RFI Attch. 2 - SDS-1.pdf

Akzo Nobel Coatings Inc. encourages and expects you to read and understand this entire MSDS, as there is important information throughout the document. Further, Akzo Nobel Coatings Inc. expects you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.

To promote safe handling, each customer or recipient should: 1) Notify its employees, agents, contractors, and others whom it knows or believes will use this material of the information contained in this MSDS and any other information regarding hazards and safety; 2) Furnish this same information to each of its customers for the product; 3) Request its customers to notify their employees, customers, and other users of the product of this information; and 4) Notify its employees, agents, contractors, and others that the precautions identified for this product and any other products with which mixtures may be created are transferable and cumulative to the mixture.

SAFETY DATA SHEET

Date of issue / Date of revision :

Safety Data Sheet Version :

Composite Filler Putty 467-9

CHEMTREC +1 (800) 424-9300 (Inside the US) CHEMTREC International +1 (703) 527-3887 (Outside the US, collect calls accepted)

GHS product identifier Other means of identification :

Supplier/Manufacturer :

Emergency telephone number :

Section 1. Identification

Akzo Nobel Coatings Ltd.

110 Woodbine Downs Blvd.

Unit #4 Etobicoke, Ontario Canada M9W 5S6 +1 (800) 618-1010

Canadian Supplier :

Relevant identified uses of the substance or mixture and uses advised against

FOR INDUSTRIAL USE ONLY:

22 June 2020 4.01

Composite Filler Putty 467-9

Akzo Nobel Coatings, Inc.

22 June 2020Date of printing :

Akzo Nobel Coatings, Inc.

1 East Water Street Waukegan, IL 60085

USA

Tel. 1 847 623 4200 Email: customer.

service@akzonobel.com

467-9_WHITE HIGH BUILD FILLER PUTTY

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 2 EYE IRRITATION - Category 2A CARCINOGENICITY - Category 1A

Classification of the substance or mixture

GHS label elements

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

For additional information call Akzo Nobel at (847) 625-4200 To request an updated SDS please visit http://www.formstack.com/forms/AkzoNobel-document_request_form

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International Paint LLC

Section 2. Hazards identification

Signal word : Danger Hazard statements : Highly flammable liquid and vapor.

Causes serious eye irritation.

May cause cancer.

Hazard pictograms :

Precautionary statements

Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.

Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Ground/bond container and receiving equipment.

Keep container tightly closed. Wash hands thoroughly after handling.

Response : IF exposed or concerned: Get medical attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF IN EYES:

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Store locked up. Store in a well-ventilated place. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

: None known.

Section 3. Composition/information on ingredients

Talc , not containing asbestiform fibres 15 - 20 14807-96-6 Mica-group minerals 15 - 20 12001-26-2 2-butoxyethanol 10 - 15 111-76-2 Kaolin 10 - 15 1332-58-7 titanium dioxide 10 - 15 13463-67-7 butanone 5 - 10 78-93-3 n-butyl acetate 1 - 5 123-86-4 Urea, polymer with formaldehyde, butylated 1 - 5 68002-19-7 butan-1-ol 1 - 5 71-36-3 crystalline silica, respirable powder 1 - 5 14808-60-7 ethylbenzene 0 - 1 100-41-4

Ingredient name CAS number%

Substance/mixture :

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

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Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Description of necessary first aid measures

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

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Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides

Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

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Section 6. Accidental release measures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area.

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink.

Store locked up. Eliminate all ignition sources. Separate from oxidizing materials.

Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.

Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.

Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

Section 8. Exposure controls/personal protection Control parameters

Occupational exposure limits

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Section 8. Exposure controls/personal protection

Talc , not containing asbestiform fibres NIOSH REL (United States, 10/2016).

TWA: 2 mg/m³ 10 hours. Form: Respirable fraction ACGIH TLV (United States, 3/2016).

TWA: 2 mg/m³ 8 hours. Form: Respirable fraction

Mica-group minerals ACGIH TLV (United States, 3/2016).

TWA: 3 mg/m³ 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2016).

TWA: 3 mg/m³ 10 hours. Form: Respirable fraction OSHA PEL Z3 (United States, 6/2016).

TWA: 20 mppcf 8 hours.

2-butoxyethanol ACGIH TLV (United States, 3/2017).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 10/2016).

Absorbed through skin.

TWA: 24 mg/m³ 10 hours.

TWA: 5 ppm 10 hours.

OSHA PEL (United States, 6/2016).

Absorbed through skin.

TWA: 240 mg/m³ 8 hours.

TWA: 50 ppm 8 hours.

Kaolin ACGIH TLV (United States, 3/2016).

TWA: 2 mg/m³ 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2016).

TWA: 5 mg/m³ 10 hours. Form: Respirable fraction TWA: 10 mg/m³ 10 hours. Form: Total OSHA PEL (United States, 6/2016).

TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust titanium dioxide OSHA PEL (United States, 6/2016).

TWA: 15 mg/m³ 8 hours. Form: Total dust ACGIH TLV (United States, 3/2016).

TWA: 10 mg/m³ 8 hours.

butanone ACGIH TLV (United States, 3/2016).

STEL: 885 mg/m³ 15 minutes.

STEL: 300 ppm 15 minutes.

TWA: 590 mg/m³ 8 hours.

TWA: 200 ppm 8 hours.

NIOSH REL (United States, 10/2016).

STEL: 885 mg/m³ 15 minutes.

STEL: 300 ppm 15 minutes.

TWA: 590 mg/m³ 10 hours.

TWA: 200 ppm 10 hours.

OSHA PEL (United States, 6/2016).

Ingredient name Exposure limits

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Section 8. Exposure controls/personal protection TWA: 590 mg/m³ 8 hours.

TWA: 200 ppm 8 hours.

n-butyl acetate NIOSH REL (United States, 10/2016).

STEL: 950 mg/m³ 15 minutes.

STEL: 200 ppm 15 minutes.

TWA: 710 mg/m³ 10 hours.

TWA: 150 ppm 10 hours.

OSHA PEL (United States, 6/2016).

TWA: 710 mg/m³ 8 hours.

TWA: 150 ppm 8 hours.

ACGIH TLV (United States, 3/2017).

STEL: 150 ppm 15 minutes.

TWA: 50 ppm 8 hours.

Urea, polymer with formaldehyde, butylated None.

butan-1-ol ACGIH TLV (United States, 3/2016).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 10/2016).

Absorbed through skin.

CEIL: 150 mg/m³ CEIL: 50 ppm OSHA PEL (United States, 6/2016).

TWA: 300 mg/m³ 8 hours.

TWA: 100 ppm 8 hours.

crystalline silica, respirable powder OSHA PEL Z3 (United States, 6/2016).

TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:

Respirable TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:

Respirable OSHA PEL (United States, 6/2016).

TWA: 50 µg/m³ 8 hours. Form: Respirable dust ACGIH TLV (United States, 3/2016).

TWA: 0.025 mg/m³ 8 hours. Form:

Respirable fraction NIOSH REL (United States, 10/2016).

TWA: 0.05 mg/m³ 10 hours. Form: respirable dust ethylbenzene ACGIH TLV (United States, 3/2017).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 10/2016).

STEL: 545 mg/m³ 15 minutes.

STEL: 125 ppm 15 minutes.

TWA: 435 mg/m³ 10 hours.

TWA: 100 ppm 10 hours.

OSHA PEL (United States, 6/2016).

TWA: 435 mg/m³ 8 hours.

TWA: 100 ppm 8 hours.

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Section 8. Exposure controls/personal protection

Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

Respiratory protection :

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting/freezing point

Liquid.

Not available.

Solvent.Odor pH

White.Color

Not available.

Not available.Odor threshold

Appearance

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Section 9. Physical and chemical properties

Vapor pressure

Relative density

Vapor density

Solubility

1.57

Not available.

Not available.

Not available.

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: -5°C (23°F)

Not available.

Viscosity Kinematic (room temperature): 10.19 cm2/s (1019 cSt)

Partition coefficient: n-octanol/water

Boiling point : 80°C (176°F)

Flammability (solid, gas) : Not available.

Decomposition temperature : Not available.

Solubility in water : Not available.

Upper/lower flammability or explosive limits Upper: : Not determined.

Lower: Not determined.:

Weight Volatiles : 25.94% (w/w)

Volume Volatiles : 47.23 %(v/v)

Weight Solids : 74.06 %(w/w)

Volume Solids 52.77 %(v/v):

boiling range : Not available.

Density : 13.10 lbs/gal 1.57 g/cm³

VOC Actual 4073.4 g/llbs/gal:

Regulatory VOC 4073.4: g/llbs/gal minus water and exempt solvents

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Reactive or incompatible with the following materials:

oxidizing materials

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

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Section 11. Toxicological information

Acute toxicity butanone LD50 Dermal Rabbit 6480 mg/kg - LD50 Oral Rat 2737 mg/kg -n-butyl acetate LC50 Inhalation Vapor Rat 390 ppm 4 hours LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg -butan-1-ol LD50 Dermal Rabbit 3400 mg/kg - LD50 Oral Rat 790 mg/kg -ethylbenzene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg -

Product/ingredient name Result Species Dose Exposure

Mutagenicity

Not available.

Irritation/Corrosion

Talc , not containing asbestiform fibres

Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent

2-butoxyethanol Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams

Eyes - Severe irritant Rabbit - 100 milligrams

Skin - Mild irritant Rabbit - 500 milligrams titanium dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent butanone Skin - Mild irritant Rabbit - 24 hours 14 milligrams

Skin - Moderate irritant Rabbit - 24 hours 500 milligrams n-butyl acetate Eyes - Moderate irritant Rabbit - 100 milligrams

Skin - Moderate irritant Rabbit - 24 hours 500 milligrams butan-1-ol Eyes - Severe irritant Rabbit - 24 hours 2 milligrams

Eyes - Severe irritant Rabbit - 0.005 Mililiters

Skin - Moderate irritant Rabbit - 24 hours 20 milligrams ethylbenzene Eyes - Severe irritant Rabbit - 500 milligrams

Skin - Mild irritant Rabbit - 24 hours 15 milligrams

Product/ingredient name Result Score Exposure Observation

Sensitization

Not available.

Species

Information on toxicological effects

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Section 11. Toxicological information Carcinogenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Information on the likely routes of exposure

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure) n-butyl acetate Category 3 Not applicable. Narcotic effects

Name Category

Not available.

Aspiration hazard

Name Result ethylbenzene ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

: Not available.

Potential acute health effects

Classification

Talc , not containing asbestiform fibres

- 3 -

2-butoxyethanol - 3 -titanium dioxide - 2B -crystalline silica, respirable powder

- 1 Known to be a human carcinogen.

ethylbenzene - 2B -

Product/ingredient name NTPIARCOSHA

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Section 11. Toxicological information

Not available.

No known significant effects or critical hazards.General :

May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Oral 3754.4 mg/kg Dermal 47842 mg/kg

Route ATE value

Acute toxicity estimates

Potential immediate effects

: Not available.

Short term exposure

Potential delayed effects : Not available.

Potential immediate effects

: Not available.

Long term exposure

Potential delayed effects : Not available.

Section 12. Ecological information Toxicity

2-butoxyethanol Acute EC50 >1000 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 800000 to 1000000 µg/l Marine water

Crustaceans - Crangon crangon 48 hours

Acute LC50 1250000 µg/l Marine water Fish - Menidia beryllina 96 hours butanone Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours

Acute EC50 5091000 to 6440000 µg/l Fresh water

Daphnia - Daphnia magna - Larvae

48 hours

Acute LC50 5600 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours n-butyl acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours

Acute LC50 62000 µg/l Fish - Danio rerio 96 hours butan-1-ol Acute EC50 1983000 to 2072000 µg/l

Fresh water Daphnia - Daphnia magna 48 hours

Acute LC50 1910000 µg/l Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling)

96 hours

Product/ingredient name SpeciesResult Exposure

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Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

2-butoxyethanol 0.81 - low butanone 0.3 - low n-butyl acetate 2.3 - low butan-1-ol 1 - low ethylbenzene 3.6 - low ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata

72 hours

Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata

96 hours

Acute EC50 2930 to 4400 µg/l Fresh water

Daphnia - Daphnia magna - Neonate

48 hours

Acute LC50 40000 µg/l Marine water Crustaceans - Cancer magister - Zoea

48 hours

Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Not available.

Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

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Section 14. Transport information

PAINT

II

PAINT

II

PAINT

UN1263

II

UN1263 UN1263

DOT

Classification

IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Environmental hazards

Special precautions for user

No. No. No.

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

TDG

Classification

UN1263

PAINT

II

No.

Mexico Classification

UN1263

PAINT

II

No.

Please Note: The information provided in section 14 is based on a bulk package shipment via ground transport in North America. All shippers are responsible for ensuring the proper transportation classification and package/container requirements are followed for the relevant mode of transport.

United States inventory (TSCA 8b): All components are listed or exempted.

Section 15. Regulatory information

U.S. Federal regulations

SARA 311/312

Classification : Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard

SARA 313

Product name CAS number %

2-butoxyethanol 111-76-2 10 - 15 butan-1-ol 71-36-3 1 - 5 ethylbenzene 100-41-4 0.1 - 1

Form R - Reporting requirements

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

California Prop. 65

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Composite Filler Putty 467-9 Page: 15/16

Section 15. Regulatory information WARNING: This product contains a chemical known to the State of California to cause cancer.

WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.

International lists

National inventory

Australia : All components are listed or exempted.

All components are listed or exempted.:Canada China : All components are listed or exempted.

All components are listed or exempted.:Europe

Japan : Japan inventory (ENCS): All components are listed or exempted.

Japan inventory (ISHL): At least one component is not listed.

At least one component is not listed.:Malaysia

New Zealand : At least one component is not listed.

All components are listed or exempted.:Philippines

Republic of Korea : All components are listed or exempted.

All components are listed or exempted.:Taiwan

Turkey : At least one component is not listed.

Ingredient name Cancer Reproductive No significant risk level

Maximum acceptable dosage level titanium dioxide Yes. No. No. No.

ethylbenzene Yes. No. No. No.

Formaldehyde, solution Yes. No. No. No.

benzene Yes. Yes. 6.4 µg/day

(ingestion) 13 µg/day (inhalation)

24 µg/day (ingestion) 49 µg/day (inhalation) toluene No. Yes. No. 7000 µg/day (ingestion)

Section 16. Other information Hazardous Material Information System (U.S.A.)

*Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

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Section 16. Other information

History

Date of issue/Date of revision

Version

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Notice to reader

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

4.01

National Fire Protection Association (U.S.A.)

Health

Special

Instability/Reactivity

Flammability

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals.

The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

22 June 2020

MSDS # : 004114 0004 0030449140

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Akzo Nobel Coatings Inc. encourages and expects you to read and understand this entire MSDS, as there is important information throughout the document. Further, Akzo Nobel Coatings Inc. expects you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.

To promote safe handling, each customer or recipient should: 1) Notify its employees, agents, contractors, and others whom it knows or believes will use this material of the information contained in this MSDS and any other information regarding hazards and safety; 2) Furnish this same information to each of its customers for the product; 3) Request its customers to notify their employees, customers, and other users of the product of this information; and 4) Notify its employees, agents, contractors, and others that the precautions identified for this product and any other products with which mixtures may be created are transferable and cumulative to the mixture.

SAFETY DATA SHEET

Date of issue / Date of revision :

Safety Data Sheet Version :

Composite Filler Putty CA-41B

CHEMTREC +1 (800) 424-9300 (Inside the US) CHEMTREC International +1 (703) 527-3887 (Outside the US, collect calls accepted)

GHS product identifier Other means of identification :

Supplier/Manufacturer :

Emergency telephone number :

Section 1. Identification

Akzo Nobel Coatings Ltd.

110 Woodbine Downs Blvd.

Unit #4 Etobicoke, Ontario Canada M9W 5S6 +1 (800) 618-1010

Canadian Supplier :

Relevant identified uses of the substance or mixture and uses advised against

FOR INDUSTRIAL USE ONLY:

28 October 2020

Composite Filler Putty CA-41B

Akzo Nobel Coatings, Inc.

28 October 2020Date of printing :

Akzo Nobel Coatings, Inc.

1 East Water Street Waukegan, IL 60085

USA

Tel. 1 847 623 4200 Email: customer.

service@akzonobel.com

CA-41B_Curing Solution for 467-9

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (inhalation) - Category 2 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A

Classification of the substance or mixture

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

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Section 2. Hazards identification

Signal word : Danger Hazard statements : Highly flammable liquid and vapor.

Fatal if inhaled.

Harmful if swallowed.

Causes serious eye irritation.

Causes skin irritation.

Hazard pictograms :

Precautionary statements

Prevention : Wear protective gloves. Wear eye or face protection. Wear respiratory protection.

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Ground/bond container and receiving equipment. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.

Response : IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Immediately call a POISON CENTER or physician. IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:

Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Store locked up. Store in a well-ventilated place. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

GHS label elements

Hazards not otherwise classified

: None known.

Section 3. Composition/information on ingredients

2,2'-iminodiethylamine 45 - 50 111-40-0 butanone 40 - 45 78-93-3 n-butyl acetate 5 - 10 123-86-4 toluene 1 - 5 108-88-3

Ingredient name CAS number%

Substance/mixture :

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

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Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation : Fatal if inhaled.

Harmful if swallowed.:Ingestion

Skin contact : Causes skin irritation.

Causes serious eye irritation.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

Adverse symptoms may include the following:

irritation redness

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

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Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Specific treatments : No specific treatment.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon dioxide carbon monoxide nitrogen oxides

Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

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Section 6. Accidental release measures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area.

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink.

Store locked up. Eliminate all ignition sources. Separate from oxidizing materials.

Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

Section 8. Exposure controls/personal protection Control parameters

Occupational exposure limits

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Section 8. Exposure controls/personal protection

2,2'-iminodiethylamine ACGIH TLV (United States, 3/2017).

Absorbed through skin.

TWA: 4.2 mg/m³ 8 hours.

TWA: 1 ppm 8 hours.

NIOSH REL (United States, 10/2016).

Absorbed through skin.

TWA: 4 mg/m³ 10 hours.

TWA: 1 ppm 10 hours.

butanone ACGIH TLV (United States, 3/2016).

STEL: 885 mg/m³ 15 minutes.

STEL: 300 ppm 15 minutes.

TWA: 590 mg/m³ 8 hours.

TWA: 200 ppm 8 hours.

NIOSH REL (United States, 10/2016).

STEL: 885 mg/m³ 15 minutes.

STEL: 300 ppm 15 minutes.

TWA: 590 mg/m³ 10 hours.

TWA: 200…