ESBD_386901_1734639631670_Attachment C - SDS-PHOS-CHEK-LC95A-PHOS-CHEK-LC95A-MV-Version-1.4.pdf

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Attached to
IFB-25-012 - Three 10, 000 Fiberglass Liquid Storage Tanks
Solicitation number
IFB-25-012
Issued by
Hockley County, Texas

About this file

This is a Safety Data Sheet (SDS) for PHOS-CHEK LC95A and PHOS-CHEK LC95A-MV Concentrate fire retardant products from Perimeter Solutions. The document provides detailed safety and handling information for these fire retardant concentrates manufactured by Perimeter Solutions facilities in Rancho Cucamonga, CA and Kamloops, B.C. The SDS was issued on 05/16/2019 and revised on 11/16/2022 (Version 1.4).

The product is classified as non-hazardous and contains 80-100% Ammonium Polyphosphate Solution, 5-10% Performance Additives, and 1-5% Iron oxide. The concentrate is a red liquid with no odor, pH of 5-6.5, relative density of 1.4-1.5, and water solubility >95%. The document outlines safety precautions, first aid measures, handling procedures, exposure controls, and ecological information, noting that while the product may cause long-term adverse effects in aquatic environments, it has minimal health, fire, and physical hazards according to NFPA ratings.

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PHOS-CHEK® LC95A /

PHOS-CHEK® LC95A-MV Concentrate

Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

Date of issue: 05/16/2019 Revision date: 11/16/2022 Version: 1.4

11/16/2022 EN (English) Page 1

SECTION 1: Identification

1.1. Identification

Product form : Mixture Product name : PHOS-CHEK® LC95A/ PHOS-CHEK® LC95A-MV Concentrate

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Fire retardant

1.3. Details of the supplier or manufacturer or distributor of the safety data sheet Perimeter Solutions 10667 Jersey Blvd.

Rancho Cucamonga CA, 91730 T 1-800-682-3626

Perimeter Solutions Canada Ltd., 3060 Airport Rd., Kamloops B.C., V2B 7X2 T. 250 554 3530

1.4. Emergency telephone number

Emergency number : CHEMTREC 800-424-9300

CANUTEC 613-996-6666 (transport only)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS classification Not classified.

2.2. Label elements

GHS labelling No labeling applicable

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity

Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substances

3.2. Mixtures

Name Product identifier % Ammonium Polyphosphate Solution (Non-hazardous) (CAS-No.) Trade Secret 80 - 100 Performance Additives (Non-hazardous) (CAS-No.) Trade Secret 5 - 10 Iron oxide

(CAS-No.) 1309-37-1 1 - 5

*Chemical name, CAS number and/or exact concentration have been withheld as a trade secret

SECTION 4: First-aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell.

First-aid measures after skin contact : If skin irritation occurs: Wash skin with plenty of water. Obtain medical attention if irritation persists.

First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

First-aid measures after ingestion : Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : May cause irritation to the respiratory tract.

Symptoms/effects after skin contact : May cause skin irritation. Repeated exposure may cause skin dryness or cracking.

PHOS-CHEK® LC95A / PHOS-CHEK® LC95A-MV Concentrate Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

11/16/2022 EN (English) 2/6

Symptoms/effects after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling.

Symptoms/effects after ingestion : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea.

4.3. Indication of any immediate medical attention and special treatment needed Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

Unsuitable extinguishing media : None known.

5.2. Special hazards arising from the substance or mixture

Fire hazard : None known.

5.3. Advice for firefighters

Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

6.2. Environmental precautions

Prevent entry to sewers and public waters.

6.3. Methods and material for containment and cleaning up

For containment : Absorb and/or contain spill with inert material (sand, vermiculite or other appropriate material), then place in suitable container. Do not flush into surface water or sewer system. Wear recommended personal protective equipment.

Methods for cleaning up : Sweep or shovel spills into appropriate container for disposal.

6.4. Reference to other sections

For further information refer to section 8: "Exposure controls/personal protection"

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Ensure adequate ventilation.

Hygiene measures : Wash contaminated clothing before reuse. Always wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Attapulgus Clay (8031-18-3)

According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

11/16/2022 EN (English) 3/6

Iron oxide (1309-37-1)

ACGIH

ACGIH TWA (mg/m³) 5 mg/m³ (respirable particulate matter)

ACGIH

Remark (ACGIH) Pneumoconiosis

OSHA OSHA PEL (TWA) (mg/m³) 10 mg/m³ (fume) 15 mg/m³ (total dust (Rouge) 5 mg/m³ (respirable fraction (Rouge)

IDLH US IDLH (mg/m³) 2500 mg/m³ (dust and fume)

NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ (dust and fume)

Performance Additives (Non-hazardous) (Trade Secret)

Ammonium Polyphosphate Solution (Non-hazardous) (Trade Secret)

8.2. Exposure controls

Appropriate engineering controls : Ensure good ventilation of the work station.

Hand protection : Wear suitable gloves.

Eye protection : Safety glasses or goggles are recommended when using product.

Skin and body protection : Wear suitable protective clothing.

Respiratory protection : Avoid breathing vapour or mist. Use NIOSH/MSHA approved respiratory protection equipment when airborne exposure limits are exceeded. Consult respirator manufacturer to determine appropriate type equipment for given application. Observe respirator use limitations specified by NIOSH / MSHA or the manufacturer. Refer to U.S. OSHA regulations 29 CFR 1910.134 or European Standard EN 149.

Environmental exposure controls : Not applicable when used as intended.

Other information : Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Colour : Red

Odour : None

Odour threshold : No data available pH : 5 - 6.5

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Relative evaporation rate (butylacetate=1) : No data available

Flammability (solid, gas) : No data available

Vapour pressure : No data available

Relative vapour density at 20 °C : No data available

Relative density : 1.4 - 1.5 @ 25 ºC (77 ºF)

Solubility : Water: > 95 %

Partition coefficient n-octanol/water : No data available

Auto-ignition temperature : No data available

According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

11/16/2022 EN (English) 4/6

Decomposition temperature : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : > 100 cP

Explosive limits : No data available

Explosive properties : No data available

Oxidising properties : No data available

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity

No dangerous reactions known under normal conditions of use.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified.

Acute toxicity (dermal) : Not classified.

Acute toxicity (inhalation) : Not classified.

PHOS-CHEK® LC95A / PHOS-CHEK® LC95A-MV

LD50 oral rat > 5050 mg/kg LD50 dermal rabbit > 2020 mg/kg

Skin corrosion/irritation : Not classified. Rabbit: 0.0/8.0 (24-hr. exp.)

pH: 5 - 6.5

Serious eye damage/irritation : Not classified. Rabbit: 10.2/110.0 pH: 5 - 6.5

Respiratory or skin sensitisation : Not classified.

Germ cell mutagenicity : Not classified.

Carcinogenicity : Not classified.

Iron oxide (1309-37-1) IARC group 3 - Not classifiable

Reproductive toxicity : Not classified.

STOT-single exposure : Not classified.

STOT-repeated exposure : Not classified.

Aspiration hazard : Not classified.

Symptoms/effects after inhalation : May cause irritation to the respiratory tract.

Symptoms/effects after skin contact : May cause skin irritation. Repeated exposure may cause skin dryness or cracking.

Symptoms/effects after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling.

Symptoms/effects after ingestion : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea.

According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

11/16/2022 EN (English) 5/6

Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : May cause long-term adverse effects in the aquatic environment.

LC50 fish 1 386 mg/l

12.2. Persistence and degradability

Persistence and degradability Not established.

12.3. Bioaccumulative potential

Bioaccumulative potential Not established.

12.4. Mobility in soil

12.5. Other adverse effects

Other information : No other effects known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.

Additional information : Empty containers or liners may retain some product residues. Do not re-use empty containers.

SECTION 14: Transport information

Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG) In accordance with DOT/TDG Not regulated

SECTION 15: Regulatory information

15.1. Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory.

All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic Substances List) inventories.

15.2. International regulations

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

Revision date : 11/16/2022 Other information : None.

Prepared by : Nexreg Compliance Inc.

www.Nexreg.com

NFPA health hazard : 0

NFPA fire hazard : 0 NFPA reactivity : 0 http://www.nexreg.com/

According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

11/16/2022 EN (English) 6/6

Hazard Rating Health : 0 Minimal Hazard Flammability : 0 Minimal Hazard Physical : 0 Minimal Hazard

SDS HazCom 2012 - WHMIS 2015 (NexReg)

Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use.

SECTION 1: Identification
1.1. Identification
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier or manufacturer or distributor of the safety data sheet
1.4. Emergency telephone number
2.1. Classification of the substance or mixture
GHS classification
2.2. Label elements
GHS labelling
2.3. Other hazards
2.4. Unknown acute toxicity
3.1. Substances
3.2. Mixtures
SECTION 4: First-aid measures
4.1. Description of first aid measures
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
6.4. Reference to other sections
SECTION 7: Handling and storage
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
SECTION 10: Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
10.5. Incompatible materials
SECTION 11: Toxicological information
11.1. Information on toxicological effects
SECTION 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
SECTION 13: Disposal considerations
13.1. Waste treatment methods
SECTION 14: Transport information
SECTION 15: Regulatory information
15.1. Federal regulations
15.2. International regulations
15.3. US State regulations

File details come from the government source that posted it. Updated .