Reference_Question-Answer_1_ROOFLINER_MSDS_SHEETS.pdf

MATERIAL DATA SHEETS POLYUREA

ROOFLINER

Roofliner is the first generation of Aromatic Polyurea to combine both the waterproofing and chemical resistance of a Polyurea instant set membrane with the addition of a micro-blowing agent to create a Polyurea that expands between 5 to 7 times its original volume. Primary uses include, but are not limited to: Complete seamless, self-flashing roofing systems as a standalone product or sprayed over almost existing roof systems. On a sloped visible roof applications an application of THPolymer 101 single component colored Aliphatic can be applied if special colors are desired. Foundation Waterproofing: Roofliner is self-priming and eliminates the need for bug hole fillers.

Physical Properties Tensile Strength D412 1395 Elongation D412 300% 100% Modulus D412 1300 Tear Strength (PLI) D2240 162 Hardness (Shore D) D1737 30 Flexibility (1/8” Mandrel) D1737 85 Flashpoint (F) Pensky-Martin >200 Taper Abrasion (mg loss) CS18 Wheel

1kg per 1000 cycles 22 Hail Stone E822 Pass Thermal Resistance Summer Flow R 2

Roofliner is to be applied by a Hot High Pressure Plural Component Machine A – Side Temperature 120 Degrees F B – Side Temperature 120 Degrees F Hose Heat – 120 Degrees F Pressure at Machine – 1500 PSI **Temperature degrees and pressure may need adjusting due to ambient temperature

MSDS

Spray Equipment and Coatings INC.

ROOFLINER, INC.

Roofliner A-Side Material Safety Data Sheet

SECTION 1 – MATERIAL IDENTIFICATION

Product Name: Roofliner A-side Product Class: Polymeric MDI

SECTION 2 – HAZARDOUS INGREDIENTS

Ingredient CAS # Weight % TLV 4, 4” – Diphenylmethane Diisocyanate 101-68-8 50% 0.02 ppm

SECTION 3 – PHYSCIAL DATA

BOILING POINT: Decomposes at 646 degrees F, 341.1 degrees C

SPECIFIC GRAVITY: 1.2

VAPOR PRESSURE: @20oC <0,0001

PERCENT VOLATILE: NA

VAPOR DENSITY: NA

EVAPORATION RATE: NA

APPEARANCE: Light yellow liquid with faint odor

SECTION 4 – FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: 400 degrees F, 204 degrees C (COC) EXTINGUISHING MEDIA: Dry chemical, foam, CO2, halogenated agents. If water is used, use very large quantities. The reaction between water and hot isocyanate may be vigorous.

SPECIAL FIRE FIGHTING PRODDERS: Fire fighters should be equipped with self-contained breathing apparatus.

UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid water contamination in closed containers or confined area (carbon dioxide evolved)

SECTION 5 – HEALTH HAZARD DATA

PERMISSIBLE EXPOSURE LEVEL: See section 2 EFFECTS OF OVEREXPOSURE: Respiratory irritant-also causes respiratory sensitization with asthma like symptoms in exposed individuals. Skin and eyes contact can cause irritation, reddening, swelling, rash, scaling, or blistering; ingestion – irritation or ulceration EMERGENCY AND FIRST AID PROCEDURES: Eyes – Flush with water-obtain medical attention; Skin – wash with soap and water – clean contaminated clothing;

Ingestion – do not induce vomiting, call physician and/or transport to emergency facility immediately; Inhalation – remove victim to fresh air, give oxygen – and call a physician.

SECTION 6 – REACTIVITY DATA

STABILITY: Stable under normal conditions CONDITIONS TO AVOID: Reaction with water forming carbon dioxide INCOMPATIBILITY: This product will react with any materials containing active hydrogens, such as water, alcohol, ammonia, amines, alkalies, and acids. The reaction with water is very slow under 50 degrees C, but is accelerated at higher temperatures and in the presence of alkalies, tertiary amines and metal compounds.

Some reactions can be violent.

HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2, NO2, NO trace HCN HAZARDOUS POLYMERIZATION: May occur. High temperatures in the presence of alkalies, tertiary amines, and metal compounds will accelerate polymerization.

Possible evolution of CO2 gas may rupture closed containers.

CONDITIONS TO AVOID: Moisture contamination.

SECTION 7 – SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate and ventilate area, dike spill, prevent entry of water; clean up personnel, wear full protective equipment. Absorb with sawdust and shovel into unsealed containers.

WASTE DISPOSAL METHOD: Follow federal, state and local regulations. Incineration is the preferred method or material should be neutralized in accordance with state and local regulations.

SECTION 8 – SPECIAL PROTECTION INFORMATION

RESPIRATORY PROTECTION: Wear a NIOSH approved air supply VENTILATION: As necessary to maintain below PEL PROTECTIVE GLOVES: Rubber or PVC

EYE PROTECTION: Chemical goggles OTHER PROTECTIVE EQUIPMENT: Use impervious protective clothing

SECTION 9 - SPECIAL PRECAUTIONS

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep containers tightly closed, store between 60 to 80 degrees F in a cool, dry place to protect from freezing OTHER PRECAUTIONS: In case of Emergency contact Chemtree: 800-424-9300

SECTION 10 – ADDITIONAL REGULATORY INFORMATION

TSCA (Toxic Substances Control Act) Regulations, 40 CFR 710:

All ingredients are on the TSCA Chemical Substance Inventory.

SARA TITLE III SECTION 313:

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and of CFR 372:

CAS # Chemical Name Percent by Weight None

PROP 65 (CARCINOGEN)

Warning: This product contains a chemical known to the state of California to cause cancer.

CAS # Chemical Name Percent by Weight None

PROP 65 (TERATOGEN)

Warning: This product contains a chemical known to the state of California to cause birth defects or other reproductive harm.

CAS # Chemical Name Percent by Weight None

TRANSPORTATION CLASSIFICATION: Not regulated

This information herein is given in good faith, but no warranty, expressed or implied, is made.

MSDS B Side

Roofliner B-Side Material Safety Data Sheet

SECTION 1 – MATERIAL IDENTIFICATION

Product Name: Roofliner B-side Product Class: Polymeric Polyol

SECTION 2 – HAZARDOUS INGREDIENTS

Ingredient CAS # Weight % TLV Di-(methylthio) toluendediamine 106264-79-3 15 Not Est. (1) Polyoxypropylenglycol 9082-00-2 85 Not Est. (1)

SECTION 3 – PHYSCIAL DATA

BOILING POINT: Not established

SPECIFIC GRAVITY: 1.05

VAPOR PRESSURE: Not established SOL IN WATER: Soluble

APPEARANCE: Cloudy white liquid

SECTION 4 – FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: N/A LEL: NA UFL: NA

EXTINGUISHING MEDIA: Water fog, CO2, dry chemical, chemical foam SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing, use water to cool containers to prevent spillage UNUSUAL FIRE AND EXPLOSION HAZARDS: low hazard

SECTION 5 – HEALTH HAZARD DATA

PERMISSIBLE EXPOSURE LEVEL: See section 2 EFFECTS OF OVEREXPOSURE: Eyes: irritation, possible eye injury; inhalation: odor considered only annoying; skin: moderately irritating, can cause redness or drying of skin; ingestion: small amounts not likely to cause injury EMERGENCY AND FIRST AID PROCEEDURES: Eyes – Flush with water-obtain medical attention; Skin – wash with soap and water; Ingestion – induce vomiting, call physician.

SECTION 6 – REACTIVITY DATA

STABILITY: Stable CONDITIONS TO AVOID: Do not inhale smoke when burning and extreme high temperatures INCOMPATIBILITY: alkali or alkaline earth metals, strong acids, copper, brass and elastomeric materials.

HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2, Nox; under fire conditions HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Isocyanates, oxidizing materials or strong acids

SECTION 7 – SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Contain spill, avoid personal contact, apply absorbent material (sawdust or inert dirt) or wipe up with suitable material, place in open container – wash area with detergent and water.

WASTE DISPOSAL METHOD: Because this is a petroleum base product, it may cause pollution - do not discharge into ground, streams, ponds or public water. Follow federal, state, and local regulations.

SECTION 8 – SPECIAL PROTECTION INFORMATION

RESPIRATORY PROTECTION: None required VENTILATION: No special requirements PROTECTIVE GLOVES: Rubber or PVC EYE PROTECTION: Chemical goggles OTHER PROTECTIVE EQUIPMENT: None

SECTION 9 – SPECIAL PRECAUTIONS

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep containers tightly closed, store between 60 to 80 F in a cool, dry place to protect from freezing OTHER PRECAUTIONS: In case of emergency contact Chemtree 800-424-9300 TRANSPORTATION CLASSIFICATION: Not regulated

SECTION 10 – ADDITIONAL REGULATORY INFORMATION

TSCA (Toxic Substances Control Act) Regulations, 40 CFR 710:

All ingredients are on the TSCA Chemical Substance Inventory.

SARA TITLE III SECTION 313:

This product contains the following toxic chemicals seduce to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and of CFR 372:

CAS # Chemical Name Percent by Weight 101-68-8 Methylenebis 50% MDI

PROP 65 (CARCINOGEN)

Warning: This product contains a chemical known to the state of California to cause cancer.

CAS # Chemical Name Percent by Weight None

PROP 65 (TERATOGEN)

Warning: This product contains a chemical known to the state of California to cause birth defects or other reproductive harm.

CAS # Chemical Name Percent by Weight None

TRANSPORATION REGULATION: Not regulated

This information herein is given in good faith, but no warranty, expressed or implied, is made.