NFM MSDS.pdf

NFM

Safety Data Sheet

1.Safety Data Sheet

1.1 The first department Chemicals and business labeling

Sodium nickel-iron manganate Lithium sodium battery cathode material

2. Hazardous Overview According to the UN GHS (6th Revision), the product belongs to the hazard category and labeling elements.

2.1 GHS hazard category.

Skin sensitization Category 1 Carcinogenicity Category 1b Warning

2.3 Hazard statement.

H317 May cause skin sensitization.

H50 May be carcinogenic Precautions.

P201 Obtain special instructions before use.

P280 Wear protective gloves/protective clothing/eye protection/face protection. P264 Wash thoroughly after work.

P261 Avoid breathing dust/fume/gas/fumes/vapors/spray. P271 Use only outdoors or in a well-ventilated area Incident response.

P303+P361+P353 If skin (or hair) is contaminated: Remove all contaminated clothing immediately. Wash skin with water/shower.

P302+P352 If skin is contaminated: Wash well with water.

Page 1 of 6 P332+P313 If skin irritation occurs: Seek medical attention/consultation.

P362+P364 Remove contaminated clothing and wash before reuse P305+P351+P338 If in eyes: Rinse carefully with water for a few minutes.

P337+P313 If you still feel eye irritation: Seek medical attention/medical consultation. P312 If feeling unwell, call a POISON CENTER/doctor.

Secure storage.

P405 Store under lock and key.

Disposal.

P501 Dispose of contents/container according to local regulations.

2.4 Other Hazards

Physical and chemical hazards.

None Health Hazards.

Causes skin irritation. May cause allergic skin reactions. Causes severe eye irritation.

Environmental Hazards.

No information available

3. Ingredient/composition information

3.1 Components

Chemical name: Sodium nickel-cobalt-iron-manganate Molecular formula: NaNiFeMnO Molecular weight:115

4. First-aid measures

4.1. First aid

Inhalation:

In case of inhalation, remove the patient to fresh air. Skin contact:

Remove contaminated clothing and rinse skin thoroughly with soapy water and water. If discomfort occurs, seek medical attention.

Eye contact:

Separate eyelids and flush with running water or saline. Seek immediate medical attention.

Ingestion:

Rinse mouth and do not induce vomiting. Seek immediate medical attention. First responder protection: Ensure that healthcare workers are aware of the hazardous properties of the product and take their own protective measures to protect themselves and prevent the spread of contamination.

4.2 Description of emergency medical treatment and special treatment No data available

5. Fire Fighting Measures

5.1 Extinguishing media

Suitable extinguishing media.

Use water mist, dry powder, foam or carbon dioxide extinguishing agent to extinguish the fire.

Avoid using direct running water to extinguish the fire. Direct running water may cause splashing of combustible liquid and spread the fire.

5.2. Special hazards. No information available

5.3. Fire extinguishing precautions and protective measures.

Isolate the accident site and prohibit the entry of unrelated personnel. Take in and dispose of fire water to prevent pollution of the environment.

6. Leakage emergency treatment

6.1. protective measures for workers, protective equipment and emergency procedures:

It is recommended that emergency personnel wear respirators, anti-static clothing, and rubber oil-resistant gloves.

6.2 Environmental protection measures

Contain the spill to avoid contaminating the environment. Prevent spills from entering sewers, surface water and groundwater.

6.3 Reception and removal methods of spilled chemicals and disposal materials used. Collect in sealable containers as far as possible.

7. Handling, disposal, and storage

7.1. Handling precautions

Operators should be specially trained and strictly follow the operation procedures.

Operation and disposal should be carried out in a place with local ventilation or full ventilation facilities.

Avoid eye and skin contact and inhalation.

See Part 8 for individual protective measures.

7.2. Storage precautions.

Store in a cool, ventilated storage area.

Keep containers sealed.

The storage area should be equipped with spill response equipment and suitable containment materials.

8. Exposure Control/Individual Protection

8.1. Exposure Limits.

Occupational exposure limits.

Component Name

CAS

Standard source Type Standard value Remarks Sodium nickel-iron-manganate 12190-79-3

GBZ2.1--2007

MAC: -

Not specified

PC-TWA：-

PC-STEL: -

Biological limits.

No information available Monitoring methods.

No information available

8.2 Engineering Controls.

The workplace is recommended to be separated from other workplaces.

Seal the operation to prevent leakage.

Enhance ventilation.

Handle in accordance with good industrial hygiene and safety practices. Wash hands before breaks and at the end of the workday.

Provide safety showers and eyewash facilities.

8.3 Personal Protection.

Respiratory protection.

Wear a filtered gas mask (half mask) when airborne concentrations exceed the standard. In case of emergency rescue or evacuation Air-carrying respirators should be worn.

Hand protection.

Wear rubber oil-resistant gloves.

Eye protection.

Wear chemical safety eye protection.

Skin and body protection.

Acid and alkali resistant clothing.

9. Physical and Chemical Properties Appearance and properties.

Black powder Odor.

No information pH value.

No information available Melting point / freezing point (℃).

No information available Boiling point, initial boiling point and boiling range (°C). No information available Chromaticity (Pt-Co).

≦20 Flash point (℃) (closed cup).

No information Self-ignition temperature (℃).

No information Explosion limit [% (v/v)]. No information Decomposition temperature (℃).

No information Saturated vapor pressure. No information Evaporation rate [of (n)butyl acetate in 1].

Not available Relative density (water as 1) 25°C. No Information

Flammability (solid, gas).

No information available Odor threshold (mg/m3).

No information available Vapor density (air in 1). No information available Solubility.

Soluble in acidic aqueous solution

10. Stability and reactivity

10.1 Stability.

Sealed storage, sensitive to air

10.2 Hazardous Reactions.

No information available.

10.3 Conditions to Avoid Exposure.

Humidity, etc.

10.4 Prohibited Compounds.

Strong oxides, strong acids, strong bases Part XI Toxicological Information

11. Acute toxicity By mouth:

No information available Inhalation:

No information available Transdermal:

No information available

11.2 Skin irritation or corrosion:

No information available

11.3 Eye irritation or corrosion.

No information available

11.4 Respiratory or skin sensitization.

No information available

11.5 Germ cell mutagenicity.

No information available

11.6 Carcinogenicity. No

information available

11.7 Reproductive toxicity.

No information available

11.8 Specific target organ system toxicity - single

Exposure.

No information available

11.9 Specific Target Organ System Toxicity-Repeated

Exposure.

No information available

11.10 Inhalation hazard.

No information available

12. Ecological Information

12.1 Ecotoxicity.

Acute toxicity tests in fish:

No information available Acute activity inhibition test for Daphnia magna: No information available Algae growth inhibition test:

Toxicity to microorganisms:

12.2 Persistence and degradability. No

information available

12.3 Bioconcentration or bioaccumulation.

No information available

12.4 Mobility in Soil.

No information available

13. Waste disposal

13.1 Waste chemicals. Recycle

as much as possible.

If recycling is not possible, incineration should be used for disposal. Do not dispose of this product by discharging into the sewer.

13.2 Contaminated Packaging.

Return the container to the manufacturer or dispose of it in accordance with national and local regulations.

13.3 Disposal Precautions.

Before disposal, refer to national and local regulations. See Part 8 for safety precautions for disposal personnel.

14. Transportation Information

14.3 UN Hazardous Classification.

Non-dangerous goods

14.5 Packing method.

Packed according to the manufacturer's recommended method, e.g. open steel drums.

Plain wooden box outside the ampoule. Threaded mouth Glass bottles, glass bottles with iron cap and pressed mouth, plastic bottles or metal barrels (cans) outside the ordinary wooden box, etc.

15) Regulatory information Regulations/regulations specifically for the safety, health and environment of this substance or mixture.

Applicable regulations:

Regulations on the Safety Administration of Hazardous Chemicals (Adopted by The State Council on December 4, 2013)

Please note that waste disposal should also meet local regulatory requirements.