Attachment 7 Safety Data Sheets.pdf

SDS #00066.0001

SAFETY DATA

SHEET

Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe, Japanese Standard JIS Z 7250:2000, and EU REACH Regulations

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: BULLETS – FRANGIBLE LEAD-FREE CAS Number: Mixture – Metal Alloy or Metal/Polymer Alloy Synonyms: Sinterfire, 5.56 Jacketed Frangible Projectile Product Use: Centerfire Ammunition Projectile U.N. Number: None U.N. Dangerous Goods Class

Not regulated

Manufacturer/Responsible Party:

Olin Winchester, LLC

Manufacturers’ Address: 600 Powder Mill Road, East Alton, IL 62024 www.winchester.com

Emergency Telephone Number:

US/Canada: 1-800-424-9300 Outside US/Canada: 703-527-3887

SDS Control Group: 618-258-3507 (Technical Information Only)

Olin SDS No.: 00066.0001 Issue Date: 05/13/2015

Revision Date: 02/28/2019

Revision No.: 05

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW: DO NOT TAKE INTERNALLY.

US DOT SYMBOLS CANADA (WHMIS) SYMBOLS GHS HAZARD SYMBOLS

None

This Product is not subject to WHMIS

None

SDS No.: 00066.0001

GHS Classifications: Hazardous to the Aquatic Environment, Chronic Category 3 Signal Word: None

Hazard Statements : H412: Harmful to aquatic life with long lasting effects

Target organs: None

Precautionary Statements: P273: Avoid release to the environment P391: Collect spillage P501: Dispose of product properly

GHS Pictograms: None

EU Classifications:

Hazard Symbols None Risk Phrases R52/53: Harmful to aquatic organisms and may cause long-term adverse effects

Safety Phrases S61: Avoid release to the environment

Health Hazards or Risks From Exposure This product is a finished metal alloy solid. Therefore, under normal handling of this product, no exposure to any harmful materials will occur. The bullet contains these harmful substances:

Copper: Inhalation of high concentrations of metallic copper dusts or fumes may cause nasal irritation and/or nausea, vomiting and stomach pain.

Tin: Tin dust is irritating to the eyes and airways. Prolonged inhalation of tin dust or fumes can cause benign pneumoconiosis (aka:

stannosis).

It is unlikely that someone would be exposed to a significant amount of copper or tin dust from handling these bullets.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Components % By Weight CAS Number EINECS/ ELINCS #

Copper 80 – 95 7440-50-8 231-159-6 Tin 0 – 10 7440-31-5 231-141-8 Zinc 0 – 4 7440-66-6 231-175-3 Ecomass Compound 1050C093

0 – 5 25038-74-8 Polymer

4. FIRST AID MEASURES

Eye Contact: Immediately flush out trace material with water, occasionally lifting the upper and lower eyelids. If eye irritation develops, call a physician at once.

Skin Contact: Wash skin with plenty of soap and water.

Inhalation: Not applicable Ingestion: If ingested, immediately call a physician.

Medical Conditions Aggravated By Exposure:

There are no medical conditions known to be aggravated by exposure to this product in its solid form.

Recommendations To Physcians:

No specific antidote available, treat symptoms

HEALTH HAZARD (BLUE)

FLAMMABILITY HAZARD (RED)

PHYSICAL HAZARD (YELLOW)

PROTECTIVE EQUIPMENT

EYES PPE

CODE

RESPIRATORY HEARING

See Sect 8

5. FIRE FIGHTING MEASURES

PROPERTY VALUE PROPERTY VALUE

Explosive No Flammable Not applicable

Combustible Not applicable Pyrophoric No Flash Point (C): Not applicable Burning Rate of Material: Not applicable

Lower Explosive Limit: Not applicable Autoignition Temp.: No data Upper Explosive Limit: Not applicable Flammability Classification: (defined by 29 CFR 1910.1200) Not applicable

Unusal Fire and Explosion Hazards: None.

Extinguishing Media: Choose extinguishing media suitable for surrounding materials.

Special Firefighting Procedures: In case of fire, use normal fire fighting equipment.

NFPA RATING SYSTEM

Flammability

Health 0 0 Reactivity

Other

HMIS RATING SYSTEM

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard

6. ACCIDENTAL RELEASE MEASURES

FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC AT 800-424-9300.

Spill Response: A spill of this material will normally not require emergency response team capabilities. If, however, a large spill occurs, call 1-888-289-1911 for technical assistance.

Accidental Release Procedures: Collect material and place in a designated, labeled waste container. See Section 13 for waste disposal.

7. HANDLING AND STORAGE

Precautions for Safe Handling: Use appropriate personal protective equipment (see Section 8). Workers should wash hands after handling.

Conditions for Safe Storage: Store in original containers away from acids and caustics.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters:

CAS # CHEMICAL NAME ACGIH TLV OSHA PEL INTERNATIONAL OELS

7440-50-8 Copper 0.2 mg/m3 (fume), 1 mg/m3 (dusts and mists)

0.1 mg/m3 (fume) 1 mg/m3 (dusts and mists)

Austria, Belgium, Canada: 0.2 mg/m3 (fumes), 1 mg/m3 (dusts) Denmark: 1.0 mg/m3 (dust and powder) Germany (MAK): 0.1 mg/m3 (fume), 1 mg/m3 (dusts and mists)

7440-31-5 Tin 2 mg/m3 2 mg/m3 U.K. (LTEL): 5 mg/m3 Austria & Germany (MAK), Belgium, Finland, Denmark, The Netherlands, Poland, Switzerland: 2 mg/m3 Hungary, Norway: 1 mg/m3

7440-66-6 Zinc None established None established None established 25038-74-8 Ecomass Compound

1050C093 None established None established None established

Engineering Controls: Local exhaust ventilation is recommended if significant dusting occurs or fumes are generated.

Otherwise, use general exhaust ventilation.

Respiratory Protection: Not normally needed. Maintain airborne contaminant concentrations below guidelines listed above.

Use an appropriate approved air-purifying respirator equipped with HEPA cartridges/canisters where there is the potential for exceeding established occupational exposure limits.

Eye/Face Protection: Not normally needed Hand Protection: Not normally needed Skin Protection: Not normally needed.

Hearing Protection: Not normally needed.

General Hygiene: Wash hands thoroughly after use.

9. PHYSICAL AND CHEMICAL PROPERTIES

PROPERTY VALUE PROPERTY VALUE

Appearance: Cylindrical projectile – copper colored if copper plated, gray if not plated

Physical State: Solid

Odor: None Odor Threshold: None Boiling Point (F): Not applicable Melting point: Not applicable

Vapor Pressure (mm Hg): Not applicable Freezing point: Not applicable Vapor Density(air = 1): Not applicable Bulk Density Not applicable Specific gravity (g/cc): Not applicable Viscosity (cps): Not applicable pH: Not applicable Decomposition Temperature: Not applicable Solubility in Water (20 C): Insoluble Evaporation Rate: Not applicable

Volatiles, Percent by volume: Not applicable Octanol/water partition coefficient: Not applicable

10. STABILITY AND REACTIVITY

Stability: Stable under normal temperatures and pressure.

Possibility of Hazardous Reactions: Hazardous polymerization will not occur Incompatible Materials: Acids and caustics Hazardous Decomposition Products: None. Reaction with acids may liberate explosive hydrogen gas.

Conditions to Avoid: Contact with incompatible materials.

11. TOXICOLOGICAL INFORMATION

Potential Routes of Entry: Inhalation, Skin, and by Ingestion.

The physical nature of this product makes absorption from any route unlikely.

Effects Of Acute Exposure:

PRODUCT

COMPONENTS

Copper Tin Zinc Ecomass Compound

Inhalation

LC50

Inhalation unlikely No data No data No data No data

Skin Contact

LD50

Skin absorption unlikely

375 mg/kg, sc (rabbit)

No data No data No data

Ingestion

LD50

Ingestion unlikely 3.5 mg/kg, ip (mouse)

No data No data No data

Irritation Not a skin or eye irritant as a solid.

Respiratory irritant Eye irritant Eye irritant No data

Sensitization Sensitization to this Product has not been reported

No data No data No data No data

Other Adverse Effects:

Target Organ Toxicity: No reported target organ toxicity from this product.

Reproductive Toxicity: This product is not known or reported to cause reproductive effects.

Teratogenicity (Birth Defects): This product is not known or reported to cause developmental toxicity.

Mutagenicity: This product is not known or reported to be mutagenic.

Carcinogenicity: This product is not listed as a carcinogen by OSHA, NTP or IARC.

12. ECOLOGICAL INFORMATION

Environmental Effects:

PRODUCT: Product has not been tested for environmental properties.

COMPONENTS:

Copper: Copper concentrations from 0.1 to 1.0 mg/l have been found to be not toxic for most fish. However, concentrations of 0.015 to 3.0 mg/l have been reported as toxic, particularly in soft water to many kinds of fish, crustacea, mollusks, insects, and plankton.

Zinc: The following concentrations of zinc have been reported as lethal to fish: 0.13 mg/l, for 12 – 24 hours to Rainbow trout fingerlings; 1.9 – 3.6 mg/l, 6 hr TLM (soft water, 30°C) to Bluegill Sunfish; 4 mg/l, 3 days (hard water) to Rainbow trout; 1 mg/l, 24 hours (soft water) to Sticklebacks.

Tin: No information

Environmental Fate:

MOBILITY: No data PERSISTANCE/DEGRADABILITY: Not biodegradable.

BIOACCUMULATION: No data

13. DISPOSAL CONSIDERATIONS

Care must be taken to prevent environmental contamination from the use of this material. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding the treatment, storage and disposal for hazardous and nonhazardous wastes.

14. TRANSPORT INFORMATION

Regulatory Information for US DOT, IATA, IMO, and ADR:

Proper Shipping Name: None This material is not regulated as a DOT hazardous material.

Hazard Class Number and Description: None

UN Identification Number: None

Packing Group: None

DOT Label(s) Required: None

Additional Information: None

15. REGULATORY INFORMATION

US FEDERAL

TSCA The components of this product are listed on the Toxic Substance Control Act inventory.

CERCLA: Copper, R.Q.* = 5000 lbs. Zinc, R.Q. – 1000 lbs. (No reporting is required if diameter of the pieces of metal is equal to or exceeds 100 micrometers (0.004 inches).

SARA 313: Copper, Zinc (fume or dust) SARA 311/312: Health: Acute – No

Chronic - No Fire: No Reactivity: None Release of Pressure: No

SARA 302 EHS List: None of the components of this product are listed.

*RQ = Reportable Quantity

STATE RIGHT-TO-KNOW STATUS

Component California New Jersey Pennsylvania Massachusetts Michigan Copper Not listed X X X X Tin Not listed Not listed X X Not listed Zinc Not listed X Not listed X X Ecomass compound 1050C093 Not listed Not listed Not listed Not listed Not listed

CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65)

No components listed

GHS CLASSIFICATION

Hazardous to the Aquatic Environment, Chronic Category 3

EUROPEAN REGULATIONS

All chemical components listed on EINECS

Hazard Classification Danger Symbols: None

Risk Phrases: R52/53

Safety Phrases: S61

German WGK Classification: Not known.

CANADIAN REGULATIONS

DSL/NDSL Inventory: The components of this product are on the DSL

IDL: Copper, Tin

CEPA PRIORITIES LIST: None

WHMIS: This product is considered to be a manufactured article and therefore not subject to WHMIS requirements.

JAPANESE REGULATIONS

Existing National Inventory of Chemical Substances (ENCS): The components of this product are listed

Japanese Priority Assessment Chemical Substances: None of the components of this product are listed

OTHER INTERNATIONAL CHEMICAL INVENTORIES

Swiss Giftliste List of Toxic Substances: All Components Listed Australian Inventory (AICS): All Components Listed

16. OTHER INFORMATION

REVISIONS:

DATE:

2/28/2019

PREPARED BY: Olin Winchester, LLC OTHER: Additional information available from: www.winchester.com NOTICE: THE INFORMATION IN THIS SDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. OLIN BELIEVES THIS INFORMATION TO BE RELIABLE AND CURRENT AS OF THE DATE OF PUBLICATION, BUT

MAKES NO WARRANTY THAT IT IS.

5, Montée des Arsenaux Repentigny, QC, Canada, J5Z 2P4

Phone: (450) 581-3080

©2013 General Dynamics Ordnance and Tactical Systems - Canada Inc.

Cartridge, 9mm Greenshield® Frangible Toxfree®

SDS Preparation Date (mm/dd/yyyy): 09/12/2013

Revision No.: 2

5302056

NSN: 1305-20-002-5523

SAFETY DATA SHEET

SECTION 1. IDENTIFICATION

Product identifier used on the label : Cartridge, 9mm Greenshield® Frangible Toxfree®

Product Code(s) : 5302056

NSN: 1305-20-002-5523

Recommended use of the chemical and restrictions on use

: Small arms cartridges / ammunition.

Use pattern: Paramilitary / Military ammunition. Lead-free / non-toxic frangible training cartridge designed to reduce health and safety hazards by eliminating exposure to lead and other heavy metals. Reduced ricochet and splashback, and designed for use in duty weapons without conversion. Ideal for training indoor and outdoor as well as in built up areas.

Chemical family : Explosive article.

Name, address, and telephone number of the manufacturer:

General Dynamics Ordnance and Tactical Systems - Canada Inc.

5, Montée des Arsenaux Repentigny, QC, Canada J5Z 2P4

Name, address, and telephone number of the supplier:

Refer to manufacturer

Manufacturer's Telephone # : (450) 581-3080

24 Hr. Emergency Tel # : (888) 992-3330 (Canada / U.S.A.)

(514) 981-5228 (International)

SECTION 2. HAZARDS IDENTIFICATION

Classification of the chemical

WHMIS information: This product is not a WHMIS controlled product in Canada. Explosive. The Controlled Products Regulations (CPR) do not apply to explosives [Hazardous Products Act Section 12(a)].

OSHA: This material is classified as hazardous under OSHA regulations (29CFR 1910.1200) (Hazcom 2012). Classification:

Explosives - Division 1.4

Label elements

The following label information is applicable only to the United States according to OSHA Regulations (29 CFR 1910.1200) (Hazcom 2012):

Signal Word

Warning!

Hazard statement(s)

Fire or projection hazard.

Precautionary statement(s)

Keep away from heat, open flames and hot surfaces. - No smoking.

Do not subject to excessive friction or mechanical shock.

Wear face protection.

In case of fire: Evacuate area.

DO NOT fight fire when fire reaches explosives.

Fight fire with normal precautions from a reasonable distance.

Store in accordance with local regulations.

Dispose of contents/container in accordance with local regulation.

The following label information is applicable only to Canada according to the Canadian Controlled Products Regulations

(CPR/WHMIS):

The Controlled Products Regulations (CPR) do not apply to explosives [Hazardous Products Act Section 12(a)]. As such, this product does not require a WHMIS Supplier label.

Other hazards

This product is an explosive article which is composed of a finished cartridge containing various components that are sealed completely within the cartridge. Under normal conditions of handling, no exposure to any of the harmful components inside th e cartridge is expected and no health effects are generally expected as supplied.

When cartridges are fired, or otherwise discharged, gases, fumes and projections may be formed. These gases, fumes and projections may contain trace amounts of the components inside the cartridges.

See TOXICOLOGICAL INFORMATION, Section 11.

Environmental precautions: Avoid release to the environment.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name CAS # Concentration

The cartridge case contains the following components:

Copper 7440-50-8 26.38%

Zinc 7440-66-6 11.31%

The primer contains the following chemicals:

Diazodinitrophenol 87-31-0 < 0.10%

Potassium nitrate 7757-79-1 < 0.10%

Other metal and urea compounds Proprietary < 0.10%

Pentaerythritol (PETN) 115-77-5 < 0.01%

The projectile contains the following chemicals:

Copper 7440-50-8 51.24%

Nylon 63428-83-1 3.86%

The propellant contains the following chemicals:

Nitrocellulose 9004-70-0 3.90%

Nitroglycerin 55-63-0 0.51%

Diphenylamine 122-39-4 < 0.10%

Note: The exact concentrations of the above listed chemicals are being withheld as a trade secret. Concentrations listed above are the final concentration in the complete finished cartridge.

SECTION 4. FIRST-AID MEASURES

Description of first aid measures

Ingestion

Inhalation

: If ingested, immediately call a physician. Inducing vomiting should only be performed under direct supervision of medical personnel. Never give anything by mouth to an unconscious person.

: None required under normal conditions. If cartridges are fired, or otherwise discharged and gases, fumes or projections are formed and inhaled, the following treatment may be necessary:

Immediately remove person to fresh air. Obtain medical attention if symptoms develop and persist.

Skin contact : None required when used as intended. If cartridges are fired, or otherwise discharged, the following treatment may be necessary for skin contact with gases, fumes or projections that may be formed:

Remove contaminated clothing. Wash affected areas with soap and water. Seek medical attention if symptoms develop or persist, or if projection has caused any injury.

Eye contact : None required when used as intended. If cartridges are fired, or otherwise discharged, the following treatment may be necessary for eye contact with gases, fumes or projections that may be formed. Immediately flush eyes with running water for at least 15 minutes. If irritation or symptoms develop, seek medical attention. Remove contact lenses if present and easy to do.

Most important symptoms and effects, both acute and delayed

: When cartridges are fired, or otherwise discharged, gases, fumes and projections may be formed. These gases, fumes and projections may contain trace amounts of the components inside the cartridges. These gases, fumes and projections may be irritating to the eyes, skin and respiratory tract.

Indication of any immediate medical attention and special treatment needed

: Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Extinguishing media Suitable extinguishing media

Use flooding quantities of water to fight fires. If water is not available, use carbon dioxide (CO2), dry chemical or dirt.

Unsuitable extinguishing media

None known.

Special hazards arising from the substance or mixture / Conditions of flammability

: Explosive! Fire or projection hazard Cartridges may ignite and explode if heated to 120°C (248°F) independant of air. Cartridges may ignite and explode if the primer is struck.

Flammability classification (OSHA 29 CFR 1910.106)

: Not applicable.

Explosion Data: Sensitivity to Mechanical Impact / Static Discharge:

: May be ignited if subjected to shock. Sensitive to mechanical impact. May be sensitive to static discharge.

Hazardous combustion products

Carbon oxides; sulfur oxides; Nitrogen oxides (NOx); Metal oxides; Aldehydes; Other unidentified organic compounds.

Special protective equipment and precautions for firefighters

Protective equipment for fire-fighters

: Firefighters should wear an approved full-face, self-contained breathing apparatus (SCBA) and impervious clothing. Unconfined ignited cartridges can produce low velocity metallic fragments which may cause eye injury or superficial skin wounds if unprotected by standard firefighter turnout gear.

Special fire-fighting procedures

In case of fire: Evacuate area.

DO NOT fight fire when fire reaches explosives.

Do not enter fire area without proper protection. Shield personnel from exploding cartridges.

Move containers from fire area if safe to do so. Water spray may be useful in cooling equipment exposed to heat and flame.

Cargo fires:

Packages bearing the 1.4S label or packages containing material classified as 1.4S are designed or packaged in such manner that when involved in a fire, may burn vigorously with localized detonations and projection of fragments.

Effects are usually confined to immediate vicinity of packages.

If fire threatens cargo area containing packages bearing the 1.4S label or packages containing material classified as 1.4S, consider isolating at least 15 meters (50 feet) in all directions. Fight fire with normal precautions from a reasonable distance.

Tire or vehicle fires:

Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt.

If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to prevent fire from spreading to cargo area.

Pay special attention to the tire fires as re-ignition may occur. Stand by with extinguisher ready.

Evacuation:

Large spill: Consider initial evacuation for 50 meters (150 feet) in all directions.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Environmental precautions :

Restrict access to area until completion of clean-up. Do not clean up or dispose of, except under supervision of a specialist. All persons dealing with the clean-up should wear the appropriate chemically protective equipment. Refer to protective measures listed in sections 7 and 8.

Ensure spilled product does not enter drains, sewers, waterways, or confined spaces.

Methods and material for containment and cleaning up

: For solid, intact cartridges:

Handle spills carefully. Do not subject cartridges to mechanical shock. Ventilate the area.

Remove all sources of ignition. Pick up and transfer to properly labelled containers.

If spill occurs in an area where there is a fire burning:

Large spill: Consider initial evacuation for 50 meters (150 feet) in all directions. Refer to Section 5 for firefighting instructions.

If loose powder is present:

All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Do not operate radio transmitters within 100 meters (330 feet) of electric detonators. Pick up and arrange disposal without creating dust.

Contact the proper local authorities.

Special spill response procedures

: If a spill/release in excess of the EPA reportable quantity is made into the environment, immediately notify the national response center in the United States (phone:

1-800-424-8802).

US CERCLA Reportable quantity (RQ): None reportable.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling

Conditions for safe storage :

Incompatible materials :

Keep away from heat, open flames and hot surfaces. - No smoking. Ground all equipment during handling. Do not subject to excessive friction or mechanical shock.

Use in a well-ventilated area. Wear suitable protective equipment during handling. For personal protection see section 8. Do not breathe fumes or dusts. Do not store near acids.

Do not store near any incompatible materials (see Section 10).

In the United States, handle in accordance with 29 CFR Part 1910.109 for Explosives.

While explosives are being handled or used, smoking shall not be permitted and no one near the explosives shall possess matches, open light or other fire or flame. No person shall be allowed to handle explosives while under the influence of intoxicating substances or alcohol.

Store in a cool, dry, well ventilated area, away from incompatibles. Keep away from heat.

Inspect periodically for damage or leaks. Protect against physical damage. Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. No smoking in the area.

In the United States, ensure the storage requirements of 29 CFR Part 1910.109 for Explosives are met:

Small arms ammunition shall be separated from flammable liquids, flammable solids as classified in 49 CFR part 172, and from oxidizing materials, by a fire-resistive wall of 1-hour rating or by a distance of 25 feet. No quantity limitations are imposed on the storage of small arms ammunition in warehouses, retail stores, and other general occupancy facilities, except those imposed by limitations of storage facilities.

Acids; caustics ; Ammonia; Chlorate; Acetylene; Ammonium nitrate; fluorine; Bromine; Oils;

Class A and B explosives (U.S.); Strong oxidizers (e.g. Chlorine, Peroxides, etc.).

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Limits:

Chemical Name

ACGIH TLV

TWA STEL

OSHA PEL

PEL STEL

The cartridge case contains the

Copper following components:

0.2 mg/m³ (fume); 1 N/Av mg/m³ (dust and mist)

0.1 mg/m³ (fume); 1 N/Av mg/m³ (dust and mist)

Zinc N/Av N/Av N/Av N/Av

The primer contains the followin

Diazodinitrophenol g chemicals:

N/Av N/Av

Potassium nitrate N/Av N/Av N/Av N/Av

Other metal and urea compounds N/Av N/Av N/Av N/Av

Pentaerythritol (PETN) 10 mg/m³ N/Av 15 mg/m³ (total N/Av dust); 5 mg/m³

(respirable)

The projectile contains the follo

Copper wing chemicals:

0.2 mg/m³ (fume); 1 N/Av mg/m³ (dust and mist)

0.1 mg/m³ (fume); 1 N/Av mg/m³ (dust and mist)

Nylon N/Av N/Av N/Av N/Av

The propellant contains the follo

Nitrocellulose wing chemicals:

Nitroglycerin 0.05 ppm (skin) N/Av 0.2 ppm (Ceiling) N/Av (skin)

Diphenylamine 10 mg/m³ N/Av 10 mg/m³ (final rule N/Av limit)

Exposure controls

Ventilation and engineering measures

: Ensure adequate ventilation, especially in confined areas.

Respiratory protection : Not required under normal conditions of handling.

Skin protection Eye / face protection

: Not required under normal conditions of handling.

: Safety glasses with side shields should be used with this product. If necessary, refer to U.S.

OSHA 29 1910.133 or Canadian CSA Standard Z94.3-02.

Other protective equipment : Use hearing protection. Hearing protection should have an EPA-NRR of 20 or greater. If necessary refer to OSHA regulation 29 CFR 1910.95 or 1926.01. Ensure that eyewash stations and safety showers are close to the workstation location.

General hygiene considerations

: Do not breathe fumes or dusts. Do not ingest. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Remove and wash contaminated clothing before re-use.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Odour

: Small caliber cartridge Copper alloy cartridge case Copper/nylon projectile

: Odourless.

Odour threshold : N/Ap pH

Melting/Freezing point : N/Ap

: N/Ap

Initial boiling point and boiling range

: N/Ap

Flash point : N/Ap Flashpoint (Method) : N/Av

Evaporation rate (BuAe = 1) : N/Ap

Flammability (solid, gas) : Not applicable.

Lower flammable limit (% by vol.)

: N/Ap

Upper flammable limit (% by vol.)

Oxidizing properties

: N/Ap

: None known.

Explosive properties : Explosive

Vapour pressure

Vapour density : N/Ap

: N/Ap

Relative density / Specific gravity

: N/Ap

Solubility in water : Insoluble. If loose powder is present, may be water reactive.

Other solubility(ies) : No information available.

Partition coefficient: n-octanol/water or Coefficient of water/oil distribution

Auto-ignition temperature

: N/Av

: Primer component: 120°C (250°F) Decomposition temperature : N/Av Viscosity :

Volatiles (% by weight) :

N/Ap

N/Av

Volatile organic Compounds (VOC's)

Absolute pressure of container

N/Av

: N/Ap

Flame projection length : N/Ap

Other physical/chemical comments

: No additional information.

SECTION 10. STABILITY AND REACTIVITY

Reactivity

Chemical stability

: Cartridge may ignite if the primer is struck or if heated to 120°C (248°F).

: Stable under normal conditions.

Possibility of hazardous reactions : Sensitive to mechanical impact / static discharge. Hazardous polymerization does not occur.

Conditions to avoid : Avoid heat, open flames, sparks, static electricity and electrical equipment. Avoid contact with incompatible materials.

Incompatible materials : Acids; caustics ; Ammonia; Chlorate; Acetylene; Ammonium nitrate; fluorine; Bromine; Oils;

Class A and B explosives (U.S.); Strong oxidizers (e.g. Chlorine, Peroxides, etc.).

Hazardous decomposition products

: None known, refer to hazardous combustion products in Section 5.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure:

Routes of entry inhalation

Routes of entry skin & eye

Routes of entry Ingestion

: YES

: YES

: YES

Routes of exposure skin absorption

Potential Health Effects:

: NO

Signs and symptoms of short-term (acute) exposure

Sign and symptoms Inhalation

Sign and symptoms ingestion

Sign and symptoms skin :

When cartridges are fired, or otherwise discharged, gases, fumes and projections may be formed. These gases, fumes and projections may contain trace amounts of the components inside the cartridges. These gases, fumes and projections may be irritating to the respiratory tract.

Ingestion of complete catridges or dusts may cause gastrointestinal discomfort, including nausea, cramping, vomiting and diarrhea.

When cartridges are fired, or otherwise discharged, gases, fumes and projections may be formed. These gases, fumes and projections may contain trace amounts of the components inside the cartridges. These gases, fumes and projections may be irritating to the skin.

Fragmented projections from primers can cause puncture wounds or cuts.

Sign and symptoms eyes : When cartridges are fired, or otherwise discharged, gases, fumes and projections may be formed. These gases, fumes and projections may contain trace amounts of the components inside the cartridges. These gases, fumes and projections may be irritating to the eyes.

Fragmented projections from primers can cause puncture wounds or cuts.

This product is an explosive article which is composed of a finished cartridge containing various components that are sealed completely within the cartridge. Under normal conditions of handling, no exposure to any of the harmful components inside the cartridge is expected and no health effects are generally expected as supplied.

Potential Chronic Health Effects

When cartridges are fired, or otherwise discharged, gases, fumes and projections may be formed. These gases, fumes and projectiles may contain trace amounts of the components inside the rockets. Inner cartridge components include: diphenylamine. Chronic exposure to diphenylamine can cause kidney and liver damage, and blood system effects (methemoglobinemia).

Mutagenicity : Not considered to be a hazard.

Under normal conditions of handling, no exposure to any of the harmful components inside the cartridge is expected and no health effects are generally expected as supplied.

Carcinogenicity : Not known to be carcinogenic.

Reproductive effects & Teratogenicity

: Not expected to cause reproductive effects.

Senitization to material : Not expected to be a skin or respiratory sensitizer.

Specific target organ effects : Under normal conditions of handling, no exposure to any of the harmful components inside

Irritancy : Not a hazard under normal conditions of use.

Medical conditions aggravated by overexposure

: Pre-existing skin, eye and respiratory disorders.

Synergistic materials : Not available.

Toxicological data : There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data.

Phone: (450) 581-3080

©2013 General Dynamics Ordnance and Tactical Systems - Canada Inc.

Cartridge, 9mm Greenshield® Frangible Toxfree®

Chemical name

LC50(4hr) inh, rat

LD50

(Oral, rat) (Rabbit, dermal)

The cartridge case contains the following components:

Copper N/Av > 2500 mg/kg > 2000 mg/kg

Zinc N/Av N/Av N/Av

The primer contains the following chemicals:

Diazodinitrophenol N/Av N/Av N/Av

Potassium nitrate N/Av 3015 mg/kg N/Av

Other metal and urea compounds

N/Av N/Av N/Av

Pentaerythritol (PETN) N/Av 19 500 mg/kg N/Av

The projectile contains the following chemicals:

Copper N/Av > 2500 mg/kg > 2000 mg/kg

Nylon N/Av N/Av N/Av

The propellant contains the following chemicals:

Nitrocellulose N/Av > 5000 mg/kg N/Av

Nitroglycerin N/Av 105 mg/kg > 280 mg/kg

Diphenylamine N/Av 1120 mg/kg > 5000 mg/kg

Other important toxicological hazards : None known or reported by the manufacturer.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity : No data is available on the product itself. The product should not be allowed to enter drains or water courses, or be deposited where it can affect ground or surface waters. Contains:

Zinc; Nitroglycerin; diphenylamine.

The acute toxicity of zinc powder is (WHO 2001, EHC # 221):

Toxicity to daphnia - EC50/48h/daphnia = 0.07 mg/L Toxicity to algae - EC50/72h/algae = 0.15 mg/L

The acute toxicity of Nitroglycerin is (literature);

Toxicity to fish - LC50/96h/bluegill sunfish = 1.28 mg/L Toxicity to daphnia - EC50/48h/daphnia = 17.23 mg/L Toxicity to algae - EC50/96h/green algae = 1.15 mg/L

The acute toxicity of diphenylamine is (literature):

Toxicity to fish - LC50/96h/Fathead minnows = 3.79 mg/L Toxicity to daphnia

EC50/48h/daphnia = 0.31 mg/L NOEC = 0.16 mg/L

Toxicity to algae - EC50/72h/algae = 1.5 mg/L

Persistence and degradability

The product itself has not been tested. Not expected to be rapidly biodegradable.

Bioaccumulation potential : The product itself has not been tested.

Mobility in soil : The product itself has not been tested.

Other Adverse Environmental effects

: None known.

SECTION 13. DISPOSAL CONSIDERATIONS

Handling for Disposal : Handle waste according to recommendations in Section 7. Empty product containers may contain hazardous product residue.

Methods of Disposal : The recommended means for disposing of scrap material usually involves demilitarization of cartridges (i.e.: separating all explosive elements for individual destruction) it can also be done by open detonation but it is not the preferred way.

After components are scrapped by proper incineration, the remaining scrap material should be disposed of or recycled in accordance with all applicable local, provincial (state) and federal regulations.

Dispose in accordance with all applicable federal, state, provincial and local regulations.

RCRA : If this product, as supplied, becomes a waste in the United States, it may meet the criteria of a hazardous waste as defined under RCRA, Title 40 CFR 261. It is the responsibility of the waste generator to determine the proper waste identification and disposal method. For disposal of unused or waste material, check with local, state and federal environmental agencies.

SECTION 14. TRANSPORTATION INFORMATION

Regulatory Information

UN Number

UN proper shipping name

Transport hazard class(es)

Packing Group

Label

TDG

TDG

Additional information

UN0012 CARTRIDGES FOR WEAPONS, INERT PROJECTILE;

or

CARTRIDGES, SMALL ARMS

1.4S II

Placards are not required in accordance with TDG Section 4.17.

49CFR/DOT

49CFR/DOT

Additional information

UN0012 Cartridges for weapons, inert projectile or

Cartridges, small arms

1.4S II

Until December 31, 2013, may be marked as "Cartridges, small arms" and reclassed as "ORM-D" material.

Special precautions for user : Avoid shock and friction. Appropriate advice on safety must accompany the package.

Environmental hazards : See ECOLOGICAL INFORMATION, Section 12.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

: Not applicable.

SECTION 15. REGULATORY INFORMATION

US Federal Information:

TSCA: All listed ingredients appear on the Toxic Substances Control Act (TSCA) inventory.

CERCLA Reportable Quantity (RQ) (40 CFR 117.302): None reportable.

SARA TITLE III: Sec. 302, Extremely Hazardous Substances, 40 CFR 355: No Extremely Hazardous Substances are present in this material.

SARA TITLE III: Sec. 311 and 312, MSDS Requirements, 40 CFR 370 Hazard Classes: Explosive. Under SARA Sections 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. The current thresholds are 500 pounds for the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

SARA TITLE III: Sec. 313, Toxic Chemicals Notification, 40 CFR 372: This product may be subject to SARA notification requirements, since it contains Toxic Chemical constituents above their de minimus concentrations. This product contains:

Copper; Zinc.

US State Right to Know Laws:

California Proposition 65: To the best of our knowledge, this product does not contain any chemicals known to the State of California to cause cancer or reproductive harm.

Canadian Information:

Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List

(DSL).

WHMIS information: Refer to Section 2 for a WHMIS Classification for this product.

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR.

International Information:

European EINECs information: All ingredients listed appear on the European EINECs inventory.

SECTION 16. OTHER INFORMATION

Legend

: ACGIH: American Conference of Governmental Industrial Hygienists

CAS: Chemical Abstract Services CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act of CFR: Code of Federal Regulations CSA: Canadian Standards Association ECHA: European Chemicals Agency DOT: Department of Transportation EHC: Environmental Health Criteria EPA: Environmental Protection Agency HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer Inh: Inhalation LC: Lethal Concentration LD: Lethal Dose N/Ap: Not Applicable N/Av: Not Available NIOSH: National Institute of Occupational Safety and Health NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PEL: Permissible exposure limit RCRA: Resource Conservation and Recovery Act RTECS: Registry of Toxic Effects of Chemical Substances SARA: Superfund Amendments and Reauthorization Act SDS: Safety Data Sheet / Material Safety Data Sheet STEL: Short Term Exposure Limit TDG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TWA: Time Weighted Average WHO: World Health Organization WHMIS: Workplace Hazardous Materials Identification System

References :

Preparation Date (mm/dd/yyyy)

1. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices for 2013.

2. International Agency for Research on Cancer Monographs, searched 2013.

3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2013 (Chempendium, HSDB and RTECs).

4. Material Safety Data Sheets from manufacturer.

5. US EPA Title III List of Lists - October 2012 version.

6. California Proposition 65 List - July 26, 2013 version.

: 09/12/2013 Revision No. : 2 Other special considerations for handling

: Provide adequate information, instruction and training for operators.

Prepared for:

General Dynamics Ordnance and Tactical Systems - Canada Inc.

5, Montée des Arsenaux Repentigny, QC, Canada, J5Z 2P4 Phone: (450) 581-3080 Website: www.gd-otscanada.com/ Direct all enquiries to: General Dynamics.

Prepared by:

ICC The Compliance Center Inc.

Telephone: (888) 442-9628 (U.S.): (888) 977-4834 (Canada) http://www.thecompliancecenter.com

DISCLAIMER

This Safety Data Sheet was prepared by ICC The Compliance Center Inc. using information provided by / obtained from General Dynamics Ordnance and Tactical Systems - Canada Inc.. and CCOHS’ Web Information Service. The information in the Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc and General Dynamics Ordnance and Tactical Systems - Canada Inc. expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this SDS does not apply to use with any other product or in any other process.

This Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc. and General Dynamics Ordnance and Tactical Systems - Canada Inc.

END OF DOCUMENT

SDS No.: 000068.0001

Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe, Japanese Standard JIS Z 7250:2000, and EU REACH Regulations

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: CARTRIDGES – SHOTSHELL CAS Number: Mixture – Metal Alloy Synonyms: Shotshell Brands: Super-X, Supreme, Supreme High Velocity, Game Loads, Heavy Game Loads, AA, AA International Target, AA Target, AA Traacker, AA Plus, AA Sporting Clays, AA Super Pigeon, Double X, Double X Magnum,Upland, BRI, International Sporting, Ranger, Ranger Spreader, Ranger Low Recoil, Thunder Gold, Black Diamond, Super Dove, Super Lite, Super Speed, Super Speed Xtra, Super Sport, Rabbit and Squirrel, Dove and Quail, Duck and Pheasant, Pheasant, Super Pheasant, USA Brand, USA Dove & Clay, USA Game & Target, Super Target, Win3Gun, Rooster XR, Long Beard XR, Dual Bond, Partition Gold, Platinum Tip, RazorBoar XT, Rackmaster, Power Point, PDX1 Defender, Target and Game, Xtra-Lite, Universal, Fast Dove, Western, Winner, WinLite, Turkey, Hunter, White Wing, Grex, Shot-Lok, M19, Deer Season, Varmint X, Reduced Hazard Shotshell Slug Load; Reduced Hazard “00” Buckshot Shell, Frangible Slug Shotshell, Frangible “00” Buckshot Load, Xtended Range™ High Density Shotshell Loads, Xtended Range Bismuth, Zinc Slug Load 12 ga.

1oz, XP3, Xpert, Xpert Steel, Xpert HV, Xpert Snow Goose, Drylok Siper Steel Non-Toxic, Blind Side, Steel Shot, Plated Steel Shot, Hex Steel Shot, Drylok Wad, WWII Victory Series, Service Grade, Deer Season, Shotshell Payload Names: Lead Shot, Lead Slug, Copper Plated Lead Shot, BRI Slug, Lead Buckshot, Saboted Slug, Bonded Dual Jacket Saboted Slug, BRI Rifled Slug, Platinum Tip, Razorback Slug, Rackmaster Slug, Power Point Slug, PDX1 Segmenting Slug, Grex buffer, Shot-Lok buffer, AA wad, BRI sabot, M19, Deer Season Slug, Dual Bond Slug

Shotshell Gauges: 410 Bore 2-1/2 inch, 410 Gauge 2-1/2 inch, 410 Bore 3 inch, 410 Gauge 3 inch, 28 Gauge 2-3/4 inch, 20 Gauge 2-3/4 inch, 20 Gauge 3 inch, 16 Gauge 2-3/4 inch, 12 Gauge 2-3/4 inch, 12 Gauge 3 inch, 12 Gauge 3-1/2 inch, 10 Gauge 3-1/2 inch.

Shotshell Proof Loads

Product Use: Shotgun Loaded Ammunition U.N. Number: UN 0012 U.N. Dangerous Goods Class

Explosive, 1.4S

Manufacturer/Responsible Party:

Olin Winchester, LLC

Manufacturers’ Address: 600 Powder Mill Road, East Alton, IL 62024 www.winchester.com

Emergency Telephone Number:

US/Canada: 1-800-424-9300 Outside US/Canada: 703-527-3887

SDS Control Group: 618-258-3507 (Technical Information Only)

Olin SDS No.: 00068.0001

Issue Date: 6/1/15

Revision Date: 02/28/2019

Revision No.: 5

SAFETY DATA

SHEET

SDS No.: 000068.0001

2. HAZARDS IDENTIFICATION

US DOT SYMBOLS CANADA (WHMIS) SYMBOLS GHS HAZARD SYMBOLS

This Product is not subject to WHMIS

Class 6 Explosive

GHS Classifications: Carcinogenicity Category 1A Reproductive Toxicity Category 1A

Explosive Division 1.4 STOT RE Category 1 Aquatic Environment, Chronic II

Signal Word: Danger

Hazard Statements : H204: Fire or projection hazard H350: May cause cancer H360: May damage fertility or the unborn child H362: May cause harm to breast-fed children

H372: Causes damage to nervous system, kidney, and hematopoietic system through prolonged or repeated exposure H411: Toxic to aquatic life with long lasting effects

Target organs: Nervous, renal and hematopoietic systems

EMERGENCY OVERVIEW: EXPLOSIVE. KEEP AWAY FROM HEAT. DO NOT SUBJECT TO MECHANICAL SHOCK.

PARTICLES FROM FIRING MAY BE HARMFUL IF INHALED. DO NOT TAKE INTERNALLY.

SDS No.: 00068.0001

Precautionary Statements: P102: Keep out of reach of children P210: Keep away from heat/sparks/open flame/hot surfaces P250: Do not subject to shock/friction P260: Do not breathe fumes P264: Wash hands thoroughly after handling P270: Do not eat, drink or smoke when using this product P271: Use only outdoors or in a well-ventilated area P273: Avoid release to the environment P280: Wear protective clothing/eye protection/hearing protection P370+P380: In case of fire: Evacuate area P374: Fight fire with normal precautions from a reasonable distance P410: Store in accordance with local regulations P501: Dispose of contents in accordance with local regulations

GHS Pictograms: Explosive; Pictogram: exploding bomb Specific Target Organ Toxicity; Pictogram Code: GHS08 Environment; Pictogram Code: GHS09

EU Classifications:

Hazard Symbols E, T, N Risk Phrases R2: Risk of explosion by shock, friction, fire or other sources of ignition

R45 (Category 1): May cause cancer R48: Danger of serious damage to health by prolonged exposure

R60/61 (Category 1): May impair fertility or cause harm to the unborn child R63: Possible risk of harm to the unborn child R64: May cause harm to breast-fed children R51/53: Toxic to aquatic organisms and many cause long-term adverse effects in the aquatic environment

Safety Phrases S2: Keep out of reach of children S15: Keep away from heat S20/21: When using do not eat, drink or smoke S23: Do not breathe fumes S39: Wear eye/face protection S43: In case of fire, use Class A equipment S51: Use only in well-ventilated areas S61: Avoid release to the environment

Health Hazards or Risks From Exposure

This product is composed of a plastic tube and finished metal alloy cartridge which contains the various components completely sealed within. Therefore, under normal handling of this product, no exposure to any harmful materials will occur. When the ammunition is fired, a small amount of particles may be generated which may be slightly irritating to the eyes and the respiratory tract. The particles may contain trace amounts of these harmful substances:

Lead: Ingestion of large amounts of lead can cause abdominal pain, constipation, cramps, nausea and/or vomiting. Chronic exposure to lead can cause kidney damage, anemia, reproductive effects, developmental effects and permanent nervous system damage in humans including changes in cognitive function. Occupational exposure to lead is associated with lung and stomach cancer. Lead is classified as a probable human carcinogen.

Copper: Inhalation of high concentrations of metallic copper dusts or fumes may cause nasal irritation and/or nausea, vomiting and stomach pain.

Nitroglycerin: Will produce dilation of blood vessels and drop in blood pressure which may affect the heart. It has also been shown to cause methemoglobinemia (cyanosis).

Dibutyl phthalate: May cause harm to the unborn child based on animal experiments. Possible risk of impaired fertility.

Nickel: Repeated exposure may cause an allergic skin reaction consisting of itching, redness, swelling, and rash or urticaria (hives) in sensitized individuals. Epidemiological studies in humans have shown an association between lung and nasal cancers and prolonged occupational exposures to high concentrations of nickel.

Arsenic: Epidemiological studies in humans have shown an association between increased incidences of lung and skin cancer and prolonged exposures to high concentrations of arsenic. Arsenic is classified as a known human carcinogen.

It is unlikely that the amount of particles that someone would be exposed to from firing a loaded round would be sufficient to cause any of these effects.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Components % By Weight CAS Number EINECS/ ELINCS #

Lead 0 - 61 7439-92-1 231-100-4 Bismuth 0 – 75 7440-69-9 231-177-4 Tin 0 - 5 7440-31-5 231-141-8 Antimony 0 - 5 7440-36-0 231-146-5 Arsenic 0 – 1.5 7440-38-2 231-148-6 Copper 0 -15 7440-50-8 231-159-6 Nickel 0 – 8 7440-02-0 231-111-4 Zinc 1 – 15 7440-66-6 231-175-3 Polyethylene 10 – 17 9002-88-4 Polymer Nitrocellulose 5 - 10 9004-70-0 Polymer Nitroglycerin 0.5 – 2 55-63-0 200-240-8 Dibutyl phthalate 0.5 – 2 84-74-2 201-55-74 Iron 1 -20 7439-89-6 231-096-4

4. FIRST AID MEASURES

Eye Contact: Immediately flush out fume or particles with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If eye irritation develops, call a physician at once.

Skin Contact: Wash skin with plenty of soap and water.

Inhalation: If symptoms of lung irritation occur (coughing, wheezing or breathing difficulty), remove from exposure area to fresh air immediately. If breathing has stopped, perform artificial respiration. Keep affected person warm and at rest. Get medical attention.

Ingestion: If ingested, immediately call a physician.

Medical Conditions Aggravated By Exposure:

There are no medical conditions known to be aggravated by exposure to this product in its solid form. Exposure to lead can aggravate anemia, cardiovascular and respiratory disease.

Recommendations To Physcians:

Remove from exposure, if possible, and treat symptoms

5. FIRE FIGHTING MEASURES

PROPERTY VALUE PROPERTY VALUE

Explosive Yes Flammable Not applicable

Combustible Not applicable Pyrophoric No Flash Point (C): Not applicable Burning Rate of Material: Not applicable

Lower Explosive Limit: Not applicable Autoignition Temp.: No data

Upper Explosive Limit: Not applicable Flammability Classification: (defined by 29 CFR 1910.1200) Explosive

Unusal Fire and Explosion Hazards: Possible projection hazard.

Extinguishing Media: Flood area with water. If no water is available, carbon dioxide, dry chemical or earth may be used.

0 2

Special Firefighting Procedures: Do not fight fire when fire reaches cargo. Cargo may explode.

Firefighters must wear self-contained breathing apparatus (SCBA) and full protective equipment. Structural firefighters’ protective clothing will only provide limited protection.

Isolate materials not yet involved in the fire. Move containers from fire area if possible; otherwise, cool with carefully applied water spray.

Prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas, if practical.

NFPA RATING SYSTEM

HMIS RATING SYSTEM

HEALTH HAZARD (BLUE) 0*

FLAMMABILITY HAZARD (RED) 1

PHYSICAL HAZARD (YELLOW) 2

PROTECTIVE EQUIPMENT

EYES PPE

CODE

RESPIRATORY HEARING

A

See Sect 8 See

Sect 8

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard

6. ACCIDENTAL RELEASE MEASURES

FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC AT 800-424-9300.

Flammability

Health Reactivity

Other

Spill Response: A spill of this material will normally not require emergency response team capabilities. If, however, a large spill occurs, call 1-888-289-1911 for technical assistance.

Accidental Release Procedures: Spills of this material should be handled carefully. Do not subject materials to mechanical shock. Collect material and place in a designated, labeled waste container. See Section 13 for waste disposal.

7. HANDLING AND STORAGE

Precautions for Safe Handling: Use appropriate personal protective equipment (see Section 8). Workers should wash hands thoroughly after handling. Eating, drinking and smoking should be prohibited in areas where this material is handled and stored.

Conditions for Safe Storage: Store in…