Series_156_Envirocrete_Safety.pdf

Safety Data Sheet

Issue Date 05-Dec-2023 Revision Date 05-Dec-2023 Revision Number 15

1. IDENTIFICATION

Product identifier Product Code F156-00WH Product Name ENVIRO-CRETE TNEMEC WHITE

Other means of identification Common Name SERIES 156 Synonyms None

Recommended use of the chemical and restrictions on use Recommended Use industrial paint.

Uses advised against Consumer use, For professional use only. Not for residential use.

Details of the supplier of the safety data sheet

Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac)

2. HAZARDS IDENTIFICATION

Classification

OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation Category 2A Carcinogenicity Category 1A Specific target organ toxicity (repeated exposure) Category 1

Label elements

EMERGENCY OVERVIEW

Manufacturer Address Tnemec Company, Inc. 123 W. 23rd Avenue, North Kansas City, MO 64116-3094 (816) 474-3400 Distributor Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203, Boisbriand, Quebec Canada J7G 2T3

Danger

Hazard statements Causes serious eye irritation May cause cancer Causes damage to organs through prolonged or repeated exposure

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F156-00WH ENVIRO-CRETE TNEMEC WHITE Revision Date 05-Dec-2023

Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not breathe dust/fume/gas/mist/vapors/spray Do not eat, drink or smoke when using this product

Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention

Storage Store locked up Keep away from children

Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Other information Causes mild skin irritation Toxic to aquatic life with long lasting effects

SEE SAFETY DATA SHEET

Acute Toxicity 29.6123 % of the mixture consists of ingredient(s) of unknown toxicity.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name CAS No. Weight-%

TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 1 - <10%

ZINC COMPOUNDS 1314-13-2 1 - <10%

COAL FIRED FLY ASH BI-PRODUCT 68131-74-8 1 - <10%

MINERAL OIL MIST C129 1 - <10%

*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

Description of first aid measures

General advice If symptoms persist, call a physician.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician.

Appearance opaque Physical state liquid Odor Slight

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Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician.

Inhalation Remove to fresh air. Oxygen or artificial respiration if needed. If inhaled, remove to fresh air.

If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.

Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing.

Most important symptoms and effects, both acute and delayed

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media Carbon dioxide. Foam. Dry chemical.

Unsuitable extinguishing media Water.

Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes

Hazardous combustion products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon oxides. Hydrocarbons. Oxides of nitrogen. Sulfur oxides. Hydrogen chloride.

Protective equipment and precautions for firefighters Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. Solvent vapors are heavier than air and may spread along floors. Flash back possible over considerable distance.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all sources of ignition.

Environmental Precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.

Methods and material for containment and cleaning up

Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal.

Methods for cleaning up

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If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

Handling Close container after each use. Avoid contact with eyes, skin and clothing. Do not eat, drink or smoke when using this product. If splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum. When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling. Wear personal protective equipment.

Conditions for safe storage, including any incompatibilities

Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children.

Incompatible products Strong oxidizing agents. Bases. Acids. Amines. Alkaline. Reducing agents.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH

TITANIUM DIOXIDE (TOTAL DUST)

13463-67-7

TWA: 0.2 mg/m3 nanoscale respirable particulate matter

TWA: 2.5 mg/m3 finescale respirable particulate matter

TWA: 15 mg/m3 total dust 5000 mg/m3

ZINC COMPOUNDS

1314-13-2

TWA: 2 mg/m3 respirable particulate matter

STEL: 10 mg/m3

TWA: 5 mg/m3 fume TWA: 15 mg/m3 total dust

TWA: 5 mg/m3 respirable fraction

500 mg/m3

COAL FIRED FLY ASH

BI-PRODUCT

68131-74-8

TWA: 1 mg/m3 dust and mist - 100 mg/m3 dust and mist 10 mg/m3

Appropriate engineering controls

Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV).

Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product.

Individual protection measures, such as personal protective equipment

Eye/face protection Use chemical resistant splash type goggles. If splashes are likely to occur, wear face-shield.

Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.

Avoid breathing dust created by cutting, sanding, or grinding.

9. PHYSICAL AND CHEMICAL PROPERTIES

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Information on basic physical and chemical properties

Physical state liquid

Other Information

Molecular weight No information available Density 11.94718 lbs/gal Volatile organic compounds (VOC) content

0.4064 lbs/gal

Total volatiles weight percent 33.8517 % Total volatiles volume percent 48.9215 % Bulk density No information available

10. STABILITY AND REACTIVITY

Reactivity

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous reactions None under normal processing.

Conditions to avoid Heat, flames and sparks.

Incompatible materials Strong oxidizing agents, Bases, Acids, Amines, Alkaline, Reducing agents

Hazardous decomposition products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke).

Carbon monoxide. Unidentified organic and inorganic compounds. Carbon oxides. Hydrocarbons. Oxides of nitrogen. Sulfur oxides.

Hydrogen chloride.

Appearance opaque Odor Slight Color No information available Odor threshold No information available

Property Values Remarks pH Melting point / freezing point 0 °C / 32 °F freezing point Boiling point / boiling range Flash point No information available Evaporation rate Flammability (solid, gas) No data available Flammability Limit in Air

Upper flammability limit N/A Lower flammability limit 1.0

Vapor pressure Vapor density Specific gravity 1.43252 g/cm3 Water solubility Insoluble in cold water Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature No data available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity 1100 centipoises approx

No data available

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11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure

Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. May cause irritation.

Eye contact Causes serious eye irritation.

Skin contact Irritating to skin.

Ingestion Harmful if swallowed.

Information on toxicological effects

Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.

Skin disorders. Irritating to eyes and skin.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Irritating to skin.

Eye damage/irritation May cause eye irritation.

Chronic Toxicity NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. May cause cancer.

Sensitization No information available.

Mutagenicity No information available.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical name ACGIH IARC NTP OSHA

TITANIUM DIOXIDE (TOTAL

DUST)

13463-67-7

A3 Group 2B - X

COAL FIRED FLY ASH

BI-PRODUCT

68131-74-8

Group 1 Known

Reproductive effects No information available.

STOT - single exposure No information available STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure

Target organ effects blood, Central nervous system, Central Vascular System (CVS), Gastrointestinal tract, Eyes, kidney, liver, Lungs, respiratory system, Skin, Nasal Cavities.

Aspiration hazard Not applicable.

Acute Toxicity 29.6123 % of the mixture consists of ingredient(s) of unknown toxicity.

The following values are calculated based on chapter 3.1 of the GHS document

12. ECOLOGICAL INFORMATION

Ecotoxicity

Very toxic to aquatic life with long lasting effects

Chemical name Toxicity to algae Toxicity to fish Toxicity to daphnia

ZINC COMPOUNDS

1314-13-2

- LC50: 1.55 mg/L Danio rerio 96 h static

Persistence and degradability No information available.

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Bioaccumulation No information available.

Mobility in Environmental Media

Other Adverse Effects No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.

California Hazardous Waste Status

Chemical name CAWAST

ZINC COMPOUNDS

1314-13-2 Toxic

COAL FIRED FLY ASH BI-PRODUCT

68131-74-8

Toxic Corrosive

14. TRANSPORT INFORMATION

DOT

Proper Shipping Name PAINT & RELATED MATERIAL water base freezable Additional Information The above transport information is for non-bulk packaging only (≤ 119 gallons). For additional information, contact Tnemec Traffic Department at 816-474-3400 or traffic@tnemec.com.

IATA

UN/ID no. UN3082 Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s, (ZINC DUST) Hazard Class 9 Packing Group III ERG Code 171

IMDG/IMO

UN/ID no. UN3082 Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s, (ZINC DUST) Hazard Class 9 Packing Group III EmS No. F-A,S-F Marine Pollutant Yes

Additional Information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation.

15. REGULATORY INFORMATION

International Inventories

TSCA

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Complies

DSL/NDSL Complies EINECS/ELINCS Does Not Comply ENCS Does Not Comply IECSC Complies KECL Does Not Comply PICCS Does Not Comply AICS Complies

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):

Chemical name HAPS Data

COAL FIRED FLY ASH BI-PRODUCT

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372:

Chemical name SARA 313 - Threshold Values

ZINC COMPOUNDS - 1314-13-2 1.0

COAL FIRED FLY ASH BI-PRODUCT - 68131-74-8 1.0

0.1

SARA 311/312 Hazardous Categorization

Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

Clean Water Act

Chemical name CWA - Reportable Quantities

CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances

ZINC COMPOUNDS

1314-13-2

X

COAL FIRED FLY ASH

BI-PRODUCT

68131-74-8

X

TSCA 5(a)2 Significant New Use Rule (SNUR) This product contains one or more substances which are subject to a TSCA Section 5 Significant New Use Rule (SNUR).

Chemical name TSCA 5(a)2 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-1 62 FR 34421, Jun 26, 1997 proposed rule PMN P-95-0116

62 FR 34421, Jun 26, 1997 proposed rule PMN P-96-1250 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-1 62 FR 34421, Jun 26, 1997 proposed rule PMN P-95-0116

62 FR 34421, Jun 26, 1997 proposed rule PMN P-96-1250

California Prop. 65

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WARNING: This product can expose you to the following chemicals which are known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.

Chemical name California Prop. 65

TITANIUM DIOXIDE (TOTAL DUST) - 13463-67-7 Carcinogen COAL FIRED FLY ASH BI-PRODUCT - 68131-74-8 Carcinogen

AMORPHOUS SILICA - 7631-86-9 Carcinogen CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen

ETHANOL - 64-17-5 Carcinogen Developmental

California SCAQMD Rule 443 Does Not Contain Photochemically Reactive Solvent

State Right-to-Know

Chemical name New Jersey Massachusetts Pennsylvania

TITANIUM DIOXIDE (TOTAL DUST)

13463-67-7 X X X

ZINC COMPOUNDS

1314-13-2

X X X

COAL FIRED FLY ASH

BI-PRODUCT

68131-74-8

X X

16. OTHER INFORMATION

Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 05-Dec-2023 Revision Summary 9 4 5 7 10 8 11 14 1 15 13 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910.

To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.

End of SDS

NFPA Health 2 Flammability 0 Instability 1 Physical hazard -

HMIS (Hazardous Material Information System)

Health 2 Flammability 0 Reactivity 1

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