HPH_MSDS _26_Jan_2010_(Arch).pdf

Arch Chemicals.

Inc.

FOR ANY EMERGENCY, 24 HOURS /7 DAYS, CALL: 1-800-654-6911 (OUTSIDE

USA: 1-423-780-2970)

FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: 1-800-424-9300 (OUTSIDE

USA: 1-703-527-3887)

FOR ALL MSDS QUESTIONS & REQUESTS, CALL: 1-800-511-MSDS (OUTSIDE

USA: 1-423-780-2347)

PRODUCT NAME: ULTRA PURE(TM) HYDRAZINE 5F

1. PRODUCT AND COMPANY IDENTIFICATION

REVISION DATE 01/26/2010

Arch Chemicals, Inc. SUPERCEDES: 09/16/2009 501 Merritt 7 PO Box 5204 Norwalk, CT 06856·5204

MSDS Number: 000000000390 SYNONYMS. None CHEMICAL FAMILY Hydrazine DESCRIPTION 1USE: Aerospace fuel component.

FORMULA None established

2.-HAZARDS IDENTIFICATION

OSHA Hazard Classification:

Toxic by ingestion and inhalation, Highly toxic by dermal contact, Possible carcinogen., Corrosive to eyes, skin and mucous membranes, Lung, liver, kidney and nervous system toxin, Skin sensitizer, Combustible liquid

Routes of Entry: Inhalation, skin, eyes, ingestion Chemical Interactions: No known or reported interactions.

Medical Conditions Aggravated: Liver, kidney, respiratory and central nervous system disorders

Human Threshold Response Data

Odor Threshold Irritation Threshold

HYDRAZINE Not established.

Hazardous Materials Identification System I National Fire Protection Association Classifications

Hazard Ratings: Flammability PhYSical 1 Instability PPII Special hazard.

HMIS 3* 3 3

NFPA 3 3 3

ULTRA PURE(TM) HYDRAZINE 5F

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Immediate (Acute) Health Effects Inhalation Toxicity Toxic by inhalation. This product is rapidly absorbed through the lungs.

Immediate and prolonged contact may result in the following: damage to the liver and kidneys with symptoms of vomiting, diarrhea, nausea, dizziness and convulsions. Inhalation of this material may produce severe irritating and/or corrosive effects to the nose, mouth, throat, and respiratory tract. It may cause burns which can result in symptoms which may include coughing, wheezing, choking, shortness of breath, chest pain, and impairment of lung function. Inhalation of high concentrations can also result in permanent lung damage. May cause pulmonary edema (fluid build-up in lungs).

Skin Toxicity May be highly toxic or fatal if absorbed. This product is rapidly absorbed through the skin, and may result in the following: damage to the liver and kidneys with symptoms of vomiting, diarrhea, nausea, dizziness and convulsions. Dermal exposure can cause severe irritation and/or burns characterized by redness, swelling, and scab formation. Prolonged skin exposure may cause permanent damage. Dermal contact may cause defatting of skin and/or dermatitis.

Eye Toxicity: Severe irritation and/or burns can occur following exposure. Direct contact may cause impairment of vision and corneal damage. Rinsing of the eye should take place immediately.

Ingestion Toxicity Toxic if swallowed. Irritation and/or burns can occur to the entire gastrointestinal tract, including the stomach and intestines, characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding, and/or tissue ulceration or perforation. This product is rapidly absorbed through the lungs. Immediate and prolonged contact may result in the following: damage to the liver and kidneys with symptoms of vomiting, diarrhea, nausea, dizziness and convulsions.

Acute Target Organ Toxicity: This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to mucous membranes and respiratory tract., Damage occurs to liver, kidney, central nervous system, and lungs.

Prolonged (Chronic) Health Effects

Carcinogenicity:

Reproductive and Developmental Toxicity:

Inhalation:

Skin Contact

Skin Absorption

Ingestion:

The International Agency for Research on Cancer (lARC) has classified this product or a component of this product as a Group 28 substance, Possibly Carcinogenic to Humans.

Reproductive and/or developmental toxicity was observed in laboratory animals only at high doses that were maternally toxic.

Prolonged or repeated exposure may cause continuous bronchitis.

Prolonged or repeated inhalation may cause lung damage.

Prolonged or repeated exposure may cause extensive permanent skin damage.

This product is rapidly absorbed through the skin, and may result in the following: damage to the liver and kidneys with symptoms of vomiting, diarrhea, nausea, dizziness and convulsions. Prolonged or repeated exposure may be fatal.

Chronic ingestion of this product may cause severe irritation and possible corrosive effects. The acute corrosivity of this product, makes chronic ingestion of significant amounts unlikely.

ULTRA PLlRE(TM) HYDRAZINE 5F REVISION DATE: 01/26/2010 Page 2 of 12

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Eye Contact Prolonged contact may result in permanent damage. Corneal involvement or visual impairment is expected.

Sensitization: May cause allergic skin sensitization in some individuals.

Chronic Target Organ Toxicity Liver, Kidneys, Lungs, Central nervous system Supplemental Health Hazard No additional health information available.

Information:

3. COMPOSITION I INFORMATION ON INGREDIENTS

CAS OR CHEMICAL NAME CAS # % RANGE

HYDRAZINE 302-01-2 99.5 - 100

4. FIRST AID MEASURES

Inhalation:

Skin Contact

Eye Contact:

Ingestion

Notes to Physician:

IF INHALED: Remove individual to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops. If not breathing, give artificial respiration. Call for medical assistance.

IF ON SKIN: Immediately flush skin with plenty of water for 15 minutes. If clothing comes in contact with the product, the clothing should be removed immediately and disposed of. Call a physician.

IF IN EYES: Immediately flush eyes with plenty of water for at least 15 minutes.

Seek medical attention immediately.

IF SWALLOWED: Call a physician immediately. DO NOT induce vomiting unless directed to do so by a physician. Never give anything by mouth to an unconscious person.

Pyridoxine (Vitamin B6) has been used successfully to treat the neurological symptoms of hydrazine exposure.

5. FIRE FIGHTING MEASURES

Flammability Summary (OSHA):

Flammable Properties Flash Point:

Autoignition Temperature:

Fire / Explosion Hazards:

Extinguishing Media:

Combustible.

38 DEGoC / 100 DEGoF Test Method: US Bureau of Mines Bulletin 627: 270 DEGoC 518 DEGoF Material may be ignited if preheated to temperatures above the flash point in the presence of a source of ignition. Can form explosive mixtures at temperatures at or above the flash point.

Use alcohol foam, carbon dioxide, dry chemical or water spray when fighting fires.

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Fire Fighting Instructions: Response to this material requires the use of a full encapsulated suit and full-face (NIOSH approved) self-contained breathing apparatus (SCBA). Use water to cool containers.

Hazardous Combustion Products: Ammonia, Hydrogen Upper Flammable I Explosive limit, % in air: 100 Vol%

Lower Flammable I Explosive limit, % in air: 4.7 Vol%

6. ACCIDENTAL RELEASE MEASURES

Personal Protection for Emergency Situations

Spill Mitigation Procedures

Air Release:

Water Release:

Land Release:

Additional Spill Information:

Response to this material requires the use of a full encapsulated suit and full-face (NIOSH approved) self-contained breathing apparatus

(SCBA).

Vapors may be suppressed by the use of water fog. Contain all liquid for treatment and/or disposal as a (potential) hazardous waste.

This material is heavier than water. This material is miscible in water. Notify all downstream users of possible contamination. Divert water flow around spill if possible and safe to do so.

Dike spill area as soon as possible. Dilute the spilled material to about 10% with water. Neutralize the diluted material by slowly adding a 5-8% calcium hypochlorite solution until all the diluted material has been reacted. DO NOT ADD DRY CALCIUM

HYPOCHLORITE TO THE SPILL AS A VIOLENT REACTION MAY

RESULT. If unable to remove as a liquid, absorb in clay, sand or a commercial absorbent. Do not place spill materials back in their original containers. This substance cannot be removed from leather.

All contaminated leather articles should be rinsed with water and discarded.

Remove all sources of ignition. If this material is released into a work area, evacuate the area immediately. Hazardous concentrations in air may be found in local spill area and immediately downwind.

Utilize emergency response personal protection equipment prior to the start of any response. Stop source of spill as soon as possible and notify appropriate personnel. This material may be neutralized for disposal; you are requested to contact Arch Chemicals at 1-800 654-6911 before beginning any such procedure. Decontaminate all clothing and the spill area using a detergent and flush with large amounts of water.

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7. HANDLING AND STORAGE

Handling: Avoid contact with material, avoid breathing vapors, use only in a well ventilated area, use bonding and grounding when transferring quantities of material. Do not take internally. Avoid contact with skin, eyes and clothing. Upon contact with skin or eyes, wash off with water.

Storage: Store in a cool dry ventilated location, away from sources of ignition or other incompatible conditions and chemicals. Keep container(s) closed. Avoid direct exposure to sunlight or ultraviolet (UV) light sources. Keep under a nitrogen blanket.

Shelf Life limitations: 5 Years if not opened and exposed to the atmosphere. Material older than five years should be retested before use.

Incompatible Materials for Storage: Strong oxidizing agents metal oxides organic materials with high surface area such as rags, cotton waste, sawdust, etc. peroxides Package only in T eflon® high density polyethylene or 304L or 347 stainless steels containing less than 0.5% molybdenum.

Do Not Store At temperatures Above: 51 DEG"C I 123DEG"F

8. EXPOSURE CONTROLS I PERSONAL PROTECTION

Ventilation: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep airborne exposures below the TLV, PEL or other recommended exposure limit.

Protective Equipment for Routine Use of Product

Respiratory Protection :

Respirator Type:

Skin Protection :

Eye Protection:

Protective Clothing Type:

Exposure limit Data

CHEMICAL NAME

HYDRAZINE

HYDRAZINE

Wear a NIOSH approved respirator if any exposure occurs.

NIOSH approved positive pressure supplied air respirator.

Wear impervious gloves, boots and apron to avoid skin contact. A full impervious suit is recommended if exposure is possible to a large portion of the body. A safety shower should be provided in the immediate work area.

Use chemical goggles and a faceshield. Emergency eyewash should be provided in the immediate work area.

Butyl rubber, Neoprene. Nitrile

CAS #

302-01-2

302-01-2

Name of limit Exposure ZUS_ACGIH 0.01 ppm TWA

ZUS_OSHAP1 1 ppm TWA

1.3 mg/m3 TWA

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9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State:

Form

Color:

Odor:

Molecular Weight:

Specific Gravity:

pH:

Boiling Point:

Freezing Point:

Melting Point:

Density:

Vapor Pressure:

Vapor Density:

Viscosity:

Fat Solubility:

Solubility in Water:

Partition coefficient n octanollwater:

Evaporation Rate:

Oxidizing:

Volatiles, % by vol.:

VOC Content

HAP Content liquid liquid colorless

Ammonia

32.04

1.004

10.1 -10.7 (1% solution in neutral, distilled water)

113 DEG"C 236 DEG"F

1 DEG"C 1 34 DEG"F

No data

1.004g/cc

14.9 mmHg (@ 25 Deg. C)

1.1 (air=1)

Miscible

100%

10. STABILITY AND REACTIVITY

Stability and Reactivity Summary:

Conditions to Avoid:

Chemical Incompatibility:

Hazardous Decomposition Products:

Decomposition Temperature:

Corrosive. Strong reducing agent. May become unstable at elevated temperatures andlor pressure. Not sensitive to mechanical shock. Product will not undergo hazardous polymerization.

Temperatures above the flash point in combination with sparks, open flames, or other sources of ignition., Avoid contact with organic materials.

Strong oxidizing agents, peroxides, nitrogen tetroxide, fuming nitric acid, fluorine, halogen fluorides, metal oxides such as those of iron, copper, lead, manganese, and molybdenum, Package only in T eflon® high density polyethylene or 304L or 347 stainless steels containing less than 0.5% molybdenum.

Ammonia, Hydrogen 270 DEG"C - , 518DEGoF

11. TOXICOLOGICAL INFORMATION

lILTRA PURE(TM) HYDRAZINE 5F REVISION DATE: 01/26/2010 Page 6 of 12

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IComponent Animal Toxicology Oral LD50 value:

HYDRAZINE LD50 60 mg/kg Rat

Dermal LD50 value:

HYDRAZINE LD50 91 mg/kg Rabbit

Inhalation LC50 value:

HYDRAZINE Inhalation LC50 4.00 h 570 ppm Rat HYDRAZINE Inhalation LC50 1 h 1.49 MG/L Rat HYDRAZINE Inhalation LC50 4.00 h 0.747 MG/L Rat

Product Animal Toxicity Oral LD50 value: LD50 = 60 mg/kg Rat Dermal LD50 value: LD50 = 91 mglkg Rabbit Inhalation LC50 Inhalation LC50 1 h = 1.49 MG/L Rat Inhalation LC50 4 h = 0.747 MG/L value Rat Skin Irritation: This material is expected to be corrosive.

Eye Irritation This material is expected to cause irreversible effects to the cornea with impairment of vision or corrosion to the eyes.

Skin Sensitization: ) Various species of untreated wood dust can elicit an allergic type skin irritation in sensitized persons., This material tested positive for skin sensitization in humans.

Acute Toxicity This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to mucous membranes and respiratory tract.Damage occurs to liver, kidney, central nervous system, and lungs.

Subchronic 1Chronic Damage occurs to liver, kidney, central nervous system, and lungs.

Toxicity

HYDRAZINE Damage occurs to liver, kidney, central nervous system, and lungs.

Reproductive and Reproductive and/or developmental toxicity was observed in laboratory Developmental Toxicity animals only at high doses that were maternally toxic.

Mutagenicity: This product has been tested and was found to be mutagenic.

Carcinogenicity: This chemical is considered to be a suspect human carcinogen based on animal data.

HYDRAZINE The International Agency for Research on Cancer (IARC) has classified this product or a component of this product as a Group 2B substance. Possibly Carcinogenic to Humans.

12. ECOLOGICAL INFORMATION

Overview: Moderately toxic to fish and other aquatic organisms.

REVISION DATE: 01/26/2010 Page 7 of 12

Arch MATERIAL SAFETY Chemicals. DATA SHEET lne.

Ecological Toxicity Values for: HYDRAZINE Rainbow trout (Salmo gairdneri), - 76 h LC50 6 mgll

Fathead minnow (Pimephales - (flow-through). 96 h LC50 5.98 mg/I promelas), Channel Catfish (lctalurus - (static). 96 h LC50 1.0 mgll punctatus rafinesque), Bluegill - (static). 96 h LC50 1.08 mgll Bluegill - (nominal, static). 96 h LC50 4.2 mgll (35% Hydrazine) Rainbow trout (Salmo gairdneri), - (nominal, static). 96 h LC50 4.3 mg/I (35% Hydrazine)

Daphnia magna, - 24 h EC50 2.3 mg/I Daphnia magna, - (nominal, static). 48 h LC50 0.46 mg/I (35% Hydrazine)

Green algae (Selenastrum - 72 h EC50 0.0061 mgll capricornutum),

13. DISPOSAL CONSIDERATIONS

CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF

THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF

UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT

LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE

AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES.

Waste Disposal Summary: If this product becomes a waste, it will be a hazardous waste.

Disposal Methods: As a hazardous liquid waste it must be disposed of in accordance with local, state and federal regulations.

Potential US EPA Waste Codes: U133

14. TRANSPORT INFORMATION

Land (US DOT): UN2029 RO, HYDRAZINE, ANHYDROUS 8 3, 6.1 I MARINE

POLLUTANT

Water (IMDG): UN2029 HYDRAZINE, ANHYDROUS, 8 3,6.1 MARINE POLLUTANT

Flash Point: 38 DEGoC Air (lATA): CONTACT ARCH'S TRANSPORTATION DEPARTMENT, Emergency Response Guide Number: ERG # 132

REVISION DATE: 01/26/2010 Page 8 of 12

Arch MATERIAL SAFETY Chemicals, DATA SHEET Inc.

Transportation Notes: Forbidden on passenger aircraft.

EMS: F-E, S-C

15. REGULATORY INFORMATION

UNITED STATES:

Toxic Substances Control Act (TSCA): The components of this product are listed on the TSCA

Inventory of Existing Chemical Substances.The components of this product are listed on the TSCA Inventory of Existing Chemical Substances.

EPA Pesticide Registration Number: None established

FIFRA Listing of Pesticide Chemicals Not registered in the US under FIFRA.Not registered in the US (40 CFR 180): under FIFRA.

Superfund Amendments and Reauthorization Act (SARA) Title III:

Hazard Categories Sections 311/312 (40 CFR 370.2):

Health Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard Physical Fire Hazard

Emergency Planning & Community Right to Know (40 CFR 355, App. A):

Extremely Hazardous Substance Section 302 - Threshold Planning Quantity:

ZUS_SAR302 TPQ (threshold planning None established quantity)

Reportable Quantity (49 CFR 172.101, Appendix):

ZUS_CERCLA Reportable quantity Hydrazine

Value: 11bs

ZUS_SAR302 Reportable quantity Hydrazine Value: 11bs

Supplier Notification Requirements (40 CFR 372.45),313 Reportable Components

ZUS_SAR313 De minimis concel)tration Hydrazine Value: < 0.1% by weight

Clean Air Act Toxic ARP Section 112r:

CM 112R

US. EPA Clean Air Act (CM) Section 112(r) Accidental Release Prevention (40 CFR 68.130) 011999 Threshold Quantity: 15,0001bs

HYDRAZINE

ULTRA PURE(TM) HYDRAZINE SF

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us. EPA Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) 01 1999 Toxic endpoint: 0.011 mg/L

HYDRAZINE

CM 112R None established

Clean Air Act Socmi:

HON SOC None established HON SOC None established

Clean Air Act VOC Section 111:

CM 111 None established CM 111 None established

Clean Air Act Haz. Air Pollutants Section 112:

ZUS_CMHAP

US. Clean Air Act - Hazardous Air Pollutants (HAP) 1990-01-01 Listed Hydrazine

US. Clean Air Act - High Risk Pollutants (HRP) 1994-10-21 Weighting Factor 100 Hydrazine

CMAP None established CMAP None established

State Right-to-Know Regulations Status of Ingredients

I COMPONENT NAME

HYDRAZINE

COMPONENT NAME

HYDRAZINE

Pennsylvania: Hazardous substance list 1989-08-11

HYDRAZINE

Environmental hazard, Special hazardous substance

Pennsylvania: Hazardous substance list 1990-01-01

HYDRAZINE (ANHYDROUS)

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hazardous substance

Pennsylvania: Hazardous substance list 1989-08-11

HYDRAZINE (ANHYDROUS)

New Jerse

CAS # COMPONENT NAME

302-01-2 HYDRAZINE

New Jersey:

ICAS # I COMPONENT NAME

HYDRAZINE

New Jersey Right to Know Hazardous Substance List (RTK-HSL) 2007-03-01

HYDRAZINE

Special Health Hazard - Carcinogen, Special Health Hazard - Corrosive, Special Health Hazard - Flammable - Fourth Degree, Special Health Hazard - Mutagen, Special Health Hazard - Reactive - Third Degree, Special Health Hazard - Teratogen

Massachusetts:

I CAS # I COMPONENT NAME

California Proposition 65:

CAS # COMPONENT NAME

302-01-2 HYDRAZINE

302-01-2 HYDRAZINE

California Proposition 65. Safe drinking water and toxic enforcement act.

No Significant Risk Levels 0.04 ug/day Hydrazine Carcinogen

California Proposition 65. Safe drinking water and toxic enforcement act.

No Significant Risk Levels 0.04 micrograms per day Hydrazine

California Proposition 65. Safe drinking water and toxic enforcement act.

Hydrazine Carcinogen

WHMIS Hazard Classification:

Ingredient Disclosure List (WHMIS)

REVISION DATE: 01/26/2010 Page 11 of 12

2007-08-24 Threshold limits: 0.1 Weight percent Hydrazine

Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 0.1 Weight percent Hydrazine

16. OTHER INFORMATION

MSDS REVISION STATUS: Revised to meet the ANSI standard of 16 sections

SECTIONS REVISED: 14

Major References : Available upon request.

THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO"eE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS.

ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT .•

ULTRA PURE(TM) HYDRAZINE SF

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