RFI Attch. 3 - SDS-2.pdf

CA8221/F26173 BASE COMPONENT

Not available.

Liquid.

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Section 1. Identification

Product code : CA8221/F26173 BASE COMPONENT

Date of issue/Date of revision 12 June 2021

Version 11

Relevant identified uses of the substance or mixture and uses advised against

Uses advised against Not applicable.

Product use : Industrial applications.

Use of the substance/ mixture

: Coating.

Manufacturer PPG Aerospace PRC-DeSoto 12780 San Fernando Road Sylmar, CA 91342 Phone: 818 362 6711

(412) 434-4515 (U.S.)

(514) 645-1320 (Canada) 01-800-00-21-400 (Mexico)

Emergency telephone number

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2

Classification of the substance or mixture

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 5.2% (oral), 10.9% (dermal), 39.8% (inhalation)

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many PPG products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8).

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CA8221/F26173 BASE COMPONENTProduct name

11Product code Date of issue VersionCA8221/F26173 BASE COMPONENT 12 June 2021

Section 2. Hazards identification

Signal word : Warning

Hazard statements : Flammable liquid and vapor.

Harmful if inhaled.

Suspected of causing cancer.

Suspected of damaging fertility or the unborn child.

Hazard pictograms :

Precautionary statements

Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.

Use non-sparking tools. Take action to prevent static discharges. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Avoid breathing vapor.

Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.

Storage : Store locked up. Store in a well-ventilated place. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

: Sanding and grinding dusts may be harmful if inhaled. Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.

Hazards not otherwise classified

: Prolonged or repeated contact may dry skin and cause irritation.

Section 3. Composition/information on ingredients titanium dioxide ≥10 - ≤20 13463-67-7 barium sulfate ≥10 - ≤20 7727-43-7 heptan-2-one ≥10 - ≤15 110-43-0 pentane-2,4-dione ≥10 - ≤15 123-54-6 2,6-dimethylheptan-4-one ≥5.0 - ≤10 108-83-8 1,3-Benzenedicarboxylic acid, polymer with 2,2-dimethyl-1,3-propanediol, 1,2-ethanediol, hexanedioic acid and 1,6-hexanediol

≥1.0 - ≤4.6 69929-19-7 butanone ≥0.10 - ≤2.5 78-93-3 Acetic acid, C8-10-branched alkyl esters, C9-rich ≤1.5 108419-33-6 xylene ≤1.2 1330-20-7

Ingredient name CAS number%

Substance/mixture : Mixture Product name CA8221/F26173 BASE COMPONENT:

United States Page: 2/18

Section 3. Composition/information on ingredients carbon black ≤1.0 1333-86-4 toluene <1.0 108-88-3 ethylbenzene <1.0 100-41-4 4-methylpentan-2-one <1.0 108-10-1

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

SUB codes represent substances without registered CAS Numbers.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation :

:Ingestion Skin contact :

:Eye contact

Over-exposure signs/symptoms

Skin contact

Inhalation Adverse symptoms may include the following:

reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following:

irritation dryness cracking reduced fetal weight increase in fetal deaths skeletal malformations

Eye contact : No specific data.

Potential acute health effects

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

No known significant effects or critical hazards.

Harmful if inhaled.

No known significant effects or critical hazards.

Defatting to the skin. May cause skin dryness and irritation.

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Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Ingestion Adverse symptoms may include the following:

reduced fetal weight increase in fetal deaths skeletal malformations

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon oxides sulfur oxides metal oxide/oxides

Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For non-emergency personnel

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Section 6. Accidental release measures

Environmental precautions

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

Special precautions : Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Vapors are heavier than air and may spread along floors. If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts.

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Section 7. Handling and storage Conditions for safe storage, including any incompatibilities

Do not store above the following temperature: 50°C (122°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Use appropriate containment to avoid environmental contamination.

titanium dioxide OSHA PEL (United States, 5/2018).

TWA: 15 mg/m³ 8 hours. Form: Total dust ACGIH TLV (United States, 3/2020).

TWA: 10 mg/m³ 8 hours.

barium sulfate ACGIH TLV (United States, 3/2020).

TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction OSHA PEL (United States, 5/2018).

TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust heptan-2-one ACGIH TLV (United States, 3/2020).

TWA: 233 mg/m³ 8 hours.

TWA: 50 ppm 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 465 mg/m³ 8 hours.

TWA: 100 ppm 8 hours.

pentane-2,4-dione ACGIH TLV (United States, 3/2020).

Absorbed through skin.

TWA: 25 ppm 8 hours.

2,6-dimethylheptan-4-one ACGIH TLV (United States, 3/2020).

TWA: 145 mg/m³ 8 hours.

TWA: 25 ppm 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 290 mg/m³ 8 hours.

TWA: 50 ppm 8 hours.

1,3-Benzenedicarboxylic acid, polymer with 2,2-dimethyl- 1,3-propanediol, 1,2-ethanediol, hexanedioic acid and 1,6-hexanediol

None.

butanone ACGIH TLV (United States, 3/2020).

STEL: 885 mg/m³ 15 minutes.

STEL: 300 ppm 15 minutes.

TWA: 590 mg/m³ 8 hours.

TWA: 200 ppm 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 590 mg/m³ 8 hours.

TWA: 200 ppm 8 hours.

Acetic acid, C8-10-branched alkyl esters, C9-rich None.

xylene

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits

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Section 8. Exposure controls/personal protection ACGIH TLV (United States, 3/2020).

STEL: 651 mg/m³ 15 minutes.

STEL: 150 ppm 15 minutes.

TWA: 434 mg/m³ 8 hours.

TWA: 100 ppm 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 435 mg/m³ 8 hours.

TWA: 100 ppm 8 hours.

carbon black ACGIH TLV (United States, 3/2020).

TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction OSHA PEL (United States, 5/2018).

TWA: 3.5 mg/m³ 8 hours.

toluene OSHA PEL Z2 (United States, 2/2013).

AMP: 500 ppm 10 minutes.

CEIL: 300 ppm TWA: 200 ppm 8 hours.

ACGIH TLV (United States, 3/2020).

TWA: 20 ppm 8 hours.

ethylbenzene ACGIH TLV (United States, 3/2020).

TWA: 20 ppm 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 435 mg/m³ 8 hours.

TWA: 100 ppm 8 hours.

4-methylpentan-2-one ACGIH TLV (United States, 3/2020).

STEL: 75 ppm 15 minutes.

TWA: 20 ppm 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 410 mg/m³ 8 hours.

TWA: 100 ppm 8 hours.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Recommended monitoring procedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards.

Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Key to abbreviations A Acceptable Maximum Peak=

ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

Potential skin absorptionS SR = Respiratory sensitization

= Skin sensitizationSS

TD = Total dust

Consult local authorities for acceptable exposure limits.

= Threshold Limit ValueTLV TWA = Time Weighted Average

Fume=F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration.OSHA R = Respirable

OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z

STEL =

Short term Exposure limit values

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Section 8. Exposure controls/personal protection

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Eye/face protection

Respiratory protection :

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection :

Safety glasses with side shields.

Gloves For prolonged or repeated handling, use the following type of gloves:

May be used: nitrile rubber Recommended: butyl rubber, polyvinyl alcohol (PVA), Viton®, neoprene, natural rubber (latex)

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.

The respiratory protection shall be in accordance to 29 CFR 1910.134.

Section 9. Physical and chemical properties

Physical state

Melting point

Liquid.

Not available.

Not available.Odor pH

Gray.Color

Not applicable.

Not available.Odor threshold

Appearance

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Section 9. Physical and chemical properties

Vapor pressure

Relative density

Vapor density

Solubility

1.3

Not available.

Not available.

Insoluble in the following materials: cold water.

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: 26.67°C (80°F)

Not applicable.

Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)

Partition coefficient: n-octanol/water

Boiling point : >37.78°C (>100°F)

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

VOC : 490.5 g/l

% Solid. (w/w) : 62.36

Density ( lbs / gal ) : 10.85

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

The product is stable.Chemical stability :

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

When exposed to high temperatures may produce hazardous decomposition products.

Keep away from the following materials to prevent strong exothermic reactions:

oxidizing agents, strong alkalis, strong acids.

Refer to protective measures listed in sections 7 and 8.

Depending on conditions, decomposition products may include the following materials:

carbon oxides sulfur oxides metal oxide/oxides

Section 11. Toxicological information

Acute toxicity

Information on toxicological effects

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Section 11. Toxicological information titanium dioxide LC50 Inhalation Dusts and mists Rat >6.82 mg/l 4 hours LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat >5000 mg/kg -barium sulfate LD50 Dermal Rat >2000 mg/kg - LD50 Oral Rat >5000 mg/kg -heptan-2-one LC50 Inhalation Vapor Rat 16.7 mg/l 4 hours LD50 Dermal Rabbit 10.206 g/kg - LD50 Oral Rat 1.6 g/kg -pentane-2,4-dione LC50 Inhalation Vapor Rat 5.1 mg/l 4 hours LD50 Dermal Rat 790 mg/kg - LD50 Oral Rat 570 mg/kg -

2,6-dimethylheptan-4-one LD50 Dermal Rabbit 16 g/kg - LD50 Oral Rat 5750 mg/kg -butanone LD50 Dermal Rabbit 6480 mg/kg - LD50 Oral Rat 2737 mg/kg -

Acetic acid, C8-10-branched alkyl esters, C9-rich

LD50 Oral Rat - Female >2000 mg/kg -xylene LD50 Dermal Rabbit 1.7 g/kg - LD50 Oral Rat 4.3 g/kg -carbon black LD50 Oral Rat >10 g/kg -toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours

LD50 Dermal Rabbit 8.39 g/kg - LD50 Oral Rat 5580 mg/kg -ethylbenzene LC50 Inhalation Vapor Rat 17.8 mg/l 4 hours LD50 Dermal Rabbit 17.8 g/kg - LD50 Oral Rat 3.5 g/kg -

4-methylpentan-2-one LC50 Inhalation Vapor Rat 12.3 mg/l 4 hours LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 2.08 g/kg -

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary :

Mutagenicity

Irritation/Corrosion xylene Skin - Moderate irritant Rabbit - 24 hours 500 mg

Product/ingredient name Result Score Exposure Observation

Conclusion/Summary Skin :

Eyes :

Respiratory :

Sensitization

Conclusion/Summary Skin :

Respiratory :

Species

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

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Section 11. Toxicological information

Carcinogenicity

Conclusion/Summary :

Acetic acid, C8-10-branched alkyl esters, C9-rich

OECD 471 Bacterial Reverse Mutation Test

Experiment: In vitro Subject: Bacteria

Positive

Product/ingredient name Test Experiment Result

Conclusion/Summary :

Teratogenicity

Conclusion/Summary :

Reproductive toxicity

Conclusion/Summary :

Specific target organ toxicity (single exposure)

Classification titanium dioxide - 2B -xylene - 3 -carbon black - 2B -toluene - 3 -ethylbenzene - 2B - 4-methylpentan-2-one - 2B -

Product/ingredient name NTPIARCOSHA

Carcinogen Classification code:

IARC: 1, 2A, 2B, 3, 4

NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen

OSHA: +

Not listed/not regulated: -

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

Specific target organ toxicity (repeated exposure)

Name heptan-2-one Category 3 - Narcotic effects 2,6-dimethylheptan-4-one Category 3 - Respiratory tract irritation butanone Category 3 - Narcotic effects Acetic acid, C8-10-branched alkyl esters, C9-rich Category 3 - Respiratory tract irritation Category 3 Narcotic effects xylene Category 3 - Respiratory tract irritation toluene Category 3 - Narcotic effects 4-methylpentan-2-one Category 3 - Respiratory tract irritation

Category Route of exposure

Target organs

Name Category toluene Category 2 - -ethylbenzene Category 2 - hearing organs

Route of exposure

Target organs

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Section 11. Toxicological information

Conclusion/Summary :

Information on the likely routes of exposure

Delayed and immediate effects and also chronic effects from short and long term exposure

Aspiration hazard

Name Result

2,6-dimethylheptan-4-one ASPIRATION HAZARD - Category 1 Acetic acid, C8-10-branched alkyl esters, C9-rich ASPIRATION HAZARD - Category 1 xylene ASPIRATION HAZARD - Category 1 toluene ASPIRATION HAZARD - Category 1 ethylbenzene ASPIRATION HAZARD - Category 1

Potential acute health effects

Inhalation : Harmful if inhaled.

No known significant effects or critical hazards.:Ingestion Skin contact : Defatting to the skin. May cause skin dryness and irritation.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:

reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following:

reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following:

irritation dryness cracking reduced fetal weight increase in fetal deaths skeletal malformations

Eye contact : No specific data.

There are no data available on the mixture itself. This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification.

For many PPG products, TiO2 is utilized as a raw material in a liquid coating formulation.

In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8). Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.

Symptoms and signs include headache, dizziness, fatigue, muscular weakness, Target organs : Contains material which causes damage to the following organs: mucous membranes, brain, .

Contains material which may cause damage to the following organs: kidneys, lungs, the nervous system, liver, peripheral nervous system, upper respiratory tract, immune system, skin, central nervous system (CNS), eye, lens or cornea.

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Section 11. Toxicological information

General :

Carcinogenicity :

Mutagenicity :

Reproductive toxicity :

Potential chronic health effects

Numerical measures of toxicity

Acute toxicity estimates

Potential immediate effects

Short term exposure

Potential delayed effects :

Potential immediate effects

Long term exposure

Potential delayed effects :

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

drowsiness and, in extreme cases, loss of consciousness. Solvents may cause some of the above effects by absorption through the skin. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. If splashed in the eyes, the liquid may cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.

Suspected of damaging fertility or the unborn child.

No known significant effects or critical hazards.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

Product/ingredient name

CA8221/F26173 BASE COMPONENT 2651.8 4489.3 N/A 19.8 6.9

barium sulfate N/A 2500 N/A N/A N/A heptan-2-one 1600 10206 N/A 16.7 1.5 pentane-2,4-dione 570 790 N/A 5.1 N/A 2,6-dimethylheptan-4-one 5750 16000 N/A N/A N/A 1,3-Benzenedicarboxylic acid, polymer with 2,2-dimethyl-1,3-propanediol, 1,2-ethanediol, hexanedioic acid and 1,6-hexanediol

500 N/A N/A N/A N/A butanone 2737 6480 N/A N/A N/A Acetic acid, C8-10-branched alkyl esters, C9-rich 2500 N/A N/A N/A N/A xylene 4300 1700 N/A 11 1.5 toluene 5580 8390 N/A 49 N/A ethylbenzene 3500 17800 N/A 17.8 1.5 4-methylpentan-2-one 2080 N/A N/A 12.3 1.5

Oral (mg/ kg)

Dermal (mg/kg)

Inhalation (gases) (ppm)

Inhalation (vapors) (mg/l)

Inhalation (dusts and mists) (mg/ l)

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Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Product/ingredient name heptan-2-one 2.26 - low pentane-2,4-dione 0.68 - low 2,6-dimethylheptan-4-one 3.71 - low butanone 0.3 - low xylene 3.12 7.4 to 18.5 low toluene 2.73 8.32 low ethylbenzene 3.6 79.43 low 4-methylpentan-2-one 1.9 - low

Product/ingredient name Aquatic half-life Photolysis Biodegradability heptan-2-one - - Readily xylene - - Readily toluene - - Readily ethylbenzene - - Readily 4-methylpentan-2-one - - Readily

Toxicity titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours heptan-2-one Acute LC50 131 mg/l Fish 96 hours ethylbenzene Acute LC50 150 to 200 mg/l Fresh water Fish 96 hours 4-methylpentan-2-one Acute LC50 >179 mg/l Fish 96 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability heptan-2-one OECD 310 69 % - Readily - 28 days - - 4-methylpentan-2-one OECD 301F 83 % - Readily - 28 days - -

Product/ingredient name Test DoseResult Inoculum

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.

:Disposal methods

United States Page: 14/18

Section 13. Disposal considerations Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures

14. Transport information

PAINT

III

PAINT

III

PAINT

UN1263

III

UN1263 UN1263

DOT IMDG IATA

UN number

UN proper shipping name

Transport hazard class (es)

Packing group

Environmental hazards No. No. No.

Marine pollutant substances

Not applicable.Not applicable.

RQ substances

8771.6

(xylene)

Not applicable.

Not applicable.

Not applicable.

Not applicable.

Not applicable.

Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Additional information Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.

None identified.

DOT

IMDG

IATA : None identified.

Product RQ (lbs)

Transport in bulk according to IMO instruments

: Not applicable.

Section 15. Regulatory information

All components are active or exempted.United States inventory (TSCA 8b) :

United States

United States - TSCA 12(b) - Chemical export notification:

pentane-2,4-dione One time notification

United States - TSCA 5(a)2 - Proposed significant new use rules:

pentane-2,4-dione Listed

United States Page: 15/18

Section 15. Regulatory information

SARA 302/304

SARA 304 RQ : Not applicable.

Composition/information on ingredients

No products were found.

SARA 311/312

Classification : FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 HNOC - Defatting irritant titanium dioxide ≥10 - ≤20 CARCINOGENICITY - Category 2 heptan-2-one ≥10 - ≤15 FLAMMABLE LIQUIDS - Category 3

ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (inhalation) - Category 4

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Narcotic effects) - Category 3 HNOC - Defatting irritant pentane-2,4-dione ≥10 - ≤15 FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 3 ACUTE TOXICITY (inhalation) - Category 3

2,6-dimethylheptan-4-one ≥5.0 - ≤10 FLAMMABLE LIQUIDS - Category 3

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Respiratory tract irritation) - Category 3 ASPIRATION HAZARD - Category 1 HNOC - Defatting irritant

1,3-Benzenedicarboxylic acid, polymer with 2,2-dimethyl- 1,3-propanediol, 1,2-ethanediol, hexanedioic acid and 1,6-hexanediol

≥1.0 - ≤4.6 COMBUSTIBLE DUSTS

ACUTE TOXICITY (oral) - Category 4 EYE IRRITATION - Category 2A butanone ≥0.10 - ≤2.5 FLAMMABLE LIQUIDS - Category 2 EYE IRRITATION - Category 2A

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Narcotic effects) - Category 3 HNOC - Defatting irritant

Acetic acid, C8-10-branched alkyl esters, C9-rich

≤1.5 FLAMMABLE LIQUIDS - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Respiratory tract irritation) - Category 3

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Narcotic effects) - Category 3 ASPIRATION HAZARD - Category 1 xylene ≤1.2 FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (dermal) - Category 4 ACUTE TOXICITY (inhalation) - Category 4

Name % Classification

Composition/information on ingredients

United States Page: 16/18

Section 15. Regulatory information

SARA 313

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

California Prop. 65

Supplier notification Chemical name

: xylene 1330-20-7 0.5 - 1.5 ethylbenzene 100-41-4 0.1 - 1 4-methylpentan-2-one 108-10-1 0.1 - 1

CAS number Concentration

SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Respiratory tract irritation) - Category 3 ASPIRATION HAZARD - Category 1 carbon black ≤1.0 COMBUSTIBLE DUSTS CARCINOGENICITY - Category 2 toluene <1.0 FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 TOXIC TO REPRODUCTION - Category 2

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Narcotic effects) - Category 3

SPECIFIC TARGET ORGAN TOXICITY (REPEATED

EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 HNOC - Defatting irritant ethylbenzene <1.0 FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (inhalation) - Category 4 CARCINOGENICITY - Category 2

SPECIFIC TARGET ORGAN TOXICITY (REPEATED

EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 HNOC - Defatting irritant

4-methylpentan-2-one <1.0 FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (inhalation) - Category 4 EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Respiratory tract irritation) - Category 3 HNOC - Defatting irritant

WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.

Section 16. Other information Hazardous Material Information System (U.S.A.)

3Health Flammability Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

: : :2 * 0 ( * ) - Chronic effects

United States Page: 17/18

Section 16. Other information

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations

National Fire Protection Association (U.S.A.)

Health InstabilityFlammability

Disclaimer

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products.

Date of previous issue 5/14/2021:

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Indicates information that has changed from previously issued version.

Organization that prepared the SDS

: EHS

:: :2

United States Page: 18/18

CA 8200B M&D ACTIVATOR COMPONENT

Liquid.

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Section 1. Identification

Product code : CA 8200B M&D ACTIVATOR COMPONENT

Date of issue/Date of revision 2 September 2023

Version 21

Relevant identified uses of the substance or mixture and uses advised against

Uses advised against Not applicable.

Product use : Industrial applications.

Use of the substance/ mixture

: Coating.; Hardener.

Manufacturer PPG Aerospace PRC-DeSoto 12780 San Fernando Road Sylmar, CA 91342 Phone: 818 362 6711

(412) 434-4515 (U.S.)

(514) 645-1320 (Canada) 01-800-00-21-400 (Mexico)

Emergency telephone number

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

Classification of the substance or mixture

Signal word : Danger

Hazard pictograms :

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1.3% (dermal), 2.3% (inhalation)

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

United States Page: 1/16

CA 8200B M&D ACTIVATOR COMPONENTProduct name

21Product code Date of issue VersionCA 8200B M&D ACTIVATOR

COMPONENT

2 September 2023

Section 2. Hazards identification Hazard statements : Flammable liquid and vapor.

May cause an allergic skin reaction.

Harmful if inhaled.

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

May cause respiratory irritation.

Precautionary statements

Prevention : Wear protective gloves, protective clothing and eye or face protection. Wear respiratory protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.

Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Contaminated work clothing must not be allowed out of the workplace.

Response : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. If experiencing respiratory symptoms:

Call a POISON CENTER or doctor. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention.

Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

: Moisture-sensitive material. Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Skin contact to isocyanate monomer may lead to allergic lung reaction. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.

Hazards not otherwise classified

: Prolonged or repeated contact may dry skin and cause irritation.

Section 3. Composition/information on ingredients Substance/mixture : Mixture Product name CA 8200B M&D ACTIVATOR COMPONENT:

United States Page: 2/16

COMPONENT

2 September 2023

Section 3. Composition/information on ingredients

Hexamethylene diisocyanate, oligomers. ≥75 - ≤90 28182-81-2 heptan-2-one ≥5.0 - ≤10 110-43-0 n-butyl acetate ≥1.0 - ≤5.0 123-86-4 Solvent naphtha (petroleum), light aromatic ≥0.10 - ≤2.7 64742-95-6 1,2,4-trimethylbenzene ≤1.6 95-63-6 hexamethylene-di-isocyanate <1.0 822-06-0

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

SUB codes represent substances without registered CAS Numbers.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation :

:Ingestion

Skin contact :

:Eye contact

Over-exposure signs/symptoms

Inhalation Adverse symptoms may include the following:

respiratory tract irritation coughing wheezing and breathing difficulties asthma

Eye contact : No specific data.

Potential acute health effects

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

No known significant effects or critical hazards.

Harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

No known significant effects or critical hazards.

Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin reaction.

United States Page: 3/16

COMPONENT

2 September 2023

Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments : No specific treatment.

Skin contact

Ingestion No specific data.

Adverse symptoms may include the following:

irritation redness dryness cracking

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon oxides nitrogen oxides Cyanate and isocyanate.

hydrogen cyanide

Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

United States Page: 4/16

COMPONENT

2 September 2023

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.