Attachment J- Environmental and Hazardous Material Report.pdf
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- Solicitation number
- N6247021R0003
About this file
This document is an environmental survey report for Area A1 at Aviano Air Base in Italy. The report details soil and hazardous materials sampling conducted to assess environmental conditions ahead of a construction project to build a new Entry Control Point. Twenty-six soil samples were collected from boreholes and analyzed for parameters including dry matter, fractions of elements, and heavy metals. Seventeen samples of potential hazardous materials like asbestos, fiberglass, and heavy metals were also taken from Buildings 103 and 106 for analysis. Test results showed levels of certain contaminants exceeded regulatory limits for commercial and industrial use. In conclusion, the survey assessed existing soil and building material conditions to inform design and construction of the new Entry Control Point for the Navy at Aviano Air Base in support of solicitation N6247021R0003.
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www.socotec.it
SOCOTEC ITALIA Srl – P.Iva 01872430648 - Capitale sociale 7.144.000,00 euro
Sede Legale: Via Bariola, 101-103 - 20020 Lainate (MI)
Tel.: +39 02 9375 0000 - Fax: +39 02 9375 0099
ENVIRONMENT
Client : GOLDER ASSOCIATES
Environmental and hazardous materials survey report, Area A1, Aviano Air Base Italy
GOLDER ASSOCIATES - ENVIRONMENTAL SURVEY: FINAL REPORT
Environmental and hazardous materials survey, Area A1, Aviano Air Base Italy
Summary
1. INTRODUCTION
2. SITE OVERVIEW
3. SAMPLING
3.1 Soil samples
3.2 Hazardous materials
4. ANALYTES AND METHOD OF ANALYSIS
4.1 Soil samples
4.2 Hazardous materials
5. ANALYSES RESULTS
5.1 Soil samples
5.2 Hazardous materials
6. CONCLUSIONS
6.1 Soil samples
6.2 Hazardous materials
ANNEX
1. Photographic Annex
2. Laboratory Test reports
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1. INTRODUCTION
Socotec Italia S.r.l. (“Socotec”) has been commissioned by Golder Associates S.r.l. (“Golder” or “Client”) to carry out the geotechnical, geophysical, topographic and environmental survey of the portion of Aviano
Air Base’s Area A1 that will be subject to the new Entry Control Point design and construction.
This document describes the work and presents the results of the environmental survey conducted between June 11th and 17th, 2020 together with the results of the chemical testing of the soil samples and potential hazardous materials collected.
All activities have been performed in compliance with the Client’s sampling plan and the applicable Italian
Environmental Laws, in particular Legislative Decree n. 152/06 - Part IV and its amendments.
2. SITE OVERVIEW
Aviano Air Base is located in the Friuli-Venezia Giulia Region, Northeast Italy. It is comprised of nine geographically separated areas, eight of which are indicated in Figure 1:
Figure 1 – Aviano Air Base areas
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A new Access Control Point will be built in Area A1, in the proximity of the current Gate 1 access point
(Figure 2). The project includes demolition of existing buildings and construction of new ones, roads, pedestrian pavements and facilities. For this reason, preliminary environmental monitoring has been planned.
Figure 2. A1 area: project plan of the new Access Control Point around Gate 1
Buildings with offices and equipment rooms, parking lots and green areas are present around Gate 1 in
Area A1. The applicable environmental Italian regulation to the project site is Legislative Decree n. 152/06.
Considering the type of activities performed at the site, the applicable limits for soil contamination are those listed in Part Fourth, Title V, Annex 5, Table 1, Column B: commercial and industrial use.
Based on the Client’s sampling plan, Socotec survey covered the following zones of Area A1 (see Figure
3):
Green and paved areas the Gate 1 area;
Building 103, ground floor and first floor;
Building 106.
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Figure 3. Area A1, Gate 1: area object of the environmental and HazMat survey (red line)
3. SAMPLING
Socotec collected a total of 26 soil samples from the seven (7) soil borings S1 to S7 drilled in the green and paved areas near Gate 1 and a total of 17 samples from potentially hazardous materials ("HazMat") from Buildings 103 (only inside samples) and 106 (both inside and from the outside samples).
3.1 Soil samples
As required by the Client, Socotec carried out the following investigation plan:
Three (3) continuous coring boreholes drilled until 10 meters depth, inclusive of Standard
Penetration tests ("SPT") and geotechnical and environmental sampling (green dot in Figure 4);
Four (4) continuous coring boreholes drilled until 3 meters depth, inclusive of SPT tests and geotechnical and environmental sampling (red dot in Figure 4).
The boreholes locations are indicated in Figure 4 below.
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Figure 4. Boreholes location
The results of the geotechnical sampling and analysis are described in the specific report and will not be discussed in this document.
Soil cores were placed in plastic boxes, following the natural stratigraphy. For each sample, using a stainless scoop, Socotec collected 8-10 punctual portions of the core soil, to create a composite amount of soil intended for analysis of volatile parameters. This amount of soil was stored in an airtight glass 200 ml volume container, filled to the brim and rapidly closed, taking care to minimize the disturbance of the sample and the loss of the volatile components.
Socotec collected also 10 increments per sample intended for non-volatile parameters analysis. The soil was passed through a 2 cm sieve, collected in a clean bucket, well-homogenized, and finally stored in a
800 ml volume airtight glass container.
Each containers was labeled, specifying the sampling point location, name of sample and depth. Socotec prepared a chain of custody with the date, name of technician, matrix and sample id.
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All sampling devices were washed with clean fresh water and decontaminated with distilled water solution after each sample collection.
Samples were stored in a portable fridge and maintained at 4°C until arrival at the laboratory.
The list of soil samples collected is provided in Table 1 below.
Sampling Point Sample ID Depth Analyzed/Stored
Borehole S1
S1 CA1 Depth: 0-1 m Analyzed
S1 CA2 Depth: 1-2 m Analyzed
S1 CA3 Depth: 2-3 m Analyzed
S1 CA4 Depth: 4-5 m Stored
S1 CA5 Depth: 9-10 m Stored
Borehole S2
S2 CA1 Depth: 0-1 m Analyzed
S2 CA2 Depth: 1-2 m Analyzed
S2 CA3 Depth: 2-3 m Analyzed
Borehole S3
S3 CA1 Depth: 0-1 m Analyzed
S3 CA2 Depth: 1-2 m Analyzed
S3 CA3 Depth: 2-3 m Analyzed
Borehole S4
S4 CA1 Depth: 0-1 m Analyzed
S4 CA2 Depth: 1-2 m Analyzed
S4 CA3 Depth: 4-5 m Stored
S4 CA4 Depth: 6-7 m Stored
S4 CA5 Depth: 9-10 m Stored
Borehole S5
S5 CA1 Depth: 0-1 m Analyzed
S5 CA2 Depth: 1-2 m Stored
S5 CA3 Depth: 2-3 m Stored
Borehole S6 S6 CA1 Depth: 0-1 m Analyzed
S6 CA2 Depth: 1-2 m Analyzed
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Sampling Point Sample ID Depth Analyzed/Stored
S6 CA3 Depth: 2-3 m Stored
Borehole S7
S7 CA1 Depth: 0-1 m Analyzed
S7 CA2 Depth: 1-2 m Analyzed
S7 CA3 Depth: 4-5 m Stored
S7 CA4 Depth: 9-10 m Stored
Table 1. List of soil samples collected
3.2 Hazardous materials
During the HazMat survey, a total of 17 potential HazMat samples were collected from Building 103 and
106 (see Figures 5-6-7) of various potentially hazardous materials, to determine:
Presence of asbestos containing material (ACM);
Presence and characteristics of man-made vitreous fibers (“MMVF”);
Presence of heavy metals, PCB, mercury.
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Figure 5. Plan of potential HazMat samples location in Building 103 – Ground floor
Figure 6. Plan of potential HazMat samples location in Building 103 – First floor
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Figure 7. Plan of potential HazMat samples location in Building 106
Samples collection was undertaken after laying a tarp near or under the sampling area to minimize the spread of potentially contaminated particles, and, using pliers or a spatula, removing a small amount of the item to be investigated. Samples were stored in double polyethylene bags, well-closed and labeled.
ACM and MMVF samples were fixed with special transparent sealing paint spry to minimize fibers dispersion and the sampled location, when possible, was covered with sealing tape.
After sample collection, Socotec filled out the relative chain of custody for laboratory analyses.
The list of the potential HazMat samples collected from Buildings 103 and 106 during the survey, is provided in Table 2:
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Sampling Point Matrix Sample ID Note Analyzed/Stored
Building 103
Solid 103_216_ACM01 Carpet mastic - Conference room- room 216 Analyzed
Solid 103_104_ACM02 Linoleum mastic - Room
Analyzed
MMVF 103_113_FAV01
Boiler pipe insulation -room 113 – Boiler room Analyzed
MMVF 103_114_FAV02 Ceiling tile - room 114 Stored
Building 106 - Indoor samples
Solid 106_11_MET01 Wall black paint - Theatre -room 11 Analyzed
MMVF 106_18_FAV03
Insulation panel inside black bag located above the ceiling tile
Stored
MMVF 106_12_FAV04
Insulation panel inside silver bag located above the ceiling tile - room 12
Stored
MMVF 106_2P_10_FAV05
Duct insulation – storage room 2nd floor (above room 10)
Analyzed
MMVF 106_21_FAV06
Insulation panel without any protection bag located above the ceiling tile - Kitchen - room 21
Stored
Building 106 - Outside wall samples
Solid 106_OUT_ACM03
Serpentinite Green Stone
Analyzed
Solid 106_OUT_ACM04 Analyzed
Solid 106_OUT_ACM05 Analyzed
Solid 106_OUT_ACM06 Analyzed
Solid 106_OUT_ACM07 Analyzed
Solid 106_OUT_ACM08 Analyzed
Solid 106_OUT_ACM09 Analyzed
Solid 106_OUT_ACM10 Analyzed MMVF = Man-made Vitreous Fibers; ACM = Asbestos Containing Materials
Table 2. List of potential HazMat samples collected
Green stone samples ACM10 is a duplicate sample of ACM09. It was collected for analysis quality assurance/quality control (duplicate sample).
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4. ANALYTES AND METHOD OF ANALYSIS
4.1 Soil samples
Following the Client’s request and current Italian regulatory limits related to soil contamination, the following parameters have been analyzed for each of the soil samples collected:
Group Parameter u.m. Method
- Dry matter (150°C) % CNR IRSA 2 Q 64 Vol 2 1984
- Fraction<2mm % DM 13.09.1999 Met. II.1
Metals
Antimony, Arsenic, Beryllium, Cadmium, Cobalt, Chromium, Mercury, Nickel, Lead, Copper, Selenium, Thallium, Vanadium, Zinc mg/kg dm EPA3052 + EPA6010D
Chromium VI mg/kg dm CNR IRSA 16 Q 64 Vol 3 1986
Aromatic compound
Benzene, Ethylbenzene, Xylene, Styrene, Toluene, Total BTEX mg/kg dm EPA5021A + EPA8015D
Polycyclic aromatic hydrocarbons
Benzo(a) Anthracene, Benzo(a) Pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene, Benzo(g,h,i)perylene, Chrysene, Dibenzo(a,e)pyrene, Dibenzo(a,l)pyrene, Dibenzo(a,i)pyrene, Dibenzo(a,h)pyrene, Dibenzo(a,h)anthracene, Indeno(1,2,3-cd)pyrene, Pyrene, Total PAHs mg/kg dm EPA3550C + EPA8270E
Aliphatic Chlorinated
Carcinogenic Compounds
Chloromethane, Dichloromethane, Trichloromethane, Vinyl Chloride, 1,2 – Dichloroethane, 1,1 – Dichloroethylene, Trichloroethylene, Tetrachloroethylene mg/kg dm EPA5021A+EPA8021B
Aliphatic Chlorinated Non-
Carcinogenic Compounds
1,1 – Dichloroethane, 1,2 – Dichloroethylene, 1,1,1 – Trichloroethane, 1,2 – Dichloropropane, 1,1,2 – Trichloroethane, 1,1,3 – Trichloropropane, 1,1,2,2 – Tetrachloroethane mg/kg dm EPA5021A+EPA8021B
Aliphatic Halogenated Compounds
Tribromomethane, 1,2 – Dibromoethane, Dibromochloromethane, Bromodichloromethane mg/kg dm EPA5021A+EPA8021B
Nitrobenzenes Nitrobenzene, 1,2-Dinitrobenzene, 1,3-
Dinitrobenzene, Chloronitrobenzene mg/kg dm EPA3550C+EPA8270E
Chlorobenzenes
Monochlorobenzene, 1,2-Dichlorobenzene, 1,4-Dichlorobenzene, 1,2,4- Trichlorobenzene, 1,2,4,5-
Tetrachlorobenzene, Pentachlorobenzene, Esachlorobenzene mg/kg dm EPA3550C+EPA8270E
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Group Parameter u.m. Method
Non-chlorinated Phenols
Methylphenol (o,m,p), Phenol mg/kg dm EPA3550C+EPA8041A
Chlorinated Phenols
2 – Chlorophenol, 2,4 – Dichlorophenol, 2,4,6 – Trichlorophenol, Pentachlorophenol mg/kg dm EPA3550C+EPA8041A
Aromatic amines Aniline, o-Anisidine, m,p-Anisidine, Diphenylamine , p-Toluidine, Total aromatic amine mg/kg dm EPA3550C+EPA8270E
Pesticides
Alachlor, Aldrin, Atrazine, alfa-hexachlorocyclohexane, beta-hexachlorocyclohexane, gamma-hexachlorocyclohexane (Lindane), Chlordane, DDD, DDE, DDT, Dieldrin, Endrin mg/kg dm EPA3550C+EPA8270E
Polychlorinated biphenyl
Congeners, Total PCBs mg/kg dm EPA3550C+EPA8082A
Hydrocarbons Hydrocarbons C<12 mg/kg dm EPA5021A+EPA8015D
Hydrocarbons C>12 mg/kg dm ISO 16703 mg/kg dm = mg/kg dry matter
Table 3. Soil samples: analytes and methods of analysis
4.2 Hazardous materials
In order to test the potential HazMat located in Buildings 103 and 106, the survey focused on verifying:
Presence of ACM;
Type and physical dimensions of MMVF;
Presence of heavy metals in walls paints;
PCB and mercury in overhead light bulbs*.
The list of parameters and methods of analysis performed is indicated in Table 4:
Group Parameter u.m. Method
Asbestos Asbestos fibers mg/kg dm HSG 248 2005 APP.2 (Polarized Light
Optical Microscopy “MOLP”)
Alkaline and alkali earth oxides
Barium oxide (BaO), Calcium oxide
(CaO), Potassium oxide (K2O), Magnesium Oxide (MgO), Sodium oxide
% EPA3050B + EPA6010D
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Group Parameter u.m. Method
(Na2O), Alkaline and alkali earth oxides content (Na2O+K2O+CaO+MgO+BaO)
Fibers dimension
Length weighted geometric mean diameter less two standard geometric errors µm LABO 18 Ed 00
- Dry matter (150°C) % CNR IRSA 2 Q 64 Vol 2 1984
Heavy metals
Antimony, Arsenic, Beryllium, Cadmium, Cobalt, Chromium, Mercury, Nickel, Lead, Copper, Selenium, Thallium, Vanadium, Zinc mg/kg dm EPA3052 + EPA6010D
Chromium VI mg/kg dm CNR IRSA 16 Q 64 Vol 3 1986
Table 4. Hazardous materials samples: parameters and methods of analysis
* Based on information provided by Aviano AB Environmental Office and Real Estate Office, presence of PCB and mercury in overhead lamp has been excluded following building renovations and use of bulbs free of such elements, as required by European Union directives. Therefore, no sampling and analysis were conducted for PCB and mercury.
5. ANALYSES RESULTS
5.1 Soil samples
The soil samples analyses results were compared with the limits in Italian Legislative Decree 152/06, Part
Fourth, Title V, Annex 5, Table 1, Column A (sites with public, private and residential use and green areas) and column B (sites with commercial and industrial use).
The analyses results are shown in Table 5.
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Code analysis um
Legislative Decree 152/06, Part Four
Title V Annex 5 Tab. 1
20LA05273 20LA05276 20LA05277 20LA05241 20LA05242 20LA05246 20LA05235 20LA05236 20LA05237 20LA05240 20LA05245 20LA05226 20LA05227 20LA05228 20LA05238 20LA05239
Sampling date 15/06/2020 15/06/2020 15/06/2020 13/06/2020 13/06/2020 13/06/2020 12/06/2020 12/06/2020 12/06/2020 13/06/2020 13/06/2020 11/06/2020 11/06/2020 11/06/2020 12/06/2020 12/06/2020
Sample ID
S1CA1 -
Depth: 0-1 m
S1CA2 -
Depth: 1-2 m
S1CA3 -
Depth: 2-3 m
S2CA1 -
Depth: 0-1 m
S2CA2 -
Depth: 1-2 m
S2CA3 -
Depth: 2-3 m
S3CA1 -
Depth: 0-1 m
S3CA2 -
Depth: 1-2 m
S3CA3 -
Depth: 2-3 m
S4CA1 -
Depth: 0-1 m
S4CA2 -
Depth: 1-2 m
S5 CA1 -
Depth: 0-1 m
S6 CA1 -
Depth: 0-1 m
S6 CA2 -
Depth: 1-2 m
S7CA1 -
Depth: 0-1 m
S7CA2 -
Depth:1-2 m
Matrix Col.A Col. B Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Dry matter (150°C) % - - 81,2 85,1 82,8 86,2 79,3 77,7 81,6 84,9 84 92,3 85,5 80,8 89,6 93,1 81,7 84,3
Fraction<2mm % - - 54,8 69,8 65,1 76,2 93,9 88,3 55,3 56,6 65,9 70 65 69,6 54,8 47,1 65,7 70,4
Antimony mg/kg dm 10 30 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5
Arsenic mg/kg dm 20 50 < 2.5 < 2.5 < 2.5 6,6 10,7 10,2 8,8 4,7 5,1 3,4 6,8 6,9 < 2.5 < 2.5 6,4 7,1
Beryllium mg/kg dm 2 10 < 0.5 < 0.5 < 0.5 0,88 1,8 1,7 1 0,67 0,78 < 0.5 0,76 0,86 < 0.5 < 0.5 0,8 1,3
Cadmium mg/kg dm 2 15 < 0.5 < 0.5 < 0.5 < 0.5 1,2 1,1 0,68 < 0.5 < 0.5 < 0.5 0,76 0,86 < 0.5 < 0.5 0,8 0,84
Cobalt mg/kg dm 20 250 < 2.5 < 2.5 < 2.5 6,2 13 13,1 7,8 4,7 4,3 2,7 6,1 7,8 < 2.5 < 2.5 6 7,1
Chromium mg/kg dm 150 800 16,2 4,9 5,1 35 82 68 44 28 29 17,1 32 46 11 5,6 36 48
Chromium VI mg/kg dm 2 15 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2
Mercury mg/kg dm 1 5 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 < 0.25
Nickel mg/kg dm 120 500 9,8 < 2.5 2,8 19,9 53 54 28 19 19,2 11 22,8 30 6,7 3,8 24,5 34
Lead mg/kg dm 100 1000 7,1 < 2.5 < 2.5 12,8 19,5 17,6 14,2 7 5,5 10,6 11,8 15,1 < 2.5 < 2.5 12,1 10
Copper mg/kg dm 120 600 17,9 < 2.5 < 2.5 11,5 17,8 17,6 14,2 7,7 7,5 8,7 10,6 15,1 3,4 < 2.5 11,3 12,1
Selenium mg/kg dm 3 15 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5 < 2.5
Thallium mg/kg dm 1 10 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1
Vanadium mg/kg dm 90 250 24 6,6 6,7 56 111 103 72 46 50 26 49 70 15,9 9,6 59 80
Zinc mg/kg dm 150 1500 29 2,9 3,9 42 89 96 58 35 37 38 47 56 12,2 6,6 49 61
Benzene mg/kg dm 0,1 2 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Ethylbenzene mg/kg dm 0,5 50 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Xylene mg/kg dm 0,5 50 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Styrene mg/kg dm 0,5 50 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Toluene mg/kg dm 0,5 50 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Total BTEX mg/kg dm 1 100 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Benzo(a) Anthracene mg/kg dm 0,5 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Benzo(a) Pyrene mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Benzo(b)fluoranthene mg/kg dm 0,5 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Benzo(k)fluoranthene mg/kg dm 0,5 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Benzo(g,h,i)perylene mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Chrysene mg/kg dm 5 50 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Dibenzo(a,e)pyrene mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Dibenzo(a,l)pyrene mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Dibenzo(a,i)pyrene mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Dibenzo(a,h)pyrene mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Dibenzo(a,h)anthracene mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Indeno(1,2,3-cd)pyrene mg/kg dm 0,1 5 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Pyrene mg/kg dm 5 50 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 0,01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Total PAHs mg/kg dm 10 100 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Chloromethane mg/kg dm 0,1 5 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
Dichloromethane mg/kg dm 0,1 5 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
Trichloroethane mg/kg dm 0,1 5 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
Vinyl Chloride mg/kg dm 0,01 0,1 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
1,2 - Dichloroethane mg/kg dm 0,2 5 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
1,1 - Dichloroethylene mg/kg dm 0,1 1 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
Trichloroethylene mg/kg dm 1 10 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
Tetrachloroethylene mg/kg dm 0,5 20 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
1,1 - Dichloroethane mg/kg dm 0,5 30 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
1,2 - Dichloroethylene mg/kg dm 0,3 15 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
P a g . 16 | 22
Legislative Decree 152/06, Part Four
Title V Annex 5 Tab. 1
20LA05273 20LA05276 20LA05277 20LA05241 20LA05242 20LA05246 20LA05235 20LA05236 20LA05237 20LA05240 20LA05245 20LA05226 20LA05227 20LA05228 20LA05238 20LA05239
Sampling date 15/06/2020 15/06/2020 15/06/2020 13/06/2020 13/06/2020 13/06/2020 12/06/2020 12/06/2020 12/06/2020 13/06/2020 13/06/2020 11/06/2020 11/06/2020 11/06/2020 12/06/2020 12/06/2020
Sample ID
S1CA1 -
Depth: 0-1 m
S1CA2 -
Depth: 1-2 m
S1CA3 -
Depth: 2-3 m
S2CA1 -
Depth: 0-1 m
S2CA2 -
Depth: 1-2 m
S2CA3 -
Depth: 2-3 m
S3CA1 -
Depth: 0-1 m
S3CA2 -
Depth: 1-2 m
S3CA3 -
Depth: 2-3 m
S4CA1 -
Depth: 0-1 m
S4CA2 -
Depth: 1-2 m
S5 CA1 -
Depth: 0-1 m
S6 CA1 -
Depth: 0-1 m
S6 CA2 -
Depth: 1-2 m
S7CA1 -
Depth: 0-1 m
S7CA2 -
Depth:1-2 m
Matrix Col.A Col. B Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
1,1,1 - Trichloroethane mg/kg dm 0,5 50 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
1,2 - Dichloropropane mg/kg dm 0,3 5 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
1,1,2 - Trichloroethane mg/kg dm 0,5 15 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
1,1,3 - Trichloropropane mg/kg dm 1 10 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
1,1,2,2 - Tetrachloroethane mg/kg dm 0,5 10 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
Tribromomethane mg/kg dm 0,5 10 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
1,2 - Dibromoethane mg/kg dm 0,01 0,1 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
Dibromochloromethane mg/kg dm 0,5 10 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
Bromodichloromethane mg/kg dm 0,5 10 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002
Nitrobenzene mg/kg dm 0,5 30 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
1,2-Dinitrobenzene mg/kg dm 0,1 25 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
1,3-Dinitrobenzene mg/kg dm 0,1 25 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
Chloronitrobenzene mg/kg dm 0,1 10 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
Monochlorobenzene mg/kg dm 0,5 50 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
1,2-Dichlorobenzene mg/kg dm 1 50 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
1,4-Dichlorobenzene mg/kg dm 0,1 10 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
1,2,4-Trichlorobenzene mg/kg dm 1 50 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
1,2,4,5- Tetrachlorobenzene mg/kg dm 1 25 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
Pentachlorobenzene mg/kg dm 0,1 50 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
Esachlorobenzene mg/kg dm 0,05 5 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05
Methylphenol (o,m,p) mg/kg dm 0,1 25 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Phenol mg/kg dm 1 60 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
2 - Chlorophenol mg/kg dm 0,5 25 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
2,4 - Dichlorophenol mg/kg dm 0,5 50 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
2,4,6 - Trichlorophenol mg/kg dm 0,01 5 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Pentachlorophenol mg/kg dm 0,01 5 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Aniline mg/kg dm 0,05 5 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 o-Anisidine mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 m,p-Anisidine mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Diphenylamine mg/kg dm 0,1 10 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 p-Toluidine mg/kg dm 0,1 5 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Total aromatic amine mg/kg dm 0,5 25 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Alachlor mg/kg dm 0,01 1 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Aldrin mg/kg dm 0,01 0,1 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Atrazine mg/kg dm 0,01 1 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 alfa-hexachlorocyclohexane mg/kg dm 0,01 0,1 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 beta-hexachlorocyclohexane mg/kg dm 0,01 0,5 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 gamma-hexachlorocyclohexane
(Lindane) mg/kg dm 0,01 0,5 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Chlordane mg/kg dm 0,01 0,1 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
DDD, DDE, DDT mg/kg dm 0,01 0,1 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Dieldrin mg/kg dm 0,01 0,1 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
Endrin mg/kg dm 0,01 2 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01
P a g . 17 | 22
Legislative Decree 152/06, Part Four
Title V Annex 5 Tab. 1
20LA05273 20LA05276 20LA05277 20LA05241 20LA05242 20LA05246 20LA05235 20LA05236 20LA05237 20LA05240 20LA05245 20LA05226 20LA05227 20LA05228 20LA05238 20LA05239
Sampling date 15/06/2020 15/06/2020 15/06/2020 13/06/2020 13/06/2020 13/06/2020 12/06/2020 12/06/2020 12/06/2020 13/06/2020 13/06/2020 11/06/2020 11/06/2020 11/06/2020 12/06/2020 12/06/2020
Sample ID
S1CA1 -
Depth: 0-1 m
S1CA2 -
Depth: 1-2 m
S1CA3 -
Depth: 2-3 m
S2CA1 -
Depth: 0-1 m
S2CA2 -
Depth: 1-2 m
S2CA3 -
Depth: 2-3 m
S3CA1 -
Depth: 0-1 m
S3CA2 -
Depth: 1-2 m
S3CA3 -
Depth: 2-3 m
S4CA1 -
Depth: 0-1 m
S4CA2 -
Depth: 1-2 m
S5 CA1 -
Depth: 0-1 m
S6 CA1 -
Depth: 0-1 m
S6 CA2 -
Depth: 1-2 m
S7CA1 -
Depth: 0-1 m
S7CA2 -
Depth:1-2 m
Matrix Col.A Col. B Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
PCBs congeners mg/kg dm 0,06 5 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005
Hydrocarbons C<12 mg/kg dm 10 250 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1
Hydrocarbons C>12 mg/kg dm 50 750 < 20 < 20 < 20 < 20 < 20 < 20 < 20 < 20 < 20 < 20 < 20 < 20 34 50 < 20 < 20
Table 5. Soil Samples: analyses results
P a g . 18 | 22
All the collected samples results did not exceed the Italian DLgs 152/05 regulatory limits with the exception of samples S2CA2 (1-2 m) and S2CA3 (2-3 m), showing exceedance of the public, private, residential use and green areas (Column A) limit for Vanadium.
5.2 Hazardous materials
Concerning asbestos investigations, the main applicable Italian regulations are:
Law 27th March 1992, n. 257 - Rules on asbestos use ban;
Health Ministerial Decree 6th Sept 1994 - Regulations and technical methodologies for the application of art. 6, paragraph 3, and art. 12, paragraph 2, of the law of 27 March 1992, n. 257, concerning the halt of the use of asbestos;
Legislative Decree 81/08 –Workers Health and Safety Act.
The hazard of asbestos, classified as 1A Carcinogen, is due to the possible fibers dispersion in the environment that can be inhaled and have a cancerogenic effect on the lungs.
The ACM analyses results are indicated in Table 6a-6b below:
Code analysis u.m.
20LA05274 20LA05278 20LA05280 20LA05281 20LA05282
Sampling date 16/06/2020 16/06/2020 17/06/2020 17/06/2020 17/06/2020
Sample ID 103_216_ACM01 103_104_ACM02
106_OUT_ACM0
106_OUT_ACM0
106_OUT_ACM0
Matrix ACM ACM ACM ACM ACM
Asbestos (fibers) p/a n.d.(<500 mg/kg) n.d.(<500 mg/kg) n.d.(<500 mg/kg) n.d.(<500 mg/kg) n.d.(<500 mg/kg) u.m.
20LA05283 20LA05284 20LA05285 20LA05286 20LA05287
Sampling date 17/06/2020 17/06/2020 17/06/2020 17/06/2020 17/06/2020
Sample ID 106_OUT_ACM06 106_OUT_ACM07 106_OUT_ACM08 106_OUT_ACM09 106_OUT_ACM10
Matrix ACM ACM ACM ACM ACM
Asbestos (fibers) p/a n.d.(<500 mg/kg) n.d.(<500 mg/kg) n.d.(<500 mg/kg) n.d.(<500 mg/kg) n.d.(<500 mg/kg)
Table 6a-6b. ACM Samples: analyses results
None of the analyzed ACM samples shows the presence of asbestos fibers including the samples collected from the outside wall of Building 106. Such samples are constituted by a serpentine rock with a chrysotile-like composition without fibrous crystals and are all ACM-free.
Duplicate sample ACM10 showed the same analytical result of sample ACM09, confirming the quality of the results.
P a g . 19 | 22
MMFV were investigated to determine fibers harmfulness according to the following regulation:
Regulation (EC) N° 1272/2008 of the European Parliament and of the Council of 16 December
2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No
1907/2006;
MMFV Guidelines drawn up by the Italian State-Regions Conference (2016).
As with asbestos, the danger of the MMVF is related to the possible release of fibers that can be inhaled and cause lung cancer.
The MMVF samples analyses results are indicated in Table 7 below:
Code analysis u.m.
Harmonized classification - Annex VI of Regulation
(EC) No 1272/2008 (CLP Regulation)
20LA05275 20LA05279
Sampling date 16/06/2020 16/06/2020
Sample ID 103_113_FAV01 106_2P_10_FAV05
Type MMVF MMVF
Compliance N Y
Matrix Pipe insulation Duct insulation
Barium oxide (BaO) % w/w - 0,04 < 0.01
Calcium oxide (CaO) % w/w - 13,2 1,4
Potassium oxide (K2O) % w/w - 0,9 0,06
Magnesium oxide (MgO) % w/w - 8,2 0,34
Sodium oxide (Na2O) % w/w - 1,2 1,8
Alkaline and alkali earth oxides content (Na2O+K2O+CaO+MgO+BaO)
% w/w
≤18%: Refractory Ceramic Fibres
<18%: Man-made vitreous (silicate) fibres
23,4
3,6
Length weighted geometric mean diameter minus two standard geometric errors µm Carcinogen ≤ 6
3,9
7,1
Table 7. MMVF Samples: analyses results
Socotec analyzed two pipes insulation MMVF: one in the boiler room in Building 103 and one in a duct inside Building 106. The MMVF sample collected in Building 103 resulted hazardous because of its fibers dimension.
No specific regulatory limits are defined in the Italian regulations regarding the presence of heavy metals in wall paints. However, pigments containing lead sulphochromate and lead sulphochromomolybdate were included in February 2012 in Annex XIV to the REACH Regulation
(Regulation (EC) N 1907/2006 of the European Parliament and of the Council of 18th December 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals.
P a g . 20 | 22
Termination of use was expected by 21st May 2015 and a request for authorization to use only in industrial paint products to be forwarded by 21st November 2013.
The wall paint sample analysis results for the heavy metals concentrations are indicated in Table 8 below:
Code analysis u.m.
20LA05288
Sampling date 16/06/2020
Sample ID 106_11_MET01
Matrix Solid
Antimony mg/kg < 2.5
Arsenic mg/kg < 2.5
Beryllium mg/kg < 0.5
Cadmium mg/kg < 0.5
Cobalt mg/kg 37
Chromium mg/kg 44
Chromium VI mg/kg < 5
Mercury mg/kg 18
Nickel mg/kg 5,5
Lead mg/kg 516
Copper mg/kg 12
Selenium mg/kg < 2.5
Thallium mg/kg < 2.5
Vanadium mg/kg
Zinc mg/kg 185
Table 8. Wall paint sample: analyses results
P a g . 21 | 22
6. CONCLUSIONS
6.1 Soil samples
Analyses results of the soil samples collected from the soil bores undertaken in Area A1 near Gate 1 comply with the regulatory limits applicable to Aviano AB for “sites with commercial and industrial use”
(Table 1, Column B, Annex 5, Part IV, of D.Lgs.n°152/2006), and no further action or investigation is required.
Even if not applicable to Aviano AB, the analyses results showed compliance even for the most restrictive Italian residential limits (Table 1, Column A, Annex 5, Part IV, D.Lgs.n°152/2006), with the exception of Vanadium in the two S2 samples collected between 1 and 3 m below ground surface.
6.2 Hazardous materials
As shown in table 6a-6b, no ACM sample analyzed show the presence of asbestos fibers, so no further activity is required.
From the available information Building 103 was completely renovated in 2007. The renovation date is later than the year in which the use of asbestos was banned in Italy (1992).
The ornamental stones used to decorate the outside walls of building 106, although they are made of green stones (serpentine), do not show fibrous crystals and therefore cannot release hazardous fibers.
Concerning the two MMVF samples of insulating materials, the analyses results show that:
103_113_FAV01 is constituted by “Man-made vitreous (silicate) fibers with random orientation with alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content greater than 18 % by weight”. The length weighted geometric mean diameter minus two standard geometric errors is less than 6 µm: applying the classification criteria of the CLP regulation (European Union
Regulation n. 1272/2008), and the 2016 Italian MMVF Guidelines drawn up by the Italian State-
Regions Conference, the sample is classified as carcinogenic 2.
106_2P_10_FAV05 is properly a “Refractory Ceramic Fiber”, made up of “Man-made vitreous
(silicate) fibers with random orientation with alkaline oxide and alkali earth oxide
(Na2O+K2O+CaO+ MgO+BaO) content less or equal to 18 % by weight”. The length weighted geometric mean diameter minus two standard geometric errors is greater than 6 µm: applying the
P a g . 22 | 22 note R1 of Annex VI of the Reg.1272/2008 and the 2016 Italian MMVF Guidelines, the sample is not classified as carcinogenic.
The 103_113_FAV01 sample was collected from the pipe insulation connected to the rear of the boiler called "103 A" (as shown on the boiler side), and it was marked on-site with red paint, as indicated in
Annex 1.
Italian regulations do not provide for the removal or disposal of MMVF if classified as hazardous.
However, to minimize the possible exposure of personnel and workers to airborne fibers during demolition and disposal activities, it is recommended to adopt the same approach used for ACMs according to the following approaches (from most effective to less effective):
Elimination of the risk (removal);
Minimization of the risk (enclosure, encapsulation, sealing);
Administrative controls (safe work practices such as regulation of access to the boiler room, including signs; appropriate information for personnel who must maintain and/or repair the equipment);
Using personal protective equipment;
Monitoring airborne fibers during maintenance work.
A combination of the measures above may be required to adequately manage and control the hazardous MMVF. Title IX of Italian Legislative Decree 81/2008 mandatorily requires to protect workers from hazardous substances risk of exposure.
The handling and eventual removal of the pipe insulation at boiler "103 A", has to be conducted implementing measures to avoid any fiber dispersion. The workers have to wear the correct health and safety protection means (such as FFP3 masks).
The waste generated by the removal has to be managed as dangerous waste.
About the wall paint sample “106_11_MET01”, analyzed for the evaluation of heavy metals concentrations, a significant concentration of lead (516 mg/kg) was detected. In case of demolition, all precautions should be taken and it is recommended to perform an environmental monitoring for dust dispersion.
1 Note R: The classification as a carcinogen need not apply to fibres with a length weighted geometric mean diameter less two standard geometric errors greater than 6 μm.
| 2020-07-09T15:46:02+0000 | |
| LONGHI SILVIA |
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