PURGING FLUID SDS.pdf

Section 1. Identification

PURGING FLUID

Distillates, petroleum, hydrotreated light; Hydrotreated light distillate; Hydrotreated light distillates (petroleum); DISTILLATES.

Liquid.

24 hr. CHEMTREC 1-800-424-9300 / International 1-703-527-3887

SAFETY DATA SHEET

GHS product identifier: Purging Fluid Product Code: MIL-F-38299B Chemical Name: Hydrotreated Petroleum Distillate Product type: Liquid

Identified Uses: Petrochemical industry: Petroleum refining. Solvent

Supplier's details: KAP TECHNOCHEM USA, INC. Missouri City, TX. 281-403-0242 24hr. CHEMTREC: 1-800-424-9300 /International 1-703-527-3887

.Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Classification of the ASPIRATION HAZARD - Category 1 substance or mixture

Hazard statements : May be fatal if swallowed and enters airways.

Hazard pictograms:

Signal word : Danger Hazard statements : May be fatal if swallowed and enters airways.

Precautionary statements Prevention : Not applicable.

Response : IF SWALLOW ED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting.

Storage : Store locked up.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise Classified: None known.

Date of issue: 01/02/2020

Section 3. Composition/information on ingredients Substance/mixture: Substance Chemical name: Distillates (petroleum), hydrotreated light Other means of identification: Distillates (petroleum), hydrotreated light Ingredient name: Distillates, petroleum, hydrotreated light 100% CAS: 64742-47-8 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact: Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion: Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed Potential acute health effects Inhalation : No known significant effects or critical hazards.

Ingestion : May be fatal if swallowed and enters airways.

Skin contact : Defatting to the skin. May cause skin dryness and irritation.

Eye contact : No known significant effects or critical hazards.

Over-exposure signs/symptoms Inhalation : No specific data.

Eye contact : No specific data.

Section 4. First aid measures Indication of immediate medical attention and special treatment needed, if necessary Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Skin contact: Adverse symptoms may include the following: irritation, dryness, cracking Ingestion Adverse symptoms may include the following: nausea or vomiting

Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media: Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media: Do not use water jet.

Specific hazards arising from the chemical: In a fire or if heated, a pressure increase will occur, and the container may burst.

Hazardous thermal decomposition products No specific data.

Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures

For non-emergency Personnel: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.

Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Put on appropriate personal protective equipment.

For emergency responders: If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up Small spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill :

Stop leak if without risk. Move containers from spill area. Approach release from upwind.

Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13).

Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Do not swallow.

Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Distillates (petroleum), hydrotreated light Exposure limits: ACGIH TLV (United States, 4/2014). Absorbed through skin.

TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours.

Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Skin protection Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection: Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties Appearance

Physical state: Liquid. [Mobile liquid.] Color Colorless Odor Mild. Hydrocarbon.

pH: Not applicable.

Odor threshold: Not available.

Melting point: -49°C (-56.2°F) Boiling point : 222.78 to 245°C (433 to 473°F) Flash point: Closed cup: 95°C (203°F) [Pensky-Martens.] [Product does not sustain combustion.] Evaporation rate 0.19 (butyl acetate = 1) Lower and upper explosive (flammable) limits: : Lower: 0.6%, Upper: 5.5% Vapor pressure: 0.027 kPa (0.2 mm Hg) [room temperature] Vapor density: 4.5 [Air = 1] Relative density: 0.804 Solubility: Insoluble in the following materials: cold water and hot water.

Solubility in water : 1.5 g/l Partition coefficient: noctanol/water: Not available Auto-ignition temperature: >220°C (>428°F) Decomposition temperature : Not available.

Viscosity Kinematic (40°C (104°F)): 0.02 cm2/s (2 cSt) Flammability (solid, gas) : Not available.

Section 10. Stability and reactivity Reactivity: No specific test data related to reactivity available for this product or its ingredients.

Conditions to avoid No specific data.

Chemical stability: The product is stable.

Possibility of hazardous reactions: Normal conditions of storage use, hazardous reactions will not occur.

Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Incompatible materials: No specific data.

Section 11. Toxicological information Potential acute health effects Acute toxicity Product/ingredient name: Distillates (petroleum), hydrotreated light Result: LD50 Dermal, LD50 Oral Species Rabbit, Rat Dose >2000 mg/kg - >5000 mg/kg Irritation/Corrosion: Not available.

Sensitization: Not available.

Mutagenicity: Not available.

Carcinogenicity: Not available.

Reproductive toxicity: Not available.

Teratogenicity: Not available.

Specific target organ toxicity (single exposure): Not available.

Specific target organ toxicity (repeated exposure): Not available.

Aspiration hazard Name: Distillates (petroleum), hydrotreated light Result: ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure: Routes of entry anticipated: Oral, Dermal, Inhalation.

Inhalation: No known significant effects or critical hazards.

Ingestion: May be fatal if swallowed and enters airways.

Skin contact: Defatting to the skin. May cause skin dryness and irritation.

Eye contact: No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics Inhalation: No specific data.

Eye contact: No specific data.

Skin contact: Adverse symptoms may include the following: irritation, dryness, cracking Ingestion Adverse symptoms may include the following: nausea or vomiting Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects: Not available Potential delayed effects: Not available Long term exposure Potential immediate effects: Not available Potential delayed effects: Not available.

Potential chronic health effects: Not available General: Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.

Carcinogenicity: No known significant effects or critical hazards.

Mutagenicity: No known significant effects or critical hazards.

Teratogenicity: No known significant effects or critical hazards.

Developmental effects: No known significant effects or critical hazards.

Fertility effects: No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicity estimates: Not available

Section 12. Ecological information Toxicity: Not available Persistence and degradability: Not available.

Bioaccumulative potential: Not available.

Mobility in soil Soil/water partition coefficient (KOC): Not available Other adverse effects: No known significant effects or critical hazards.

Section 13. Disposal considerations Disposal methods :

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information DOT Classification: Not regulated.

TDG Classification: Not regulated IMDG IATA: Not regulated UN number Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Transport in bulk according to Annex II of MARPOL and the IBC Code: Not available.

Section 15. Regulatory information U.S. Federal regulations: TSCA 8(a) CDR Exempt/Partial exemption: This material is listed or exempted.

Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs): Not listed Clean Air Act Section 602 Class I Substances: Not listed Clean Air Act Section 602 Class II Substances: Not listed DEA List I Chemicals (Precursor Chemicals): Not listed DEA List II Chemicals (Essential Chemicals): Not listed This material is listed or exempted.

SARA 302/304

Composition/information on ingredients: No products were found.

SARA 304 RQ : Not applicable

SARA 311/312

Classification: Not applicable.

Composition/information on ingredients

Section 15. Regulatory information Name: Distillates (petroleum), hydrotreated light %: 100 Fire hazard: Yes.

Sudden release of pressure: No Reactive: No Immediate (acute) health hazard: No Delayed (chronic) health hazard: No State regulations Massachusetts: This material is not listed.

New York: This material is not listed.

New Jersey: This material is not listed.

Pennsylvania: This material is not listed.

California Prop. 65: This product is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.

International lists National inventory Australia : This material is listed or exempted.

Canada : This material is listed or exempted.

China : This material is listed or exempted.

Europe : This material is listed or exempted.

Japan : This material is listed or exempted.

Republic of Korea : This material is listed or exempted.

Malaysia : This material is listed or exempted.

New Zealand : This material is listed or exempted.

Philippines : This material is listed or exempted.

Taiwan : This material is listed or exempted.

Section 16. Other information Procedure used to derive the classification Classification: Asp. Tox. 1, H304 Justification: On basis of test data History Date of issue: 01/02/2020

Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, the supplier, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.