Exhibit_B-1-Analysis_Large_Facilities.pdf

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Attached to
Biosolids Hauling Service State and local contract opportunity
Solicitation number
25-8403
Issued by
Collier County, Florida

About this file

Written by GovTribe AI ·

These documents are laboratory analytical reports from Pace Analytical Services, LLC for water reclamation sludge samples collected by Collier County Water Reclamation in Naples, Florida on May 23, 2024. The reports detail Toxicity Characteristic Leaching Procedure (TCLP) and other analytical tests performed on sludge cake samples from multiple water reclamation facilities (SCWRF and NCWRF), analyzing various chemical components including metals (arsenic, barium, cadmium, chromium, lead, selenium, silver), mercury, and sulfate. The samples underwent multiple testing methods including EPA 6010 (metal analysis), EPA 7470 (mercury), EPA 8270 (semi-volatile organic compounds), EPA 8260 (volatile organic compounds), and moisture content determination.

The laboratory reports include comprehensive quality control data, demonstrating the analytical processes met TNI/NELAC Standards and the laboratory's Quality Manual. Each report contains detailed information such as sample collection and receipt dates, analytical methods, detection limits, preparation and analysis dates, and quality control metrics like matrix spike recoveries and laboratory control sample results. The reports show most analyte concentrations were below detection limits, with some trace amounts of metals and organic compounds detected. The sludge cake samples had high moisture content ranging from approximately 6% to 85%. These analytical reports appear to be part of Collier County's routine environmental monitoring and compliance testing for water reclamation facility waste materials.

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#=CL#

June 06, 2024

LIMS USE: FR - SCOTT COOPER

LIMS OBJECT ID: 35881853

35881853 Project:

Pace Project No.:

RE:

Scott Cooper Collier County Water Reclamation 5600 Warren Street Naples, FL 34113

SCWRF Sludge

Dear Scott Cooper:

Enclosed are the analytical results for sample(s) received by the laboratory on May 24, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.

The test results provided in this final report were generated by each of the following laboratories within the Pace Network:

• Pace Analytical Services - Ormond Beach

If you have any questions concerning this report, please feel free to contact me.

Sincerely, Martha Montero martha.montero@pacelabs.com

Project Manager (386)672-5668

Enclosures cc: Jon Flomerfelt, Collier County Water Reclamati Tyler Horst, Collier County Water Reclamati Samuel Jinkins, Collier County Water Reclamation Lab Katia Leite, Collier County Water Reclamation Diane Di Pascale, Collier County Water Reclamation Lab

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174 (386)672-5668

#=CP#

CERTIFICATIONS

Pace Project No.:

Project:

35881853 SCWRF Sludge

Pace Analytical Services Ormond Beach 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 California Certification# 3096 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity DoD-ANAB #:ADE-3199 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maine Certification #: FL01264 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911

Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Ohio DEP 87780 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=SS#

SAMPLE SUMMARY

Pace Project No.:

Project:

35881853 SCWRF Sludge

Lab ID Sample ID Matrix Date Collected Date Received

35881853001 SCWRF PRT-R AG95230 Solid 05/23/24 08:16 05/24/24 10:40

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=SA#

SAMPLE ANALYTE COUNT

Pace Project No.:

Project:

35881853 SCWRF Sludge

Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts

35881853001 SCWRF PRT-R AG95230 EPA 6010 10 PASI-OASB

EPA 7471 1 PASI-OJNK

ASTM D2974-87 1 PASI-ORLVR

PASI-O = Pace Analytical Services - Ormond Beach

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=AR#

ANALYTICAL RESULTS

Pace Project No.:

Project:

35881853 SCWRF Sludge

Sample: SCWRF PRT-R AG95230 Lab ID: 35881853001 Collected: 05/23/24 08:16 Received: 05/24/24 10:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 6010 Preparation Method: EPA 3050 Pace Analytical Services - Ormond Beach

6010 MET ICP

Arsenic 1.8 U mg/kg 06/06/24 00:55 7440-38-206/05/24 10:243.5 1.8 1 Cadmium 0.52 mg/kg 06/06/24 00:55 7440-43-906/05/24 10:240.35 0.18 1 Chromium 16.2 mg/kg 06/06/24 00:55 7440-47-306/05/24 10:241.8 0.88 1 Copper 160 mg/kg 06/06/24 00:55 7440-50-806/05/24 10:241.8 0.88 1 Lead 5.4 mg/kg 06/06/24 00:55 7439-92-106/05/24 10:243.5 1.8 1 Molybdenum 6.2 mg/kg 06/06/24 00:55 7439-98-706/05/24 10:243.5 1.8 1 Nickel 10.5 mg/kg 06/06/24 00:55 7440-02-006/05/24 10:241.8 0.88 1 Potassium 0.82 % (w/w) 06/06/24 00:55 7440-09-7 J(M1)06/05/24 10:240.035 0.018 1 Selenium 4.6 I mg/kg 06/06/24 00:55 7782-49-206/05/24 10:245.3 2.6 1 Zinc 609 mg/kg 06/06/24 00:55 7440-66-606/05/24 10:2435.2 12.7 1

Analytical Method: EPA 7471 Preparation Method: EPA 7471 Pace Analytical Services - Ormond Beach

7471 Mercury

Mercury 0.22 mg/kg 06/05/24 13:01 7439-97-6 J(M1)06/05/24 11:000.053 0.026 1

Analytical Method: ASTM D2974-87 Pace Analytical Services - Ormond Beach

Percent Moisture

Percent Moisture 83.2 % 06/05/24 12:240.10 0.10 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=QC#

QUALITY CONTROL DATA

Pace Project No.:

Project:

35881853 SCWRF Sludge

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1016554

EPA 7471

EPA 7471

7471 Mercury

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881853001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5586879

Associated Lab Samples: 35881853001

Matrix: Solid

AnalyzedMDL

Mercury mg/kg 0.0047 U 0.0093 06/05/24 12:520.0047

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5586880LABORATORY CONTROL SAMPLE:

LCSSpike

Mercury mg/kg 0.0880.094 93 80-120

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5586881MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35881853001

5586882

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Mercury mg/kg J(M1)0.47 20 80-12016 6 200.480.22 0.31 0.29

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881853 SCWRF Sludge

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1016585

EPA 3050

EPA 6010

6010 MET Solid

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881853001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5586998

Associated Lab Samples: 35881853001

Matrix: Solid

AnalyzedMDL

Arsenic mg/kg 0.22 U 0.45 06/06/24 00:470.22 Cadmium mg/kg 0.022 U 0.045 06/06/24 00:470.022 Chromium mg/kg 0.11 U 0.22 06/06/24 00:470.11 Copper mg/kg 0.11 U 0.22 06/06/24 00:470.11 Lead mg/kg 0.22 U 0.45 06/06/24 00:470.22 Molybdenum mg/kg 0.22 U 0.45 06/06/24 00:470.22 Nickel mg/kg 0.11 U 0.22 06/06/24 00:470.11 Potassium % (w/w) 0.0022 U 0.0045 06/06/24 00:470.0022 Selenium mg/kg 0.34 U 0.67 06/06/24 00:470.34 Zinc mg/kg 1.6 U 4.5 06/06/24 00:471.6

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5586999LABORATORY CONTROL SAMPLE:

LCSSpike

Arsenic mg/kg 22.725.5 89 80-120 Cadmium mg/kg 2.52.5 99 80-120 Chromium mg/kg 13.412.7 105 80-120 Copper mg/kg 13.112.7 103 80-120 Lead mg/kg 25.925.5 102 80-120 Molybdenum mg/kg 25.225.5 99 80-120 Nickel mg/kg 13.212.7 103 80-120 Potassium % (w/w) 0.0620.064 98 80-120 Selenium mg/kg 33.638.2 88 80-120 Zinc mg/kg 49.851 98 80-120

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5587000MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35881853001

5587001

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Arsenic mg/kg 159 90 75-12588 10 201471.8 U 144 130 Cadmium mg/kg 16.1 98 75-12596 10 2014.90.52 16.2 14.6 Chromium mg/kg 79.8 106 75-125105 8 2073.216.2 100 92.9 Copper mg/kg 79.8 103 75-125107 1 2073.2160 242 239 Lead mg/kg 159 100 75-12597 10 201475.4 164 148 Molybdenum mg/kg 159 98 75-12596 10 201476.2 163 147 Nickel mg/kg 79.8 105 75-125102 9 2073.210.5 94.0 85.4 Potassium % (w/w) J(M1)0.4 115 75-125102 7 200.370.82 1.3 1.2

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881853 SCWRF Sludge

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5587000MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35881853001

5587001

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Selenium mg/kg 239 89 75-12587 10 202204.6 I 217 197 Zinc mg/kg 318 101 75-12591 6 20293609 930 876

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881853 SCWRF Sludge

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1016675

ASTM D2974-87

ASTM D2974-87

Dry Weight/Percent Moisture

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881853001

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35881853001

5587344SAMPLE DUPLICATE:

Percent Moisture % 84.3 1 1083.2

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35882092008

5587345SAMPLE DUPLICATE:

Percent Moisture % 23.8 1 1024.0

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35882916001

5587346SAMPLE DUPLICATE:

Percent Moisture % 7.2 6 106.8

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35883010003

5587347SAMPLE DUPLICATE:

Percent Moisture % 19.2 2 1019.6

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=QL#

QUALIFIERS

Pace Project No.:

Project:

35881853 SCWRF Sludge

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.

ND - Not Detected at or above adjusted reporting limit.

TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit.

PQL - Practical Quantitation Limit.

RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix.

S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable.

SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration.

Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

TNI - The NELAC Institute.

ANALYTE QUALIFIERS

The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. I Compound was analyzed for but not detected. U Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.

J(M1)

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.:

Project:

35881853 SCWRF Sludge

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch

35881853001 1016585 1016724SCWRF PRT-R AG95230 EPA 3050 EPA 6010

35881853001 1016554 1016656SCWRF PRT-R AG95230 EPA 7471 EPA 7471

35881853001 1016675SCWRF PRT-R AG95230 ASTM D2974-87

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

June 06, 2024

LIMS USE: FR - SCOTT COOPER

LIMS OBJECT ID: 35881860

35881860 Project:

Pace Project No.:

RE:

Scott Cooper Collier County Water Reclamation 5600 Warren Street Naples, FL 34113

NCWRF Sludge

Dear Scott Cooper:

Enclosed are the analytical results for sample(s) received by the laboratory on May 24, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.

The test results provided in this final report were generated by each of the following laboratories within the Pace Network:

• Pace Analytical Services - Ormond Beach

If you have any questions concerning this report, please feel free to contact me.

Sincerely, Martha Montero martha.montero@pacelabs.com

Project Manager (386)672-5668

Enclosures cc: Jon Flomerfelt, Collier County Water Reclamati Tyler Horst, Collier County Water Reclamati Samuel Jinkins, Collier County Water Reclamation Lab Katia Leite, Collier County Water Reclamation Diane Di Pascale, Collier County Water Reclamation Lab

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

Pace Analytical Services Ormond Beach 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 California Certification# 3096 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity DoD-ANAB #:ADE-3199 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maine Certification #: FL01264 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911

Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Ohio DEP 87780 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

Lab ID Sample ID Matrix Date Collected Date Received

35881860001 NCWRF PRT-R AG95293 Solid 05/23/24 11:58 05/24/24 10:40

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts

35881860001 NCWRF PRT-R AG95293 EPA 6010 10 PASI-OASB

EPA 7471 1 PASI-OJNK

ASTM D2974-87 1 PASI-ORLVR

PASI-O = Pace Analytical Services - Ormond Beach

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

Sample: NCWRF PRT-R AG95293 Lab ID: 35881860001 Collected: 05/23/24 11:58 Received: 05/24/24 10:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 6010 Preparation Method: EPA 3050 Pace Analytical Services - Ormond Beach

6010 MET ICP

Arsenic 2.0 U mg/kg 06/06/24 01:09 7440-38-206/05/24 10:244.0 2.0 1 Cadmium 0.53 mg/kg 06/06/24 01:09 7440-43-906/05/24 10:240.40 0.20 1 Chromium 13.6 mg/kg 06/06/24 01:09 7440-47-306/05/24 10:242.0 0.99 1 Copper 187 mg/kg 06/06/24 01:09 7440-50-806/05/24 10:242.0 0.99 1 Lead 7.1 mg/kg 06/06/24 01:09 7439-92-106/05/24 10:244.0 2.0 1 Molybdenum 5.9 mg/kg 06/06/24 01:09 7439-98-706/05/24 10:244.0 2.0 1 Nickel 9.2 mg/kg 06/06/24 01:09 7440-02-006/05/24 10:242.0 0.99 1 Potassium 0.89 % (w/w) 06/06/24 01:09 7440-09-706/05/24 10:240.040 0.020 1 Selenium 4.9 I mg/kg 06/06/24 01:09 7782-49-206/05/24 10:246.0 3.0 1 Zinc 720 mg/kg 06/06/24 01:09 7440-66-606/05/24 10:2439.7 14.3 1

Analytical Method: EPA 7471 Preparation Method: EPA 7471 Pace Analytical Services - Ormond Beach

7471 Mercury

Mercury 0.12 mg/kg 06/05/24 13:13 7439-97-606/05/24 11:000.055 0.028 1

Analytical Method: ASTM D2974-87 Pace Analytical Services - Ormond Beach

Percent Moisture

Percent Moisture 85.5 % 06/05/24 12:240.10 0.10 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1016554

EPA 7471

EPA 7471

7471 Mercury

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881860001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5586879

Associated Lab Samples: 35881860001

Matrix: Solid

AnalyzedMDL

Mercury mg/kg 0.0047 U 0.0093 06/05/24 12:520.0047

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5586880LABORATORY CONTROL SAMPLE:

LCSSpike

Mercury mg/kg 0.0880.094 93 80-120

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5586881MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35881853001

5586882

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Mercury mg/kg J(M1)0.47 20 80-12016 6 200.480.22 0.31 0.29

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1016585

EPA 3050

EPA 6010

6010 MET Solid

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881860001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5586998

Associated Lab Samples: 35881860001

Matrix: Solid

AnalyzedMDL

Arsenic mg/kg 0.22 U 0.45 06/06/24 00:470.22 Cadmium mg/kg 0.022 U 0.045 06/06/24 00:470.022 Chromium mg/kg 0.11 U 0.22 06/06/24 00:470.11 Copper mg/kg 0.11 U 0.22 06/06/24 00:470.11 Lead mg/kg 0.22 U 0.45 06/06/24 00:470.22 Molybdenum mg/kg 0.22 U 0.45 06/06/24 00:470.22 Nickel mg/kg 0.11 U 0.22 06/06/24 00:470.11 Potassium % (w/w) 0.0022 U 0.0045 06/06/24 00:470.0022 Selenium mg/kg 0.34 U 0.67 06/06/24 00:470.34 Zinc mg/kg 1.6 U 4.5 06/06/24 00:471.6

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5586999LABORATORY CONTROL SAMPLE:

LCSSpike

Arsenic mg/kg 22.725.5 89 80-120 Cadmium mg/kg 2.52.5 99 80-120 Chromium mg/kg 13.412.7 105 80-120 Copper mg/kg 13.112.7 103 80-120 Lead mg/kg 25.925.5 102 80-120 Molybdenum mg/kg 25.225.5 99 80-120 Nickel mg/kg 13.212.7 103 80-120 Potassium % (w/w) 0.0620.064 98 80-120 Selenium mg/kg 33.638.2 88 80-120 Zinc mg/kg 49.851 98 80-120

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5587000MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35881853001

5587001

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Arsenic mg/kg 159 90 75-12588 10 201471.8 U 144 130 Cadmium mg/kg 16.1 98 75-12596 10 2014.90.52 16.2 14.6 Chromium mg/kg 79.8 106 75-125105 8 2073.216.2 100 92.9 Copper mg/kg 79.8 103 75-125107 1 2073.2160 242 239 Lead mg/kg 159 100 75-12597 10 201475.4 164 148 Molybdenum mg/kg 159 98 75-12596 10 201476.2 163 147 Nickel mg/kg 79.8 105 75-125102 9 2073.210.5 94.0 85.4 Potassium % (w/w) J(M1)0.4 115 75-125102 7 200.370.82 1.3 1.2

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5587000MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35881853001

5587001

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Selenium mg/kg 239 89 75-12587 10 202204.6 I 217 197 Zinc mg/kg 318 101 75-12591 6 20293609 930 876

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1016675

ASTM D2974-87

ASTM D2974-87

Dry Weight/Percent Moisture

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881860001

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35881853001

5587344SAMPLE DUPLICATE:

Percent Moisture % 84.3 1 1083.2

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35882092008

5587345SAMPLE DUPLICATE:

Percent Moisture % 23.8 1 1024.0

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35882916001

5587346SAMPLE DUPLICATE:

Percent Moisture % 7.2 6 106.8

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35883010003

5587347SAMPLE DUPLICATE:

Percent Moisture % 19.2 2 1019.6

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.

ND - Not Detected at or above adjusted reporting limit.

TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit.

PQL - Practical Quantitation Limit.

RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix.

S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable.

SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration.

Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

TNI - The NELAC Institute.

ANALYTE QUALIFIERS

The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. I Compound was analyzed for but not detected. U Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.

J(M1)

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881860 NCWRF Sludge

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch

35881860001 1016585 1016724NCWRF PRT-R AG95293 EPA 3050 EPA 6010

35881860001 1016554 1016656NCWRF PRT-R AG95293 EPA 7471 EPA 7471

35881860001 1016675NCWRF PRT-R AG95293 ASTM D2974-87

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/06/2024 12:53 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

June 11, 2024

LIMS USE: FR - SCOTT COOPER

LIMS OBJECT ID: 35881855

35881855 Project:

Pace Project No.:

RE:

Scott Cooper Collier County Water Reclamation 5600 Warren Street Naples, FL 34113

Annual TCLP NCWRF

Dear Scott Cooper:

Enclosed are the analytical results for sample(s) received by the laboratory on May 24, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.

The test results provided in this final report were generated by each of the following laboratories within the Pace Network:

• Pace Analytical Services - Ormond Beach

If you have any questions concerning this report, please feel free to contact me.

Sincerely, Martha Montero martha.montero@pacelabs.com

Project Manager (386)672-5668

Enclosures cc: Jon Flomerfelt, Collier County Water Reclamati Tyler Horst, Collier County Water Reclamati Samuel Jinkins, Collier County Water Reclamation Lab Katia Leite, Collier County Water Reclamation Diane Di Pascale, Collier County Water Reclamation Lab

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Pace Analytical Services Ormond Beach 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 California Certification# 3096 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity DoD-ANAB #:ADE-3199 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maine Certification #: FL01264 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911

Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Ohio DEP 87780 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Lab ID Sample ID Matrix Date Collected Date Received

35881855001 N. Sludge Cake AG952994 Solid 05/23/24 11:58 05/24/24 10:40

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts

35881855001 N. Sludge Cake AG952994 EPA 6010 7 PASI-OTMA

EPA 7470 1 PASI-OJNK

EPA 8270 18 PASI-OBLB

EPA 8260 TCLP 14 PASI-OAS4

ASTM D2974-87 1 PASI-ORLVR

EPA 9056 1 PASI-OLL

PASI-O = Pace Analytical Services - Ormond Beach

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Sample: N. Sludge Cake AG952994 Lab ID: 35881855001 Collected: 05/23/24 11:58 Received: 05/24/24 10:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311; 06/05/24 14:39 Pace Analytical Services - Ormond Beach

6010 MET ICP, TCLP

Arsenic 0.034 U mg/L 06/07/24 02:01 7440-38-206/06/24 14:150.10 0.034 1 Barium 0.029 I mg/L 06/07/24 02:01 7440-39-306/06/24 14:150.10 0.0084 1 Cadmium 0.0033 U mg/L 06/07/24 02:01 7440-43-906/06/24 14:150.010 0.0033 1 Chromium 0.017 U mg/L 06/07/24 02:01 7440-47-306/06/24 14:150.050 0.017 1 Lead 0.021 U mg/L 06/07/24 02:01 7439-92-106/06/24 14:150.10 0.021 1 Selenium 0.039 U mg/L 06/07/24 02:01 7782-49-206/06/24 14:150.15 0.039 1 Silver 0.010 U mg/L 06/07/24 02:01 7440-22-406/06/24 14:150.050 0.010 1

Analytical Method: EPA 7470 Preparation Method: EPA 7470 Leachate Method/Date: EPA 1311; 06/05/24 14:39 Pace Analytical Services - Ormond Beach

7470 Mercury, TCLP

Mercury 0.0014 U mg/L 06/06/24 14:55 7439-97-606/06/24 11:120.0020 0.0014 1

Analytical Method: EPA 8270 Preparation Method: EPA 3510 Leachate Method/Date: EPA 1311; 06/05/24 14:39 Pace Analytical Services - Ormond Beach

8270 MSSV TCLP Sep Funnel

1,4-Dichlorobenzene 0.015 U mg/L 06/09/24 04:49 106-46-706/07/24 09:150.050 0.015 1 2,4-Dinitrotoluene 0.012 U mg/L 06/09/24 04:49 121-14-206/07/24 09:150.13 0.012 1 Hexachloro-1,3-butadiene 0.0035 U mg/L 06/09/24 04:49 87-68-306/07/24 09:150.050 0.0035 1 Hexachlorobenzene 0.0029 U mg/L 06/09/24 04:49 118-74-106/07/24 09:150.050 0.0029 1 Hexachloroethane 0.014 U mg/L 06/09/24 04:49 67-72-106/07/24 09:150.050 0.014 1 2-Methylphenol(o-Cresol) 0.0030 U mg/L 06/09/24 04:49 95-48-706/07/24 09:150.050 0.0030 1 3&4-Methylphenol(m&p Cresol) 0.0022 U mg/L 06/09/24 04:4906/07/24 09:150.10 0.0022 1 Nitrobenzene 0.0037 U mg/L 06/09/24 04:49 98-95-306/07/24 09:150.050 0.0037 1 Pentachlorophenol 0.034 U mg/L 06/09/24 04:49 87-86-506/07/24 09:150.20 0.034 1 Pyridine 0.011 U mg/L 06/09/24 04:49 110-86-106/07/24 09:150.20 0.011 1 2,4,5-Trichlorophenol 0.0023 U mg/L 06/09/24 04:49 95-95-406/07/24 09:150.050 0.0023 1 2,4,6-Trichlorophenol 0.0036 U mg/L 06/09/24 04:49 88-06-206/07/24 09:150.050 0.0036 1 Surrogates Phenol-d6 (S) 42 % 06/09/24 04:49 13127-88-306/07/24 09:1510-48 1 2-Fluorobiphenyl (S) 59 % 06/09/24 04:49 321-60-806/07/24 09:1512-110 1 Nitrobenzene-d5 (S) 53 % 06/09/24 04:49 4165-60-006/07/24 09:1510-104 1 p-Terphenyl-d14 (S) 88 % 06/09/24 04:49 1718-51-006/07/24 09:1538-139 1 2-Fluorophenol (S) 48 % 06/09/24 04:49 367-12-406/07/24 09:1510-57 1 2,4,6-Tribromophenol (S) 76 % 06/09/24 04:49 118-79-606/07/24 09:1525-121 1

Analytical Method: EPA 8260 TCLP Leachate Method/Date: EPA 1311; 05/28/24 15:00 Pace Analytical Services - Ormond Beach

8260 MSV TCLP

Benzene 0.00030 U mg/L 05/29/24 13:46 71-43-20.0010 0.00030 1 2-Butanone (MEK) 0.33 I mg/L 06/03/24 06:45 78-93-30.50 0.067 10 Carbon tetrachloride 0.00044 U mg/L 05/29/24 13:46 56-23-50.0030 0.00044 1 Chlorobenzene 0.00035 U mg/L 05/29/24 13:46 108-90-70.0010 0.00035 1 Chloroform 0.00056 U mg/L 05/29/24 13:46 67-66-30.0010 0.00056 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/11/2024 11:42 AM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Sample: N. Sludge Cake AG952994 Lab ID: 35881855001 Collected: 05/23/24 11:58 Received: 05/24/24 10:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 8260 TCLP Leachate Method/Date: EPA 1311; 05/28/24 15:00 Pace Analytical Services - Ormond Beach

8260 MSV TCLP

1,4-Dichlorobenzene 0.00028 U mg/L 05/29/24 13:46 106-46-70.0010 0.00028 1 1,2-Dichloroethane 0.00027 U mg/L 05/29/24 13:46 107-06-20.0010 0.00027 1 1,1-Dichloroethene 0.00059 U mg/L 05/29/24 13:46 75-35-40.0010 0.00059 1 Tetrachloroethene 0.00038 U mg/L 05/29/24 13:46 127-18-40.0010 0.00038 1 Trichloroethene 0.00036 U mg/L 05/29/24 13:46 79-01-60.0010 0.00036 1 Vinyl chloride 0.00039 U mg/L 05/29/24 13:46 75-01-4 J(v2)0.0010 0.00039 1 Surrogates Toluene-d8 (S) 96 % 05/29/24 13:46 2037-26-570-130 1 4-Bromofluorobenzene (S) 103 % 05/29/24 13:46 460-00-470-130 1 1,2-Dichlorobenzene-d4 (S) 100 % 05/29/24 13:46 2199-69-170-130 1

Analytical Method: ASTM D2974-87 Pace Analytical Services - Ormond Beach

Percent Moisture

Percent Moisture 84.9 % 06/10/24 12:470.10 0.10 1

Analytical Method: EPA 9056 Preparation Method: EPA 9056 Pace Analytical Services - Ormond Beach

9056 IC Anions

Sulfate 261 I mg/kg 06/04/24 21:58 14808-79-806/04/24 10:58329 114 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/11/2024 11:42 AM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1017049

EPA 7470

EPA 7470

7470 Mercury TCLP

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881855001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5587074

Associated Lab Samples: 35881855001

Matrix: Water

AnalyzedMDL

Mercury mg/L 0.00014 U 0.00020 06/06/24 14:280.00014

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5589509LABORATORY CONTROL SAMPLE:

LCSSpike

Mercury mg/L 0.00190.002 96 80-120

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5589510MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35882935001

5589511

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Mercury mg/L 0.02 98 75-12597 1 200.020.0014 U 0.021 0.020

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/11/2024 11:42 AM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1017080

EPA 3010

EPA 6010

6010 MET TCLP

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881855001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5587074

Associated Lab Samples: 35881855001

Matrix: Water

AnalyzedMDL

Arsenic mg/L 0.0034 U 0.010 06/07/24 01:550.0034 Barium mg/L 0.0058 I 0.010 06/07/24 01:550.00084 Cadmium mg/L 0.00033 U 0.0010 06/07/24 01:550.00033 Chromium mg/L 0.0017 U 0.0050 06/07/24 01:550.0017 Lead mg/L 0.0021 U 0.010 06/07/24 01:550.0021 Selenium mg/L 0.0039 U 0.015 06/07/24 01:550.0039 Silver mg/L 0.0010 U 0.0050 06/07/24 01:550.0010

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5589696LABORATORY CONTROL SAMPLE:

LCSSpike

Arsenic mg/L 0.250.25 102 80-120 Barium mg/L 0.250.25 99 80-120 Cadmium mg/L 0.0250.025 99 80-120 Chromium mg/L 0.250.25 98 80-120 Lead mg/L 0.240.25 96 80-120 Selenium mg/L 0.260.25 105 80-120 Silver mg/L 0.0260.025 103 80-120

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5589697MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35881855001

5589698

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Arsenic mg/L 2.5 96 75-12595 2 202.50.034 U 2.4 2.4 Barium mg/L 2.5 104 75-125104 0 202.50.029 I 2.6 2.6 Cadmium mg/L 0.25 101 75-12599 2 200.250.0033 U 0.25 0.25 Chromium mg/L 2.5 101 75-12599 2 202.50.017 U 2.5 2.5 Lead mg/L 2.5 102 75-125100 2 202.50.021 U 2.6 2.5 Selenium mg/L 2.5 97 75-12596 2 202.50.039 U 2.4 2.4 Silver mg/L 0.25 101 75-125100 1 200.250.010 U 0.25 0.25

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/11/2024 11:42 AM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1015131

EPA 8260 TCLP

EPA 8260 TCLP

8260 MSV TCLP

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881855001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5577566

Associated Lab Samples: 35881855001

Matrix: Solid

AnalyzedMDL

1,1-Dichloroethene mg/L 0.00059 U 0.0010 05/29/24 13:010.00059 1,2-Dichloroethane mg/L 0.00027 U 0.0010 05/29/24 13:010.00027 1,4-Dichlorobenzene mg/L 0.00028 U 0.0010 05/29/24 13:010.00028 2-Butanone (MEK) mg/L 0.0067 U 0.050 05/29/24 13:010.0067 Benzene mg/L 0.00030 U 0.0010 05/29/24 13:010.00030 Carbon tetrachloride mg/L 0.00044 U 0.0030 05/29/24 13:010.00044 Chlorobenzene mg/L 0.00035 U 0.0010 05/29/24 13:010.00035 Chloroform mg/L 0.00056 U 0.0010 05/29/24 13:010.00056 Tetrachloroethene mg/L 0.00038 U 0.0010 05/29/24 13:010.00038 Trichloroethene mg/L 0.00036 U 0.0010 05/29/24 13:010.00036 Vinyl chloride mg/L 0.00039 U 0.0010 J(v2)05/29/24 13:010.00039 1,2-Dichlorobenzene-d4 (S) % 98 70-130 05/29/24 13:01 4-Bromofluorobenzene (S) % 103 70-130 05/29/24 13:01 Toluene-d8 (S) % 97 70-130 05/29/24 13:01

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5578555LABORATORY CONTROL SAMPLE:

LCSSpike

1,1-Dichloroethene mg/L 0.0180.02 89 66-133 1,2-Dichloroethane mg/L 0.0190.02 93 70-130 1,4-Dichlorobenzene mg/L 0.0200.02 100 70-130 2-Butanone (MEK) mg/L 0.110.1 106 47-143 Benzene mg/L 0.0200.02 100 70-130 Carbon tetrachloride mg/L 0.0190.02 95 63-126 Chlorobenzene mg/L 0.0210.02 105 70-130 Chloroform mg/L 0.0200.02 101 70-130 Tetrachloroethene mg/L 0.0210.02 106 64-134 Trichloroethene mg/L 0.0200.02 102 70-130 Vinyl chloride mg/L 0.015 J(v3)0.02 75 68-131 1,2-Dichlorobenzene-d4 (S) % 98 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 98 70-130

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/11/2024 11:42 AM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5578556MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35881858001

5578557

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

1,1-Dichloroethene mg/L J(M1), J(R1)

0.02 17 66-13392 139 400.020.00059 U

0.0033 0.018

1,2-Dichloroethane mg/L J(M1), J(R1)

0.02 15 70-13090 142 400.020.00027 U

0.0031 0.018

1,4-Dichlorobenzene mg/L J(M1), J(R1)

0.02 16 70-13096 143 400.020.00028 U

0.0032 0.019

2-Butanone (MEK) mg/L 0.1 113 47-143106 3 400.10.11 0.22 0.22 Benzene mg/L J(M1), J(R1)

0.02 17 70-130101 141 400.020.00030

U

0.0035 0.020

Carbon tetrachloride mg/L J(M1), J(R1)

0.02 16 63-12698 145 400.020.00044 U

0.0031 0.020

Chlorobenzene mg/L J(M1), J(R1)

0.02 17 70-130101 144 400.020.00035 U

0.0033 0.020

Chloroform mg/L J(M1), J(R1)

0.02 18 70-13098 138 400.020.00056 U

0.0036 0.020

Tetrachloroethene mg/L J(M1), J(R1)

0.02 16 64-134102 144 400.020.00038 U

0.0033 0.020

Trichloroethene mg/L J(M1), J(R1)

0.02 18 70-130102 140 400.020.00036 U

0.0036 0.020

Vinyl chloride mg/L J(v3)0.02 73 68-13174 1 400.020.00039 U

0.015 0.015

1,2-Dichlorobenzene-d4 (S) % 98 70-13099 4-Bromofluorobenzene (S) % 101 70-130101 Toluene-d8 (S) % 99 70-13098

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/11/2024 11:42 AM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1017310

EPA 3510

EPA 8270

8270 TCLP MSSV

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881855001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5587075

Associated Lab Samples: 35881855001

Matrix: Water

AnalyzedMDL

1,4-Dichlorobenzene mg/L 0.015 U 0.050 06/09/24 03:060.015 2,4,5-Trichlorophenol mg/L 0.0023 U 0.050 06/09/24 03:060.0023 2,4,6-Trichlorophenol mg/L 0.0036 U 0.050 06/09/24 03:060.0036 2,4-Dinitrotoluene mg/L 0.012 U 0.13 06/09/24 03:060.012 2-Methylphenol(o-Cresol) mg/L 0.0030 U 0.050 06/09/24 03:060.0030 3&4-Methylphenol(m&p Cresol) mg/L 0.0022 U 0.10 06/09/24 03:060.0022 Hexachloro-1,3-butadiene mg/L 0.0035 U 0.050 06/09/24 03:060.0035 Hexachlorobenzene mg/L 0.0029 U 0.050 06/09/24 03:060.0029 Hexachloroethane mg/L 0.014 U 0.050 06/09/24 03:060.014 Nitrobenzene mg/L 0.0037 U 0.050 06/09/24 03:060.0037 Pentachlorophenol mg/L 0.034 U 0.20 06/09/24 03:060.034 Pyridine mg/L 0.011 U 0.20 06/09/24 03:060.011 2,4,6-Tribromophenol (S) % 67 25-121 06/09/24 03:06 2-Fluorobiphenyl (S) % 63 12-110 06/09/24 03:06 2-Fluorophenol (S) % 45 10-57 06/09/24 03:06 Nitrobenzene-d5 (S) % 50 10-104 06/09/24 03:06 p-Terphenyl-d14 (S) % 88 38-139 06/09/24 03:06 Phenol-d6 (S) % 39 10-48 06/09/24 03:06

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5590912LABORATORY CONTROL SAMPLE:

LCSSpike

1,4-Dichlorobenzene mg/L 0.260.47 56 26-91 2,4,5-Trichlorophenol mg/L 0.360.47 76 47-114 2,4,6-Trichlorophenol mg/L 0.350.47 75 45-114 2,4-Dinitrotoluene mg/L 0.340.47 72 46-119 2-Methylphenol(o-Cresol) mg/L 0.290.47 62 23-75 3&4-Methylphenol(m&p Cresol) mg/L 0.290.47 62 10-106 Hexachloro-1,3-butadiene mg/L 0.290.47 62 27-102 Hexachlorobenzene mg/L 0.350.47 75 47-113 Hexachloroethane mg/L 0.270.47 57 22-93 Nitrobenzene mg/L 0.300.47 64 33-103 Pentachlorophenol mg/L 0.400.47 85 33-117 Pyridine mg/L 0.20 I0.47 42 10-46 2,4,6-Tribromophenol (S) % 85 25-121 2-Fluorobiphenyl (S) % 66 12-110 2-Fluorophenol (S) % 51 10-57 Nitrobenzene-d5 (S) % 61 10-104 p-Terphenyl-d14 (S) % 78 38-139

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/11/2024 11:42 AM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5590912LABORATORY CONTROL SAMPLE:

LCSSpike

Phenol-d6 (S) % 44 10-48

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5590913MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35881855001

5590914

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

1,4-Dichlorobenzene mg/L 0.47 55 26-9152 5 400.470.015 U 0.26 0.25 2,4,5-Trichlorophenol mg/L 0.47 83 47-11473 14 400.470.0023 U 0.39 0.34 2,4,6-Trichlorophenol mg/L 0.47 82 45-11471 13 400.470.0036 U 0.38 0.34 2,4-Dinitrotoluene mg/L 0.47 77 46-11970 9 400.470.012 U 0.36 0.33 2-Methylphenol(o-Cresol) mg/L 0.47 64 23-7559 8 400.470.0030 U 0.30 0.28 3&4-Methylphenol(m&p Cresol) mg/L 0.47 64 10-10659 9 400.470.0022 U 0.30 0.28

Hexachloro-1,3-butadiene mg/L 0.47 63 27-10256 10 400.470.0035 U 0.29 0.27 Hexachlorobenzene mg/L 0.47 78 47-11372 8 400.470.0029 U 0.37 0.34 Hexachloroethane mg/L 0.47 56 22-9353 5 400.470.014 U 0.26 0.25 Nitrobenzene mg/L 0.47 67 33-10360 11 400.470.0037 U 0.31 0.28 Pentachlorophenol mg/L 0.47 92 33-11787 5 400.470.034 U 0.43 0.41 Pyridine mg/L 0.47 36 10-4646 400.470.011 U 0.17 I 0.22 2,4,6-Tribromophenol (S) % 91 25-12183 40 2-Fluorobiphenyl (S) % 72 12-11061 40 2-Fluorophenol (S) % 50 10-5748 40 Nitrobenzene-d5 (S) % 63 10-10457 40 p-Terphenyl-d14 (S) % 81 38-13977 40 Phenol-d6 (S) % 44 10-4841 40

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/11/2024 11:42 AM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1017873

ASTM D2974-87

ASTM D2974-87

Dry Weight/Percent Moisture

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881855001

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35881855001

5594112SAMPLE DUPLICATE:

Percent Moisture % 85.2 0 1084.9

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35883509012

5594113SAMPLE DUPLICATE:

Percent Moisture % 16.4 J(D6)16 1019.3

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35883538093

5594114SAMPLE DUPLICATE:

Percent Moisture % 5.8 9 106.3

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35883538103

5594115SAMPLE DUPLICATE:

Percent Moisture % 12.7 5 1012.1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 06/11/2024 11:42 AM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35881855 Annual TCLP NCWRF

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1016272

EPA 9056

EPA 9056

9056 IC Anions

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35881855001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5584995

Associated Lab Samples: 35881855001

Matrix: Solid

AnalyzedMDL

Sulfate mg/kg 17.0 U 49.4 06/04/24 18:4817.0

Parameter Units

LCS

Result % Rec…

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