J64007-2_Std_Tal_L4_Final_Report.pdf

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Attached to: Maintenance Dredging of Newark Bay, New Jersey Federal Navigation Project
Solicitation number: W912DS18B0006
Issued by: Department of the Army Corps of Engineers Engineering District New York

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J64007-2 Std_Tal_L4 Final Report

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ANALYTICAL REPORT

Job Number: 180-64007-2

Job Description: USACE/NYD

For:

Battelle

397 Washington Street Duxbury, MA 02332

Attention: Elisabeth Barrows

Approved for release.

Carrie L Gamber Senior Project Manager

3/31/2017 12:16 PM

Carrie L Gamber, Senior Project Manager 301 Alpha Drive, Pittsburgh, PA, 15238

(412)963-2428 carrie.gamber@testamericainc.com

03/31/2017

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to the NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory. This report is confidential and is intended for the sole use of TestAmerica and its client. All questions regarding this report should be directed to the TestAmerica Project Manager or designee who has signed this report.

TestAmerica Laboratories, Inc.

TestAmerica Pittsburgh 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238

Tel (412) 963-7058 Fax (412) 963-2468 www.testamericainc.com mailto:carrie.gamber@testamericainc.com http://www.testamericainc.com http://

Table of Contents Cover Title Page

Data Summaries

Definitions

Case Narrative

Detection Summary

Client Sample Results

Default Detection Limits

Surrogate Summary

Isotope Dilution Summary

QC Sample Results

QC Association

Chronicle

Certification Summary

Method Summary

Sample Summary

Manual Integration Summary

Reagent Traceability

COAs

Organic Sample Data

Dioxin

1613B 1613B QC Summary 1613B Sample Data Standards Data

1613B ICAL Data 1613B Resolution Data

Table of Contents 1613B CCAL Data

Raw QC Data 1613B Tune Data 1613B Blank Data 1613B LCS/LCSD Data

1613B Run Logs 1613B Prep Data

Subcontracted Data

Shipping and Receiving Documents

Client Chain of Custody

Sample Receipt Checklist

Definitions/Glossary TestAmerica Job ID: 180-64007-2Client: Battelle

Project/Site: USACE/NYD

Qualifiers

Dioxin

Qualifier Description

B Compound was found in the blank and sample.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

q The reported result is the estimated maximum possible concentration of this analyte, quantitated using the theoretical ion ratio. The measured ion ratio does not meet qualitative identification criteria and indicates a possible interference.

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica Pittsburgh

CASE NARRATIVE

Client: Battelle

Project: USACE/NYD

Report Number: 180-64007-2

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

RECEIPT

The samples were received on 03/03/2017; the samples arrived in good condition, properly preserved and on ice. The temperatures of the 2 coolers at receipt time were 2.0º C and 2.9º C.

DIOXINS

OCDD was detected in method blank LB 140-9748/19-A at a level that was above the method detection limit but below the reporting limit.

The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

1,2,3,4,7,8,9-HpCDF, 1,2,3,7,8,9-HxCDD, OCDD and OCDF were detected in method blank MB 140-9748/20-A at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Detection Summary

Project/Site: USACE/NYD

Client Sample ID: #20170157 AMENDED COMPOSITE K Lab Sample ID: 180-64007-1

OCDD

96 pg/L

EDL

0.25

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J q B1.4 1613B

Client Sample ID: #20170159 AMENDED COMPOSITE M Lab Sample ID: 180-64007-2

OCDD

96 pg/L

EDL

0.18

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J q B0.72 1613B

Client Sample ID: #20170161 AMENDED COMPOSITE O Lab Sample ID: 180-64007-3

No Detections.

Client Sample ID: #20170162 AMENDED COMPOSITE P Lab Sample ID: 180-64007-4

No Detections.

Client Sample ID: #20170163 AMENDED COMPOSITE Q Lab Sample ID: 180-64007-5

No Detections.

Client Sample ID: #20170168 AMENDED COMPOSITE V Lab Sample ID: 180-64007-6

OCDD

96 pg/L

EDL

0.11

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J q B0.78 1613B

Client Sample ID: #20170158 AMENDED COMPOSITE L Lab Sample ID: 180-64007-10

No Detections.

Client Sample ID: #20170160 AMENDED COMPOSITE N Lab Sample ID: 180-64007-11

OCDD

96 pg/L

EDL

0.35

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J B q1.9 1613B

Client Sample ID: #20170169 AMENDED COMPOSITE W Lab Sample ID: 180-64007-12

No Detections.

TestAmerica Pittsburgh

This Detection Summary does not include radiochemical test results.

Client Sample Results

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-64007-1Client Sample ID: #20170157 AMENDED COMPOSITE K Matrix: SedimentDate Collected: 02/24/17 09:55

Date Received: 03/03/17 09:00

RL EDL

2,3,7,8-TCDD ND 9.6 1.8 pg/L 03/22/17 12:07 03/30/17 15:14 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.58 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,7,8-PeCDD ND

48 0.41 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,4,7,8-HxCDD ND

48 0.43 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,6,7,8-HxCDD ND

48 0.39 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,7,8,9-HxCDD ND

48 0.48 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,4,6,7,8-HpCDD ND

96 0.25 pg/L 03/22/17 12:07 03/30/17 15:14 1OCDD 1.4 J q B

9.6 1.1 pg/L 03/22/17 12:07 03/30/17 15:14 12,3,7,8-TCDF ND

48 0.36 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,7,8-PeCDF ND

48 0.34 pg/L 03/22/17 12:07 03/30/17 15:14 12,3,4,7,8-PeCDF ND

48 0.29 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,4,7,8-HxCDF ND

48 0.28 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,6,7,8-HxCDF ND

48 0.27 pg/L 03/22/17 12:07 03/30/17 15:14 12,3,4,6,7,8-HxCDF ND

48 0.34 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,7,8,9-HxCDF ND

48 0.14 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,4,6,7,8-HpCDF ND

48 0.20 pg/L 03/22/17 12:07 03/30/17 15:14 11,2,3,4,7,8,9-HpCDF ND

96 0.94 pg/L 03/22/17 12:07 03/30/17 15:14 1OCDF ND

13C-2,3,7,8-TCDD 63 25 - 164 03/22/17 12:07 03/30/17 15:14 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 68 03/22/17 12:07 03/30/17 15:14 125 - 181

13C-1,2,3,4,7,8-HxCDD 65 03/22/17 12:07 03/30/17 15:14 132 - 141

13C-1,2,3,6,7,8-HxCDD 64 03/22/17 12:07 03/30/17 15:14 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 68 03/22/17 12:07 03/30/17 15:14 123 - 140

13C-OCDD 70 03/22/17 12:07 03/30/17 15:14 117 - 157

13C-2,3,7,8-TCDF 56 03/22/17 12:07 03/30/17 15:14 124 - 169

13C-1,2,3,7,8-PeCDF 60 03/22/17 12:07 03/30/17 15:14 124 - 185

13C-2,3,4,7,8-PeCDF 60 03/22/17 12:07 03/30/17 15:14 121 - 178

13C-1,2,3,4,7,8-HxCDF 57 03/22/17 12:07 03/30/17 15:14 126 - 152

13C-1,2,3,6,7,8-HxCDF 59 03/22/17 12:07 03/30/17 15:14 126 - 123

13C-2,3,4,6,7,8-HxCDF 60 03/22/17 12:07 03/30/17 15:14 128 - 136

13C-1,2,3,7,8,9-HxCDF 61 03/22/17 12:07 03/30/17 15:14 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 57 03/22/17 12:07 03/30/17 15:14 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 59 03/22/17 12:07 03/30/17 15:14 126 - 138

13C-OCDF 64 03/22/17 12:07 03/30/17 15:14 117 - 157

37Cl4-2,3,7,8-TCDD 88 35 - 197 03/22/17 12:07 03/30/17 15:14 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-64007-2Client Sample ID: #20170159 AMENDED COMPOSITE M Matrix: SedimentDate Collected: 02/24/17 13:10

Date Received: 03/03/17 09:00

RL EDL

2,3,7,8-TCDD ND 9.6 1.6 pg/L 03/22/17 12:07 03/30/17 16:14 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.41 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,7,8-PeCDD ND

48 0.12 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,4,7,8-HxCDD ND

48 0.13 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,6,7,8-HxCDD ND

48 0.12 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,7,8,9-HxCDD ND

48 0.57 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,4,6,7,8-HpCDD ND

96 0.18 pg/L 03/22/17 12:07 03/30/17 16:14 1OCDD 0.72 J q B

9.6 0.95 pg/L 03/22/17 12:07 03/30/17 16:14 12,3,7,8-TCDF ND

48 0.048 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,7,8-PeCDF ND

48 0.044 pg/L 03/22/17 12:07 03/30/17 16:14 12,3,4,7,8-PeCDF ND

48 0.39 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,4,7,8-HxCDF ND

48 0.38 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,6,7,8-HxCDF ND

48 0.36 pg/L 03/22/17 12:07 03/30/17 16:14 12,3,4,6,7,8-HxCDF ND

48 0.48 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,7,8,9-HxCDF ND

48 0.074 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,4,6,7,8-HpCDF ND

48 0.099 pg/L 03/22/17 12:07 03/30/17 16:14 11,2,3,4,7,8,9-HpCDF ND

96 0.62 pg/L 03/22/17 12:07 03/30/17 16:14 1OCDF ND

13C-2,3,7,8-TCDD 67 25 - 164 03/22/17 12:07 03/30/17 16:14 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 71 03/22/17 12:07 03/30/17 16:14 125 - 181

13C-1,2,3,4,7,8-HxCDD 70 03/22/17 12:07 03/30/17 16:14 132 - 141

13C-1,2,3,6,7,8-HxCDD 72 03/22/17 12:07 03/30/17 16:14 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 73 03/22/17 12:07 03/30/17 16:14 123 - 140

13C-OCDD 75 03/22/17 12:07 03/30/17 16:14 117 - 157

13C-2,3,7,8-TCDF 63 03/22/17 12:07 03/30/17 16:14 124 - 169

13C-1,2,3,7,8-PeCDF 66 03/22/17 12:07 03/30/17 16:14 124 - 185

13C-2,3,4,7,8-PeCDF 63 03/22/17 12:07 03/30/17 16:14 121 - 178

13C-1,2,3,4,7,8-HxCDF 60 03/22/17 12:07 03/30/17 16:14 126 - 152

13C-1,2,3,6,7,8-HxCDF 64 03/22/17 12:07 03/30/17 16:14 126 - 123

13C-2,3,4,6,7,8-HxCDF 65 03/22/17 12:07 03/30/17 16:14 128 - 136

13C-1,2,3,7,8,9-HxCDF 66 03/22/17 12:07 03/30/17 16:14 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 62 03/22/17 12:07 03/30/17 16:14 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 66 03/22/17 12:07 03/30/17 16:14 126 - 138

13C-OCDF 72 03/22/17 12:07 03/30/17 16:14 117 - 157

37Cl4-2,3,7,8-TCDD 88 35 - 197 03/22/17 12:07 03/30/17 16:14 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-64007-3Client Sample ID: #20170161 AMENDED COMPOSITE O Matrix: SedimentDate Collected: 02/24/17 12:41

Date Received: 03/03/17 09:00

RL EDL

2,3,7,8-TCDD ND 9.7 1.9 pg/L 03/22/17 12:07 03/30/17 17:15 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.51 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,7,8-PeCDD ND

48 0.33 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,4,7,8-HxCDD ND

48 0.35 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,6,7,8-HxCDD ND

48 0.32 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,7,8,9-HxCDD ND

48 0.43 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,4,6,7,8-HpCDD ND

97 0.27 pg/L 03/22/17 12:07 03/30/17 17:15 1OCDD ND

9.7 1.4 pg/L 03/22/17 12:07 03/30/17 17:15 12,3,7,8-TCDF ND

48 0.65 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,7,8-PeCDF ND

48 0.56 pg/L 03/22/17 12:07 03/30/17 17:15 12,3,4,7,8-PeCDF ND

48 0.28 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,4,7,8-HxCDF ND

48 0.26 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,6,7,8-HxCDF ND

48 0.25 pg/L 03/22/17 12:07 03/30/17 17:15 12,3,4,6,7,8-HxCDF ND

48 0.34 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,7,8,9-HxCDF ND

48 0.19 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,4,6,7,8-HpCDF ND

48 0.27 pg/L 03/22/17 12:07 03/30/17 17:15 11,2,3,4,7,8,9-HpCDF ND

97 1.0 pg/L 03/22/17 12:07 03/30/17 17:15 1OCDF ND

13C-2,3,7,8-TCDD 60 25 - 164 03/22/17 12:07 03/30/17 17:15 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 63 03/22/17 12:07 03/30/17 17:15 125 - 181

13C-1,2,3,4,7,8-HxCDD 64 03/22/17 12:07 03/30/17 17:15 132 - 141

13C-1,2,3,6,7,8-HxCDD 66 03/22/17 12:07 03/30/17 17:15 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 68 03/22/17 12:07 03/30/17 17:15 123 - 140

13C-OCDD 71 03/22/17 12:07 03/30/17 17:15 117 - 157

13C-2,3,7,8-TCDF 55 03/22/17 12:07 03/30/17 17:15 124 - 169

13C-1,2,3,7,8-PeCDF 59 03/22/17 12:07 03/30/17 17:15 124 - 185

13C-2,3,4,7,8-PeCDF 56 03/22/17 12:07 03/30/17 17:15 121 - 178

13C-1,2,3,4,7,8-HxCDF 54 03/22/17 12:07 03/30/17 17:15 126 - 152

13C-1,2,3,6,7,8-HxCDF 59 03/22/17 12:07 03/30/17 17:15 126 - 123

13C-2,3,4,6,7,8-HxCDF 61 03/22/17 12:07 03/30/17 17:15 128 - 136

13C-1,2,3,7,8,9-HxCDF 60 03/22/17 12:07 03/30/17 17:15 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 57 03/22/17 12:07 03/30/17 17:15 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 60 03/22/17 12:07 03/30/17 17:15 126 - 138

13C-OCDF 67 03/22/17 12:07 03/30/17 17:15 117 - 157

37Cl4-2,3,7,8-TCDD 86 35 - 197 03/22/17 12:07 03/30/17 17:15 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-64007-4Client Sample ID: #20170162 AMENDED COMPOSITE P Matrix: SedimentDate Collected: 02/24/17 11:37

Date Received: 03/03/17 09:00

RL EDL

2,3,7,8-TCDD ND 9.6 1.6 pg/L 03/22/17 12:07 03/30/17 18:15 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.45 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,7,8-PeCDD ND

48 0.22 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,4,7,8-HxCDD ND

48 0.25 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,6,7,8-HxCDD ND

48 0.22 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,7,8,9-HxCDD ND

48 0.32 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,4,6,7,8-HpCDD ND

96 0.31 pg/L 03/22/17 12:07 03/30/17 18:15 1OCDD ND

9.6 1.1 pg/L 03/22/17 12:07 03/30/17 18:15 12,3,7,8-TCDF ND

48 0.38 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,7,8-PeCDF ND

48 0.34 pg/L 03/22/17 12:07 03/30/17 18:15 12,3,4,7,8-PeCDF ND

48 0.29 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,4,7,8-HxCDF ND

48 0.29 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,6,7,8-HxCDF ND

48 0.30 pg/L 03/22/17 12:07 03/30/17 18:15 12,3,4,6,7,8-HxCDF ND

48 0.35 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,7,8,9-HxCDF ND

48 0.17 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,4,6,7,8-HpCDF ND

48 0.22 pg/L 03/22/17 12:07 03/30/17 18:15 11,2,3,4,7,8,9-HpCDF ND

96 0.94 pg/L 03/22/17 12:07 03/30/17 18:15 1OCDF ND

13C-2,3,7,8-TCDD 69 25 - 164 03/22/17 12:07 03/30/17 18:15 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 76 03/22/17 12:07 03/30/17 18:15 125 - 181

13C-1,2,3,4,7,8-HxCDD 69 03/22/17 12:07 03/30/17 18:15 132 - 141

13C-1,2,3,6,7,8-HxCDD 75 03/22/17 12:07 03/30/17 18:15 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 72 03/22/17 12:07 03/30/17 18:15 123 - 140

13C-OCDD 68 03/22/17 12:07 03/30/17 18:15 117 - 157

13C-2,3,7,8-TCDF 63 03/22/17 12:07 03/30/17 18:15 124 - 169

13C-1,2,3,7,8-PeCDF 65 03/22/17 12:07 03/30/17 18:15 124 - 185

13C-2,3,4,7,8-PeCDF 66 03/22/17 12:07 03/30/17 18:15 121 - 178

13C-1,2,3,4,7,8-HxCDF 63 03/22/17 12:07 03/30/17 18:15 126 - 152

13C-1,2,3,6,7,8-HxCDF 67 03/22/17 12:07 03/30/17 18:15 126 - 123

13C-2,3,4,6,7,8-HxCDF 66 03/22/17 12:07 03/30/17 18:15 128 - 136

13C-1,2,3,7,8,9-HxCDF 68 03/22/17 12:07 03/30/17 18:15 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 60 03/22/17 12:07 03/30/17 18:15 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 66 03/22/17 12:07 03/30/17 18:15 126 - 138

13C-OCDF 64 03/22/17 12:07 03/30/17 18:15 117 - 157

37Cl4-2,3,7,8-TCDD 86 35 - 197 03/22/17 12:07 03/30/17 18:15 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-64007-5Client Sample ID: #20170163 AMENDED COMPOSITE Q Matrix: SedimentDate Collected: 02/24/17 10:33

Date Received: 03/03/17 09:00

RL EDL

2,3,7,8-TCDD ND 9.6 1.4 pg/L 03/22/17 12:07 03/30/17 19:16 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.57 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,7,8-PeCDD ND

48 0.17 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,4,7,8-HxCDD ND

48 0.18 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,6,7,8-HxCDD ND

48 0.16 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,7,8,9-HxCDD ND

48 0.56 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,4,6,7,8-HpCDD ND

96 0.21 pg/L 03/22/17 12:07 03/30/17 19:16 1OCDD ND

9.6 1.2 pg/L 03/22/17 12:07 03/30/17 19:16 12,3,7,8-TCDF ND

48 0.39 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,7,8-PeCDF ND

48 0.36 pg/L 03/22/17 12:07 03/30/17 19:16 12,3,4,7,8-PeCDF ND

48 0.17 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,4,7,8-HxCDF ND

48 0.17 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,6,7,8-HxCDF ND

48 0.16 pg/L 03/22/17 12:07 03/30/17 19:16 12,3,4,6,7,8-HxCDF ND

48 0.21 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,7,8,9-HxCDF ND

48 0.092 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,4,6,7,8-HpCDF ND

48 0.13 pg/L 03/22/17 12:07 03/30/17 19:16 11,2,3,4,7,8,9-HpCDF ND

96 0.60 pg/L 03/22/17 12:07 03/30/17 19:16 1OCDF ND

13C-2,3,7,8-TCDD 68 25 - 164 03/22/17 12:07 03/30/17 19:16 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 72 03/22/17 12:07 03/30/17 19:16 125 - 181

13C-1,2,3,4,7,8-HxCDD 73 03/22/17 12:07 03/30/17 19:16 132 - 141

13C-1,2,3,6,7,8-HxCDD 76 03/22/17 12:07 03/30/17 19:16 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 78 03/22/17 12:07 03/30/17 19:16 123 - 140

13C-OCDD 87 03/22/17 12:07 03/30/17 19:16 117 - 157

13C-2,3,7,8-TCDF 60 03/22/17 12:07 03/30/17 19:16 124 - 169

13C-1,2,3,7,8-PeCDF 66 03/22/17 12:07 03/30/17 19:16 124 - 185

13C-2,3,4,7,8-PeCDF 65 03/22/17 12:07 03/30/17 19:16 121 - 178

13C-1,2,3,4,7,8-HxCDF 63 03/22/17 12:07 03/30/17 19:16 126 - 152

13C-1,2,3,6,7,8-HxCDF 68 03/22/17 12:07 03/30/17 19:16 126 - 123

13C-2,3,4,6,7,8-HxCDF 68 03/22/17 12:07 03/30/17 19:16 128 - 136

13C-1,2,3,7,8,9-HxCDF 70 03/22/17 12:07 03/30/17 19:16 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 65 03/22/17 12:07 03/30/17 19:16 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 73 03/22/17 12:07 03/30/17 19:16 126 - 138

13C-OCDF 85 03/22/17 12:07 03/30/17 19:16 117 - 157

37Cl4-2,3,7,8-TCDD 88 35 - 197 03/22/17 12:07 03/30/17 19:16 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-64007-6Client Sample ID: #20170168 AMENDED COMPOSITE V Matrix: SedimentDate Collected: 02/24/17 09:30

Date Received: 03/03/17 09:00

RL EDL

2,3,7,8-TCDD ND 9.6 1.2 pg/L 03/22/17 12:07 03/30/17 20:17 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.56 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,7,8-PeCDD ND

48 0.17 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,4,7,8-HxCDD ND

48 0.18 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,6,7,8-HxCDD ND

48 0.16 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,7,8,9-HxCDD ND

48 0.14 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,4,6,7,8-HpCDD ND

96 0.11 pg/L 03/22/17 12:07 03/30/17 20:17 1OCDD 0.78 J q B

9.6 0.83 pg/L 03/22/17 12:07 03/30/17 20:17 12,3,7,8-TCDF ND

48 0.30 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,7,8-PeCDF ND

48 0.29 pg/L 03/22/17 12:07 03/30/17 20:17 12,3,4,7,8-PeCDF ND

48 0.057 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,4,7,8-HxCDF ND

48 0.060 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,6,7,8-HxCDF ND

48 0.056 pg/L 03/22/17 12:07 03/30/17 20:17 12,3,4,6,7,8-HxCDF ND

48 0.063 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,7,8,9-HxCDF ND

48 0.047 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,4,6,7,8-HpCDF ND

48 0.068 pg/L 03/22/17 12:07 03/30/17 20:17 11,2,3,4,7,8,9-HpCDF ND

96 0.66 pg/L 03/22/17 12:07 03/30/17 20:17 1OCDF ND

13C-2,3,7,8-TCDD 73 25 - 164 03/22/17 12:07 03/30/17 20:17 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 78 03/22/17 12:07 03/30/17 20:17 125 - 181

13C-1,2,3,4,7,8-HxCDD 71 03/22/17 12:07 03/30/17 20:17 132 - 141

13C-1,2,3,6,7,8-HxCDD 77 03/22/17 12:07 03/30/17 20:17 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 79 03/22/17 12:07 03/30/17 20:17 123 - 140

13C-OCDD 83 03/22/17 12:07 03/30/17 20:17 117 - 157

13C-2,3,7,8-TCDF 65 03/22/17 12:07 03/30/17 20:17 124 - 169

13C-1,2,3,7,8-PeCDF 70 03/22/17 12:07 03/30/17 20:17 124 - 185

13C-2,3,4,7,8-PeCDF 69 03/22/17 12:07 03/30/17 20:17 121 - 178

13C-1,2,3,4,7,8-HxCDF 61 03/22/17 12:07 03/30/17 20:17 126 - 152

13C-1,2,3,6,7,8-HxCDF 62 03/22/17 12:07 03/30/17 20:17 126 - 123

13C-2,3,4,6,7,8-HxCDF 69 03/22/17 12:07 03/30/17 20:17 128 - 136

13C-1,2,3,7,8,9-HxCDF 73 03/22/17 12:07 03/30/17 20:17 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 66 03/22/17 12:07 03/30/17 20:17 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 71 03/22/17 12:07 03/30/17 20:17 126 - 138

13C-OCDF 81 03/22/17 12:07 03/30/17 20:17 117 - 157

37Cl4-2,3,7,8-TCDD 89 35 - 197 03/22/17 12:07 03/30/17 20:17 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-64007-10Client Sample ID: #20170158 AMENDED COMPOSITE L Matrix: SedimentDate Collected: 02/27/17 10:15

Date Received: 03/03/17 09:00

RL EDL

2,3,7,8-TCDD ND 9.7 0.95 pg/L 03/22/17 12:07 03/31/17 03:46 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.45 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,7,8-PeCDD ND

48 0.56 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,4,7,8-HxCDD ND

48 0.60 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,6,7,8-HxCDD ND

48 0.54 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,7,8,9-HxCDD ND

48 0.27 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,4,6,7,8-HpCDD ND

97 0.27 pg/L 03/22/17 12:07 03/31/17 03:46 1OCDD ND

9.7 0.68 pg/L 03/22/17 12:07 03/31/17 03:46 12,3,7,8-TCDF ND

48 0.24 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,7,8-PeCDF ND

48 0.23 pg/L 03/22/17 12:07 03/31/17 03:46 12,3,4,7,8-PeCDF ND

48 0.15 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,4,7,8-HxCDF ND

48 0.14 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,6,7,8-HxCDF ND

48 0.14 pg/L 03/22/17 12:07 03/31/17 03:46 12,3,4,6,7,8-HxCDF ND

48 0.20 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,7,8,9-HxCDF ND

48 0.066 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,4,6,7,8-HpCDF ND

48 0.11 pg/L 03/22/17 12:07 03/31/17 03:46 11,2,3,4,7,8,9-HpCDF ND

97 0.55 pg/L 03/22/17 12:07 03/31/17 03:46 1OCDF ND

13C-2,3,7,8-TCDD 57 25 - 164 03/22/17 12:07 03/31/17 03:46 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 62 03/22/17 12:07 03/31/17 03:46 125 - 181

13C-1,2,3,4,7,8-HxCDD 67 03/22/17 12:07 03/31/17 03:46 132 - 141

13C-1,2,3,6,7,8-HxCDD 70 03/22/17 12:07 03/31/17 03:46 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 69 03/22/17 12:07 03/31/17 03:46 123 - 140

13C-OCDD 64 03/22/17 12:07 03/31/17 03:46 117 - 157

13C-2,3,7,8-TCDF 56 03/22/17 12:07 03/31/17 03:46 124 - 169

13C-1,2,3,7,8-PeCDF 59 03/22/17 12:07 03/31/17 03:46 124 - 185

13C-2,3,4,7,8-PeCDF 57 03/22/17 12:07 03/31/17 03:46 121 - 178

13C-1,2,3,4,7,8-HxCDF 63 03/22/17 12:07 03/31/17 03:46 126 - 152

13C-1,2,3,6,7,8-HxCDF 65 03/22/17 12:07 03/31/17 03:46 126 - 123

13C-2,3,4,6,7,8-HxCDF 67 03/22/17 12:07 03/31/17 03:46 128 - 136

13C-1,2,3,7,8,9-HxCDF 61 03/22/17 12:07 03/31/17 03:46 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 63 03/22/17 12:07 03/31/17 03:46 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 61 03/22/17 12:07 03/31/17 03:46 126 - 138

13C-OCDF 66 03/22/17 12:07 03/31/17 03:46 117 - 157

37Cl4-2,3,7,8-TCDD 79 35 - 197 03/22/17 12:07 03/31/17 03:46 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-64007-11Client Sample ID: #20170160 AMENDED COMPOSITE N Matrix: SedimentDate Collected: 02/27/17 09:15

Date Received: 03/03/17 09:00

RL EDL

2,3,7,8-TCDD ND 9.6 1.2 pg/L 03/22/17 12:07 03/31/17 04:47 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.44 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,7,8-PeCDD ND

48 0.012 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,4,7,8-HxCDD ND

48 0.012 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,6,7,8-HxCDD ND

48 0.011 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,7,8,9-HxCDD ND

48 0.24 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,4,6,7,8-HpCDD ND

96 0.35 pg/L 03/22/17 12:07 03/31/17 04:47 1OCDD 1.9 J B q

9.6 0.72 pg/L 03/22/17 12:07 03/31/17 04:47 12,3,7,8-TCDF ND

48 0.27 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,7,8-PeCDF ND

48 0.26 pg/L 03/22/17 12:07 03/31/17 04:47 12,3,4,7,8-PeCDF ND

48 0.19 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,4,7,8-HxCDF ND

48 0.18 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,6,7,8-HxCDF ND

48 0.18 pg/L 03/22/17 12:07 03/31/17 04:47 12,3,4,6,7,8-HxCDF ND

48 0.27 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,7,8,9-HxCDF ND

48 0.21 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,4,6,7,8-HpCDF ND

48 0.34 pg/L 03/22/17 12:07 03/31/17 04:47 11,2,3,4,7,8,9-HpCDF ND

96 0.48 pg/L 03/22/17 12:07 03/31/17 04:47 1OCDF ND

13C-2,3,7,8-TCDD 63 25 - 164 03/22/17 12:07 03/31/17 04:47 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 72 03/22/17 12:07 03/31/17 04:47 125 - 181

13C-1,2,3,4,7,8-HxCDD 72 03/22/17 12:07 03/31/17 04:47 132 - 141

13C-1,2,3,6,7,8-HxCDD 76 03/22/17 12:07 03/31/17 04:47 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 74 03/22/17 12:07 03/31/17 04:47 123 - 140

13C-OCDD 72 03/22/17 12:07 03/31/17 04:47 117 - 157

13C-2,3,7,8-TCDF 62 03/22/17 12:07 03/31/17 04:47 124 - 169

13C-1,2,3,7,8-PeCDF 70 03/22/17 12:07 03/31/17 04:47 124 - 185

13C-2,3,4,7,8-PeCDF 65 03/22/17 12:07 03/31/17 04:47 121 - 178

13C-1,2,3,4,7,8-HxCDF 70 03/22/17 12:07 03/31/17 04:47 126 - 152

13C-1,2,3,6,7,8-HxCDF 70 03/22/17 12:07 03/31/17 04:47 126 - 123

13C-2,3,4,6,7,8-HxCDF 71 03/22/17 12:07 03/31/17 04:47 128 - 136

13C-1,2,3,7,8,9-HxCDF 62 03/22/17 12:07 03/31/17 04:47 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 69 03/22/17 12:07 03/31/17 04:47 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 64 03/22/17 12:07 03/31/17 04:47 126 - 138

13C-OCDF 70 03/22/17 12:07 03/31/17 04:47 117 - 157

37Cl4-2,3,7,8-TCDD 85 35 - 197 03/22/17 12:07 03/31/17 04:47 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-64007-12Client Sample ID: #20170169 AMENDED COMPOSITE W Matrix: SedimentDate Collected: 02/27/17 10:40

Date Received: 03/03/17 09:00

RL EDL

2,3,7,8-TCDD ND 9.6 1.1 pg/L 03/22/17 12:07 03/31/17 05:47 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.52 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,7,8-PeCDD ND

48 0.24 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,4,7,8-HxCDD ND

48 0.27 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,6,7,8-HxCDD ND

48 0.23 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,7,8,9-HxCDD ND

48 0.21 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,4,6,7,8-HpCDD ND

96 0.59 pg/L 03/22/17 12:07 03/31/17 05:47 1OCDD ND

9.6 0.64 pg/L 03/22/17 12:07 03/31/17 05:47 12,3,7,8-TCDF ND

48 0.30 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,7,8-PeCDF ND

48 0.29 pg/L 03/22/17 12:07 03/31/17 05:47 12,3,4,7,8-PeCDF ND

48 0.15 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,4,7,8-HxCDF ND

48 0.14 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,6,7,8-HxCDF ND

48 0.15 pg/L 03/22/17 12:07 03/31/17 05:47 12,3,4,6,7,8-HxCDF ND

48 0.22 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,7,8,9-HxCDF ND

48 0.13 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,4,6,7,8-HpCDF ND

48 0.21 pg/L 03/22/17 12:07 03/31/17 05:47 11,2,3,4,7,8,9-HpCDF ND

96 0.79 pg/L 03/22/17 12:07 03/31/17 05:47 1OCDF ND

13C-2,3,7,8-TCDD 65 25 - 164 03/22/17 12:07 03/31/17 05:47 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 64 03/22/17 12:07 03/31/17 05:47 125 - 181

13C-1,2,3,4,7,8-HxCDD 74 03/22/17 12:07 03/31/17 05:47 132 - 141

13C-1,2,3,6,7,8-HxCDD 79 03/22/17 12:07 03/31/17 05:47 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 68 03/22/17 12:07 03/31/17 05:47 123 - 140

13C-OCDD 60 03/22/17 12:07 03/31/17 05:47 117 - 157

13C-2,3,7,8-TCDF 60 03/22/17 12:07 03/31/17 05:47 124 - 169

13C-1,2,3,7,8-PeCDF 65 03/22/17 12:07 03/31/17 05:47 124 - 185

13C-2,3,4,7,8-PeCDF 62 03/22/17 12:07 03/31/17 05:47 121 - 178

13C-1,2,3,4,7,8-HxCDF 71 03/22/17 12:07 03/31/17 05:47 126 - 152

13C-1,2,3,6,7,8-HxCDF 72 03/22/17 12:07 03/31/17 05:47 126 - 123

13C-2,3,4,6,7,8-HxCDF 71 03/22/17 12:07 03/31/17 05:47 128 - 136

13C-1,2,3,7,8,9-HxCDF 62 03/22/17 12:07 03/31/17 05:47 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 67 03/22/17 12:07 03/31/17 05:47 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 60 03/22/17 12:07 03/31/17 05:47 126 - 138

13C-OCDF 61 03/22/17 12:07 03/31/17 05:47 117 - 157

37Cl4-2,3,7,8-TCDD 83 35 - 197 03/22/17 12:07 03/31/17 05:47 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Default Detection Limits Client: Battelle TestAmerica Job ID: 180-64007-2 Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East Prep: HRMS-Sepf

501,2,3,4,6,7,8-HpCDD pg/L

Analyte Units MethodRL

1613B

501,2,3,4,6,7,8-HpCDF pg/L 1613B

501,2,3,4,7,8,9-HpCDF pg/L 1613B

501,2,3,4,7,8-HxCDD pg/L 1613B

501,2,3,4,7,8-HxCDF pg/L 1613B

501,2,3,6,7,8-HxCDD pg/L 1613B

501,2,3,6,7,8-HxCDF pg/L 1613B

501,2,3,7,8,9-HxCDD pg/L 1613B

501,2,3,7,8,9-HxCDF pg/L 1613B

501,2,3,7,8-PeCDD pg/L 1613B

501,2,3,7,8-PeCDF pg/L 1613B

502,3,4,6,7,8-HxCDF pg/L 1613B

502,3,4,7,8-PeCDF pg/L 1613B

102,3,7,8-TCDD pg/L 1613B

102,3,7,8-TCDF pg/L 1613B

100OCDD pg/L 1613B

100OCDF pg/L 1613B

Surrogate Summary

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: Total/NAMatrix: Sediment

Lab Sample ID Client Sample ID (35-197)

37TCDD

82LB 140-9748/19-A

Percent Surrogate Recovery (Acceptance Limits)

Method Blank

92MB 140-9748/20-A Method Blank

Surrogate Legend

37TCDD = 37Cl4-2,3,7,8-TCDD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: Total/NAMatrix: Sediment

Lab Sample ID Client Sample ID (31-191)

37TCDD

87LCS 140-9748/21-A

Percent Surrogate Recovery (Acceptance Limits)

Lab Control Sample

Surrogate Legend

37TCDD = 37Cl4-2,3,7,8-TCDD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: SPLP EastMatrix: Sediment

Lab Sample ID Client Sample ID (35-197)

37TCDD

88180-64007-1

Percent Surrogate Recovery (Acceptance Limits)

#20170157 AMENDED COMPOSITE K

88180-64007-2 #20170159 AMENDED COMPOSITE M

86180-64007-3 #20170161 AMENDED COMPOSITE O

86180-64007-4 #20170162 AMENDED COMPOSITE P

88180-64007-5 #20170163 AMENDED COMPOSITE Q

89180-64007-6 #20170168 AMENDED COMPOSITE V

79180-64007-10 #20170158 AMENDED COMPOSITE L

85180-64007-11 #20170160 AMENDED COMPOSITE N

83180-64007-12 #20170169 AMENDED COMPOSITE W

Surrogate Legend

37TCDD = 37Cl4-2,3,7,8-TCDD

Isotope Dilution Summary

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: Total/NAMatrix: Sediment

Lab Sample ID Client Sample ID (25-164) (25-181) (32-141) (28-130) (23-140) (17-157) (24-169) (24-185)

TCDD PeCDD HxCDD1 HxCDD2 HpCDD OCDD TCDF PeCDF1

71 70 74 80 67 61 72 69LB 140-9748/19-A

Percent Isotope Dilution Recovery (Acceptance Limits)

Method Blank

73 73 70 7075 69 71 71MB 140-9748/20-A Method Blank

Lab Sample ID Client Sample ID (21-178) (26-152) (26-123) (28-136) (29-147) (28-143) (26-138) (17-157)

PeCDF2 HxCDF1 HxCDF2 HxCDF3 HxCDF4 HpCDF1 HpCDF2 13C-OCDF

66 75 80 77 65 69 64 64LB 140-9748/19-A

Percent Isotope Dilution Recovery (Acceptance Limits)

Method Blank

69 64 69 7272 64 72 77MB 140-9748/20-A Method Blank

Surrogate Legend

TCDD = 13C-2,3,7,8-TCDD

PeCDD = 13C-1,2,3,7,8-PeCDD

HxCDD1 = 13C-1,2,3,4,7,8-HxCDD

HxCDD2 = 13C-1,2,3,6,7,8-HxCDD

HpCDD = 13C-1,2,3,4,6,7,8-HpCDD

OCDD = 13C-OCDD

TCDF = 13C-2,3,7,8-TCDF

PeCDF1 = 13C-1,2,3,7,8-PeCDF

PeCDF2 = 13C-2,3,4,7,8-PeCDF

HxCDF1 = 13C-1,2,3,4,7,8-HxCDF

HxCDF2 = 13C-1,2,3,6,7,8-HxCDF

HxCDF3 = 13C-2,3,4,6,7,8-HxCDF

HxCDF4 = 13C-1,2,3,7,8,9-HxCDF

HpCDF1 = 13C-1,2,3,4,6,7,8-HpCDF

HpCDF2 = 13C-1,2,3,4,7,8,9-HpCDF

13C-OCDF = 13C-OCDF

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: Total/NAMatrix: Sediment

Lab Sample ID Client Sample ID (20-175) (21-227) (21-193) (25-163) (26-166) (13-199) (22-152) (21-192)

TCDD PeCDD HxCDD1 HxCDD2 HpCDD OCDD TCDF PeCDF1

74 77 75 74 71 73 74 77LCS 140-9748/21-A

Percent Isotope Dilution Recovery (Acceptance Limits)

Lab Control Sample

Lab Sample ID Client Sample ID (13-328) (19-202) (21-159) (22-176) (17-205) (21-158) (20-186) (13-199)

PeCDF2 HxCDF1 HxCDF2 HxCDF3 HxCDF4 HpCDF1 HpCDF2 13C-OCDF

72 71 75 72 79 66 71 82LCS 140-9748/21-A

Percent Isotope Dilution Recovery (Acceptance Limits)

Lab Control Sample

Surrogate Legend

TCDD = 13C-2,3,7,8-TCDD

PeCDD = 13C-1,2,3,7,8-PeCDD

HxCDD1 = 13C-1,2,3,4,7,8-HxCDD

HxCDD2 = 13C-1,2,3,6,7,8-HxCDD

HpCDD = 13C-1,2,3,4,6,7,8-HpCDD

OCDD = 13C-OCDD

TCDF = 13C-2,3,7,8-TCDF

PeCDF1 = 13C-1,2,3,7,8-PeCDF

PeCDF2 = 13C-2,3,4,7,8-PeCDF

HxCDF1 = 13C-1,2,3,4,7,8-HxCDF

Isotope Dilution Summary

Project/Site: USACE/NYD

HxCDF2 = 13C-1,2,3,6,7,8-HxCDF

HxCDF3 = 13C-2,3,4,6,7,8-HxCDF

HxCDF4 = 13C-1,2,3,7,8,9-HxCDF

HpCDF1 = 13C-1,2,3,4,6,7,8-HpCDF

HpCDF2 = 13C-1,2,3,4,7,8,9-HpCDF

13C-OCDF = 13C-OCDF

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: SPLP EastMatrix: Sediment

Lab Sample ID Client Sample ID (25-164) (25-181) (32-141) (28-130) (23-140) (17-157) (24-169) (24-185)

TCDD PeCDD HxCDD1 HxCDD2 HpCDD OCDD TCDF PeCDF1

63 68 65 64 68 70 56 60180-64007-1

Percent Isotope Dilution Recovery (Acceptance Limits)

#20170157 AMENDED COMPOSITE K

67 71 70 7372 75 63 66180-64007-2 #20170159 AMENDED COMPOSITE M

60 63 64 6866 71 55 59180-64007-3 #20170161 AMENDED COMPOSITE O

69 76 69 7275 68 63 65180-64007-4 #20170162 AMENDED COMPOSITE P

68 72 73 7876 87 60 66180-64007-5 #20170163 AMENDED COMPOSITE Q

73 78 71 7977 83 65 70180-64007-6 #20170168 AMENDED COMPOSITE V

57 62 67 6970 64 56 59180-64007-10 #20170158 AMENDED COMPOSITE L

63 72 72 7476 72 62 70180-64007-11 #20170160 AMENDED COMPOSITE N

65 64 74 6879 60 60 65180-64007-12 #20170169 AMENDED COMPOSITE W

Lab Sample ID Client Sample ID (21-178) (26-152) (26-123) (28-136) (29-147) (28-143) (26-138) (17-157)

PeCDF2 HxCDF1 HxCDF2 HxCDF3 HxCDF4 HpCDF1 HpCDF2 13C-OCDF

60 57 59 60 61 57 59 64180-64007-1

Percent Isotope Dilution Recovery (Acceptance Limits)

#20170157 AMENDED COMPOSITE K

63 60 64 6665 62 66 72180-64007-2 #20170159 AMENDED COMPOSITE M

56 54 59 6061 57 60 67180-64007-3 #20170161 AMENDED COMPOSITE O

66 63 67 6866 60 66 64180-64007-4 #20170162 AMENDED COMPOSITE P

65 63 68 7068 65 73 85180-64007-5 #20170163 AMENDED COMPOSITE Q

69 61 62 7369 66 71 81180-64007-6 #20170168 AMENDED COMPOSITE V

57 63 65 6167 63 61 66180-64007-10 #20170158 AMENDED COMPOSITE L

65 70 70 6271 69 64 70180-64007-11 #20170160 AMENDED COMPOSITE N

62 71 72 6271 67 60 61180-64007-12 #20170169 AMENDED COMPOSITE W

Surrogate Legend

TCDD = 13C-2,3,7,8-TCDD

PeCDD = 13C-1,2,3,7,8-PeCDD

HxCDD1 = 13C-1,2,3,4,7,8-HxCDD

HxCDD2 = 13C-1,2,3,6,7,8-HxCDD

HpCDD = 13C-1,2,3,4,6,7,8-HpCDD

OCDD = 13C-OCDD

TCDF = 13C-2,3,7,8-TCDF

PeCDF1 = 13C-1,2,3,7,8-PeCDF

PeCDF2 = 13C-2,3,4,7,8-PeCDF

HxCDF1 = 13C-1,2,3,4,7,8-HxCDF

HxCDF2 = 13C-1,2,3,6,7,8-HxCDF

HxCDF3 = 13C-2,3,4,6,7,8-HxCDF

HxCDF4 = 13C-1,2,3,7,8,9-HxCDF

HpCDF1 = 13C-1,2,3,4,6,7,8-HpCDF

HpCDF2 = 13C-1,2,3,4,7,8,9-HpCDF

13C-OCDF = 13C-OCDF

QC Sample Results

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS)

Client Sample ID: Method BlankLab Sample ID: LB 140-9748/19-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 10116 Prep Batch: 9748

RL EDL

2,3,7,8-TCDD ND 9.6 2.4 pg/L 03/22/17 12:07 03/31/17 02:46 1

LB LB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

ND 0.6848 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,7,8-PeCDD

ND 0.7348 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,4,7,8-HxCDD

ND 0.7448 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,6,7,8-HxCDD

ND 0.6848 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,7,8,9-HxCDD

ND 1.448 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,4,6,7,8-HpCDD

2.02 J q 0.4996 pg/L 03/22/17 12:07 03/31/17 02:46 1OCDD

ND 0.909.6 pg/L 03/22/17 12:07 03/31/17 02:46 12,3,7,8-TCDF

ND 0.5448 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,7,8-PeCDF

ND 0.4548 pg/L 03/22/17 12:07 03/31/17 02:46 12,3,4,7,8-PeCDF

ND 0.5748 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,4,7,8-HxCDF

ND 0.5248 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,6,7,8-HxCDF

ND 0.6248 pg/L 03/22/17 12:07 03/31/17 02:46 12,3,4,6,7,8-HxCDF

ND 0.8948 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,7,8,9-HxCDF

ND 0.4648 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,4,6,7,8-HpCDF

ND 0.7248 pg/L 03/22/17 12:07 03/31/17 02:46 11,2,3,4,7,8,9-HpCDF

ND 1.796 pg/L 03/22/17 12:07 03/31/17 02:46 1OCDF

13C-2,3,7,8-TCDD 71 25 - 164 03/31/17 02:46 1

LB LB

Isotope Dilution

03/22/17 12:07

Dil FacPrepared AnalyzedQualifier Limits%Recovery

70 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,7,8-PeCDD 25 - 181

74 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,4,7,8-HxCDD 32 - 141

80 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,6,7,8-HxCDD 28 - 130

67 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,4,6,7,8-HpCDD 23 - 140

61 03/22/17 12:07 03/31/17 02:46 113C-OCDD 17 - 157

72 03/22/17 12:07 03/31/17 02:46 113C-2,3,7,8-TCDF 24 - 169

69 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,7,8-PeCDF 24 - 185

66 03/22/17 12:07 03/31/17 02:46 113C-2,3,4,7,8-PeCDF 21 - 178

75 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,4,7,8-HxCDF 26 - 152

80 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,6,7,8-HxCDF 26 - 123

77 03/22/17 12:07 03/31/17 02:46 113C-2,3,4,6,7,8-HxCDF 28 - 136

65 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,7,8,9-HxCDF 29 - 147

69 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,4,6,7,8-HpCDF 28 - 143

64 03/22/17 12:07 03/31/17 02:46 113C-1,2,3,4,7,8,9-HpCDF 26 - 138

64 03/22/17 12:07 03/31/17 02:46 113C-OCDF 17 - 157

37Cl4-2,3,7,8-TCDD 82 35 - 197 03/31/17 02:46 1

LB LB

Surrogate

03/22/17 12:07

Dil FacPrepared AnalyzedQualifier Limits%Recovery

Client Sample ID: Method BlankLab Sample ID: MB 140-9748/20-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 10063 Prep Batch: 9748

RL EDL

2,3,7,8-TCDD ND 10 1.7 pg/L 03/22/17 12:07 03/30/17 01:17 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

ND 1.050 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,7,8-PeCDD

ND 0.2650 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,7,8-HxCDD

ND 0.2850 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,6,7,8-HxCDD

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) (Continued)

Client Sample ID: Method BlankLab Sample ID: MB 140-9748/20-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 10063 Prep Batch: 9748

RL EDL

1,2,3,7,8,9-HxCDD 0.769 J 50 0.25 pg/L 03/22/17 12:07 03/30/17 01:17 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

ND 0.5150 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,6,7,8-HpCDD

7.49 J 0.54100 pg/L 03/22/17 12:07 03/30/17 01:17 1OCDD

ND 0.9510 pg/L 03/22/17 12:07 03/30/17 01:17 12,3,7,8-TCDF

ND 0.3750 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,7,8-PeCDF

ND 0.3450 pg/L 03/22/17 12:07 03/30/17 01:17 12,3,4,7,8-PeCDF

ND 0.3150 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,7,8-HxCDF

ND 0.3250 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,6,7,8-HxCDF

ND 0.3150 pg/L 03/22/17 12:07 03/30/17 01:17 12,3,4,6,7,8-HxCDF

ND 0.4050 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,7,8,9-HxCDF

ND 0.1750 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,6,7,8-HpCDF

0.410 J q 0.2250 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,7,8,9-HpCDF

4.90 J q 1.0100 pg/L 03/22/17 12:07 03/30/17 01:17 1OCDF

13C-2,3,7,8-TCDD 73 25 - 164 03/30/17 01:17 1

MB MB

Isotope Dilution

03/22/17 12:07

Dil FacPrepared AnalyzedQualifier Limits%Recovery

73 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,7,8-PeCDD 25 - 181

70 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,7,8-HxCDD 32 - 141

75 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,6,7,8-HxCDD 28 - 130

70 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,6,7,8-HpCDD 23 - 140

69 03/22/17 12:07 03/30/17 01:17 113C-OCDD 17 - 157

71 03/22/17 12:07 03/30/17 01:17 113C-2,3,7,8-TCDF 24 - 169

71 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,7,8-PeCDF 24 - 185

69 03/22/17 12:07 03/30/17 01:17 113C-2,3,4,7,8-PeCDF 21 - 178

64 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,7,8-HxCDF 26 - 152

69 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,6,7,8-HxCDF 26 - 123

72 03/22/17 12:07 03/30/17 01:17 113C-2,3,4,6,7,8-HxCDF 28 - 136

72 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,7,8,9-HxCDF 29 - 147

64 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,6,7,8-HpCDF 28 - 143

72 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,7,8,9-HpCDF 26 - 138

77 03/22/17 12:07 03/30/17 01:17 113C-OCDF 17 - 157

37Cl4-2,3,7,8-TCDD 92 35 - 197 03/30/17 01:17 1

MB MB

Surrogate

03/22/17 12:07

Dil FacPrepared AnalyzedQualifier Limits%Recovery

Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-9748/21-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 10063 Prep Batch: 9748

2,3,7,8-TCDD 200 203 pg/L 102 67 - 158

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

1,2,3,7,8-PeCDD 1000 950 pg/L 95 70 - 142

1,2,3,4,7,8-HxCDD 1000 956 pg/L 96 70 - 164

1,2,3,6,7,8-HxCDD 1000 948 pg/L 95 76 - 134

1,2,3,7,8,9-HxCDD 1000 1010 pg/L 101 64 - 162

1,2,3,4,6,7,8-HpCDD 1000 937 pg/L 94 70 - 140

OCDD 2000 1790 pg/L 90 78 - 144

2,3,7,8-TCDF 200 196 pg/L 98 75 - 158

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) (Continued)

Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-9748/21-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 10063 Prep Batch: 9748

1,2,3,7,8-PeCDF 1000 865 pg/L 86 80 - 134

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

2,3,4,7,8-PeCDF 1000 968 pg/L 97 68 - 160

1,2,3,4,7,8-HxCDF 1000 939 pg/L 94 72 - 134

1,2,3,6,7,8-HxCDF 1000 919 pg/L 92 84 - 130

2,3,4,6,7,8-HxCDF 1000 910 pg/L 91 70 - 156

1,2,3,7,8,9-HxCDF 1000 914 pg/L 91 78 - 130

1,2,3,4,6,7,8-HpCDF 1000 964 pg/L 96 82 - 122

1,2,3,4,7,8,9-HpCDF 1000 937 pg/L 94 78 - 138

OCDF 2000 1690 pg/L 85 63 - 170

13C-2,3,7,8-TCDD 20 - 175

Isotope Dilution

LCS LCS

Qualifier Limits%Recovery

7713C-1,2,3,7,8-PeCDD 21 - 227

7513C-1,2,3,4,7,8-HxCDD 21 - 193

7413C-1,2,3,6,7,8-HxCDD 25 - 163

7113C-1,2,3,4,6,7,8-HpCDD 26 - 166

7313C-OCDD 13 - 199

7413C-2,3,7,8-TCDF 22 - 152

7713C-1,2,3,7,8-PeCDF 21 - 192

7213C-2,3,4,7,8-PeCDF 13 - 328

7113C-1,2,3,4,7,8-HxCDF 19 - 202

7513C-1,2,3,6,7,8-HxCDF 21 - 159

7213C-2,3,4,6,7,8-HxCDF 22 - 176

7913C-1,2,3,7,8,9-HxCDF 17 - 205

6613C-1,2,3,4,6,7,8-HpCDF 21 - 158

7113C-1,2,3,4,7,8,9-HpCDF 20 - 186

8213C-OCDF 13 - 199

37Cl4-2,3,7,8-TCDD 31 - 191

Surrogate

LCS LCS

Qualifier Limits%Recovery

QC Association Summary

Project/Site: USACE/NYD

Specialty Organics

Prep Batch: 9748

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment HRMS-Sepf180-64007-1 #20170157 AMENDED COMPOSITE K SPLP East

Sediment HRMS-Sepf180-64007-2 #20170159 AMENDED COMPOSITE M SPLP East

Sediment HRMS-Sepf180-64007-3 #20170161 AMENDED COMPOSITE O SPLP East

Sediment HRMS-Sepf180-64007-4 #20170162 AMENDED COMPOSITE P SPLP East

Sediment HRMS-Sepf180-64007-5 #20170163 AMENDED COMPOSITE Q SPLP East

Sediment HRMS-Sepf180-64007-6 #20170168 AMENDED COMPOSITE V SPLP East

Sediment HRMS-Sepf180-64007-10 #20170158 AMENDED COMPOSITE L SPLP East

Sediment HRMS-Sepf180-64007-11 #20170160 AMENDED COMPOSITE N SPLP East

Sediment HRMS-Sepf180-64007-12 #20170169 AMENDED COMPOSITE W SPLP East

Sediment HRMS-SepfLB 140-9748/19-A Method Blank Total/NA

Sediment HRMS-SepfMB 140-9748/20-A Method Blank Total/NA

Sediment HRMS-SepfLCS 140-9748/21-A Lab Control Sample Total/NA

Analysis Batch: 10063

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 1613B 9748MB 140-9748/20-A Method Blank Total/NA

Sediment 1613B 9748LCS 140-9748/21-A Lab Control Sample Total/NA

Analysis Batch: 10084

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 1613B 9748180-64007-1 #20170157 AMENDED COMPOSITE K SPLP East

Sediment 1613B 9748180-64007-2 #20170159 AMENDED COMPOSITE M SPLP East

Sediment 1613B 9748180-64007-3 #20170161 AMENDED COMPOSITE O SPLP East

Sediment 1613B 9748180-64007-4 #20170162 AMENDED COMPOSITE P SPLP East

Sediment 1613B 9748180-64007-5 #20170163 AMENDED COMPOSITE Q SPLP East

Sediment 1613B 9748180-64007-6 #20170168 AMENDED COMPOSITE V SPLP East

Analysis Batch: 10116

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 1613B 9748180-64007-10 #20170158 AMENDED COMPOSITE L SPLP East

Sediment 1613B 9748180-64007-11 #20170160 AMENDED COMPOSITE N SPLP East

Sediment 1613B 9748180-64007-12 #20170169 AMENDED COMPOSITE W SPLP East

Sediment 1613B 9748LB 140-9748/19-A Method Blank Total/NA

Lab Chronicle

Project/Site: USACE/NYD

Client Sample ID: #20170157 AMENDED COMPOSITE K Lab Sample ID: 180-64007-1 Matrix: SedimentDate Collected: 02/24/17 09:55

Date Received: 03/03/17 09:00

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1041.7 mL 20 uL

Analysis 1613B 1 10084 03/30/17 15:14 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170159 AMENDED COMPOSITE M Lab Sample ID: 180-64007-2 Matrix: SedimentDate Collected: 02/24/17 13:10

Date Received: 03/03/17 09:00

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1039.9 mL 20 uL

Analysis 1613B 1 10084 03/30/17 16:14 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170161 AMENDED COMPOSITE O Lab Sample ID: 180-64007-3 Matrix: SedimentDate Collected: 02/24/17 12:41

Date Received: 03/03/17 09:00

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1035.8 mL 20 uL

Analysis 1613B 1 10084 03/30/17 17:15 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170162 AMENDED COMPOSITE P Lab Sample ID: 180-64007-4 Matrix: SedimentDate Collected: 02/24/17 11:37

Date Received: 03/03/17 09:00

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1044 mL 20 uL

Analysis 1613B 1 10084 03/30/17 18:15 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170163 AMENDED COMPOSITE Q Lab Sample ID: 180-64007-5 Matrix: SedimentDate Collected: 02/24/17 10:33

Date Received: 03/03/17 09:00

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1040 mL 20 uL

Analysis 1613B 1 10084 03/30/17 19:16 KBL TAL KNXSPLP East

M2AInstrument ID:

Lab Chronicle

Project/Site: USACE/NYD

Client Sample ID: #20170168 AMENDED COMPOSITE V Lab Sample ID: 180-64007-6 Matrix: SedimentDate Collected: 02/24/17 09:30

Date Received: 03/03/17 09:00

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1045.6 mL 20 uL

Analysis 1613B 1 10084 03/30/17 20:17 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170158 AMENDED COMPOSITE L Lab Sample ID: 180-64007-10 Matrix: SedimentDate Collected: 02/27/17 10:15

Date Received: 03/03/17 09:00

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1035.2 mL 20 uL

Analysis 1613B 1 10116 03/31/17 03:46 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170160 AMENDED COMPOSITE N Lab Sample ID: 180-64007-11 Matrix: SedimentDate Collected: 02/27/17 09:15

Date Received: 03/03/17 09:00

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1039.4 mL 20 uL

Analysis 1613B 1 10116 03/31/17 04:47 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170169 AMENDED COMPOSITE W Lab Sample ID: 180-64007-12 Matrix: SedimentDate Collected: 02/27/17 10:40

Date Received: 03/03/17 09:00

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1038.2 mL 20 uL

Analysis 1613B 1 10116 03/31/17 05:47 KBL TAL KNXSPLP East

M2AInstrument ID:

Laboratory References:

TAL KNX = TestAmerica Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000

Analyst References:

Lab: TAL KNX

Batch Type: Prep

SSS = Samuel Stockton

Batch Type: Analysis

KBL = Kathryn Lay

Certification Summary

Project/Site: USACE/NYD

Laboratory: TestAmerica Pittsburgh The certifications listed below are applicable to this report.

Authority Program EPA Region Certification ID Expiration Date

New Jersey PA0052NELAP 06-30-17

New York NELAP 2 11182 03-31-17 *

Laboratory: TestAmerica Knoxville All certifications held by this laboratory are listed. Not all certifications are applicable to this report.

Authority Program EPA Region Certification ID Expiration Date

N/AAFCEE

Arkansas DEQ State Program 6 88-0688 06-16-17

California State Program 9 2423 06-30-18

Colorado State Program 8 TN00009 02-28-18

Connecticut State Program 1 PH-0223 09-30-17

Florida NELAP 4 E87177 06-30-17

Georgia State Program 4 906 04-13-17

Hawaii State Program 9 N/A 04-13-17

Kansas NELAP 7 E-10349 10-31-17

Kentucky (DW) State Program 4 90101 12-31-17

L-A-B DoD ELAP L2311 02-13-19

Louisiana NELAP 6 83979 06-30-17

Louisiana (DW) NELAP 6 LA160005 12-31-17

Maryland State Program 3 277 03-31-18

Michigan State Program 5 9933 04-13-17

Nevada State Program 9 TN00009 07-31-17

New Jersey NELAP 2 TN001 06-30-17

New York NELAP 2 10781 03-31-17 *

North Carolina (DW) State Program 4 21705 07-31-17

North Carolina (WW/SW) State Program 4 64 12-31-17

Ohio VAP State Program 5 CL0059 11-22-18

Oklahoma State Program 6 9415 08-31-17

Pennsylvania NELAP 3 68-00576 12-31-17

Tennessee State Program 4 2014 04-13-17

Texas NELAP 6 T104704380-16-9 08-31-17

USDA Federal P330-13-00262 08-20-19

Utah NELAP 8 TN00009 07-31-17

Virginia NELAP 3 460176 09-14-17

Washington State Program 10 C593 01-19-18

West Virginia (DW) State Program 3 9955C 12-31-17

West Virginia DEP State Program 3 345 04-30-17

Wisconsin State Program 5 998044300 08-31-17

TestAmerica…

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