Series_73U.pdf

Safety Data Sheet

Issue Date 03-May-2024 Revision Date 03-May-2024 Revision Number 1

1. IDENTIFICATION

Product identifier Product Code F073U1327A Product Name ENDURA-SHIELD FISCHER 13SF UV PACK

Other means of identification Common Name SERIES 73U, PART A UN/ID no. 1263 Synonyms None

Recommended use of the chemical and restrictions on use Recommended Use industrial paint.

Uses advised against Consumer use, For professional use only. Not for residential use.

Details of the supplier of the safety data sheet

Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac)

2. HAZARDS IDENTIFICATION

Classification

OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation Category 2 Carcinogenicity Category 1A Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 1

Label elements

EMERGENCY OVERVIEW

Manufacturer Address Tnemec Company, Inc. 123 W. 23rd Avenue, North Kansas City, MO 64116-3094 (816) 474-3400 Distributor Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203, Boisbriand, Quebec Canada J7G 2T3

Flammable Liquids Category 2

Danger

Hazard statements Causes serious eye irritation May cause cancer May cause respiratory irritation. May cause drowsiness or dizziness Causes damage to organs through prolonged or repeated exposure Highly flammable liquid and vapor

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F073U1327A ENDURA-SHIELD FISCHER 13SF UV

PACK

Revision Date 03-May-2024

Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Do not eat, drink or smoke when using this product Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container tightly closed Ground/bond container and receiving equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Use explosion-proof electrical, ventilating, lighting and all material-handling equipment.

Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing In case of fire: Use CO2, dry chemical, or foam for extinction

Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Keep away from children

Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Other information Harmful to aquatic life with long lasting effects Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure).

Respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs

SEE SAFETY DATA SHEET

Acute Toxicity 41.85321 % of the mixture consists of ingredient(s) of unknown toxicity.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name CAS No. Weight-%

CRYSTALLINE SILICA (QUARTZ) 14808-60-7 10 - <30%

PROPYLENE GLYCOL MONOMETHYL ETHER 108-65-6 10 - <30%

Appearance viscous liquid Physical state liquid Odor No information available

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Revision Date 03-May-2024

ACETATE

TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 1 - <10%

METHYL ETHYL KETONE 78-93-3 1 - <10%

tert-BUTYL ACETATE 540-88-5 1 - <10%

P-CHLOROBENZOTRIFLUORIDE 98-56-6 1 - <10%

METHYL N-AMYL KETONE 110-43-0 1 - <10%

COPPER COMPOUNDS 147-14-8 1 - <10%

BIS (PENTAMETHYLPIPERIDYL) SEBACATE 41556-26-7 0.1 - <1%

PROPRIETARY - 0.1 - <1%

DISPERSING AGENT 68647-95-0 0.1 - <1%

ETHYL BENZENE 100-41-4 0.1 - <1%

PETROLEUM SOLVENT (NAPTHA) 64742-95-6 0.1 - <1%

*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

Description of first aid measures

General advice If symptoms persist, call a physician.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician.

Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.

Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing.

Most important symptoms and effects, both acute and delayed

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media High volume water jet.

Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes

Protective equipment and precautions for firefighters Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. Solvent vapors are heavier than air and may spread along floors. Flash back possible over considerable distance.

6. ACCIDENTAL RELEASE MEASURES

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Revision Date 03-May-2024

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all sources of ignition.

Environmental Precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.

Methods and material for containment and cleaning up

Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal.

Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

Handling Close container after each use. Avoid contact with eyes, skin and clothing. Do not eat, drink or smoke when using this product. If splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum. When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.

Conditions for safe storage, including any incompatibilities

Storage Keep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.

Incompatible products No information available.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH

CRYSTALLINE SILICA (QUARTZ)

14808-60-7

TWA: 0.025 mg/m3 respirable particulate matter

TWA: 50 µg/m3 50 mg/m3 respirable dust

TITANIUM DIOXIDE (TOTAL DUST)

13463-67-7

TWA: 0.2 mg/m3 nanoscale respirable particulate matter

TWA: 2.5 mg/m3 finescale respirable particulate matter

TWA: 15 mg/m3 total dust 5000 mg/m3

METHYL ETHYL KETONE

78-93-3

TWA: 75 ppm Skin

STEL: 150 ppm

TWA: 200 ppm TWA: 590 mg/m3

3000 ppm tert-BUTYL ACETATE 540-88-5

TWA: 50 ppm STEL: 150 ppm

TWA: 200 ppm TWA: 950 mg/m3

1500 ppm

P-CHLOROBENZOTRIFLUORIDE

98-56-6

TWA: 2.5 mg/m3 -

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250 mg/m3

Revision Date 03-May-2024

METHYL N-AMYL KETONE

110-43-0

TWA: 50 ppm TWA: 100 ppm TWA: 465 mg/m3

800 ppm

COPPER COMPOUNDS

147-14-8

TWA: 1 mg/m3 dust and mist - 100 mg/m3 dust and mist

ETHYL BENZENE

100-41-4

TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3

800 ppm

Appropriate engineering controls

Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV).

Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product.

Individual protection measures, such as personal protective equipment

Eye/face protection If splashes are likely to occur, wear Goggles

Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.

Avoid breathing dust created by cutting, sanding, or grinding.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state liquid Appearance viscous liquid Odor No information available Color No information available Odor threshold No information available

Property Values Remarks pH No data available Melting point / freezing point No data available Boiling point / boiling range No information available Flash point 27 °C / 80 °F Pensky Martens - Closed Cup Evaporation rate No data available Flammability (solid, gas) No data available Flammability Limit in Air No data available

Upper flammability limit No information available Lower flammability limit No information available

Vapor pressure No data available Vapor density No data available Specific gravity 1.37068 g/cm3 Water solubility Insoluble in cold water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity

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No data available

Revision Date 03-May-2024

Other Information

Molecular weight No information available Density 11.43148 lbs/gal Volatile organic compounds (VOC) content

3.10046 lbs/gal

Total volatiles weight percent 27.1221 % Total volatiles volume percent 40.6955 % Bulk density No information available

10. STABILITY AND REACTIVITY

Reactivity

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous reactions None under normal processing.

Conditions to avoid Heat, flames and sparks.

Incompatible materials No information available

Hazardous decomposition products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke).

Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide. Hydrocarbons.

11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure

Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination.

Eye contact Irritating to eyes.

Skin contact Irritating to skin.

Ingestion Harmful if swallowed.

Information on toxicological effects

Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.

Skin disorders.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Chronic Toxicity NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Cancer hazard.

Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure).

Sensitization No information available.

No data available

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Revision Date 03-May-2024

Mutagenicity No information available.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical name ACGIH IARC NTP OSHA

CRYSTALLINE SILICA

(QUARTZ)

14808-60-7

A2 Group 1 Known X

TITANIUM DIOXIDE (TOTAL

DUST)

13463-67-7

A3 Group 2B - X

P-CHLOROBENZOTRIFLU

ORIDE

98-56-6

Group 2B - X

ETHYL BENZENE

100-41-4

A3 Group 2B - X

Reproductive effects No information available.

STOT - single exposure No information available STOT - repeated exposure No information available

Target organ effects blood, Central nervous system, Gastrointestinal tract, Eyes, kidney, liver, Lungs, respiratory system, Skin.

Aspiration hazard Based on product level data, this product does not meet the requirement to be classified as an aspiration hazard. However, this product contains an ingredient that may cause aspiration if swallowed.

Acute Toxicity 41.85321 % of the mixture consists of ingredient(s) of unknown toxicity.

The following values are calculated based on chapter 3.1 of the GHS document

12. ECOLOGICAL INFORMATION

Ecotoxicity

47.5300138458 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical name Toxicity to algae Toxicity to fish Toxicity to daphnia

PROPYLENE GLYCOL

MONOMETHYL ETHER ACETATE

108-65-6

- LC50: 161 mg/L Pimephales promelas 96 h static

EC50: >500 mg/L Daphnia magna 48 h

METHYL ETHYL KETONE

78-93-3

- LC50: 3130 - 3320 mg/L Pimephales promelas 96 h flow-through

EC50: >520 mg/L Daphnia magna 48 h

EC50: 5091 mg/L Daphnia magna 48 h

EC50: 4025 - 6440 mg/L Daphnia magna 48 h Static tert-BUTYL ACETATE 540-88-5

- LC50: 296 - 362 mg/L Pimephales promelas 96 h flow-through

P-CHLOROBENZOTRIFLUORIDE

98-56-6

- LC50: 3 mg/L Danio rerio 96 h semi-static

EC50: 3.68 mg/L Daphnia magna 48 h

METHYL N-AMYL KETONE

110-43-0

- LC50: 126 - 137 mg/L Pimephales promelas 96 h flow-through

BIS (PENTAMETHYLPIPERIDYL)

SEBACATE

41556-26-7

- LC50: 0.97 mg/L Lepomis macrochirus 96 h static

ETHYL BENZENE

100-41-4

EC50: 4.6 mg/L Pseudokirchneriella subcapitata 72 h EC50: >438 mg/L

Pseudokirchneriella subcapitata 96 h EC50: 2.6 - 11.3 mg/L

Pseudokirchneriella subcapitata 72 h static

EC50: 1.7 - 7.6 mg/L Pseudokirchneriella subcapitata 96 h static

LC50: 11.0 - 18.0 mg/L Oncorhynchus mykiss 96 h static LC50: 4.2 mg/L Oncorhynchus mykiss 96 h semi-static LC50: 7.55 - 11 mg/L Pimephales promelas 96 h flow-through LC50: 32 mg/L Lepomis macrochirus

96 h static LC50: 9.1 - 15.6 mg/L Pimephales promelas 96 h static LC50: 9.6 mg/L Poecilia reticulata 96 h static

EC50: 1.8 - 2.4 mg/L Daphnia magna 48 h

PETROLEUM SOLVENT (NAPTHA) - LC50: 9.22 mg/L Oncorhynchus

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EC50: 6.14 mg/L Daphnia magna 48

Revision Date 03-May-2024

64742-95-6 mykiss 96 h h

Persistence and degradability No information available.

Bioaccumulation No information available.

Mobility in Environmental Media Chemical name log Pow

PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE

108-65-6

0.43

METHYL ETHYL KETONE

78-93-3

0.29 tert-BUTYL ACETATE 540-88-5

1.64

P-CHLOROBENZOTRIFLUORIDE

98-56-6

3.7

METHYL N-AMYL KETONE

110-43-0

1.98

COPPER COMPOUNDS

147-14-8

6.6

BIS (PENTAMETHYLPIPERIDYL) SEBACATE

41556-26-7

0.37

DISPERSING AGENT

68647-95-0

>5

ETHYL BENZENE

100-41-4

3.118

Other Adverse Effects No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.

Chemical name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes

METHYL ETHYL KETONE

78-93-3 U159 Included in waste streams:

F005, F039

200.0 mg/L regulatory level U159

XYLENE

1330-20-7

Included in waste stream:

F039

U239

ETHYL BENZENE

100-41-4

Included in waste stream:

F039

TOLUENE

108-88-3

U220 Included in waste streams:

F005, F024, F025, F039, K015, K036, K037, K149, K151

U220

Chemical name CAWAST

METHYL ETHYL KETONE

78-93-3 Toxic

Ignitable

COPPER COMPOUNDS

147-14-8 Toxic

ETHYL BENZENE

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Toxic

Revision Date 03-May-2024

100-41-4 Ignitable

14. TRANSPORT INFORMATION

DOT

UN/ID no. 1263 Proper Shipping Name PAINT Hazard Class 3 Packing Group II Emergency Response Guide Number

Additional Information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation.

15. REGULATORY INFORMATION

International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does Not Comply ENCS Does Not Comply IECSC Does Not Comply KECL Does Not Comply PICCS Does Not Comply AICS Does Not Comply

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):

Chemical name HAPS Data

ETHYL BENZENE

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372:

Chemical name SARA 313 - Threshold Values

METHYL ETHYL KETONE - 78-93-3 1.0

COPPER COMPOUNDS - 147-14-8 1.0

ETHYL BENZENE - 100-41-4 0.1

SARA 311/312 Hazardous Categorization

Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard

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No

Revision Date 03-May-2024

Reactive Hazard No

Chemical name CWA - Reportable Quantities

CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances tert-BUTYL ACETATE 540-88-5

X

COPPER COMPOUNDS

147-14-8

X

ETHYL BENZENE

100-41-4

1000 lb X X X

Chemical name Hazardous Substances RQs CERCLA EHS RQs RQ

METHYL ETHYL KETONE

78-93-3 5000 lb RQ 5000 lb final RQ

RQ 2270 kg final RQ tert-BUTYL ACETATE

540-88-5 5000 lb RQ 5000 lb final RQ

RQ 2270 kg final RQ

ETHYL BENZENE

100-41-4 1000 lb RQ 1000 lb final RQ

RQ 454 kg final RQ

Chemical name TSCA 5(a)2 2,4-PENTANEDIONE 54 FR 39548, Sep 27, 1989 proposed rule

California Prop. 65

WARNING: This product can expose you to the following chemicals which are known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.

Chemical name California Prop. 65 CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen

TITANIUM DIOXIDE (TOTAL DUST) - 13463-67-7 Carcinogen P-CHLOROBENZOTRIFLUORIDE - 98-56-6 Carcinogen

ETHYL BENZENE - 100-41-4 Carcinogen STYRENE - 100-42-5 Carcinogen

CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen TOLUENE - 108-88-3 Developmental ETHANOL - 64-17-5 Carcinogen

Developmental CARBON BLACK DUST & FUME - 1333-86-4 Carcinogen

California SCAQMD Rule 443 Contains Photochemically Reactive Solvent

State Right-to-Know

Chemical name New Jersey Massachusetts Pennsylvania

CRYSTALLINE SILICA (QUARTZ)

14808-60-7 X X X

TITANIUM DIOXIDE (TOTAL DUST)

13463-67-7

X X X

METHYL ETHYL KETONE

78-93-3

X X X tert-BUTYL ACETATE 540-88-5

X X X

P-CHLOROBENZOTRIFLUORIDE

98-56-6

X

METHYL N-AMYL KETONE

110-43-0

X X X

COPPER COMPOUNDS

147-14-8

X X

ETHYL BENZENE

100-41-4

X X

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X

Revision Date 03-May-2024

16. OTHER INFORMATION

Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 03-May-2024 Revision Summary 14 1 4 5 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910.

To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.

End of SDS

NFPA Health 2 Flammability 3 Instability 1 Physical hazard -

HMIS (Hazardous Material Information System)

Health 2* Flammability 3 Reactivity 1

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