MSDS_Beryllium.pdf.pdf

Aldrich- GF64512097 Page 1 of 9

The life science business of Merck operates as MilliporeSigma in the US and

Canada

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Version 6.1 Revision Date 26.03.2021

Print Date 12.04.2021

GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifiers

Product name : Beryllium

Product Number : GF64512097

Brand : Aldrich

REACH No. : A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Manufacture of substances

1.3 Details of the supplier of the safety data sheet

Company : Sigma-Aldrich Inc.

3050 Spruce Street

ST. LOUIS MO 63103

UNITED STATES

Telephone : +1 314 771-5765

Fax : +1 800 325-5052

1.4 Emergency telephone

Emergency Phone # : 800-424-9300 CHEMTREC (USA) +1-703-

527-3887 CHEMTREC (International) 24

Hours/day; 7 Days/week

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3), H301

Skin irritation (Category 2), H315

Eye irritation (Category 2), H319

Skin sensitization (Category 1), H317

Carcinogenicity (Category 1B), H350

Specific target organ toxicity - repeated exposure (Category 1), H372

For the full text of the H-Statements mentioned in this Section, see Section 16.

Aldrich- GF64512097 Page 2 of 9

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Pictogram

Signal word Danger

Hazard statement(s)

H301 Toxic if swallowed.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H350 May cause cancer.

H372 Causes damage to organs through prolonged or repeated exposure.

Precautionary statement(s)

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

P302 + P352 IF ON SKIN: Wash with plenty of water.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental Hazard

Statements none

Restricted to professional users.

Reduced Labeling (<= 125 ml)

Pictogram

Signal word Danger

Hazard statement(s)

H301 Toxic if swallowed.

H317 May cause an allergic skin reaction.

H350 May cause cancer.

H372 Causes damage to organs through prolonged or repeated exposure.

Precautionary statement(s)

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

P302 + P352 IF ON SKIN: Wash with plenty of water.

Supplemental Hazard

Statements none

Aldrich- GF64512097 Page 3 of 9

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.1 Substances

Molecular weight : 9,01 g/mol

Component Classification Concentration

Berylium foil

CAS-No.

7440-41-7

Acute Tox. 3; Skin Irrit. 2;

Eye Irrit. 2; Skin Sens. 1;

Carc. 1B; STOT RE 1;

H301, H315, H319, H317, H350, H372

<= 100 %

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1 Description of first-aid measures

General advice

Show this material safety data sheet to the doctor in attendance.

If inhaled

After inhalation: fresh air. Call in physician.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

In case of eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

If swallowed

If swallowed: give water to drink (two glasses at most). Seek medical advice immediately.

In exceptional cases only, if medical care is not available within one hour, induce vomiting

(only in persons who are wide awake and fully conscious), administer activated charcoal

(20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section

2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

Aldrich- GF64512097 Page 4 of 9

5.2 Special hazards arising from the substance or mixture

Beryllium oxides

Not combustible.

5.3 Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

5.4 Further information

Prevent fire extinguishing water from contaminating surface water or the ground water system.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions

(see sections 7 and 10). Take up carefully. Dispose of properly. Clean up affected area.

Avoid generation of dusts.

6.4 Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling

Work under hood. Do not inhale substance/mixture.

Hygiene measures

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Aldrich- GF64512097 Page 5 of 9

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Ingredients with workplace control parameters

8.2 Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm

Break through time: 480 min

Material tested:KCL 741 Dermatril® L

Splash contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm

Break through time: 480 min

Material tested:KCL 741 Dermatril® L

Body Protection protective clothing

Respiratory protection required when dusts are generated.

Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Recommended Filter type: Filter type P3

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

a) Appearance Form: solid

b) Odor No data available

c) Odor Threshold No data available

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d) pH No data available

e) Melting point/freezing point

No data available

f) Initial boiling point and boiling range

No data available

g) Flash point Not applicable

h) Evaporation rate No data available

i) Flammability (solid, gas)

The product is not flammable.

j) Upper/lower flammability or explosive limits

No data available

k) Vapor pressure No data available

l) Vapor density No data available

m) Relative density No data available

n) Water solubility No data available

o) Partition coefficient:

n-octanol/water

Not applicable for inorganic substances

p) Autoignition temperature

No data available

q) Decomposition temperature

No data available

r) Viscosity Viscosity, kinematic: No data available

Viscosity, dynamic: No data available

s) Explosive properties No data available

t) Oxidizing properties No data available

9.2 Other safety information

SECTION 10: Stability and reactivity

10.1 Reactivity

No data available

10.2 Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

10.3 Possibility of hazardous reactions

No data available

10.4 Conditions to avoid

no information available

10.5 Incompatible materials

Strong oxidizing agents

10.6 Hazardous decomposition products

In the event of fire: see section 5

Aldrich- GF64512097 Page 7 of 9

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Skin corrosion/irritation

Serious eye damage/eye irritation

No data available

Respiratory or skin sensitization

Germ cell mutagenicity

Carcinogenicity

Reproductive toxicity

Specific target organ toxicity - single exposure

Specific target organ toxicity - repeated exposure

Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard

11.2 Additional Information

Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

SECTION 12: Ecological information

12.1 Toxicity

No data available

12.2 Persistence and degradability

Not applicable for inorganic substances

12.3 Bioaccumulative potential

Aldrich- GF64512097 Page 8 of 9

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

SECTION 14: Transport information

14.1 UN number

ADR/RID: IMDG: IATA:

14.2 UN proper shipping name

ADR/RID:

IMDG:

IATA:

14.3 Transport hazard class(es)

ADR/RID: IMDG: IATA:

14.4 Packaging group

ADR/RID: IMDG: IATA:

14.5 Environmental hazards

ADR/RID: IMDG Marine pollutant: IATA:

14.6 Special precautions for user

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

This material safety data sheet complies with the requirements of Regulation (EC) No.

1907/2006.

Authorisations and/or restrictions on use

National legislation

Seveso III: Directive 2012/18/EU of the

European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.

: ACUTE TOXIC

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Other regulations

Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable.

Take note of Dir 94/33/EC on the protection of young people at work.

15.2 Chemical Safety Assessment

For this product a chemical safety assessment was not carried out

SECTION 16: Other information

Full text of H-Statements referred to under sections 2 and 3.

H301 Toxic if swallowed.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H350 May cause cancer.

H372 Causes damage to organs through prolonged or repeated exposure.

Further information

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

Copyright 2020 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only.

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