B03_Current Solvent _00212SST-1 Hentzen Type II Reducer.pdf

SAFETY DATA SHEET

Issuing Date: 22-Dec-2011 Revision Date: 26-Apr-2018

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Recommended use of the chemical and restrictions on use Industrial paint (Paint or Paint-Related), Restricted to professional users

2. HAZARDS IDENTIFICATION

Classification

OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation Category 2 Carcinogenicity Category 2 Specific target organ toxicity (single exposure) Category 3

Label Elements

Emergency Overview

Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/Bond container and receiving equipment

Product Code: 00212SST-1 Product Name: REDUCER FOR MIL-T-81772B AMEND 1, TYPE II

Hentzen Coatings, Inc. Company Phone Number: 1-414-353-4200 6937 West Mill Road, Milwaukee, WI 53218-1225 Emergency telephone number ChemTrec 1-800-424-9300

Flammable Liquids Category 2

DANGER

Hazard Statements Causes serious eye irritation Suspected of causing cancer May cause drowsiness or dizziness Highly flammable liquid and vapor

Appearance Clear Physical state Liquid

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Odor Solvent

00212SST-1 - REDUCER FOR MIL-T-81772B AMEND 1,

TYPE II

Revision Date: 26-Apr-2018

Use explosion-proof electrical/ ventilating/ lighting/ equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool

Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing In case of fire: Use CO2, dry chemical, or foam for extinction

Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store in accordance with local regulations

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Other information

• May be harmful if swallowed

3. COMPOSITION/INFORMATION ON INGREDIENTS

Contains a known or suspected carcinogen

This product contains substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. See Section 15 for list of HAPS.

Chemical Name CAS No Weight-% ACGIH OSHA

METHYL ETHYL KETONE 78-93-3 40% - 50% STEL: 300 ppm TWA: 200 ppm

TWA: 200 ppm TWA: 590 mg/m3

1-METHOXY-2-PROPANOL 107-98-2 30% - 40% STEL: 100 ppm TWA: 50 ppm

N/A

METHYL ISOBUTYL KETONE 108-10-1 10% - 20% STEL: 75 ppm TWA: 20 ppm

TWA: 100 ppm TWA: 410 mg/m3

4. FIRST AID MEASURES

First Aid Measures

General advice Show this safety data sheet to the doctor in attendance. If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Immediately flush eyes with water for at least 15 minutes. Get medical attention. If easy to do, remove contact lenses. Keep eye wide open while rinsing.

Skin Contact Immediate medical attention is not required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician.

Inhalation If symptoms persist, call a physician. Remove to fresh air. Immediate medical attention is not required. Move to fresh air in case of accidental inhalation of vapors.

Ingestion Immediate medical attention is not required. Do NOT induce vomiting. Rinse mouth. Drink plenty of water. Clean mouth with water and afterwards drink plenty of water. Never give

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Revision Date: 26-Apr-2018 anything by mouth to an unconscious person. Consult a physician if necessary.

Self-protection of the first aider Remove all sources of ignition. Use personal protective equipment as required.

Most important symptoms and effects, both acute and delayed

Most Important Symptoms and Effects

No information available.

Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media No information available.

Specific hazards arising from the chemical Extremely flammable.

Explosion Data Sensitivity to Mechanical Impact no data available.

Sensitivity to Static Discharge Yes.

Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Remove all sources of ignition. Evacuate personnel to safe areas. Ensure adequate ventilation. Use personal protective equipment as required. Keep people away from and upwind of spill/leak. Avoid breathing vapors or mists. Ventilate the area.

Environmental Precautions

Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Vapors are heavier than air, spread along floors and form explosive mixtures with air.

Methods and materials for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Pick up and transfer to properly labeled containers. Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Soak up with inert absorbent material.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Use explosion-proof electrical (ventilation and lighting) equipment. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Use with local exhaust

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TYPE II

Revision Date: 26-Apr-2018 ventilation. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe vapor or mist. To dissipate static electricity during transfer, ground drum and connect to receiving container with bonding strap. Use only non-sparking tools.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat, sparks and flame.

Incompatible Products None known based on information supplied.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .

Chemical Name ACGIH OSHA NIOSH IDLH

METHYL ETHYL KETONE

78-93-3 STEL: 300 ppm TWA: 200 ppm

TWA: 200 ppm TWA: 590 mg/m3

IDLH: 3000 ppm TWA: 200 ppm

TWA: 590 mg/m3

STEL: 300 ppm STEL: 885 mg/m3

1-METHOXY-2-PROPANOL

107-98-2

STEL: 100 ppm TWA: 50 ppm

N/A TWA: 100 ppm TWA: 360 mg/m3

STEL: 150 ppm STEL: 540 mg/m3

METHYL ISOBUTYL KETONE

108-10-1

STEL: 75 ppm TWA: 20 ppm

TWA: 100 ppm TWA: 410 mg/m3

IDLH: 500 ppm TWA: 50 ppm

TWA: 205 mg/m3

STEL: 75 ppm STEL: 300 mg/m3

NIOSH IDLH: Immediately Dangerous to Life or Health

Exposure controls

Engineering Measures Showers Eyewash stations Ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Use personal protective equipment as required.

Skin and Body Protection Chemical resistant apron.

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

Hygiene Measures Do not eat, drink or smoke when using this product. Regular cleaning of equipment, work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid Appearance Clear Odor Solvent. Odor Threshold No data available pH No data available Flash Point 16 °F / -9 °C Decomposition temperature No data available Boiling Point 175 °F / 79 °C Melting Point / Melting Range No data available Freezing Point No data available Vapor Pressure @20°C (kPa) No data available Partition coefficient: No data available

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10. STABILITY AND REACTIVITY

Reactivity

Chemical stability Stable under recommended storage conditions.

Conditions to Avoid Extremes of temperature and direct sunlight.

Incompatible Materials None known based on information supplied.

Hazardous Decomposition Products None known based on information supplied.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information The product has not been tested

Inhalation There is no data for this product.

Eye Contact There is no data for this product.

Skin Contact There is no data for this product.

Ingestion There is no data for this product.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

METHYL ETHYL KETONE

78-93-3

= 2483 mg/kg ( Rat ) = 5000 mg/kg ( Rabbit ) = 11700 ppm ( Rat ) 4 h

1-METHOXY-2-PROPANOL

107-98-2

= 5000 mg/kg ( Rat ) = 13 g/kg ( Rabbit ) > 7559 ppm ( Rat ) 6 h

METHYL ISOBUTYL KETONE

108-10-1

= 2080 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 8.2 mg/L ( Rat ) 4 h

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

MUTAGENIC EFFECTS No information available.

Carcinogenicity This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B).

Chemical Name ACGIH IARC NTP OSHA

METHYL ISOBUTYL

KETONE

108-10-1

A3 Group 2B N/A X

Vapor Density No data available Density No data available Bulk density No data available Specific Gravity 0.84 Evaporation Rate No data available Water solubility No data available Dynamic viscosity No data available Weight per Gallon (lbs/gal): 7.01

No data available

Flammability Limits in Air Upper 11.61 % Lower

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Legend:

ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present

Reproductive Toxicity No information available.

Specific target organ systemic toxicity (single exposure)

No information available.

Specific target organ systemic toxicity (repeated exposure)

No information available.

Chronic Toxicity Avoid repeated exposure. May cause adverse liver effects.

Target Organ Effects Central nervous system (CNS), Eyes, Kidney, Liver, Respiratory system, Skin.

Aspiration hazard No information available.

Numerical measures of toxicity - Product Information

The following values are calculated based on chapter 3.1 of the GHS document .

ATEmix (oral) 2878 mg/kg ATEmix (dermal) 5521 mg/kg ATEmix (inhalation-dust/mist) 8.8 mg/l

Oral LD50 2879 mg/kg (rat) Estimated Dermal LD50 5522 mg/kg (rat) Estimated Inhalation LC50 13590 mg/l (mist) (dust) mg/m3 Estimated Inhalation LC50

12. ECOLOGICAL INFORMATION

Ecotoxicity

Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to daphnia and other aquatic invertebrates

METHYL ETHYL KETONE

78-93-3

N/A 3130 - 3320: 96 h Pimephales promelas mg/L LC50 flow-through

4025 - 6440: 48 h Daphnia magna mg/L EC50 Static 5091: 48 h

Daphnia magna mg/L EC50 520: 48 h Daphnia magna mg/L EC50

1-METHOXY-2-PROPANOL

107-98-2

N/A 20.8: 96 h Pimephales promelas g/L LC50 static

23300: 48 h Daphnia magna mg/L

EC50

METHYL ISOBUTYL KETONE

108-10-1

400: 96 h Pseudokirchneriella subcapitata mg/L EC50

496 - 514: 96 h Pimephales promelas mg/L LC50 flow-through

170: 48 h Daphnia magna mg/L

EC50

Persistence and degradability No information available.

Bioaccumulation No information available.

Chemical Name Partition coefficient

METHYL ETHYL KETONE

78-93-3 0.3

1-METHOXY-2-PROPANOL

107-98-2

-0.437

METHYL ISOBUTYL KETONE

108-10-1

1.19

Other adverse effects No information available

13. DISPOSAL CONSIDERATIONS

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Waste treatment methods

TYPE II

Revision Date: 26-Apr-2018

Waste treatment methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261).

US EPA Waste Number D001

Chemical Name RCRA - Basis for Listing RCRA - D Series Wastes

METHYL ETHYL KETONE

78-93-3 Included in waste streams: F005, F039 200.0 mg/L regulatory level

METHYL ISOBUTYL KETONE

108-10-1

Included in waste stream: F039 N/A

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste Status

METHYL ETHYL KETONE

78-93-3 Toxic mixture of acetone, methyl acetate, and methyl alcohol

Ignitable mixture of acetone, methyl acetate, and methyl alcohol

14. TRANSPORT INFORMATION

DOT

UN-No UN1263 Proper shipping name PAINT RELATED MATERIAL Hazard class 3 Packing Group II Special Provisions 149, B52, IB2, T4, TP1, TP8, TP28 Description UN1263, Paint related material, 3, II, RQ Emergency Response Guide Number

TDG

UN-No UN1263 Proper shipping name PAINT RELATED MATERIAL Hazard class 3 Packing Group II Description UN1263, Paint related material, 3, II

MEX

UN-No UN1263 Proper shipping name PAINT RELATED MATERIAL Hazard class 3 Packing Group II Description UN1263, Paint related material, 3, II

ICAO

UN-No UN1263 Proper shipping name PAINT RELATED MATERIAL Hazard class 3 Packing Group II Special Provisions A3, A72 Description UN1263, Paint related material, 3, II

IATA

UN-No UN1263 Proper shipping name PAINT RELATED MATERIAL Hazard class 3 Packing Group II ERG Code 3L Special Provisions A3, A72, A192 Description UN1263, Paint, 3, II1 Paint related materialUN1263, Paint, 3, II2

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IMDG/IMO

UN-No UN1263 Proper shipping name PAINT RELATED MATERIAL Hazard class 3 Packing Group II EmS-No F-E, S-E Special Provisions 163, 367 Description UN1263, Paint, 3, II, (-9°C c.c.)1 Paint related materialUN1263, Paint, 3, II, (-9°C c.c.)2

RID

UN-No UN1263 Proper shipping name PAINT RELATED MATERIAL Hazard class 3 Packing Group II Classification Code F1 Description UN1263, Paint related material, 3, II

ADR/RID

UN-No UN1263 Proper shipping name PAINT RELATED MATERIAL Hazard class 3 Packing Group II Classification Code F1 Tunnel restriction code (D/E) Special Provisions 163, 640C, 650, 367 Description UN1263, Paint related material, 3, II, (D/E) ADR/RID-Labels 3

ADN

Proper shipping name PAINT RELATED MATERIAL Hazard class 3 Packing Group II Classification Code F1 Special Provisions 163, 640C, 650 Description UN1263, Paint related material, 3, II Hazard Labels 3 Limited Quantity (LQ) 5 L Ventilation VE01

15. REGULATORY INFORMATION

International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

US Federal Regulations

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SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name CAS No SARA 313 - Threshold Values %

METHYL ISOBUTYL KETONE 108-10-1 1.0

SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No

CAA (Clean Air Act) U.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants This product contains the following HAPs:

Chemical Name CAS No Hazardous air pollutants (HAPs) content METHYL ISOBUTYL KETONE 108-10-1 Present

Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42)

CERCLA

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs

RQ (reportable quantity)

METHYL ETHYL KETONE 5000 lb N/A RQ 5000 lb final RQ RQ 2270 kg final RQ

METHYL ISOBUTYL KETONE 5000 lb N/A RQ 5000 lb final RQ RQ 2270 kg final RQ

State Regulations

California Proposition 65 This product contains the following Proposition 65 chemicals

Chemical Name CAS No California Proposition 65 METHYL ISOBUTYL KETONE 108-10-1 Carcinogen

Developmental

U.S. State Right-to-Know Regulations

Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island

METHYL ETHYL KETONE X X X X X

1-METHOXY-2-PROPANOL X X X X X

METHYL ISOBUTYL

KETONE

X X X X X

International Regulations

Mexico - Grade Serious risk, Grade 3

Chemical Name Carcinogenic Status Exposure Limits METHYL ETHYL KETONE N/A Mexico: TWA 200 ppm

Mexico: TWA 590 mg/m3

Mexico: STEL 300 ppm Mexico: STEL 885 mg/m3

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METHYL ISOBUTYL KETONE N/A Mexico: TWA 50 ppm Mexico: TWA 205 mg/m3

Mexico: STEL 75 ppm Mexico: STEL 307 mg/m3

16. OTHER INFORMATION

NFPA Rating

Chronic Hazard Star Legend * Chronic Health Hazard

Issuing Date: 22-Dec-2011 Revision Date: 26-Apr-2018 Revision Note No information available

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 00212SST-1 end

NFPA Health Hazard 2 Flammability 3 Instability 0 Physical and Chemical Hazards -

HMIS Health Hazard 2 * Flammability 3 Physical Hazard 0 Personal protection X

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