2,3,7,8,9‐HxCDF NA NA NA NA 6.4 U 5.4 U 52 U

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 260 B 210 B 52 U

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 20 B 17 B 52 U

OCDF NA NA NA NA 430 I B 350 B 1.7 J q B

Arthur Kill North Channel Upland ‐ COMP J ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt)

SPLP

(Units: pg/L)

ASI ID # #20200477 #20200486 #20200486

COMP J Q A COMP J Q A COMP J Q

2,3,7,8‐TCDD 1 22.00 30.00 10.00 U

1,2,3,7,8‐PeCDD 1 6.60 q 5.20 J q 52.00 U

1,2,3,4,7,8‐HxCDD 0.1 0.72 B 0.57 B 0.12 J q B

1,2,3,6,7,8‐HxCDD 0.1 2.90 B 2.40 B 5.20 U

1,2,3,7,8,9‐HxCDD 0.1 2.40 B 1.90 B 5.20 U

1,2,3,4,6,7,8‐HpCDD 0.01 4.70 4.10 0.52 U

1,2,3,4,6,7,8,9‐OCDD 0.0003 1.89 E B 1.65 E B 0.00 J B

2,3,7,8‐TCDF 0.1 3.20 2.30 1.00 U

1,2,3,7,8‐PeCDF 0.03 0.48 0.33 1.56 U

2,3,4,7,8‐PeCDF 0.3 6.30 4.80 15.60 U

1,2,3,4,7,8‐HxCDF 0.1 6.30 4.90 5.20 U

1,2,3,6,7,8‐HxCDF 0.1 2.60 I 2.40 I 5.20 U

2,3,4,6,7,8‐HxCDF 0.1 1.60 1.30 5.20 U

1,2,3,7,8,9‐HxCDF 0.1 0.64 U 0.54 U 5.20 U

1,2,3,4,6,7,8‐HpCDF 0.01 2.60 B 2.10 B 0.52 U

1,2,3,4,7,8,9‐HpCDF 0.01 0.20 B 0.17 B 0.52 U

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.13 I B 0.11 B 0.00 J q B

TOTAL TEF as 2,3,7,8‐TCDD 65.26 64.77 113.04

Arthur Kill North Channel Upland - COMP K - Sediment Volatiles

Volatiles Action Level Action Level Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200478 #20200487 #20200487 ug/kg ug/L COMP K Q A COMP K Q A COMP K Q

Chloromethane (Methyl Chloride) 4000 30 11 U 9.4 U 1.0 U

Bromomethane 25000 10 11 U 9.4 U 1.0 U

Vinyl chloride 700 5 11 U 9.4 U 1.0 U

Chloroethane 220000 NA 11 U 9.4 U 1.0 U

Methylene chloride (Dichloromethane) 34000 3 11 U 9.4 U 2.5

Acetone 70000000 700 46 U 32 J 36

Carbon disulfide 7800000 NA 11 9.4 U 2.7

1,1-Dichloroethene 11000 2 11 U 9.4 U 1.0 U

1,1-Dichloroethane 8000 50 11 U 9.4 U 1.0 U

1,2-Dichloroethene (total) 10 23 U 19 U 2.0 U

Chloroform 600 6 11 U 9.4 U 1.0 U

1,2-Dichloroethane 900 NA 11 U 9.4 U 1.0 U

2-Butanone (MEK) 3100000 300 11 U 77 5.6

1,1,1-Trichloroethane 290000 30 11 U 9.4 U 1.0 U

Carbon tetrachloride 600 2 11 U 9.4 U 1.0 U

Bromodichloromethane 1000 1 11 U 9.4 U 1.0 U

1,2-Dichloropropane 2000 1 11 U 9.4 U 1.0 U cis-1,3-Dichloropropene NA NA 11 U 9.4 U 1.0 U

Trichloroethene 7000 1 11 U 9.4 U 1.0 U

Dibromochloromethane 3000 10 11 U 9.4 U 1.0 U

1,1,2-Trichloroethane 2000 3 11 U 9.4 U 1.0 U

Benzene 2000 1 11 U 9.4 U 1.0 U trans-1,3-dichloropropene NA NA 11 U 9.4 U 1.0 U

Bromoform 81000 4 11 U 9.4 U 1.0 U

Tetrachloroethene 2000 1 11 U 9.4 U 1.0 U

1,1,2,2-Tetrachloroethane 1000 NA 11 U 9.4 U 1.0 U

Toluene 6300000 1000 11 U 9.4 U 1.0 U

Chlorobenzene 510000 50 11 U 9.4 U 1.0 U

Ethyl benzene 7800000 700 11 U 9.4 U 1.0 U

Styrene 90000 100 11 U 9.4 U 1.0 U

Xylenes(Total) 12000000 1000 23 U 19 U 2.0 U

Acrolein 500 230 U 190 U 20 U

Acrylonitrile 900 110 U 94 U 20 U

1,2-Dibromo-3-chloropropane 80 11 U 9.4 U 1.0 U

1,2-Dibromoethane 8 11 U 9.4 U 1.0 U

Dichlorodifluoromethane 490000 11 U 9.4 U 1.0 U

1,2-Dichloroethene (cis) 230000 11 U 9.4 U 1.0 U

1,2-Dichloroethene (trans) 300000 11 U 9.4 U 1.0 U

Methyl acetate 78000000 57 U 47 U 5.0 U

Methyl tert-butyl ether (MTBE) 110000 11 U 9.4 U 1.0 U

Tertiary butyl alcohol (TBA) 1400000 110 U 94 U 40 U

Trichlorofluoromethane 23000000 11 U 9.4 U 1.0 U

1,4-dioxane 2300 U 1900 U 200 U n-propylbenzene 11 U 9.4 U 1.0 U sec-butylbenzene 11 U 9.4 U 1.0 U tert-butylbenzene 11 U 9.4 U 1.0 U

1,2,4-trimethylbenzene 4.5 J 2.6 J 1.0 U

1,3,5-trimethylbenzene 11 U 9.4 U 1.0 U n‐Butylbenzene 11 U 9.4 U 1.0 U

Arthur Kill North Channel Upland - COMP K - Sediment Semivolatiles

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200478 #20200487 #20200487 ug/kg ug/kg mg/L mg/L COMP K Q A COMP K Q A COMP K Q

Phenol 18000000 660 4 0.01 940 U 760 U 0.00055 J bis(2-Chloroethyl)ether 400 660 0.01 0.01 190 U 160 U 0.00018 U

2-Chlorophenol 310000 660 0.005 0.01 940 U 760 U 0.00093 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 11 U 9.4 U 0.001 U

1,4-Dichlorobenzene 5000 660 0.075 0.01 11 U 9.4 U 0.001 U

1,2-Dichlorobenzene 5300000 660 0.6 0.01 11 U 9.4 U 0.001 U

2-Methylphenol (o-cresol) 310000 660 NA 0.01 940 U 760 U 0.00093 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 190 U 160 U 0.00018 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 940 U 430 J 0.00093 U

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 190 U 160 U 0.00018 U

Hexachloroethane 35000 660 0.01 0.01 940 U 760 U 0.00093 U

Nitrobenzene 31000 660 0.01 0.01 1900 U 1500 U 0.0019 U Isophorone 510000 660 0.1 0.01 940 U 760 U 0.0005 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 940 U 350 J 0.00027 J

2,4-Dichlorophenol 180000 660 0.02 0.01 190 U 160 U 0.00018 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 11 U 9.4 U 0.001 U

Naphthalene 6000 660 0.3 0.01 490 210 0.00018 U

Hexachloro-1,3-butadiene 6000 660 NA 0.01 190 U 160 U 0.00018 U

2-Methylnaphthalene 230000 660 NA 0.01 230 180 0.00018 U

Hexachlorocyclopentadiene 45000 660 0.05 0.01 940 U 760 U 0.00093 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 940 U 760 U 0.00093 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 940 U 760 U 0.00093 U

2-Chloronaphthalene NA 660 NA 0.01 190 U 160 U 0.00018 U

2-Nitroaniline 39000 3300 NA 0.05 4800 U 3900 U 0.0046 U

Acenaphthylene 300000000 660 NA 0.01 440 280 0.00018 U

2,6-Dinitrotoluene 700 660 0.01 0.01 940 U 760 U 0.00093 U

Arthur Kill North Channel Upland - COMP K - Sediment Semivolatiles, con't.

Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200478 #20200487 #20200487 ug/kg ug/kg…