Safety Data Sheet - Propylene Glycol Ind.PDF

Safety Data Sheet

Propylene glycol Industrial

Version 1.4 Revision Date: 04/03/2017

SDS Number: 100000003334 1 / 9 Propylene glycol Industrial

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Propylene glycol Industrial

Recommended use of the chemical and restrictions on use

Recommended use : Industrial chemical

Manufacturer or supplier's details Company : Nexeo Solutions, LLC.

Address 3 Waterway Square Place Suite 1000

The Woodlands, TX. 77380 United States of America

Emergency telephone number:

Health North America: 1-855-NEXEO4U (1-855-639-3648) Health International: 1-855-NEXEO4U (1-855-639-3648) Transport North America: CHEMTREC (1-800-424-9300)

Additional Information:

: Responsible Party: Product Safety Group E-Mail: msds@nexeosolutions.com SDS Requests: 1-855-429-2661 SDS Requests Fax: 1-281-500-2370 Website: www.nexeosolutions.com

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Not a hazardous substance or mixture.

GHS Label element

Not a hazardous substance or mixture.

Other hazards

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture

: Substance

Hazardous components

CAS-No. Chemical Name Weight %

57-55-6 Propylene glycol 90 - 100

Any Concentration shown as a range is due to batch variation.

SECTION 4. FIRST AID MEASURES

General advice

: Do not leave the victim unattended.

If inhaled

: If unconscious place in recovery position and seek medical advice.

If symptoms persist, call a physician.

SDS Number: 100000003334 2 / 9 Propylene glycol Industrial

In case of skin contact

: Wash off with soap and water.

Wash contaminated clothing before reuse.

Get medical attention if irritation develops and persists.

In case of eye contact

: Remove contact lenses.

Protect unharmed eye.

If eye irritation persists, consult a specialist.

If swallowed

: Keep respiratory tract clear.

Do not give milk or alcoholic beverages.

Never give anything by mouth to an unconscious person.

If symptoms persist, call a physician.

Do not induce vomiting without medical advice.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media

: Carbon dioxide (CO2) Foam Dry chemical

Unsuitable extinguishing media

: High volume water jet

Specific hazards during fire-fighting

: Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion prod-ucts

: No hazardous combustion products are known

Further information : Standard procedure for chemical fires.

Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.

Special protective equipment for firefighters

: Wear self-contained breathing apparatus for firefighting if nec-essary.

Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Methods and materials for containment and cleaning up

: Wipe up with absorbent material (e.g. cloth, fleece).

Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Advice on safe handling

: For personal protection see section 8.

Smoking, eating and drinking should be prohibited in the ap-

SDS Number: 100000003334 3 / 9 Propylene glycol Industrial plication area.

Conditions for safe storage

: Electrical installations / working materials must comply with the technological safety standards.

Materials to avoid

: No materials to be especially mentioned.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

CAS-No. Components Value type (Form of exposure)

Control parame-ters / Permissible concentration

Basis

57-55-6 Propylene glycol TWA 10 mg/m3 US WEEL

Personal protective equipment

Respiratory protection

: General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are un-known, appropriate respiratory protection should be worn.

Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respi-rator if there is any potential for uncontrolled release, expo-sure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.

Eye protection

: Safety glasses

Skin and body protection

: Protective suit

Hygiene measures

: General industrial hygiene practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

: liquid

Colour

: Clear, Colorless

Odour

: odourless, mild

Odour Threshold

: No data available pH

: 7 @ 20 - 25 °C (68 - 77 °F)

Freezing Point (Melting point/freezing point)

: -60 - -20 °C (-76 - -4 °F)

Boiling Point (Boiling : 184 - 188 °C (363 - 370 °F)

SDS Number: 100000003334 4 / 9 Propylene glycol Industrial point/boiling range)

Flash point

: 103 °C (217 °F)

Evaporation rate

: < 0.02 (Butyl Acetate = 1)

Flammability (solid, gas)

Upper explosion limit

: 17.4 %(V)

Lower explosion limit

: 2.4 %(V)

Vapour pressure

: < 0.225 mmHg @ 25 °C (77 °F)

Relative vapour density

: < 2.62 @ 15 - 32 °C (59 - 90 °F) (Air = 1.0)

Relative density

: 1.03 - 1.04 @ 20 - 25 °C (68 - 77 °F) Reference substance: (water = 1)

Density

: 1.03 - 1.04 g/cm3 @ 20 - 25 °C (68 - 77 °F)

Solubility(ies) Water solubility

: soluble

Solubility in other solvents

Partition coefficient: n-octanol/water

: log Pow: -1.07 - -0.92

Auto-ignition temperature

: 371 - 400 °C

Thermal decomposition

Viscosity Viscosity, dynamic

: 43 - 56 mPa.s @ 20 - 25 °C (68 - 77 °F)

Viscosity, kinematic

: 42.1 mm2/s @ 25 °C (77 °F)

< 20 mm2/s @ 40 °C (104 °F)

Surface tension

: 71.6 mN/m, 21.5 °C

SECTION 10. STABILITY AND REACTIVITY

Reactivity

: No dangerous reaction known under conditions of normal use.

Chemical stability

: Stable under normal conditions.

Possibility of hazardous reac-tions

: No hazards to be specially mentioned.

SDS Number: 100000003334 5 / 9 Propylene glycol Industrial

Conditions to avoid

: Keep away from heat, flame, sparks and other ignition sources.

Exposure to light.

Incompatible materials

: Amines isocyanates mercaptans Reducing agents Strong oxidizing agents Acids Bases

Hazardous decomposition products

: Aldehydes Alcohols ethers Organic acids Carbon oxides toxic fumes

SECTION 11. TOXICOLOGICAL INFORMATION

Carcinogenicity

IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

OSHA

equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.

NTP

equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

ACGIH

equal to 0.1% is identified as a carcinogen or potential carcino-gen by ACGIH.

Further information

Product:

Remarks: No data available

SDS Number: 100000003334 6 / 9 Propylene glycol Industrial

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Other adverse effects

Product:

Ozone-Depletion Potential

: Regulation: 40 CFR Protection of Environment; Part 82 Pro-tection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufac-tured with a Class I or Class II ODS as defined by the U.S.

Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological infor-mation

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : Dispose of in accordance with all applicable local, state and federal regulations.

For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact NEXEO's Environmental Services Group at 800-637-7922.

Contaminated packaging : Empty containers should be taken to an approved waste han-dling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

DOT (Department of Transportation): Not regulated as a dangerous good

UNRTDG

Not regulated as a dangerous good

SDS Number: 100000003334 7 / 9 Propylene glycol Industrial

IATA (International Air Transport Association): Not regulated as a dangerous good

IMDG-Code: Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

WHMIS Classification

: : Not controlled.

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards

: No SARA Hazards

SARA 302

: No chemicals in this material are subject to the reporting re-quirements of SARA Title III, Section 302.

SARA 313

: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Sec-tion 12 (40 CFR 61).

This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).

The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489):

57-55-6 Propylene glycol

Clean Water Act

This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A.

This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3.

This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307

US State Regulations

Massachusetts Right To Know

No components are subject to the Massachusetts Right to Know Act.

Pennsylvania Right To Know

57-55-6 Propylene glycol 90 - 100 %

New Jersey Right To Know

57-55-6 Propylene glycol 90 - 100 %

SDS Number: 100000003334 8 / 9 Propylene glycol Industrial

California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re-productive harm.

The components of this product are reported in the following inventories:

TSCA

: On TSCA Inventory

DSL

: All components of this product are on the Canadian DSL

AICS

: On the inventory, or in compliance with the inventory

NZIoC

ENCS

KECI

PHIL

IECSC

SECTION16. OTHER INFORMATION

NFPA: HMIS III:

The information accumulated is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made become available subsequently to the date hereof, we do not assume any responsibility for the results of its use. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by NEXEO™ Solutions EHS Product Safety Department (1-855-429-2661) MSDS@nexeosolutions.com.

Revision Date

: 04/03/2017

Legacy SDS:

: R0001099

Flammability

H e a lt h

In s ta b ility

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

Special hazard.

0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 =Extreme, * = Chronic

SDS Number: 100000003334 9 / 9 Propylene glycol Industrial

Material number:

16117093, 16098634, 16056587, 16063761, 16056593, 16056591, 16056590, 16056589, 16056588, 16043949, 16022504, 16019678, 16007436, 16004870, 16004164, 16003701, 16002316, 732692, 708878, 707122, 706609, 686369, 684080, 670322, 652122, 643524, 643523, 643513, 587634, 541219, 508483, 103938, 54799, 54594, 87351, 56279, 103733, 89037, 58343, 104793, 54901, 105725, 72031, 87659, 89343, 89366, 55654, 87662, 105726, 105744, 89347, 56608, 72035, 87663, 158868, 173039, 504375, 500039, 500083, 29993, 29992, 20248, 20247, 20246

Key or legend to abbreviations and acronyms used in the safety data sheet

ACGIH American Conference of Gov-ernment Industrial Hygienists

LD50 Lethal Dose 50%

AICS Australia, Inventory of Chemical Substances

LOAEL Lowest Observed Adverse Effect Level

DSL Canada, Domestic Substances List

NFPA National Fire Protection Agency

NDSL Canada, Non-Domestic Sub-stances List

NIOSH National Institute for Occupational Safety & Health

CNS Central Nervous System NTP National Toxicology Program

CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemicals

EC50 Effective Concentration NOAEL No Observable Adverse Effect Level

EC50 Effective Concentration 50% NOEC No Observed Effect Concentration

EGEST EOSCA Generic Exposure Sce-nario Tool

OSHA Occupational Safety & Health Administra-tion

EOSCA European Oilfield Specialty Chemicals Association

PEL Permissible Exposure Limit

EINECS European Inventory of Existing Chemical Substances

PICCS Philippines Inventory of Commercial Chemical Substances

MAK Germany Maximum Concentra-tion Values

PRNT Presumed Not Toxic

GHS Globally Harmonized System RCRA Resource Conservation Recovery Act

>= Greater Than or Equal To STEL Short-term Exposure Limit

IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reauthori-zation Act.

IARC International Agency for Research on Cancer

TLV Threshold Limit Value

IECSC Inventory of Existing Chemical Substances in China

TWA Time Weighted Average

ENCS Japan, Inventory of Existing and New Chemical Substances

TSCA Toxic Substance Control Act

KECI Korea, Existing Chemical Invento-ry

UVCB Unknown or Variable Composition, Com-plex Reaction Products, and Biological Materials

<= Less Than or Equal To WHMIS Workplace Hazardous Materials Infor-mation System

LC50 Lethal Concentration 50%