J63900-2_Std_Tal_L4_Final_Report.pdf

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Attached to: Maintenance Dredging of Newark Bay, New Jersey Federal Navigation Project
Solicitation number: W912DS18B0006
Issued by: Department of the Army Corps of Engineers Engineering District New York

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J63900-2 Std_Tal_L4 Final Report

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ANALYTICAL REPORT

Job Number: 180-63900-2

Job Description: USACE/NYD

For:

Battelle

397 Washington Street Duxbury, MA 02332

Attention: Elisabeth Barrows

Approved for release.

Carrie L Gamber Senior Project Manager

3/31/2017 11:53 AM

Carrie L Gamber, Senior Project Manager 301 Alpha Drive, Pittsburgh, PA, 15238

(412)963-2428 carrie.gamber@testamericainc.com

03/31/2017

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to the NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory. This report is confidential and is intended for the sole use of TestAmerica and its client. All questions regarding this report should be directed to the TestAmerica Project Manager or designee who has signed this report.

TestAmerica Laboratories, Inc.

TestAmerica Pittsburgh 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238

Tel (412) 963-7058 Fax (412) 963-2468 www.testamericainc.com mailto:carrie.gamber@testamericainc.com http://www.testamericainc.com http://

Table of Contents Cover Title Page

Data Summaries

Definitions

Case Narrative

Detection Summary

Client Sample Results

Default Detection Limits

Surrogate Summary

Isotope Dilution Summary

QC Sample Results

QC Association

Chronicle

Certification Summary

Method Summary

Sample Summary

Manual Integration Summary

Reagent Traceability

COAs

Organic Sample Data

Dioxin

1613B 1613B QC Summary 1613B Sample Data Standards Data

1613B ICAL Data 1613B Resolution Data

Table of Contents 1613B CCAL Data

Raw QC Data 1613B Tune Data 1613B Blank Data 1613B LCS/LCSD Data 1613B MS/MSD Data

1613B Run Logs 1613B Prep Data

Subcontracted Data

Shipping and Receiving Documents

Client Chain of Custody

Sample Receipt Checklist

Definitions/Glossary TestAmerica Job ID: 180-63900-2Client: Battelle

Project/Site: USACE/NYD

Qualifiers

Dioxin

Qualifier Description

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Qualifier q The reported result is the estimated maximum possible concentration of this analyte, quantitated using the theoretical ion ratio. The measured ion ratio does not meet qualitative identification criteria and indicates a possible interference.

B Compound was found in the blank and sample.

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica Pittsburgh

CASE NARRATIVE

Client: Battelle

Project: USACE/NYD

Report Number: 180-63900-2

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

RECEIPT

The samples were received on 03/01/2017; the samples arrived in good condition, properly preserved and on ice. The temperatures of the 3 coolers at receipt time were 3.6º C, 3.9º C and 4.1º C.

DIOXINS

1,2,3,4,7,8,9-HpCDF, 1,2,3,7,8,9-HxCDD, OCDD and OCDF were detected in method blank MB 140-9748/20-A at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Detection Summary

Project/Site: USACE/NYD

Client Sample ID: #20170152 AMENDED COMPOSITE F Lab Sample ID: 180-63900-8

OCDD

96 pg/L

EDL

0.23

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J B q1.3 1613B

OCDF 96 pg/L0.59 SPLP East12.6 J B 1613B

Client Sample ID: #20170153 AMENDED COMPOSITE G Lab Sample ID: 180-63900-9

OCDF

96 pg/L

EDL

0.64

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J B q1.4 1613B

Client Sample ID: #20170155 AMENDED COMPOSITE I Lab Sample ID: 180-63900-10

1,2,3,4,7,8-HxCDD

50 pg/L

EDL

0.076

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J q0.24 1613B

OCDD 99 pg/L0.39 SPLP East13.1 J B q 1613B

Client Sample ID: #20170164 AMENDED COMPOSITE R Lab Sample ID: 180-63900-11

1,2,3,4,6,7,8-HpCDD

48 pg/L

EDL

0.15

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J0.80 1613B

OCDD 96 pg/L0.25 SPLP East11.8 J B q 1613B

Client Sample ID: #20170165 AMENDED COMPOSITE S Lab Sample ID: 180-63900-12

1,2,3,4,6,7,8-HpCDD

48 pg/L

EDL

0.094

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J q0.26 1613B

Client Sample ID: #20170166 AMENDED COMPOSITE T Lab Sample ID: 180-63900-13

OCDD

96 pg/L

EDL

0.28

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J B q2.7 1613B

Client Sample ID: #20170170 AMENDED COMPOSITE X/N-45 Lab Sample ID: 180-63900-14

OCDD

96 pg/L

EDL

0.27

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1J B q1.4 1613B

TestAmerica Pittsburgh

This Detection Summary does not include radiochemical test results.

Client Sample Results

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-63900-8Client Sample ID: #20170152 AMENDED COMPOSITE F Matrix: SedimentDate Collected: 02/23/17 12:20

Date Received: 03/01/17 09:30

RL EDL

2,3,7,8-TCDD ND 9.6 1.4 pg/L 03/22/17 12:07 03/30/17 02:18 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.44 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,7,8-PeCDD ND

48 0.20 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,4,7,8-HxCDD ND

48 0.23 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,6,7,8-HxCDD ND

48 0.20 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,7,8,9-HxCDD ND

48 0.38 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,4,6,7,8-HpCDD ND

96 0.23 pg/L 03/22/17 12:07 03/30/17 02:18 1OCDD 1.3 J B q

9.6 0.71 pg/L 03/22/17 12:07 03/30/17 02:18 12,3,7,8-TCDF ND

48 0.42 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,7,8-PeCDF ND

48 0.36 pg/L 03/22/17 12:07 03/30/17 02:18 12,3,4,7,8-PeCDF ND

48 0.57 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,4,7,8-HxCDF ND

48 0.58 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,6,7,8-HxCDF ND

48 0.57 pg/L 03/22/17 12:07 03/30/17 02:18 12,3,4,6,7,8-HxCDF ND

48 0.67 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,7,8,9-HxCDF ND

48 0.25 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,4,6,7,8-HpCDF ND

48 0.32 pg/L 03/22/17 12:07 03/30/17 02:18 11,2,3,4,7,8,9-HpCDF ND

96 0.59 pg/L 03/22/17 12:07 03/30/17 02:18 1OCDF 2.6 J B

13C-2,3,7,8-TCDD 63 25 - 164 03/22/17 12:07 03/30/17 02:18 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 61 03/22/17 12:07 03/30/17 02:18 125 - 181

13C-1,2,3,4,7,8-HxCDD 63 03/22/17 12:07 03/30/17 02:18 132 - 141

13C-1,2,3,6,7,8-HxCDD 68 03/22/17 12:07 03/30/17 02:18 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 62 03/22/17 12:07 03/30/17 02:18 123 - 140

13C-OCDD 57 03/22/17 12:07 03/30/17 02:18 117 - 157

13C-2,3,7,8-TCDF 58 03/22/17 12:07 03/30/17 02:18 124 - 169

13C-1,2,3,7,8-PeCDF 60 03/22/17 12:07 03/30/17 02:18 124 - 185

13C-2,3,4,7,8-PeCDF 60 03/22/17 12:07 03/30/17 02:18 121 - 178

13C-1,2,3,4,7,8-HxCDF 60 03/22/17 12:07 03/30/17 02:18 126 - 152

13C-1,2,3,6,7,8-HxCDF 63 03/22/17 12:07 03/30/17 02:18 126 - 123

13C-2,3,4,6,7,8-HxCDF 64 03/22/17 12:07 03/30/17 02:18 128 - 136

13C-1,2,3,7,8,9-HxCDF 67 03/22/17 12:07 03/30/17 02:18 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 59 03/22/17 12:07 03/30/17 02:18 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 64 03/22/17 12:07 03/30/17 02:18 126 - 138

13C-OCDF 66 03/22/17 12:07 03/30/17 02:18 117 - 157

37Cl4-2,3,7,8-TCDD 83 35 - 197 03/22/17 12:07 03/30/17 02:18 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-63900-9Client Sample ID: #20170153 AMENDED COMPOSITE G Matrix: SedimentDate Collected: 02/23/17 09:45

Date Received: 03/01/17 09:30

RL EDL

2,3,7,8-TCDD ND 9.6 1.7 pg/L 03/22/17 12:07 03/30/17 03:19 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.61 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,7,8-PeCDD ND

48 0.25 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,4,7,8-HxCDD ND

48 0.27 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,6,7,8-HxCDD ND

48 0.24 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,7,8,9-HxCDD ND

48 0.21 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,4,6,7,8-HpCDD ND

96 0.39 pg/L 03/22/17 12:07 03/30/17 03:19 1OCDD ND

9.6 0.93 pg/L 03/22/17 12:07 03/30/17 03:19 12,3,7,8-TCDF ND

48 0.50 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,7,8-PeCDF ND

48 0.46 pg/L 03/22/17 12:07 03/30/17 03:19 12,3,4,7,8-PeCDF ND

48 0.29 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,4,7,8-HxCDF ND

48 0.27 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,6,7,8-HxCDF ND

48 0.26 pg/L 03/22/17 12:07 03/30/17 03:19 12,3,4,6,7,8-HxCDF ND

48 0.34 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,7,8,9-HxCDF ND

48 0.11 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,4,6,7,8-HpCDF ND

48 0.16 pg/L 03/22/17 12:07 03/30/17 03:19 11,2,3,4,7,8,9-HpCDF ND

96 0.64 pg/L 03/22/17 12:07 03/30/17 03:19 1OCDF 1.4 J B q

13C-2,3,7,8-TCDD 65 25 - 164 03/22/17 12:07 03/30/17 03:19 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 62 03/22/17 12:07 03/30/17 03:19 125 - 181

13C-1,2,3,4,7,8-HxCDD 66 03/22/17 12:07 03/30/17 03:19 132 - 141

13C-1,2,3,6,7,8-HxCDD 67 03/22/17 12:07 03/30/17 03:19 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 64 03/22/17 12:07 03/30/17 03:19 123 - 140

13C-OCDD 69 03/22/17 12:07 03/30/17 03:19 117 - 157

13C-2,3,7,8-TCDF 64 03/22/17 12:07 03/30/17 03:19 124 - 169

13C-1,2,3,7,8-PeCDF 69 03/22/17 12:07 03/30/17 03:19 124 - 185

13C-2,3,4,7,8-PeCDF 61 03/22/17 12:07 03/30/17 03:19 121 - 178

13C-1,2,3,4,7,8-HxCDF 59 03/22/17 12:07 03/30/17 03:19 126 - 152

13C-1,2,3,6,7,8-HxCDF 62 03/22/17 12:07 03/30/17 03:19 126 - 123

13C-2,3,4,6,7,8-HxCDF 65 03/22/17 12:07 03/30/17 03:19 128 - 136

13C-1,2,3,7,8,9-HxCDF 67 03/22/17 12:07 03/30/17 03:19 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 64 03/22/17 12:07 03/30/17 03:19 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 67 03/22/17 12:07 03/30/17 03:19 126 - 138

13C-OCDF 77 03/22/17 12:07 03/30/17 03:19 117 - 157

37Cl4-2,3,7,8-TCDD 92 35 - 197 03/22/17 12:07 03/30/17 03:19 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-63900-10Client Sample ID: #20170155 AMENDED COMPOSITE I Matrix: SedimentDate Collected: 02/23/17 11:00

Date Received: 03/01/17 09:30

RL EDL

2,3,7,8-TCDD ND 9.9 1.0 pg/L 03/22/17 12:07 03/30/17 06:20 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

50 0.46 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,7,8-PeCDD ND

50 0.076 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,4,7,8-HxCDD 0.24 J q

50 0.079 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,6,7,8-HxCDD ND

50 0.072 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,7,8,9-HxCDD ND

50 0.38 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,4,6,7,8-HpCDD ND

99 0.39 pg/L 03/22/17 12:07 03/30/17 06:20 1OCDD 3.1 J B q

9.9 0.48 pg/L 03/22/17 12:07 03/30/17 06:20 12,3,7,8-TCDF ND

50 0.31 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,7,8-PeCDF ND

50 0.28 pg/L 03/22/17 12:07 03/30/17 06:20 12,3,4,7,8-PeCDF ND

50 0.23 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,4,7,8-HxCDF ND

50 0.22 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,6,7,8-HxCDF ND

50 0.22 pg/L 03/22/17 12:07 03/30/17 06:20 12,3,4,6,7,8-HxCDF ND

50 0.28 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,7,8,9-HxCDF ND

50 0.12 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,4,6,7,8-HpCDF ND

50 0.19 pg/L 03/22/17 12:07 03/30/17 06:20 11,2,3,4,7,8,9-HpCDF ND

99 0.66 pg/L 03/22/17 12:07 03/30/17 06:20 1OCDF ND

13C-2,3,7,8-TCDD 66 25 - 164 03/22/17 12:07 03/30/17 06:20 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 78 03/22/17 12:07 03/30/17 06:20 125 - 181

13C-1,2,3,4,7,8-HxCDD 69 03/22/17 12:07 03/30/17 06:20 132 - 141

13C-1,2,3,6,7,8-HxCDD 73 03/22/17 12:07 03/30/17 06:20 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 67 03/22/17 12:07 03/30/17 06:20 123 - 140

13C-OCDD 54 03/22/17 12:07 03/30/17 06:20 117 - 157

13C-2,3,7,8-TCDF 62 03/22/17 12:07 03/30/17 06:20 124 - 169

13C-1,2,3,7,8-PeCDF 69 03/22/17 12:07 03/30/17 06:20 124 - 185

13C-2,3,4,7,8-PeCDF 70 03/22/17 12:07 03/30/17 06:20 121 - 178

13C-1,2,3,4,7,8-HxCDF 61 03/22/17 12:07 03/30/17 06:20 126 - 152

13C-1,2,3,6,7,8-HxCDF 66 03/22/17 12:07 03/30/17 06:20 126 - 123

13C-2,3,4,6,7,8-HxCDF 68 03/22/17 12:07 03/30/17 06:20 128 - 136

13C-1,2,3,7,8,9-HxCDF 68 03/22/17 12:07 03/30/17 06:20 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 61 03/22/17 12:07 03/30/17 06:20 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 64 03/22/17 12:07 03/30/17 06:20 126 - 138

13C-OCDF 57 03/22/17 12:07 03/30/17 06:20 117 - 157

37Cl4-2,3,7,8-TCDD 84 35 - 197 03/22/17 12:07 03/30/17 06:20 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-63900-11Client Sample ID: #20170164 AMENDED COMPOSITE R Matrix: SedimentDate Collected: 02/23/17 13:59

Date Received: 03/01/17 09:30

RL EDL

2,3,7,8-TCDD ND 9.6 1.2 pg/L 03/22/17 12:07 03/30/17 04:20 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.32 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,7,8-PeCDD ND

48 0.23 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,4,7,8-HxCDD ND

48 0.24 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,6,7,8-HxCDD ND

48 0.22 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,7,8,9-HxCDD ND

48 0.15 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,4,6,7,8-HpCDD 0.80 J

96 0.25 pg/L 03/22/17 12:07 03/30/17 04:20 1OCDD 1.8 J B q

9.6 0.66 pg/L 03/22/17 12:07 03/30/17 04:20 12,3,7,8-TCDF ND

48 0.13 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,7,8-PeCDF ND

48 0.11 pg/L 03/22/17 12:07 03/30/17 04:20 12,3,4,7,8-PeCDF ND

48 0.12 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,4,7,8-HxCDF ND

48 0.13 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,6,7,8-HxCDF ND

48 0.12 pg/L 03/22/17 12:07 03/30/17 04:20 12,3,4,6,7,8-HxCDF ND

48 0.15 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,7,8,9-HxCDF ND

48 0.17 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,4,6,7,8-HpCDF ND

48 0.22 pg/L 03/22/17 12:07 03/30/17 04:20 11,2,3,4,7,8,9-HpCDF ND

96 0.52 pg/L 03/22/17 12:07 03/30/17 04:20 1OCDF ND

13C-2,3,7,8-TCDD 67 25 - 164 03/22/17 12:07 03/30/17 04:20 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 71 03/22/17 12:07 03/30/17 04:20 125 - 181

13C-1,2,3,4,7,8-HxCDD 67 03/22/17 12:07 03/30/17 04:20 132 - 141

13C-1,2,3,6,7,8-HxCDD 75 03/22/17 12:07 03/30/17 04:20 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 69 03/22/17 12:07 03/30/17 04:20 123 - 140

13C-OCDD 65 03/22/17 12:07 03/30/17 04:20 117 - 157

13C-2,3,7,8-TCDF 62 03/22/17 12:07 03/30/17 04:20 124 - 169

13C-1,2,3,7,8-PeCDF 68 03/22/17 12:07 03/30/17 04:20 124 - 185

13C-2,3,4,7,8-PeCDF 69 03/22/17 12:07 03/30/17 04:20 121 - 178

13C-1,2,3,4,7,8-HxCDF 63 03/22/17 12:07 03/30/17 04:20 126 - 152

13C-1,2,3,6,7,8-HxCDF 64 03/22/17 12:07 03/30/17 04:20 126 - 123

13C-2,3,4,6,7,8-HxCDF 69 03/22/17 12:07 03/30/17 04:20 128 - 136

13C-1,2,3,7,8,9-HxCDF 70 03/22/17 12:07 03/30/17 04:20 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 59 03/22/17 12:07 03/30/17 04:20 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 64 03/22/17 12:07 03/30/17 04:20 126 - 138

13C-OCDF 58 03/22/17 12:07 03/30/17 04:20 117 - 157

37Cl4-2,3,7,8-TCDD 77 35 - 197 03/22/17 12:07 03/30/17 04:20 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-63900-12Client Sample ID: #20170165 AMENDED COMPOSITE S Matrix: SedimentDate Collected: 02/23/17 13:00

Date Received: 03/01/17 09:30

RL EDL

2,3,7,8-TCDD ND 9.7 0.75 pg/L 03/22/17 12:07 03/30/17 05:20 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.18 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,7,8-PeCDD ND

48 0.17 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,4,7,8-HxCDD ND

48 0.19 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,6,7,8-HxCDD ND

48 0.17 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,7,8,9-HxCDD ND

48 0.094 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,4,6,7,8-HpCDD 0.26 J q

97 0.25 pg/L 03/22/17 12:07 03/30/17 05:20 1OCDD ND

9.7 0.48 pg/L 03/22/17 12:07 03/30/17 05:20 12,3,7,8-TCDF ND

48 0.18 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,7,8-PeCDF ND

48 0.17 pg/L 03/22/17 12:07 03/30/17 05:20 12,3,4,7,8-PeCDF ND

48 0.10 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,4,7,8-HxCDF ND

48 0.11 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,6,7,8-HxCDF ND

48 0.11 pg/L 03/22/17 12:07 03/30/17 05:20 12,3,4,6,7,8-HxCDF ND

48 0.13 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,7,8,9-HxCDF ND

48 0.18 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,4,6,7,8-HpCDF ND

48 0.25 pg/L 03/22/17 12:07 03/30/17 05:20 11,2,3,4,7,8,9-HpCDF ND

97 0.36 pg/L 03/22/17 12:07 03/30/17 05:20 1OCDF ND

13C-2,3,7,8-TCDD 67 25 - 164 03/22/17 12:07 03/30/17 05:20 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 75 03/22/17 12:07 03/30/17 05:20 125 - 181

13C-1,2,3,4,7,8-HxCDD 68 03/22/17 12:07 03/30/17 05:20 132 - 141

13C-1,2,3,6,7,8-HxCDD 73 03/22/17 12:07 03/30/17 05:20 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 71 03/22/17 12:07 03/30/17 05:20 123 - 140

13C-OCDD 70 03/22/17 12:07 03/30/17 05:20 117 - 157

13C-2,3,7,8-TCDF 67 03/22/17 12:07 03/30/17 05:20 124 - 169

13C-1,2,3,7,8-PeCDF 71 03/22/17 12:07 03/30/17 05:20 124 - 185

13C-2,3,4,7,8-PeCDF 68 03/22/17 12:07 03/30/17 05:20 121 - 178

13C-1,2,3,4,7,8-HxCDF 64 03/22/17 12:07 03/30/17 05:20 126 - 152

13C-1,2,3,6,7,8-HxCDF 66 03/22/17 12:07 03/30/17 05:20 126 - 123

13C-2,3,4,6,7,8-HxCDF 69 03/22/17 12:07 03/30/17 05:20 128 - 136

13C-1,2,3,7,8,9-HxCDF 71 03/22/17 12:07 03/30/17 05:20 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 64 03/22/17 12:07 03/30/17 05:20 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 70 03/22/17 12:07 03/30/17 05:20 126 - 138

13C-OCDF 73 03/22/17 12:07 03/30/17 05:20 117 - 157

37Cl4-2,3,7,8-TCDD 91 35 - 197 03/22/17 12:07 03/30/17 05:20 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-63900-13Client Sample ID: #20170166 AMENDED COMPOSITE T Matrix: SedimentDate Collected: 02/23/17 11:10

Date Received: 03/01/17 09:30

RL EDL

2,3,7,8-TCDD ND 9.6 3.5 pg/L 03/22/17 12:07 03/30/17 13:13 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 1.6 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,7,8-PeCDD ND

48 0.94 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,4,7,8-HxCDD ND

48 1.0 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,6,7,8-HxCDD ND

48 0.91 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,7,8,9-HxCDD ND

48 1.1 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,4,6,7,8-HpCDD ND

96 0.28 pg/L 03/22/17 12:07 03/30/17 13:13 1OCDD 2.7 J B q

9.6 2.3 pg/L 03/22/17 12:07 03/30/17 13:13 12,3,7,8-TCDF ND

48 0.69 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,7,8-PeCDF ND

48 0.63 pg/L 03/22/17 12:07 03/30/17 13:13 12,3,4,7,8-PeCDF ND

48 0.61 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,4,7,8-HxCDF ND

48 0.58 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,6,7,8-HxCDF ND

48 0.53 pg/L 03/22/17 12:07 03/30/17 13:13 12,3,4,6,7,8-HxCDF ND

48 0.67 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,7,8,9-HxCDF ND

48 0.47 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,4,6,7,8-HpCDF ND

48 0.66 pg/L 03/22/17 12:07 03/30/17 13:13 11,2,3,4,7,8,9-HpCDF ND

96 1.7 pg/L 03/22/17 12:07 03/30/17 13:13 1OCDF ND

13C-2,3,7,8-TCDD 66 25 - 164 03/22/17 12:07 03/30/17 13:13 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 69 03/22/17 12:07 03/30/17 13:13 125 - 181

13C-1,2,3,4,7,8-HxCDD 67 03/22/17 12:07 03/30/17 13:13 132 - 141

13C-1,2,3,6,7,8-HxCDD 66 03/22/17 12:07 03/30/17 13:13 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 73 03/22/17 12:07 03/30/17 13:13 123 - 140

13C-OCDD 73 03/22/17 12:07 03/30/17 13:13 117 - 157

13C-2,3,7,8-TCDF 61 03/22/17 12:07 03/30/17 13:13 124 - 169

13C-1,2,3,7,8-PeCDF 64 03/22/17 12:07 03/30/17 13:13 124 - 185

13C-2,3,4,7,8-PeCDF 63 03/22/17 12:07 03/30/17 13:13 121 - 178

13C-1,2,3,4,7,8-HxCDF 56 03/22/17 12:07 03/30/17 13:13 126 - 152

13C-1,2,3,6,7,8-HxCDF 61 03/22/17 12:07 03/30/17 13:13 126 - 123

13C-2,3,4,6,7,8-HxCDF 63 03/22/17 12:07 03/30/17 13:13 128 - 136

13C-1,2,3,7,8,9-HxCDF 65 03/22/17 12:07 03/30/17 13:13 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 61 03/22/17 12:07 03/30/17 13:13 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 65 03/22/17 12:07 03/30/17 13:13 126 - 138

13C-OCDF 74 03/22/17 12:07 03/30/17 13:13 117 - 157

37Cl4-2,3,7,8-TCDD 85 35 - 197 03/22/17 12:07 03/30/17 13:13 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East

Lab Sample ID: 180-63900-14Client Sample ID: #20170170 AMENDED COMPOSITE X/N-45 Matrix: SedimentDate Collected: 02/23/17 11:10

Date Received: 03/01/17 09:30

RL EDL

2,3,7,8-TCDD ND 9.6 2.2 pg/L 03/22/17 12:07 03/30/17 14:14 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

48 0.91 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,7,8-PeCDD ND

48 0.50 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,4,7,8-HxCDD ND

48 0.55 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,6,7,8-HxCDD ND

48 0.49 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,7,8,9-HxCDD ND

48 0.44 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,4,6,7,8-HpCDD ND

96 0.27 pg/L 03/22/17 12:07 03/30/17 14:14 1OCDD 1.4 J B q

9.6 1.6 pg/L 03/22/17 12:07 03/30/17 14:14 12,3,7,8-TCDF ND

48 0.50 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,7,8-PeCDF ND

48 0.45 pg/L 03/22/17 12:07 03/30/17 14:14 12,3,4,7,8-PeCDF ND

48 0.47 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,4,7,8-HxCDF ND

48 0.51 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,6,7,8-HxCDF ND

48 0.47 pg/L 03/22/17 12:07 03/30/17 14:14 12,3,4,6,7,8-HxCDF ND

48 0.56 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,7,8,9-HxCDF ND

48 0.51 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,4,6,7,8-HpCDF ND

48 0.73 pg/L 03/22/17 12:07 03/30/17 14:14 11,2,3,4,7,8,9-HpCDF ND

96 1.2 pg/L 03/22/17 12:07 03/30/17 14:14 1OCDF ND

13C-2,3,7,8-TCDD 68 25 - 164 03/22/17 12:07 03/30/17 14:14 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C-1,2,3,7,8-PeCDD 70 03/22/17 12:07 03/30/17 14:14 125 - 181

13C-1,2,3,4,7,8-HxCDD 67 03/22/17 12:07 03/30/17 14:14 132 - 141

13C-1,2,3,6,7,8-HxCDD 68 03/22/17 12:07 03/30/17 14:14 128 - 130

13C-1,2,3,4,6,7,8-HpCDD 70 03/22/17 12:07 03/30/17 14:14 123 - 140

13C-OCDD 70 03/22/17 12:07 03/30/17 14:14 117 - 157

13C-2,3,7,8-TCDF 62 03/22/17 12:07 03/30/17 14:14 124 - 169

13C-1,2,3,7,8-PeCDF 64 03/22/17 12:07 03/30/17 14:14 124 - 185

13C-2,3,4,7,8-PeCDF 63 03/22/17 12:07 03/30/17 14:14 121 - 178

13C-1,2,3,4,7,8-HxCDF 58 03/22/17 12:07 03/30/17 14:14 126 - 152

13C-1,2,3,6,7,8-HxCDF 59 03/22/17 12:07 03/30/17 14:14 126 - 123

13C-2,3,4,6,7,8-HxCDF 62 03/22/17 12:07 03/30/17 14:14 128 - 136

13C-1,2,3,7,8,9-HxCDF 63 03/22/17 12:07 03/30/17 14:14 129 - 147

13C-1,2,3,4,6,7,8-HpCDF 55 03/22/17 12:07 03/30/17 14:14 128 - 143

13C-1,2,3,4,7,8,9-HpCDF 56 03/22/17 12:07 03/30/17 14:14 126 - 138

13C-OCDF 50 03/22/17 12:07 03/30/17 14:14 117 - 157

37Cl4-2,3,7,8-TCDD 88 35 - 197 03/22/17 12:07 03/30/17 14:14 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Default Detection Limits Client: Battelle TestAmerica Job ID: 180-63900-2 Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) - SPLP East Prep: HRMS-Sepf

501,2,3,4,6,7,8-HpCDD pg/L

Analyte Units MethodRL

1613B

501,2,3,4,6,7,8-HpCDF pg/L 1613B

501,2,3,4,7,8,9-HpCDF pg/L 1613B

501,2,3,4,7,8-HxCDD pg/L 1613B

501,2,3,4,7,8-HxCDF pg/L 1613B

501,2,3,6,7,8-HxCDD pg/L 1613B

501,2,3,6,7,8-HxCDF pg/L 1613B

501,2,3,7,8,9-HxCDD pg/L 1613B

501,2,3,7,8,9-HxCDF pg/L 1613B

501,2,3,7,8-PeCDD pg/L 1613B

501,2,3,7,8-PeCDF pg/L 1613B

502,3,4,6,7,8-HxCDF pg/L 1613B

502,3,4,7,8-PeCDF pg/L 1613B

102,3,7,8-TCDD pg/L 1613B

102,3,7,8-TCDF pg/L 1613B

100OCDD pg/L 1613B

100OCDF pg/L 1613B

Surrogate Summary

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: Total/NAMatrix: Sediment

Lab Sample ID Client Sample ID (31-191)

37TCDD

87LCS 140-9748/21-A

Percent Surrogate Recovery (Acceptance Limits)

Lab Control Sample

Surrogate Legend

37TCDD = 37Cl4-2,3,7,8-TCDD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: Total/NAMatrix: Sediment

Lab Sample ID Client Sample ID (35-197)

37TCDD

92MB 140-9748/20-A

Percent Surrogate Recovery (Acceptance Limits)

Method Blank

Surrogate Legend

37TCDD = 37Cl4-2,3,7,8-TCDD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: SPLP EastMatrix: Sediment

Lab Sample ID Client Sample ID (35-197)

37TCDD

83180-63900-8

Percent Surrogate Recovery (Acceptance Limits)

#20170152 AMENDED COMPOSITE F

92180-63900-9 #20170153 AMENDED COMPOSITE G

84180-63900-10 #20170155 AMENDED COMPOSITE I

86180-63900-10 MS #20170155 AMENDED COMPOSITE I

86180-63900-10 MSD #20170155 AMENDED COMPOSITE I

77180-63900-11 #20170164 AMENDED COMPOSITE R

91180-63900-12 #20170165 AMENDED COMPOSITE S

85180-63900-13 #20170166 AMENDED COMPOSITE T

88180-63900-14 #20170170 AMENDED COMPOSITE X/N-45

Surrogate Legend

37TCDD = 37Cl4-2,3,7,8-TCDD

Isotope Dilution Summary

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: Total/NAMatrix: Sediment

Lab Sample ID Client Sample ID (20-175) (21-227) (21-193) (25-163) (26-166) (13-199) (22-152) (21-192)

TCDD PeCDD HxCDD1 HxCDD2 HpCDD OCDD TCDF PeCDF1

74 77 75 74 71 73 74 77LCS 140-9748/21-A

Percent Isotope Dilution Recovery (Acceptance Limits)

Lab Control Sample

Lab Sample ID Client Sample ID (13-328) (19-202) (21-159) (22-176) (17-205) (21-158) (20-186) (13-199)

PeCDF2 HxCDF1 HxCDF2 HxCDF3 HxCDF4 HpCDF1 HpCDF2 13C-OCDF

72 71 75 72 79 66 71 82LCS 140-9748/21-A

Percent Isotope Dilution Recovery (Acceptance Limits)

Lab Control Sample

Surrogate Legend

TCDD = 13C-2,3,7,8-TCDD

PeCDD = 13C-1,2,3,7,8-PeCDD

HxCDD1 = 13C-1,2,3,4,7,8-HxCDD

HxCDD2 = 13C-1,2,3,6,7,8-HxCDD

HpCDD = 13C-1,2,3,4,6,7,8-HpCDD

OCDD = 13C-OCDD

TCDF = 13C-2,3,7,8-TCDF

PeCDF1 = 13C-1,2,3,7,8-PeCDF

PeCDF2 = 13C-2,3,4,7,8-PeCDF

HxCDF1 = 13C-1,2,3,4,7,8-HxCDF

HxCDF2 = 13C-1,2,3,6,7,8-HxCDF

HxCDF3 = 13C-2,3,4,6,7,8-HxCDF

HxCDF4 = 13C-1,2,3,7,8,9-HxCDF

HpCDF1 = 13C-1,2,3,4,6,7,8-HpCDF

HpCDF2 = 13C-1,2,3,4,7,8,9-HpCDF

13C-OCDF = 13C-OCDF

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: Total/NAMatrix: Sediment

Lab Sample ID Client Sample ID (25-164) (25-181) (32-141) (28-130) (23-140) (17-157) (24-169) (24-185)

TCDD PeCDD HxCDD1 HxCDD2 HpCDD OCDD TCDF PeCDF1

73 73 70 75 70 69 71 71MB 140-9748/20-A

Percent Isotope Dilution Recovery (Acceptance Limits)

Method Blank

Lab Sample ID Client Sample ID (21-178) (26-152) (26-123) (28-136) (29-147) (28-143) (26-138) (17-157)

PeCDF2 HxCDF1 HxCDF2 HxCDF3 HxCDF4 HpCDF1 HpCDF2 13C-OCDF

69 64 69 72 72 64 72 77MB 140-9748/20-A

Percent Isotope Dilution Recovery (Acceptance Limits)

Method Blank

Surrogate Legend

TCDD = 13C-2,3,7,8-TCDD

PeCDD = 13C-1,2,3,7,8-PeCDD

HxCDD1 = 13C-1,2,3,4,7,8-HxCDD

HxCDD2 = 13C-1,2,3,6,7,8-HxCDD

HpCDD = 13C-1,2,3,4,6,7,8-HpCDD

OCDD = 13C-OCDD

TCDF = 13C-2,3,7,8-TCDF

PeCDF1 = 13C-1,2,3,7,8-PeCDF

PeCDF2 = 13C-2,3,4,7,8-PeCDF

HxCDF1 = 13C-1,2,3,4,7,8-HxCDF

HxCDF2 = 13C-1,2,3,6,7,8-HxCDF

HxCDF3 = 13C-2,3,4,6,7,8-HxCDF

Isotope Dilution Summary

Project/Site: USACE/NYD

HxCDF4 = 13C-1,2,3,7,8,9-HxCDF

HpCDF1 = 13C-1,2,3,4,6,7,8-HpCDF

HpCDF2 = 13C-1,2,3,4,7,8,9-HpCDF

13C-OCDF = 13C-OCDF

Method: 1613B - Dioxins and Furans (HRGC/HRMS) Prep Type: SPLP EastMatrix: Sediment

Lab Sample ID Client Sample ID (25-164) (25-181) (32-141) (28-130) (23-140) (17-157) (24-169) (24-185)

TCDD PeCDD HxCDD1 HxCDD2 HpCDD OCDD TCDF PeCDF1

63 61 63 68 62 57 58 60180-63900-8

Percent Isotope Dilution Recovery (Acceptance Limits)

#20170152 AMENDED COMPOSITE F

65 62 66 6467 69 64 69180-63900-9 #20170153 AMENDED COMPOSITE G

66 78 69 6773 54 62 69180-63900-10 #20170155 AMENDED COMPOSITE I

62 67 68 7669 81 61 65180-63900-10 MS #20170155 AMENDED COMPOSITE I

65 73 68 7470 76 65 69180-63900-10 MSD #20170155 AMENDED COMPOSITE I

67 71 67 6975 65 62 68180-63900-11 #20170164 AMENDED COMPOSITE R

67 75 68 7173 70 67 71180-63900-12 #20170165 AMENDED COMPOSITE S

66 69 67 7366 73 61 64180-63900-13 #20170166 AMENDED COMPOSITE T

68 70 67 7068 70 62 64180-63900-14 #20170170 AMENDED COMPOSITE X/N-45

Lab Sample ID Client Sample ID (21-178) (26-152) (26-123) (28-136) (29-147) (28-143) (26-138) (17-157)

PeCDF2 HxCDF1 HxCDF2 HxCDF3 HxCDF4 HpCDF1 HpCDF2 13C-OCDF

60 60 63 64 67 59 64 66180-63900-8

Percent Isotope Dilution Recovery (Acceptance Limits)

#20170152 AMENDED COMPOSITE F

61 59 62 6765 64 67 77180-63900-9 #20170153 AMENDED COMPOSITE G

70 61 66 6868 61 64 57180-63900-10 #20170155 AMENDED COMPOSITE I

66 61 64 7067 65 74 87180-63900-10 MS #20170155 AMENDED COMPOSITE I

68 62 66 7268 63 70 80180-63900-10 MSD #20170155 AMENDED COMPOSITE I

69 63 64 7069 59 64 58180-63900-11 #20170164 AMENDED COMPOSITE R

68 64 66 7169 64 70 73180-63900-12 #20170165 AMENDED COMPOSITE S

63 56 61 6563 61 65 74180-63900-13 #20170166 AMENDED COMPOSITE T

63 58 59 6362 55 56 50180-63900-14 #20170170 AMENDED COMPOSITE X/N-45

Surrogate Legend

TCDD = 13C-2,3,7,8-TCDD

PeCDD = 13C-1,2,3,7,8-PeCDD

HxCDD1 = 13C-1,2,3,4,7,8-HxCDD

HxCDD2 = 13C-1,2,3,6,7,8-HxCDD

HpCDD = 13C-1,2,3,4,6,7,8-HpCDD

OCDD = 13C-OCDD

TCDF = 13C-2,3,7,8-TCDF

PeCDF1 = 13C-1,2,3,7,8-PeCDF

PeCDF2 = 13C-2,3,4,7,8-PeCDF

HxCDF1 = 13C-1,2,3,4,7,8-HxCDF

HxCDF2 = 13C-1,2,3,6,7,8-HxCDF

HxCDF3 = 13C-2,3,4,6,7,8-HxCDF

HxCDF4 = 13C-1,2,3,7,8,9-HxCDF

HpCDF1 = 13C-1,2,3,4,6,7,8-HpCDF

HpCDF2 = 13C-1,2,3,4,7,8,9-HpCDF

13C-OCDF = 13C-OCDF

QC Sample Results

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS)

Client Sample ID: Method BlankLab Sample ID: MB 140-9748/20-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 10063 Prep Batch: 9748

RL EDL

2,3,7,8-TCDD ND 10 1.7 pg/L 03/22/17 12:07 03/30/17 01:17 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

ND 1.050 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,7,8-PeCDD

ND 0.2650 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,7,8-HxCDD

ND 0.2850 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,6,7,8-HxCDD

0.769 J 0.2550 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,7,8,9-HxCDD

ND 0.5150 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,6,7,8-HpCDD

7.49 J 0.54100 pg/L 03/22/17 12:07 03/30/17 01:17 1OCDD

ND 0.9510 pg/L 03/22/17 12:07 03/30/17 01:17 12,3,7,8-TCDF

ND 0.3750 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,7,8-PeCDF

ND 0.3450 pg/L 03/22/17 12:07 03/30/17 01:17 12,3,4,7,8-PeCDF

ND 0.3150 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,7,8-HxCDF

ND 0.3250 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,6,7,8-HxCDF

ND 0.3150 pg/L 03/22/17 12:07 03/30/17 01:17 12,3,4,6,7,8-HxCDF

ND 0.4050 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,7,8,9-HxCDF

ND 0.1750 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,6,7,8-HpCDF

0.410 J q 0.2250 pg/L 03/22/17 12:07 03/30/17 01:17 11,2,3,4,7,8,9-HpCDF

4.90 J q 1.0100 pg/L 03/22/17 12:07 03/30/17 01:17 1OCDF

13C-2,3,7,8-TCDD 73 25 - 164 03/30/17 01:17 1

MB MB

Isotope Dilution

03/22/17 12:07

Dil FacPrepared AnalyzedQualifier Limits%Recovery

73 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,7,8-PeCDD 25 - 181

70 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,7,8-HxCDD 32 - 141

75 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,6,7,8-HxCDD 28 - 130

70 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,6,7,8-HpCDD 23 - 140

69 03/22/17 12:07 03/30/17 01:17 113C-OCDD 17 - 157

71 03/22/17 12:07 03/30/17 01:17 113C-2,3,7,8-TCDF 24 - 169

71 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,7,8-PeCDF 24 - 185

69 03/22/17 12:07 03/30/17 01:17 113C-2,3,4,7,8-PeCDF 21 - 178

64 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,7,8-HxCDF 26 - 152

69 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,6,7,8-HxCDF 26 - 123

72 03/22/17 12:07 03/30/17 01:17 113C-2,3,4,6,7,8-HxCDF 28 - 136

72 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,7,8,9-HxCDF 29 - 147

64 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,6,7,8-HpCDF 28 - 143

72 03/22/17 12:07 03/30/17 01:17 113C-1,2,3,4,7,8,9-HpCDF 26 - 138

77 03/22/17 12:07 03/30/17 01:17 113C-OCDF 17 - 157

37Cl4-2,3,7,8-TCDD 92 35 - 197 03/30/17 01:17 1

MB MB

Surrogate

03/22/17 12:07

Dil FacPrepared AnalyzedQualifier Limits%Recovery

Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-9748/21-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 10063 Prep Batch: 9748

2,3,7,8-TCDD 200 203 pg/L 102 67 - 158

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

1,2,3,7,8-PeCDD 1000 950 pg/L 95 70 - 142

1,2,3,4,7,8-HxCDD 1000 956 pg/L 96 70 - 164

1,2,3,6,7,8-HxCDD 1000 948 pg/L 95 76 - 134

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) (Continued)

Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-9748/21-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 10063 Prep Batch: 9748

1,2,3,7,8,9-HxCDD 1000 1010 pg/L 101 64 - 162

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

1,2,3,4,6,7,8-HpCDD 1000 937 pg/L 94 70 - 140

OCDD 2000 1790 pg/L 90 78 - 144

2,3,7,8-TCDF 200 196 pg/L 98 75 - 158

1,2,3,7,8-PeCDF 1000 865 pg/L 86 80 - 134

2,3,4,7,8-PeCDF 1000 968 pg/L 97 68 - 160

1,2,3,4,7,8-HxCDF 1000 939 pg/L 94 72 - 134

1,2,3,6,7,8-HxCDF 1000 919 pg/L 92 84 - 130

2,3,4,6,7,8-HxCDF 1000 910 pg/L 91 70 - 156

1,2,3,7,8,9-HxCDF 1000 914 pg/L 91 78 - 130

1,2,3,4,6,7,8-HpCDF 1000 964 pg/L 96 82 - 122

1,2,3,4,7,8,9-HpCDF 1000 937 pg/L 94 78 - 138

OCDF 2000 1690 pg/L 85 63 - 170

13C-2,3,7,8-TCDD 20 - 175

Isotope Dilution

LCS LCS

Qualifier Limits%Recovery

7713C-1,2,3,7,8-PeCDD 21 - 227

7513C-1,2,3,4,7,8-HxCDD 21 - 193

7413C-1,2,3,6,7,8-HxCDD 25 - 163

7113C-1,2,3,4,6,7,8-HpCDD 26 - 166

7313C-OCDD 13 - 199

7413C-2,3,7,8-TCDF 22 - 152

7713C-1,2,3,7,8-PeCDF 21 - 192

7213C-2,3,4,7,8-PeCDF 13 - 328

7113C-1,2,3,4,7,8-HxCDF 19 - 202

7513C-1,2,3,6,7,8-HxCDF 21 - 159

7213C-2,3,4,6,7,8-HxCDF 22 - 176

7913C-1,2,3,7,8,9-HxCDF 17 - 205

6613C-1,2,3,4,6,7,8-HpCDF 21 - 158

7113C-1,2,3,4,7,8,9-HpCDF 20 - 186

8213C-OCDF 13 - 199

37Cl4-2,3,7,8-TCDD 31 - 191

Surrogate

LCS LCS

Qualifier Limits%Recovery

Client Sample ID: #20170155 AMENDED COMPOSITE ILab Sample ID: 180-63900-10 MS Matrix: Sediment Prep Type: SPLP East Analysis Batch: 10063 Prep Batch: 9748

2,3,7,8-TCDD ND 198 200 pg/L 101 67 - 158

Analyte

MS MS

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

1,2,3,7,8-PeCDD ND 990 1000 pg/L 101 70 - 142

1,2,3,4,7,8-HxCDD 0.24 J q 990 978 pg/L 99 70 - 164

1,2,3,6,7,8-HxCDD ND 990 940 pg/L 95 76 - 134

1,2,3,7,8,9-HxCDD ND 990 991 pg/L 100 64 - 162

1,2,3,4,6,7,8-HpCDD ND 990 885 pg/L 89 70 - 140

OCDD 3.1 J B q 1980 1670 pg/L 84 78 - 144

2,3,7,8-TCDF ND 198 208 pg/L 105 75 - 158

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) (Continued)

Client Sample ID: #20170155 AMENDED COMPOSITE ILab Sample ID: 180-63900-10 MS Matrix: Sediment Prep Type: SPLP East Analysis Batch: 10063 Prep Batch: 9748

1,2,3,7,8-PeCDF ND 990 937 pg/L 95 80 - 134

Analyte

MS MS

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

2,3,4,7,8-PeCDF ND 990 959 pg/L 97 68 - 160

1,2,3,4,7,8-HxCDF ND 990 985 pg/L 100 72 - 134

1,2,3,6,7,8-HxCDF ND 990 926 pg/L 94 84 - 130

2,3,4,6,7,8-HxCDF ND 990 922 pg/L 93 70 - 156

1,2,3,7,8,9-HxCDF ND 990 929 pg/L 94 78 - 130

1,2,3,4,6,7,8-HpCDF ND 990 940 pg/L 95 82 - 122

1,2,3,4,7,8,9-HpCDF ND 990 884 pg/L 89 78 - 138

OCDF ND 1980 1550 pg/L 78 63 - 170

13C-2,3,7,8-TCDD 25 - 164

Isotope Dilution

MS MS

Qualifier Limits%Recovery

6713C-1,2,3,7,8-PeCDD 25 - 181

6813C-1,2,3,4,7,8-HxCDD 32 - 141

6913C-1,2,3,6,7,8-HxCDD 28 - 130

7613C-1,2,3,4,6,7,8-HpCDD 23 - 140

8113C-OCDD 17 - 157

6113C-2,3,7,8-TCDF 24 - 169

6513C-1,2,3,7,8-PeCDF 24 - 185

6613C-2,3,4,7,8-PeCDF 21 - 178

6113C-1,2,3,4,7,8-HxCDF 26 - 152

6413C-1,2,3,6,7,8-HxCDF 26 - 123

6713C-2,3,4,6,7,8-HxCDF 28 - 136

7013C-1,2,3,7,8,9-HxCDF 29 - 147

6513C-1,2,3,4,6,7,8-HpCDF 28 - 143

7413C-1,2,3,4,7,8,9-HpCDF 26 - 138

8713C-OCDF 17 - 157

37Cl4-2,3,7,8-TCDD 35 - 197

Surrogate

MS MS

Qualifier Limits%Recovery

Client Sample ID: #20170155 AMENDED COMPOSITE ILab Sample ID: 180-63900-10 MSD Matrix: Sediment Prep Type: SPLP East Analysis Batch: 10063 Prep Batch: 9748

2,3,7,8-TCDD ND 192 170 pg/L 89 67 - 158 16 25

Analyte

MSD MSD

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

1,2,3,7,8-PeCDD ND 960 941 pg/L 98 70 - 142 6 25

1,2,3,4,7,8-HxCDD 0.24 J q 960 926 pg/L 97 70 - 164 5 25

1,2,3,6,7,8-HxCDD ND 960 912 pg/L 95 76 - 134 3 25

1,2,3,7,8,9-HxCDD ND 960 961 pg/L 100 64 - 162 3 25

1,2,3,4,6,7,8-HpCDD ND 960 912 pg/L 95 70 - 140 3 25

OCDD 3.1 J B q 1920 1700 pg/L 89 78 - 144 2 25

2,3,7,8-TCDF ND 192 171 q pg/L 89 75 - 158 20 25

1,2,3,7,8-PeCDF ND 960 868 pg/L 90 80 - 134 8 25

2,3,4,7,8-PeCDF ND 960 919 pg/L 96 68 - 160 4 25

1,2,3,4,7,8-HxCDF ND 960 911 pg/L 95 72 - 134 8 25

1,2,3,6,7,8-HxCDF ND 960 915 pg/L 95 84 - 130 1 25

Project/Site: USACE/NYD

Method: 1613B - Dioxins and Furans (HRGC/HRMS) (Continued)

Client Sample ID: #20170155 AMENDED COMPOSITE ILab Sample ID: 180-63900-10 MSD Matrix: Sediment Prep Type: SPLP East Analysis Batch: 10063 Prep Batch: 9748

2,3,4,6,7,8-HxCDF ND 960 889 pg/L 93 70 - 156 4 25

Analyte

MSD MSD

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

1,2,3,7,8,9-HxCDF ND 960 886 pg/L 92 78 - 130 5 25

1,2,3,4,6,7,8-HpCDF ND 960 969 pg/L 101 82 - 122 3 25

1,2,3,4,7,8,9-HpCDF ND 960 914 pg/L 95 78 - 138 3 25

OCDF ND 1920 1650 pg/L 86 63 - 170 6 25

13C-2,3,7,8-TCDD 25 - 164

Isotope Dilution

MSD MSD

Qualifier Limits%Recovery

7313C-1,2,3,7,8-PeCDD 25 - 181

6813C-1,2,3,4,7,8-HxCDD 32 - 141

7013C-1,2,3,6,7,8-HxCDD 28 - 130

7413C-1,2,3,4,6,7,8-HpCDD 23 - 140

7613C-OCDD 17 - 157

6513C-2,3,7,8-TCDF 24 - 169

6913C-1,2,3,7,8-PeCDF 24 - 185

6813C-2,3,4,7,8-PeCDF 21 - 178

6213C-1,2,3,4,7,8-HxCDF 26 - 152

6613C-1,2,3,6,7,8-HxCDF 26 - 123

6813C-2,3,4,6,7,8-HxCDF 28 - 136

7213C-1,2,3,7,8,9-HxCDF 29 - 147

6313C-1,2,3,4,6,7,8-HpCDF 28 - 143

7013C-1,2,3,4,7,8,9-HpCDF 26 - 138

8013C-OCDF 17 - 157

37Cl4-2,3,7,8-TCDD 35 - 197

Surrogate

MSD MSD

Qualifier Limits%Recovery

QC Association Summary

Project/Site: USACE/NYD

Specialty Organics

Prep Batch: 9748

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment HRMS-Sepf180-63900-8 #20170152 AMENDED COMPOSITE F SPLP East

Sediment HRMS-Sepf180-63900-9 #20170153 AMENDED COMPOSITE G SPLP East

Sediment HRMS-Sepf180-63900-10 #20170155 AMENDED COMPOSITE I SPLP East

Sediment HRMS-Sepf180-63900-11 #20170164 AMENDED COMPOSITE R SPLP East

Sediment HRMS-Sepf180-63900-12 #20170165 AMENDED COMPOSITE S SPLP East

Sediment HRMS-Sepf180-63900-13 #20170166 AMENDED COMPOSITE T SPLP East

Sediment HRMS-Sepf180-63900-14 #20170170 AMENDED COMPOSITE X/N-45 SPLP East

Sediment HRMS-SepfMB 140-9748/20-A Method Blank Total/NA

Sediment HRMS-SepfLCS 140-9748/21-A Lab Control Sample Total/NA

Sediment HRMS-Sepf180-63900-10 MS #20170155 AMENDED COMPOSITE I SPLP East

Sediment HRMS-Sepf180-63900-10 MSD #20170155 AMENDED COMPOSITE I SPLP East

Analysis Batch: 10063

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 1613B 9748180-63900-8 #20170152 AMENDED COMPOSITE F SPLP East

Sediment 1613B 9748180-63900-9 #20170153 AMENDED COMPOSITE G SPLP East

Sediment 1613B 9748180-63900-10 #20170155 AMENDED COMPOSITE I SPLP East

Sediment 1613B 9748180-63900-11 #20170164 AMENDED COMPOSITE R SPLP East

Sediment 1613B 9748180-63900-12 #20170165 AMENDED COMPOSITE S SPLP East

Sediment 1613B 9748MB 140-9748/20-A Method Blank Total/NA

Sediment 1613B 9748LCS 140-9748/21-A Lab Control Sample Total/NA

Sediment 1613B 9748180-63900-10 MS #20170155 AMENDED COMPOSITE I SPLP East

Sediment 1613B 9748180-63900-10 MSD #20170155 AMENDED COMPOSITE I SPLP East

Analysis Batch: 10084

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 1613B 9748180-63900-13 #20170166 AMENDED COMPOSITE T SPLP East

Sediment 1613B 9748180-63900-14 #20170170 AMENDED COMPOSITE X/N-45 SPLP East

Lab Chronicle

Project/Site: USACE/NYD

Client Sample ID: #20170152 AMENDED COMPOSITE F Lab Sample ID: 180-63900-8 Matrix: SedimentDate Collected: 02/23/17 12:20

Date Received: 03/01/17 09:30

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1042.1 mL 20 uL

Analysis 1613B 1 10063 03/30/17 02:18 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170153 AMENDED COMPOSITE G Lab Sample ID: 180-63900-9 Matrix: SedimentDate Collected: 02/23/17 09:45

Date Received: 03/01/17 09:30

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1039.4 mL 20 uL

Analysis 1613B 1 10063 03/30/17 03:19 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170155 AMENDED COMPOSITE I Lab Sample ID: 180-63900-10 Matrix: SedimentDate Collected: 02/23/17 11:00

Date Received: 03/01/17 09:30

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1008.4 mL 20 uL

Analysis 1613B 1 10063 03/30/17 06:20 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170164 AMENDED COMPOSITE R Lab Sample ID: 180-63900-11 Matrix: SedimentDate Collected: 02/23/17 13:59

Date Received: 03/01/17 09:30

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1042.2 mL 20 uL

Analysis 1613B 1 10063 03/30/17 04:20 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170165 AMENDED COMPOSITE S Lab Sample ID: 180-63900-12 Matrix: SedimentDate Collected: 02/23/17 13:00

Date Received: 03/01/17 09:30

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1034.9 mL 20 uL

Analysis 1613B 1 10063 03/30/17 05:20 KBL TAL KNXSPLP East

M2AInstrument ID:

Lab Chronicle

Project/Site: USACE/NYD

Client Sample ID: #20170166 AMENDED COMPOSITE T Lab Sample ID: 180-63900-13 Matrix: SedimentDate Collected: 02/23/17 11:10

Date Received: 03/01/17 09:30

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1042.5 mL 20 uL

Analysis 1613B 1 10084 03/30/17 13:13 KBL TAL KNXSPLP East

M2AInstrument ID:

Client Sample ID: #20170170 AMENDED COMPOSITE X/N-45 Lab Sample ID: 180-63900-14 Matrix: SedimentDate Collected: 02/23/17 11:10

Date Received: 03/01/17 09:30

Prep HRMS-Sepf SSS03/22/17 12:07 TAL KNX9748

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 1037.4 mL 20 uL

Analysis 1613B 1 10084 03/30/17 14:14 KBL TAL KNXSPLP East

M2AInstrument ID:

Laboratory References:

TAL KNX = TestAmerica Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000

Analyst References:

Lab: TAL KNX

Batch Type: Prep

SSS = Samuel Stockton

Batch Type: Analysis

KBL = Kathryn Lay

Certification Summary

Project/Site: USACE/NYD

Laboratory: TestAmerica Pittsburgh The certifications listed below are applicable to this report.

Authority Program EPA Region Certification ID Expiration Date

New Jersey PA0052NELAP 06-30-17

New York NELAP 2 11182 03-31-17 *

Laboratory: TestAmerica Knoxville All certifications held by this laboratory are listed. Not all certifications are applicable to this report.

Authority Program EPA Region Certification ID Expiration Date

N/AAFCEE

Arkansas DEQ State Program 6 88-0688 06-16-17

California State Program 9 2423 06-30-18

Colorado State Program 8 TN00009 02-28-18

Connecticut State Program 1 PH-0223 09-30-17

Florida NELAP 4 E87177 06-30-17

Georgia State Program 4 906 04-13-17

Hawaii State Program 9 N/A 04-13-17

Kansas NELAP 7 E-10349 10-31-17

Kentucky (DW) State Program 4 90101 12-31-17

L-A-B DoD ELAP L2311 02-13-19

Louisiana NELAP 6 83979 06-30-17

Louisiana (DW) NELAP 6 LA160005 12-31-17

Maryland State Program 3 277 03-31-18

Michigan State Program 5 9933 04-13-17

Nevada State Program 9 TN00009 07-31-17

New Jersey NELAP 2 TN001 06-30-17

New York NELAP 2 10781 03-31-17 *

North Carolina (DW) State Program 4 21705 07-31-17

North Carolina (WW/SW) State Program 4 64 12-31-17

Ohio VAP State Program 5 CL0059 11-22-18

Oklahoma State Program 6 9415 08-31-17

Pennsylvania NELAP 3 68-00576 12-31-17

Tennessee State Program 4 2014 04-13-17

Texas NELAP 6 T104704380-16-9 08-31-17

USDA Federal P330-13-00262 08-20-19

Utah NELAP 8 TN00009 07-31-17

Virginia NELAP 3 460176 09-14-17

Washington State Program 10 C593 01-19-18

West Virginia (DW) State Program 3 9955C 12-31-17

West Virginia DEP State Program 3 345 04-30-17

Wisconsin State Program 5 998044300 08-31-17

TestAmerica Pittsburgh

* Certification renewal pending - certification considered valid.

Method Summary

Project/Site: USACE/NYD

Method Method Description LaboratoryProtocol

40CFR136A1613B Dioxins and Furans (HRGC/HRMS) TAL KNX

Protocol References:

40CFR136A = "Methods for Organic Chemical Analysis of Municipal Industrial Wastewater", 40CFR, Part 136, Appendix A, October 26, 1984 and subsequent revisions.

Laboratory References:

TAL KNX = TestAmerica Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000

Sample Summary

Project/Site: USACE/NYD

Lab Sample ID Client Sample ID ReceivedCollectedMatrix

180-63900-8 #20170152 AMENDED COMPOSITE F Sediment 02/23/17 12:20 03/01/17 09:30

180-63900-9 #20170153 AMENDED COMPOSITE G Sediment 02/23/17 09:45 03/01/17 09:30

180-63900-10 #20170155 AMENDED COMPOSITE I Sediment 02/23/17 11:00 03/01/17 09:30

180-63900-11 #20170164 AMENDED COMPOSITE R Sediment 02/23/17 13:59 03/01/17 09:30

180-63900-12 #20170165 AMENDED COMPOSITE S Sediment 02/23/17 13:00 03/01/17 09:30

180-63900-13 #20170166 AMENDED COMPOSITE T Sediment 02/23/17 11:10 03/01/17 09:30

180-63900-14 #20170170 AMENDED COMPOSITE X/N-45 Sediment 02/23/17 11:10 03/01/17 09:30

Lab Name: Job No.:

SDG No.:

DIOXIN MANUAL INTEGRATION SUMMARY

TestAmerica Knoxville 180-63900-2

Instrument ID: Analysis Batch Number:M2A 7832

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

WDM 140-7832/1

b140303w1.d03/03/14 12:57 GC Column: RTX-5 ID: 0.32(mm)

2,3,7,8-TCDD Wrong peak layk 01/13/17 14:0430.26

1613B

DIOXIN MANUAL INTEGRATION SUMMARY

TestAmerica Knoxville 180-63900-2

Instrument ID: Analysis Batch Number:M2A 10063

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

WDMCCV 140-10063/1

b170329s3.d03/29/17 22:22 GC Column: RTX-5 ID: 0.32(mm)

2,3,7,8-TCDD Incomplete Integration parslyt 03/29/17 23:5129.34

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 140-9748/21-A

lcs140-974821-a.d03/29/17 23:34 GC Column: RTX-5 ID: 0.32(mm)

2,3,7,8-TCDD Incomplete Integration parslyt 03/30/17 02:2429.33

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

MB 140-9748/20-A

mb140-974820-a.d03/30/17 01:17 GC Column: RTX-5 ID: 0.32(mm)

OCDD Split Peak parslyt 03/30/17 02:3554.19

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-63900-8 #20170152 AMENDED COMPOSITE F

180-63900-f-8-a.d03/30/17 02:18 GC Column: RTX-5 ID: 0.32(mm)

OCDD Split Peak parslyt 03/30/17 03:3254.18

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-63900-9 #20170153 AMENDED COMPOSITE G

180-63900-f-9-a.d03/30/17 03:19 GC Column: RTX-5 ID: 0.32(mm)

OCDF Baseline parslyt 03/30/17 04:3354.33

DIOXIN MANUAL INTEGRATION SUMMARY

TestAmerica Knoxville 180-63900-2

Instrument ID: Analysis Batch Number:M2A 10063

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-63900-12 #20170165 AMENDED COMPOSITE S

180-63900-e-12-a.d03/30/17 05:20 GC Column: RTX-5 ID: 0.32(mm)

1,2,3,4,6,7,8-HpCDD Split Peak layk 03/30/17 09:0549.66

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-63900-10 #20170155 AMENDED COMPOSITE I

180-63900-f-10-a.d03/30/17 06:20 GC Column: RTX-5 ID: 0.32(mm)

1,2,3,4,7,8-HxCDD Split Peak layk 03/30/17 09:1045.08

DIOXIN MANUAL INTEGRATION SUMMARY

TestAmerica Knoxville 180-63900-2

Instrument ID: Analysis Batch Number:M2A 10084

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

WDMCCV 140-10084/1

b170330s1.d03/30/17 10:29 GC Column: RTX-5 ID: 0.32(mm)

1,2,3,7,8,9-HxCDF Baseline layk 03/30/17 11:4545.78

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-63900-14 #20170170 AMENDED COMPOSITE X/N-45

180-63900-e-14-a.d03/30/17 14:14 GC Column: RTX-5 ID: 0.32(mm)

OCDD Baseline reynoldk 03/30/17 15:2954.19

REAGENT TRACEABILITY SUMMARY

Lab Name:

SDG No.:

Job No.: 180-63900-2TestAmerica Knoxville

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

07/31/25 12/12/16 200 mL 10XXDFCL37INP_00001 0.02 mL 37Cl4-2,3,7,8-TCDD 0.2 ng/mL10CSDFCL37CUP_00012 Hexane, Lot 130362 07/31/25 09/28/16 3 mL 10INDFCL37P_00001 0.12 mL 37Cl4-2,3,7,8-TCDD 2000 ng/mL.10XXDFCL37INP_00001 Nonane, Lot SHBH0333V 07/31/25 (Purchased Reagent) 37Cl4-2,3,7,8-TCDD 50 ug/mLCambridge Isotope, Lot ER05211501..10INDFCL37P_00001

10MXDFC13ISP_00006 13C-1,2,3,4,6,7,8-HpCDD 1 ng/mL200 mL 2…

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