Attachment_A._Metals_and_nutrients_characterization.pdf

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Attached to
Request for Information WSSC Water Biosolids Market Research
Solicitation number
121592
Issued by
Prince George's County, Maryland

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Summary

This is a Request for Information (RFI) attachment submitted by WSSC Water (Washington Suburban Sanitary Commission), a Maryland water utility, regarding biosolids product development and market research. The attachment contains detailed chemical characterization data for biosolids and water treatment residuals that WSSC Water is evaluating for blending and beneficial reuse. The RFI seeks information from industry contractors on opportunities to reduce operating costs and establish a sustainable reuse pathway by combining biosolids from WSSC Water's Piscataway Bioenergy Facility with feedstock such as water treatment residuals, sand, and wood fines to improve product quality and value. Contractors are also being solicited for their capability to provide permitted land for biosolids blending and product development operations, with full responsibility for staffing and operational resources.

The chemical characterization data provided includes comprehensive analysis of both Piscataway BioEnergy biosolids and a 50:50 blend of biosolids with Potomac Water Filtration Plant water treatment residuals. The analysis covers physical characteristics (pH, total solids, volatile solids), primary nutrients (nitrogen, phosphorus, potassium), secondary nutrients, micronutrients, 40 CFR 503 regulated metals, and PFAS (per- and polyfluoroalkyl substances) contamination levels. Notably, the Potomac WTR component shows elevated PFAS concentrations across multiple analytes, including PFOS at 0.640 μg/kg and PFHxA at 0.440 μg/kg, which are key considerations for any beneficial reuse pathway development. This market research effort aims to identify viable commercial applications and partners capable of managing these materials at scale.

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Request for Information Biosolids Product Development

Attachment A

Chemical characterization of Piscataway Bioenergy Biosolids and Potomac WFP water treatment residuals (WTR): (50:50 blend dry weight basis)

Parameter

Value

Piscataway BioEnergy Biosolids

BioEnergy biosolids /

Potomac WTR blend

Physical Characteristics pH 7.1 7.4 Total Solids,% 36 45.7 Volatile Solids, % 62.1 36.3 Primary Nutrients (as % unless otherwise noted) Nitrogen (N)

Total 5.55 3.05 Ammonium-N 1.39 0.57 Organic N 4.16 2.48

Phosphorus (P) Total 3.78 1.95 Orthophosphate (P2O5) 8.65 4.46 Water Soluble P, mg/kg 118 38

Potassium (K) Total 0.10 0.11 Potash (K2O) 0.12 0.14

Secondary Nutrients (as % ) Calcium 2.37 1.29 Magnesium 0.25 0.22 Non-503 Micronutrients Iron, % 3.49 2.61 Manganese, mg/dry kg 339.86 629.01 40 CFR 503 Metals (as mg/dry kg ) Cadmium 2.5 1.4 Chromium 18.6 19.2 Copper 480.7 263.1 Lead 18.5 13.7 Mercury 0.35 0.26 Molybdenum 8.3 4.4 Nickel 17.7 20.5 Zinc 788.1 440.5 Other Aluminum, % 2.84 4.46 Soluble Salts, mmhos/cm 3.74 1.18 Calcium Carbonate Equivalent,

10.2 6.9

Phosphorus Source Coefficient 0.10 0.10

Request for Information Biosolids Product Development

Attachment A

Potomac WTR – PFAS characterization Analyte Results (µg/kg)

11Cl-PF3OUdS 0.083

8:2 FTS 0.140

4:2 FTS 0.100

6:2 FTS 0.140

7:3 FTCA 0.420

5:3 FTCA 0.520

3:3 FTCA 0.210

ADONA 0.062

9Cl-PF3ONS 0.094

HFPO-DA 0.110

NEtFOSA 0.100 NEtFOSE 0.310 NEtFOSAA 0.110 NMeFOSA 0.094 NMeFOSE 0.310 NMeFOSAA 0.083

NFDHA 0.073

PFEESA 0.052

PFMPA 0.073

PFMBA 0.052

PFBS 0.073

PFBA 0.140

PFDS 0.052

PFDA 0.080

PFDoS 0.062 PFDoA 0.073 PFHpS 0.073 PFHpA 0.073 PFHxS 0.075 PFHxA 0.440

PFNS 0.073

PFNA 0.062

PFOSA 0.094

PFOS 0.640

PFOA 0.170

PFPeS 0.062 PFPeA 0.500 PFTeDA 0.073 PFTrDA 0.073 PFUnA 0.087

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