1.3M FK-800 Resin Product Information.pdf

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68 Chemicals & Chemical Products
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B662254
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This document provides product information for 3M FK-800 Resin, a copolymer of chlorotrifluoroethylene and vinylidene fluoride. The resin is a free-flowing off-white granule with a specific gravity of 2.00 and glass transition temperature of 30C. It is nonflammable with a maximum continuous use temperature of 82C. The document outlines the resin's physical, optical, and electrical properties as well as its chemical resistance. It can be molded into thin, clear, flexible sheets and calendared on conventional equipment. Processing temperatures range from 300-400F. The resin has excellent resistance to acids, bases, hydrocarbon fuels, and inorganic salt solutions. It can be formulated into a clear, air-drying lacquer for use as a coating. The related federal contract opportunity is a pre-solicitation notice from the Department of Energy for chemicals and chemical products under NAICS code 325.

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Not for specification purposes

All measurements at 25°C, 1 atm unless noted

3M™ FK-800 Resin is a copolymer of chlorotrifluoroethylene (CTFE) and vinylidene fluoride (VF

). FK-800 is soluble in conventional solvents and therefore may be used in lacquers, paints and putties, as well as binders for plastic bonded explosives, pyrotechnics, propellants and other matrices. FK-800 is resistant to acids and most bases, and has very low permeability to moisture.

3 Product Information

Description

Typical Properties

Form ................................................................Free-flowing, off-white granule Volatiles, % ......................................................0.3 Specific Gravity ...............................................2.00 Dilute Solution Viscosity, cs ...........................0.50 Composition by Chlorine Analysis

(Mole % CTFE) (Mole % VF

).............................................Remainder

Transition Temperature, Tg.............................30°C (86°F) Transition Temperature, Tm............................105°C (220°F) Flammability....................................................Nonflammable Maximum Continuous Use Temperature........82°C (180°F)

Not for specification purposes

All measurements at 25°C, 1 atm unless noted

Physical Properties

Durometer Hardness, Shore D 64 ASTM D1706

Tensile Strength at Yield, psi 1500-3000 ASTM D638

Elongation at Yield, % 250-350 ASTM D638

Elastic Modulus in Tension, 105 psi 0.23-0.25 ASTM D638

Impact Strength, Izod, Notched No Break ASTM D256

Coefficient of Linear Thermal 6.5 ASTM D696 Expansion, 10-5 in./in./°C

FK-800 Resin

The optical and electrical properties of FK-800 make this polymer well-suited for fiber optic components; moisture-resistant coatings on printed circuits and wire; and coatings for electrical braid, wire, cable and harnesses.

Optical and Electrical Properties

3M™ FK-800 Resin can be molded into thin, clear sheets that are extremely flexible and stress-free at ambient temperatures. FK-800 may also be calendared on conventional equipment. Processing temperature for FK-800 is 300-400°F.

Molding and Calendaring

Color and Clarity Water white, transparent

Refractive Index 25 1.416 ASTM D542

Water Absorption 0.01 ASTM D570

Dielectric Constant

103 cps 3.00

106 cps 2.56

109 cps 2.29

Dissipation Factor

103 cps 0.029 ASTM D150

106 cps 0.032 ASTM D150

109 cps 0.010 ASTM D150

3M™ FK-800 Resin has excellent chemical resistance to:

• H

SO

—concentrated and dilute

• HCl—concentrated and dilute

• Red fuming nitric acid

• Hydrogen peroxide—90%

• NaOH

• Hydrocarbon fuels

• Inorganic salt solutions

Chemical Resistance

FK-800 can be formulated into a clear, air-drying lacquer which is easy to apply by brush, dip or spray techniques. Solutions may be prepared by dissolving 10-30% of the FK-800 Resin in ketone or acetate solvents.

The resultant coating is transparent, flexible, and highly resistant to acids, bases, salt solutions, hydrocarbon fuels and water. To ensure good adhesion of the FK-800 lacquer to aluminum, steel, copper, base and certain plastics, the use of an epoxy-type primer is required. The FK-800 coating has shown the ability to protect metals and woods against salt spray and weathering.

FK-800 may be compounded with such curing agents as benzoyl peroxide.

Vulcanization will change this material from a thermoplastic to a cross-linked structure having the advantage of greater mechanical strength at higher temperature and improved chemical resistance.

FK-800 has the highest specific gravity of any known commercially-available polymer that is soluble in conventional solvents. This high specific gravity plus its high fluorine content (51%), low coefficient of thermal expansion and high elastic modulus make FK-800 a strong candidate for certain applications in the field of solid propellants, pyrotechnics and plastic-bonded explosives. Compositions have been prepared in which the FK-800 binder amounts to less than 5% of total ingredients.

Lacquer

Safety and Toxicology

3M™ FK-800 Resin is considered to be low in toxicity and irritation potential, and no adverse health effects are expected during normal handling. Highly irritating and toxic decomposition products, including hydrogen fluoride, may be generated when FK-800 is heated to temperatures greater than 500°F. Good ventilation, preferably local exhaust, should be used when FK-800 is heated at elevated temperatures. Do not smoke if dusting occurs. Wash hands after handling FK-800.

3M Specialty Materials

3M Center, Building 223-6S-04 St. Paul, MN 55144-1000

Important Notice to Purchaser: The information in this publication is based on tests that we believe are reliable. Your results may vary due to differences in test types and conditions. You must evaluate and determine whether the product is suitable for your intended application.

Since conditions of product use are outside of our control and vary widely, the following is made in lieu of all express or implied warranties (including the warranties of merchantability or fitness for a particular purpose): 3M’s only obligation and your only remedy is replacement of product that is shown to be defective when you receive it. In no case will 3M be liable for any special, incidental, or consequential damages based on breach of warranty or contract, negligence, strict tort, or any other theory.

Issued: 10/00 © 2000 3M IPC 98-0212-XXXX-X (HB)

3M Specialty Materials 3M Center, Building 223-6S-04 St. Paul, MN 55144-1000 800 367 8905 800 810 8514 (Fax)

3M Corporate Headquarters

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