Special Waste Characterization Profile

I. Requested Facility Choose all that apply

□ Massachusetts: Southbridge (Southbridge, MA)

□ Maine: Hawk Ridge (Unity, ME)

□ Maine: Juniper Ridge (Old Town, ME) [!I New Hampshire: NCES (Bethlehem, NH)

□ Pennsylvania: McKean (Mt. Jewett, PA)

□ New York: Chemung County (Lowman, NY)

□ New York: Clinton County (Morrisonville, NY)

□ New York: Grasslands (Chateaugay, NY)

□ New York: Hyland (Angelica, NY)

□ New York: Ontario County (Stanley, NY)

[!I Vermont: NEWSVT (Coventry, VT) □ Other: ___________________

II. Generator Name: State of NH, Dept. of Environmental Services, Winnipesaukee River Basin Program, Franklin WWTF

Mailing Address: _P_O_ B_o_x_6_8__5_2_8_R_ iv_e_r _S_tr_e_et____________________________

State: NH ZIP Code: 03235City: Franklin

Contact Name: Sharon A. McMillin

Phone: 603-934-9930 Fax: 603-934-4831

Title: Environmental Program Administrator

Email: sharon.a.mcmillin@des.nh.gov

Ill. Bill To Customer □ Same as Generator above Company Name: Casella Organics - New England Waste Services of ME., Inc. Vendor code #500376 billing to generator

Billing Address: 58 Clifton County Road Suite 200

City: Clifton Park State: NY ZIP Code: _1_2_06_5_____

Contact Name: Matthew Kerschner Title: Staff Accountant

Phone: 518-348-3768 Fax: 518-371-1590 Email: matthew.kerschner@casella.com

IV. Consultant/Representative Company Name: _______________________________________

Contact Name: ________________ Title: ____________________

Phone: ________ Fax: _________ Email: ____________________

V. Delivery and Quantity □ One-Time Event or ~ On-Going (Annually) Amount to Be Delivered (Estimated): 2400 [!I Tons □ Cubic Yards □ Other: _______________

Density of Waste (Approximate): 1700 Pounds/Cubic Yard

Delivery Vehicle: [!I Roll-off □ Packer Truck □ Tractor Trailer □ Vac Truck □ Other: ______________

Hauler Name: Goulet Trucking

Mailing Address: 20 Industrial Drive West, South Deerfield, MA 01373 Phone: 413-665-1322

Transporter Permit #:_M_A_-_1_1_3______________________ (for State of Disposal)

Previous Disposal Facility (Name): _M_e_r_ri_m_a_c_k_W_WT__F__________________________

Application Was Submitted to/Approved by Another Disposal Facility (Name): ___________________

VI. Waste Stream Information Common Waste Name: _W_ R_B_P_B_i_o_so_l_id_s_______________________________

Location or Address ofWaste Generation Site: _5_2_8_R_i_ve_r_S_t_re_e_t_______________________

City: Franklin State: NH ZIP Code: _0_3_2_3_5____ County: Merrimack

Site Type: □ Industrial/Manufacturing □ Commercial □ Residential

□ Institutional □ Municipal [!I Other: State Owned Wastewater Treatment Facility

© 2018 CASELLA WASTE SYSTEMS, INC. I SPECIAL WASTE CHARACTERIZATION PROFILE: REVISED OCT 8, 2018 PAGE 1 OF 2

a. Waste Generation Process □ Check if detailed Process Description is attached as a separate document Describe the site and waste generating process. Please be as detailed as possible. Include a process flow diagram ifavailable.

Municipal wastewater sludge is anaerobically digested and then dewatered after polymer addition via centrifugation. The dewatered sludge (biosolids cake) then falls into a roll off container for transport off site for disposal.

b. Waste Description □ Check if detailed Waste Description is attached as a separate document

Describe the source o contaminants and materials used to enerate the waste. Please be ass eci ic and detailed as ossible.

Municipal wastewater sludge originating from residential and commercial sources. Less than 1 % of incoming flows originate from industrial sources consisting of metal finishers, municipal water treatment solids, brewery, and landfill leachate. Commercial and industrial sources are regulated by the WRBP under its Industrial Pretreatment Program . .

NIA

NIA

Consistency at 70°F: ~ Solid; □ Semi-Solid; □ Sludge; □ Liquid; □ Powder; □ Other __________________

Ignitable (per 40 CFR 261.21): □ Yes ~ No

Reactive (per 40 CFR 261.23): □ Yes ~ No

Free Liquids: □ Yes - No

% Solids:_ 2_4__________________

Odor:___N_o_n_e_________________ pH Range: 7. 7 s.u. - 8.1 s.u. (past year)

Is the waste an EPA listed hazardous waste under 40 CFR 261? □ Yes ~ No

Is the waste non-hazardous waste from a CERCLA site? □ Yes ~ No

Is the waste considered hazardous in the state oforigin or the state of disposal? □ Yes ~ No

Is the waste a treated hazardous waste, a de-listed hazardous waste or subject to land disposal restrictions (LDR) under 40 CFR 268, Subpart D? D Yes ~ No

c. Analytical Data At a minimum, full RCRA waste characterization analysis is required (§ 40 CPR 261) unless the applicant provides acceptable justification for submittal of less comprehensive data. The generator is responsible for proper waste characterization.

Is representative waste characterization analysis attached?

~ Yes ➔ Please complete Appendix A of profile form.

□ No ➔ Please provide detailed explanation supporting the use of generator knowledge in lieu of analysis:

VII. Generator Certification I hereby certify that (1) I am the duly authorized representative of the generator; (2) all information submitted on this form and on supplemental materials is true and accurate; (3) the information provided herein, including any supplemental information, such as laboratory analytical, SDS, etc., accurately describes the waste stream to be delivered to the facility and that all known or suspected hazards have been disclosed; (4) Casella can contact the laboratory directly to discuss our attached waste stream. I understand that once the waste stream is approved by Casella based on this information, any deviation in the source, composition, constituents or characteristics of the waste stream from the information described herein, may render the waste stream unacceptable for disposal, at the sole discretion of Casella. I further understand that any deviation from the information contained herein will require immediate notification to the disposal facility and cessation ofdisposal.

\I \ \,('\!,.· Signature(Generator): __~---------------------------------------- Name (Print): Sharon A. Mcmillin, PhD Company: NHDES-WRBP

Title: Env. Program Adiminstrator Date: 611412024

© 2018 CASELLA WASTE SYSTEMS, INC. I SPECIAL WASTE CHARACTERIZATION PROFILE: REVISED OCT 8, 2018 PAGE 2 OF 2

Appendix A

Additional Waste Stream Information It is the Generator's responsibility to properly characterize the waste and demonstrate it is classified as non-hazardous by State and Federal regulations.

1. Samples

Samples collected and analyzed for waste characterization should be done in accordance with the EPA SW-846 Guidance Document and most recent approved EPA Method(s) for solid wastes.

Number of Samples: __ Grab _1_ Composite

Sample Source: __ Boring(s) __ Test Pit(s) __ Stockpiles(s) Core X Container

Soil/remediation projects must include a site map indicating area ofexcavation and sample locations.

2. Analysis

Please indicate all chemical analysis provided to support waste characterization. All testing must be performed by a laboratory certified in the State the waste is to be disposed in, where applicable.

Laboratory Name: E.asten~ly-.aical Laboratory Accreditation#: _N_H_E_LA_P_#_1_0_1_2________

Applicable Laboratory Report ID #'s: _E_A_I_ID_ #_2_7_9_2_5_8__________________________

Minimum Requirements [!I TCLP RCRA 8 Metals

[!I TCLP Volatile Organic Compounds (VOCs)

[!I TCLP Semi-Volatile Organic Compounds (SVOCs)

[!I TCLP Herbicides

[!I TCLP Pesticides

[!I Reactive Sulfide

[!I Reactive Cyanide

[!I Total PCBs

[!I % Solids (Moisture Content)

[!I Free Liquids (Paint Filter)

[!I Corrosivity by pH

[!I Ignitability / Flashpoint

Additional Requirements [!I Total TPH 1

D Total PAH's 1

D Total Organic Halogens (TOX)

0 TotalBTEX

D TCLP Copper 2

D TCLP Nickel 2

D TCLP Zinc 2

0 TCLP Vanadium 3

[!I Total Sulfur/Sulfate

0 TCLP PCBs

D Total Dioxins & Furans

3. Generator Knowledge Statement

Total Analysis AND Water Leaching Procedure (ASTM) Method D3987

OCOD 2

D Total Solids 2

D Total Volatile Solids 2

D Oil and Grease or Petroleum Hydrocarbons 2

D Ammonia-Nitrogen 2

Other D Radiological analysis: U-238, RA-226, RA-228, TH-232, and K-40 by EPA test procedure 901.1 dry weight analysis expressed in pCi/g.

D Gamma field scans on the material and expressed in uR/hr or uRem/hr.

[!I Safety Data Sheets (SDS)

D Other_______

If the chemical analysis provided does not meet the minimum requirements, please provide an analysis waiver request with justification based on generator's knowledge ofthe process generating the waste.

Although TPH does not exceed acceptable disposal parameters, levels include the necessary introduction of Clarifloc NE-2090 polymer to the dewatering process. Clarifloc is 20-30% petroleum distillate (a C13 compound that is included in the test range of C9-C40). SOS is attached.

1 VT only 2 PA only 3 ME only

© 2018 CASELLA WASTE SYSTEMS, INC. I SPECIAL WASTE CHARACTERIZATION PROFILE: REVISED OCT 8, 2018 PAGE 1 OFl

9 Eastern Analytical, Inc.

professional laboratory and drilling services

Nicholas Fontaine

Franklin WWTP

PO Box 68, River Street Extension

Franklin , NH 03235

Laboratory Report for:

Eastern Analytical, Inc. ID: 279258

Client Identification: Franklin WWTF ICasella

Date Received: 5/29/2024

Enclosed are the analytical results per the Chain of Custody for sample(s) in the referenced project. All analyses were performed in accordance with our QA/QC Program, NELAP and other applicable state requirements. All quality control criteria was within acceptance criteria unless noted on the report pages. Results are for the exclusive use of the client named on this report and will not be released to a third party without consent.

The following information is contained within this report: Sample Conditions summary, Analytical Results/Data, Quality Control data (if requested) and copies of the Chain of Custody. This report may not be reproduced except in full, without the written approval of the laboratory.

The following standard abbreviations and conventions apply to all EAi reports:

< : "less than" followed by the reporting limit > : "greater than" followed by the reporting limit %R: % Recovery

Certifications:

Eastern Analytical, Inc. maintains certification in the following states: Connecticut (PH-0492), Maine (NH005), Massachusetts (M-NH005), New Hampshire/NELAP (1012), Rhode Island (269), Vermont (VT1012), New York (12072) and West Virginia (991 0C). Please refer to our website at www.easternanalytical.com for a copy of our certificates and accredited parameters.

References:

- EPA600/4-79-020, 1983

- Standard Methods for Examination of Water and Wastewater, 20th, 21st, 22nd & 23rd edition or noted revision year.

- Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates IVA and IVB

- Hach Water Analysis Handbook, 4th edition, 1992

- ASTM International

If you have any questions regarding the results contained within, please feel free to contact customer service.

Unless otherwise requested, we will dispose of the sample(s) 6 weeks from the sample receipt date.

We appreciate this opportunity to be of service and look forward to your continued patronage.

Sincerely, Lorraine Olashaw, Lab Director

51 Antrim Avenue • Concord, NH 03301 • 800-287-0525 • www.easternanalytical.com Page 1 of 24 www.easternanalytical.com

SAMPLE CONDITIONS PAGE

EAi ID#: 279258 Client: Capital Well Company, Inc.

Client Designation: Franklin WWTF I Casella

Temperature upon receipt (°C): 1.4 Received on ice or cold packs (Yes/No): y Acceptable temperature range (°C): 0-6

Date Date/Time Sample % Dry Exceptions/Comments Lab ID Sample ID Received Sampled Matrix Weight (other than thermal preservation)

279258.01 Biosolids- 052824 5/29/24 5/28/24 09:49 sludge 23.8 Adheres to Sample Acceptance Policy

All results contained in this reporl relate only to the above listed samples.

Unless otherwise noted:

- Hold times, preservation, container types, and sample conditions adhered to EPA Protocol.

- Solid samples are reporled on a dry weight basis, unless otherwise noted. pH/Corrosivity, Flashpoint, /gnitability, Paint Filter, Conductivity and Specific Gravity are always reporled on an "as received" basis.

- Analysis ofpH, Total Residual Chlorine, Dissolved Oxygen and Sulfite were performed at the laboratory outside of the recommended 15 minute hold time.

- Samples collected by Eastern Analytical, Inc. (EAi) were collected in accordance with approved EPA procedures.

Eastern Analytical, Inc. www.easternanalytical.com I 800.287.0525 I customerservice@easternanalytl2ag:en2 of 24 https://279258.01

LABORATORY REPORT

Client: Franklin WWTP

Client Designation: Franklin WWTF I Casella

Sample ID: Biosolids- 052824

Lab Sample ID: 279258.01

Matrix: sludge

Date Sampled: 5/28/24

Date Received: 5/29/24

Date Extracted:

Result Dilution

Factor Analytical

Matrix Units Date

Analyzed Method Analyst

TCLP Reg Limits (Leachate Cone.)

Vinyl chloride <20 20 TCLPsolid ug/L 6/4/24 8260C MKB 200 ug/I

1 , 1-Dichloroethene <10 20 TCLPsolid ug/L 6/4/24 8260C MKB 700 ug/I 2-Butanone(MEK) < 200 20 TCLPsolid ug/L 6/4/24 8260C MKB 200000 ug/I Chloroform < 20 20 TCLPsolid ug/L 6/4/24 8260C MKB 6000 ug/I Carbon tetrachloride < 20 20 TCLPsolid ug/L 6/4/24 8260C MKB 500 ug/I Benzene < 20 20 TCLPsolid ug/L 6/4/24 8260C MKB 500 ug/I 1,2-Dichloroethane < 20 20 TCLPsolid ug/L 6/4/24 8260C MKB 500 ug/I Trichloroethene <20 20 TCLPsolid ug/L 6/4/24 8260C MKB 500 ug/I Tetrachloroethene < 20 20 TCLPsolid ug/L 6/4/24 8260C MKB 700 ug/I Chlorobenzene < 20 20 TCLPsolid ug/L 6/4/24 8260C MKB 100000 ug/I 1,4-Dichlorobenzene < 20 20 TCLPsolid ug/L 6/4/24 8260C MKB 7500 ug/I 4-Bromofluorobenzene (surr) 93%R TCLPsolid % 6/4/24 8260C MKB 1,2-Dichlorobenzene-d4 (surr) 103 %R TCLPsolid % 6/4/24 8260C MKB Toluene-dB (surr) 105%R TCLPsolid % 6/4/24 8260C MKB

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QC REPORT

Client: Franklin WWTP Batch ID: 638531-12900/T060424TCLPV1

Client Designation: Franklin WWTF I Casella

Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method

Vinyl chloride < 20 20 (98 ¾R) 20 (102 ¾R) (3 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

1, 1-Dichloroethene <10 18 (89 ¾R) 18 (90 ¾R) (1 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

2-Butanone(MEK) < 200 20 (102 ¾R) 20 (105 ¾R) (3 RPO) 6/4/2024 ug/L 40 - 160 20 8260C

Chloroform < 20 19 (95 ¾R) 19 (97 ¾R) (2 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

Carbon tetrachloride < 20 19 (97 ¾R) 20 (99 %R) (2 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

Benzene < 20 20 (99 ¾R) 20 (100 ¾R) (2 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

1,2-Dichloroethane < 20 18 (90 ¾R) 18 (91 ¾R) (2 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

Trich loroethene < 20 20 (98 %R) 20 (100 %R) (2 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

Tetrachloroethene < 20 21 (106 ¾R) 22 (109 %R) (3 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

Chlorobenzene < 20 20 (100 ¾R) 21 (103 %R) (3 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

1,4-Dichlorobenzene < 20 20 (101 ¾R) 21 (103 ¾R) (2 RPO) 6/4/2024 ug/L 70 - 130 20 8260C

4-Bromofluorobenzene (surr) 91 ¾R 94%R 94%R 6/4/2024 % Rec 70 - 130 8260C

1,2-Dichlorobenzene-d4 (surr) 101 ¾R 103 ¾R 102 %R 6/4/2024 % Rec 70 - 130 8260C

Toluene-dB (surr) 106%R 105 %R 107%R 6/4/2024 %Rec 70 - 130 8260C

*/! Flagged analyte recoveries deviated from the QA/QC limits. Data that impacts sample results are noted on the sample report.

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Client: Franklin WWTP

Client Designation: Franklin WWTF I Casella

Sample ID: Biosolids- 052824

Lab Sample ID: 279258.01

Matrix: sludge

Date Sampled: 5/28/24 Date Received: 5/29/24 Date Extracted; 6/10/24

Result Dilution Analytical

Factor Matrix Units Date

Analyzed Method Analyst

TCLP Reg Limits (Leachate Cone.)

2,4,5-Trichlorophenol < 40 40 TCLPsolid ug/L 6/10/24 8270E JMR 400000 ug/I 2,4,6-Trichlorophenol < 40 40 TCLPsolid ug/L 6/10/24 8270E JMR 2000 ug/I Pentachlorophenol < 200 40 TCLPsolid ug/L 6/10/24 8270E JMR 100000 ug/I 2-Methylphenol <40 40 TCLPsolid ug/L 6/10/24 8270E JMR 200000 ug/I 3/4-Methylphenol < 40 40 TCLPsolid ug/L 6/10/24 8270E JMR 200000 ug/I 1,4-Dichlorobenzene < 40 40 TCLPsolid ug/L 6/10/24 8270E JMR 7500 ug/I Hexachloroethane < 40 40 TCLPsolid ug/L 6/10/24 8270E JMR 3000 ug/I Hexachlorobutadiene < 40 40 TCLPsolid ug/L 6/10/24 8270E JMR 500 ug/I Hexachlorobenzene < 40 40 TCLPsolid ug/L 6/10/24 8270E JMR 130 ug/I Nitrobenzene <40 40 TCLPsolid ug/L 6/10/24 8270E JMR 2000 ug/I 2,4-Dinitrotoluene < 80 40 TCLPsolid ug/L 6/10/24 8270E JMR 130 ug/I Pyridine < 200 40 TCLPsolid ug/L 6/10/24 8270E JMR 5000 ug/I 2-Fluorophenol (surr) 35%R TCLPsolid % 6/10/24 8270E JMR Phenol-d6 (surr) 25%R TCLPsolid % 6/10/24 8270E JMR 2,4,6-Tribromophenol (surr) 92%R TCLPsolid % 6/10/24 8270E JMR Nitrobenzene-D5 (surr) 60%R TCLPsolid % 6/10/24 8270E JMR 2-Fluorobiphenyl (surr) 68%R TCLPsolid % 6/10/24 8270E JMR p-Terphenyl-D14 (surr) 73%R TCLPsolid % 6/10/24 8270E JMR

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Client: Franklin WWTP Batch ID: 638536-03607/T061024TCLPA1

Client Designation: Franklin WWTF I Casella

Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method

2,4,5-Trichlorophenol < 1 37 (75 ¾R) 39 (78 ¾R) (4 RPO) 6/10/2024 ug/L 30 - 130 20 8270E

2,4,6-Trichlorophenol < 1 37 (74 ¾R) 39 (77 ¾R) (5 RPO) 6/10/2024 ug/L 30 - 130 20 8270E

Pentachlorophenol <5 36 (72 ¾R) 39 (77 ¾R) (7 RPO) 6/10/2024 ug/L 30 - 130 20 8270E

2-Methylphenol < 1 25 (50 ¾R) 26 (51 ¾R) (2 RPO) 6/10/2024 ug/L 30 - 130 20 8270E

3/4-Methylphenol < 1 26 (52 ¾R) 27 (53 ¾R) (2 RPO) 6/10/2024 ug/L 30 - 130 20 8270E

1,4-0ichlorobenzene < 1 13 (51 ¾R) 13 (52 ¾R) (1 RPO) 6/10/2024 ug/L 40 - 140 20 8270E

Hexachloroethane < 1 13 (51 ¾R) 13 (51 ¾R) (0 RPO) 6/10/2024 ug/L 40 - 140 20 8270E

Hexachlorobutadiene < 1 15 (61 ¾R) 16 (62 ¾R) (2 RPO) 6/10/2024 ug/L 40 - 140 20 8270E

Hexachlorobenzene < 1 19(74%R) 20 (78 ¾R) (5 RPO) 6/10/2024 ug/L 40 - 140 20 8270E

Nitrobenzene < 1 15 (59 ¾R) 15 (60 ¾R) (2 RPO) 6/10/2024 ug/L 40 - 140 20 8270E

2,4-0initrotoluene <2 18 (74 ¾R) 19 (78 ¾R) (5 RPO) 6/10/2024 ug/L 40 - 140 20 8270E

Pyridine <5 9.8 (39 ¾R) 10 (41 ¾R) (5 RPO) 6/10/2024 ug/L 15 - 140 20 8270E

2-Fluorophenol (surr) 34%R 32 ¾R 33%R 6/10/2024 % Rec 15-110 20 8270E

Phenol-d6 (surr) 24%R 22 ¾R 23%R 6/10/2024 % Rec 15-110 20 8270E

2,4,6-Tribromophenol (surr) 93 ¾R 86 ¾R 91 ¾R 6/10/2024 % Rec 15-110 20 8270E

Nitrobenzene-05 (surr) 59 ¾R 60%R 61 ¾R 6/10/2024 % Rec 30 - 130 20 8270E

2-Fluorobiphenyl (surr) 70%R 64%R 66%R 6/10/2024 % Rec 30 - 130 20 8270E p-Terphenyl-014 (surr) 76%R 70%R 73 ¾R 6/10/2024 % Rec 30 - 130 20 8270E

*/! Flagged analyte recoveries deviated from the QA/QC limits. Data that impacts sample results are noted on the sample report.

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Client: Franklin WWTP

Client Designation: Franklin WWTF I Casella

Client Sample ID: Biosolids- 052824

Lab Sample ID: 279258.01

Matrix: sludge

Date Sampled: 5/28/24

Date Received: 5/29/24

Dilution Date / Time Result RL Factor Units Analyzed Method Analyst

TPH (C9-C40) 22000 3000 95 mg/kg 5/30/24 21 :32 8100mod JMR p-Terphenyl-O14 (surr) 94%R % 5/30/24 21 :32 8100mod JMR

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Client: Franklin WWTP Batch ID: 638526-55167/S053024TPH1

Client Designation: Franklin WWTF I Casella

Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method

TPH (C9-C40) < 30 55 (68 %R) 58 (73 %R) (6 RPO) 5/30/2024 mg/kg 30 - 160 30 8100mod p-Terphenyl-D14 (surr) 75%R 77%R 83 %R 5/30/2024 % Rec 30 - 130 8100mod

*/! Flagged analyte recoveries deviated from the QA/QC limits. Data that impacts sample results are noted on the sample report.

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Client: Franklin WWTP

Client Designation: Franklin WWTF I Casella

Sample ID: Biosolids- 052824

Lab Sample ID: 279258.01

Matrix: sludge

Date Sampled: 5/28/24

Date Received: 5/29/24

Date Extracted: 6/5/24

Result Dilution Analytical

Factor Matrix Units Date

Analyzed Method Analyst

TCLP Reg Limits (Leachate Cone.)

Lindane(gamma-BHC) <5 100 TCLPsolid ug/L 6/12/24 8081B MB 400 ug/I Chlordane <10 100 TCLPsolid ug/L 6/12/24 8081B MB 30 ug/I Endrin <5 100 TCLPsolid ug/L 6/12/24 8081B MB 20 ug/I Heptachlor <5 100 TCLPsolid ug/L 6/12/24 8081B MB 8 ug/I Heptachlor Epoxide <5 100 TCLPsolid ug/L 6/12/24 8081B MB 8 ug/I Methoxychlor <5 100 TCLPsolid ug/L 6/12/24 8081B MB 10000 ug/1 Toxaphene < 50 100 TCLPsolld ug/L 6/12/24 8081B MB 500 ug/I TMX (surr) 75%R TCLP solid % 6/12/24 8081B MB DCB (surr) 66%R TC LP sol Id % 6/12/24 8081B MB

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Client: Franklin WWTP Batch ID: 638531-79169/T060524TCLPP1

Client Designation: Franklin WWTF I Casella

Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method

Lindane(gamma-BHC) < 0.05 0.39 (78 %R) 0.39 (78 %R) (0 RPO) 611212024 uglL 40 - 140 20 80818

Chlordane < 0.1 < 0.1 (%R NIA) < 0.1 (%R NIA) (RPO NIA) 611212024 uglL 20 80818

Endrin < 0.05 0.34 (67 %R) 0.37 (74 %R) (10 RPO) 611212024 uglL 40 - 140 20 8081B

Heptachlor < 0.05 0.38 (75 %R) 0.36 (72 %R) (5 RPO) 611212024 uglL 40 - 140 20 8081B

Heptachlor Epoxide < 0.05 0.39 (77 %R) 0.39 (78 %R) (1 RPO) 611212024 uglL 40 - 140 20 8081B

Methoxychlor < 0.05 0.39 (78 %R) 0.40 (80 %R) (3 RPO) 611212024 uglL 40 - 140 20 80818

Toxaphene < 0.5 < 0.5 (%R NIA) < 0.5 (%R NIA) (RPO NIA) 611212024 uglL 80818

TMX (surr) 72%R 72%R 73 %R 611212024 % Rec 30 - 150 20 80818

DCB (surr) 76 %R 77%R 78 %R 611212024 % Rec 30 - 150 20 80818

*/! Flagged analyte recoveries deviated from the QA/QC limits. Data that impacts sample results are noted on the sample report.

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Client: Franklin WWTP

Client Designation: Franklin WWTF I Casella

Client Sample ID: Biosolids- 052824

Lab Sample ID: 279258.01

Matrix: sludge

Date Sampled: 5/28/24

Date Received: 5/29/24 Dilution Date I Time Date Method

Result RL Factor Units Analyzed Prepared Prep Analytical Analyst

PCB-1016 < 1 1 62 mg/kg 6/4/24 13:30 6/3/24 3540C 8082A MB PCB-1221 < 1 1 62 mg/kg 6/4/24 13:30 6/3/24 3540C 8082A MB PCB-1232 < 1 62 mg/kg 6/4/24 13:30 6/3/24 3540C 8082A MB PCB-1242 < 1 62 mg/kg 6/4/24 13:30 6/3/24 3540C 8082A MB PCB-1248 < 1 1 62 mg/kg 6/4/24 13:30 6/3/24 3540C 8082A MB PCB-1254 < 1 1 62 mg/kg 6/4/24 13:30 6/3/24 3540C 8082A MB PCB-1260 < 1 1 62 mg/kg 6/4/24 13:30 6/3/24 3540C 8082A MB PCB-1262 < 1 62 mg/kg 6/4/24 13:30 6/3/24 3540C 8082A MB PCB-1268 < 1 62 mg/kg 6/4/24 13:30 6/3/24 3540C 8082A MB TMX (surr) 95%R % 6/4/24 13:30 6/3/24 3540C 8082A MB DCB (surr) 48 ¾R % 6/4/24 13:30 6/3/24 3540C 8082A MB

Acid clean-up was performed on the samples and associated batch QC .

Detection limits elevated due to sample matrix, a low solids content and in response to the lower initial mass used for analysis.

Eastern Analytical, Inc. www.easternanalytical.com I 800.287.0525 I customerservice@easternanalp~~r.,11 of 24 mailto:customerservice@easternanalp~~r.,11

EAi I 0#: 279258 Client: Franklin WWTP Batch ID: 638530-12112/S060324PCB2

Client Designation: Franklin WWTF I Casella

Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method

PCB-1016 < 0.02 0.12 (90 %R) 0.13 (94 %R) (4 RPD) 6/4/2024 mg/kg 40 - 140 30 8082A

PCB- 1221 < 0.02 < 0.02 (%RN/A) < O.Q2 (%R N/A) (RPD N/A) 6/4/2024 mg/kg 8082A

PCB-1232 < 0.02 < 0.02 (%RN/A) < 0.02 (%RN/A) (RPD NIA) 6/4/2024 mg/kg 8082A

PCB-1242 < 0.02 < 0.02 (%RN/A) < 0.02 (%RN/A) (RPD N/A) 6/4/2024 mg/kg 8082A

PCB-1248 < 0.02 < 0.02 (%RN/A) < 0.02 (%RN/A) (RPD N/A) 6/4/2024 mg/kg 8082A

PCB-1254 < 0.02 < 0.02 (%R NIA) < 0.02 (%RN/A) (RPD N/A) 6/4/2024 mg/kg 8082A

PCB-1260 < 0.02 0.12 (92 %R) 0.13 (96 %R) (4 RPD) 6/4/2024 mg/kg 40 - 140 30 8082A

PCB-1262 < 0.02 < 0.02 (%R NIA) < 0.02 (%RN/A) (RPD N/A) 6/4/2024 mg/kg 8082A

PCB-1268 < 0.02 < 0.02 (%R NIA) < 0.02 (%RN/A) (RPD NIA) 6/4/2024 mg/kg 8082A

TMX (surr) 95 %R 92 %R 98 %R 6/4/2024 % Rec 30 - 150 30 8082A

DCB (surr) 92 %R 91 %R 97 %R 6/4/2024 % Rec 30 - 150 30 8082A

*/I Flagged analyte recoveries deviated from the QA/QC limits. Data that impacts sample results are noted on the sample report.

Eastern Analytical, Inc. www.easternanalytical.com I 800.287.0525 I customerservice@easternanalf'iag.e:ir1i2 of 24 mailto:customerservice@easternanalf'iag.e:ir1i2

Client: Franklin WWTP

Client Designation: Franklin WWTF I Casella

Sample ID: Biosolids- 052824

Lab Sample ID: 279258.01

Matrix: sludge

Date Sampled: 5/28/24 Analytical Analysis Date Received: 5/29/24 Matrix Units Date Time Method AnalystRL

Solids Total 23.8 SolAsRec Percen 5/30/24 11:15 2540G-11 ASF

Sulfate <40 40 SolTotDry mg/kg 5/30/24 17:00 9056A ALS pH 7.73 0.1 SolAsRec SU 5/31/24 11:00 9045D PHA lgnltability Pass SolAsRec None 5/30/24 13:30 1030 PHA

Reactive Cyanide < 1 1 SolTotDry mg/kg 6/6/24 9:07 7.3.3.2 PHA

Reactive Sulfide < 10 10 SolTotDry mg/kg 6/6/24 9:07 7.3.4.2 PHA

Paint Filter (Free Liquid) Absent SolAsRec None 6/10/24 16:20 9095 MNT

Due to the sample matrix, the pH method was modified to add approximately 1 0g of sample to 20ml of water.

Eastern Analytical, Inc. www.easternanalytical.com I 800.287.0525 I customerservice@easternanaly~~~c~rlJi of 3 24 https://279258.01

EAi I 0#: 279258

Client: Franklin WWTP

Client Designation: Franklin WWTF I Casella

Date of Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method

Solids Total < 1 NA NA Percent 5/30/24 2540G-11

Sulfate <10 180 (96 %R) 190 (97 %R) (1 RPD) mg/kg 5/30/24 90 - 110 15 9056A pH NA 7.93 (99 %R) 7.95 (99 %R) (0 RPD) SU 5/31/24 7.91 - 8.09 10 9045D

Reactive Cyanide < 1 11(12%R) NA mg/kg 6/6/24 0 - 73 7.3.3.2

Reactive Sulfide < 10 < 10 (30 %R) NA mg/kg 6/6/24 10 - 160 7.3.4.2

*/! Flagged analyte recoveries deviated from the QA/QC limits. Unless noted, flagged data does not impact the sample data.

Eastern Analytical, Inc. www.easternanalytical.com I 800.287.0525 I customerservice@easternana1~9~m of14 24

Client: Franklin WWTP

Client Designation: Franklin WWTF I Casella

Sample ID: Biosolids- 052824

Lab Sample ID: 279258.01

Matrix: sludge

Date Sampled:

Date Received:

5/28/24

5/29/24 RL

Analytical

Matrix Units Analysis Date Method Analyst

Arsenic < 0.5 0.5 TCLPsolid mQ/L 6/05/24 6020A OS Barium < 0.5 0.5 TCLPsolid mQ/L 6/05/24 6020A OS Cadmium < 0.1 0.1 TCLPsolid mQ/L 6/05/24 6020A OS Chromium < 0.1 0.1 TCLPsolid mQ/L 6/05/24 6020A OS Lead < 0.5 0.5 TCLPsolid mQ/L 6/05/24 6020A OS Mercury < 0.01 0.01 TCLPsolid mQ/L 6/05/24 6020A OS Selenium < 0.1 0.1 TCLPsolid mQ/L 6/05/24 6020A OS Silver < 0.1 0.1 TCLPsolid mQ/L 6/05/24 6020A OS

Eastern Analytical, Inc. www.easternanalytical.com I 800.287.0525 I customerservice@easternanaliffi~ri15 of 24

Client: Franklin WWTP

Client Designation: Franklin WWTF I Casella

Date of Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method

Arsenic < 0.5 1.0 (99 %R) NA mg/L 6/5/24 80 - 120 20 6020A

Barium < 0.5 1.0 (97 %R) NA mg/L 6/5/24 80 - 120 20 6020A

Cadmium < 0.1 1.0 (100 %R) NA mg/L 6/5/24 80 - 120 20 6020A

Chromium < 0.1 1.0 (100 %R) NA mg/L 6/5/24 80 - 120 20 6020A

Lead < 0.5 1.0 (97 %R) NA mg/L 6/5/24 80 - 120 20 6020A

Mercury < 0.01 0.09 (90 %R) NA mg/L 6/5/24 80 - 120 20 6020A

Selenium < 0.1 1.0 (103 %R) NA mg/L 6/5/24 80 - 120 20 6020A

Silver < 0.1 1.0 (97 %R) NA mg/L 6/5/24 80 - 120 20 6020A

*/! Flagged analyte recoveries deviated from the QA/QC limits . Unless noted, flagged data does not impact the sample data.

Eastern Analytical, Inc. www.easternanalytical.com I 800.287.0525 I customerservice@easternanal~rrl 6 of 24

Friday, June 07, 2024

Attn: Front Office Eastern Analytical 51 Antrim Ave Concord, NH 03301

Project ID: 279258

SDGID: GCQ83601

Sample ID#s: CQ83601

This laboratory is in compliance with the NELAC requirements of procedures used except where indicated.

This report contains results for the parameters tested, under the sampling conditions described on the Chain Of Custody, as received by the laboratory. This report is incomplete unless all pages indicated in the pagination at the bottom of the page are included.

A scanned version of the COC form accompanies the analytical report and is an exact duplicate of the original.

If you are the client above and have any questions concerning this testing, please do not hesitate to contact Phoenix Client Services at ext.200. The contents of this report cannot be discussed with anyone other than the client listed above without their written consent.

Sincerely yours, pe.J:, j~ Laboratory Director

NJ Lab Registration #CT-003 NELAC -#NY11301 NY Lab Registration #11301 CT Lab Registration #PH-0618 PA Lab Registration #68-03530 MA Lab Registration #M-CT007 RI Lab Registration #63 ME Lab Registration #CT-007 VT Lab Registration #VT11301 NH Lab Registration #213693-A,B

587 East Middle Turnpike, P.O. Box 370, Manchester, CT 06040 Telephone (860) 645-1102

Page 1 of7

PHOENIX _.

Environmental Laboratories, Inc.

587 East Middle Turnpike, P.O.Box 370, Manchester, CT 06045 Tel. (860) 645-1102 Fax (860) 645-0823

Sample Id Cross Reference June 07, 2024

SDG I.D.: GCQ83601

Project ID: 279258

Client Id Lab Id Matrix

IBIOSOLIDS-052824 IC083601 !SLUDGE

Page 2of7

PHOENIX

587 East Middle Turnpike, P.O.Box 370, Manchester, CT 06045 Tel. (860) 645-1102 Fax (860) 645-0823

FOR: Attn: Front OfficeAnalysis Report Eastern Analytical

June 07, 2024 51 Antrim Ave Concord, NH 03301

Sample Information Custody Information Date

Matrix: SLUDGE Collected by: 05/28/24

Location Code: EASTANAL-NH Received by: SR1 05/30/24 15:00

Rush Request: Standard Analyzed by: see "By" below

P.O.#: 62529 SDG ID: GCQ83601Laboratory Data

Phoenix ID: CQ83601

Project ID: 279258

Client ID: BIOSOLIDS-052824

RU

Parameter Result PQL Units Dilution Date/Time By Reference

TCLP Herbicides Extraction

TCLP Extraction for Organics

Completed

Completed

06/04/24

05/30/24

CV/D

AL

SW8150 MOD

SW1311

TCLP Herbicides 2,4,5-TP (Silvex) 2,4-D

QA/QC Surrogates

%DCM

% DCM (Confirmation)

ND

ND

ug/L ug/L

06/05/24

06/05/24

06/05/24

06/05/24

JRB

JRB

JRB

JRB

SW8461 311 /8151

SW846 1311/8 151

30-150 %

30 - 150 %

RUPQL=Reporting/Practical Quantitation Level (Equivalent to NELAC LOQ, Limit of Quantltation) ND=Not Detected at RUPQL BRL=Below Reporting Level L=Biased Low QA/QC Surrogates: Surrogates are compounds (preceeded with a %) added by the lab to determine analysis efficiency. Surrogate results(%) listed in the report are not "detected" compounds.

Comments:

If you are the client above and have any questions concerning this testing, please do not hesitate to contact Phoenix Client Services at ext.200.

The contents of this report cannot be discussed with anyone other than the client listed above without their written consent.

Pe!.~Labd!±,o, June 07, 2024

Reviewed and Released by: Anll Makol, Project Manager

Ver1

Page 3 of7

PHOENIX .:

587 East Middle Turnpike, P.O.Box 370, Manchester, CT 06045 Tel. (860) 645-1102

QA/QC Report June 07, 2024 QA/QC Data SDG I.D.: GCQ83601

Blk LCS LCSD LCS MS MSD MS Rec RPD

Parameter Blank RL % % RPD % % RPD Limits Limits

QA/QC Batch 734231 (ug/L), QC Sample No: CQ86004 10X (CQ83601)

TCLP Herbicides 2,4,5-TP (Silvex) ND 50 94 94 0.0 112 40-140 20

2,4-D ND 100 93 83 11.4 108 40- 140 20

% DCM 62 % 72 67 7.2 83 30-150 20

% DCAA (Confirmation) 57 o/o 68 65 4.5 79 30-150 20

Comment:

Additional criteria: LCS acceptance range is 40-140% MS acceptance range 30-150%.

If there are any questions regarding this data , please call Phoenix Client Services at extension 200.

RPD - Relative Percent Difference

LCS - Laboratory Control Sample

LCSD - Laboratory Control Sample Duplicate

MS - Matrix Spike

MS Dup - Matrix Spike Duplicate

NC - No Criteria

I ntf - Interference

Page 4 of7

'<j" N-0

Friday, June 07, 2024

Criteria: None

State: NH

SampNo Acode Phoenix Analyte

Sample Criteria Exceedances Report

GCQ83601 - EASTANAL-NH

Criteria Result RL Criteria

RL

Criteria Analysis

Units

N Q.)

0) co a..

*** No Data to Display***

Phoenix Laboratories does not assume responsibility for the data contained in this exceedance report. It is provided as an additional tool to identify requested criteria exceedences. All efforts are made to ensure the accuracy of the data (obtained from appropriate agencies). A lack of exceedence information does not necessarily suggest conformance to the criteria. It is ultimately the site professional's responsibility to determine appropriate compliance.

Page 5 ofl

PHOENIX:

587 East Middle Turnpike, P.O.Box 370, Manchester, CT 06045 Tel. (860) 645-1102 Fax (860) 645-0823

Analysis Comments June 07, 2024 SDG I.D.: GCQ83601

The following analysis comments are made regarding exceptions to criteria not already noted in the Analysis Report or QA/QC Report: None.

custon-ferservice@·easterna

'<j"

•,Z. Eastern Analytical,. Inc.

professional laboratory and drilling servicesCHAIN-OF-CUSTODY RECORD

Sample ID Date Sampled Matrix

Biosolids- 052824 5/28/2024 Isludge

109:49

EAi ID# 279258 Project State: NH

Project ID: 618

Company Phoenix Environmental Labs

Address 587 East Middle Turnpike

Address Manchester , CT 06040

Account#

Phone# (860) 645-1102

Eastern Analytical, Inc. 51 Antrim Ave Concord, NH 03301 Phone: (603)228-0525 1-800-287-0525 As a subcontract lab to EAi, you will defend, indemnify and hold Eastern Analytical, Inc., its officers, employees, and agents harmless from and against any and all liability, loss, expense or clajm,'ror injury or damages arising out of the performance against this chain of custody but only in proportion to and to the extent such liability, loss, expense, or claims for injury or damages are caused by or result from 1/lr{ negligent or intentional acts or omissions of you as a subcontract lab, your officers, agents or employees

EAi ID# 279258 Page 1 aParameters Sam.e,le Notes

'-ISubcontract-TCLP Herbicides 1311/8151

2 ✓½~'zs3C2cD \

Results Needed: Preferred Date: Standard

RUSH Due Date:

QC Deliverables ----

0 A □ A+ 1818 OB+ De OMAMCP

Notes about project:

Email login confirmation, pdf of results and invoice to customerservice@eastemanalytical.com.

P0#:62529 EAi ID# 279258 Data Deliverable (circle)

Excel NH EMD EQulS ME EGA

Call prior to analyzing, if RUSH charges will be applied.

N

N Q.)

0) co a..

mailto:customerservice@eastemanalytical.com

CHAIN-OF-CUSTODY RECORD 279258

Page ___ of ___ ~-BOLD FIELDS REQUIRED. PLEASE CIRCLE REQUESTED ANALYSIS.

5~ 2"t -'2. '\ -=t '. ,q, DATE: TIME: RECEIVED BY:

s-2.1-2..,1 \ l'-3 (i ,t-(o,·

: ):~.. ,<\; ';)~:: ':-~~'>: :;:.~ ':j~/ ;(-.;,~.< J w

I- .::, SAMPLING ..I iii ~

DATE /TIME

w 0 n.co :Ew

*IF COMPOSITE,

w 0 ~ u ~~

INDICATE BoTH ~ *-- ~

Ill:'. =co .... g SAMPLE I.D. I START & FINISH t: <!'. = 0Ill:'.

DATE/TIME I: CJ

o,oso\\o<Ji -rti.08Jif I Bl"\11 - Ol[q~ ff/a.sj~Y S C.

MATRIX:l=AIR; 5-SOIL; GW-GROUND WATER; sw:suRFACE WATER; OW-DRINKING WATER;

WW-WASTE WATER

PRESERVATIVE: H-HCL; N-HN0

; S-H

S0

; Na-NaOH; M-MEOH

PROJECT MANAGER: .h\w:ll~foec::c-._:__J'r;,'-"-"\V\..('.,..=,_____ _______

COMPANY: t.:,\\-\OtS-""1'2.GP

ADDRE SS: 6°'22> t,.... er s.\,,re~ .... '

ClTY: 6:on\t.,\\"" STATE: _t-IH ZIP: o?,21,S

PHONE: Lp03 -G\"b4- 2so~ EXT.: ___ _

E-MAIL: ~l> l;,S . d. £01"\l-iilliY. @des. n \.t. %=-o_,,_✓ _ _

SITE NAME: F'<-af'-1(..\, ""- WWT'-

PROJECT#: Case\la

STATE: ~ MA ME VT OTHER: _ ________

REGULATORY PROGRAM: NPDES: RGP POTW STORMWATER OR

GWP, Oil FUND, BROWNFIELD OR OTIIER: _ ______ _ _ _

QUOTE#: - - ------ PO#:________

~,: I~ l~:I = 0.. 1:.::~1 r' -·1 ,~~, ~?;;; ~::z:::......; i:;;:::< 0

= -o O. 1--ci"

= ;"'.= = = = ~= 0.. = = =< ,- =

QA/QC REPORTING

A B C

MAMCP

TEMP. \ · Lj '(

ICE? {jjj) No

RELINQUISHED BY:

~~I :;:; l=I..._J- 0 1l-J I

0..0..

x I /)(IXllC I

REPORTINAO PTIONS

PRELIMS: 1$' OR No

ELECTRONIC OPTIONS

PDF Exm

EQUI S

OTHF.R ____

1.- ::::-1 o...

I l< I I I X

TURN AROUND TIME

24hr* 48hr*

3-4 Days*

S Day /1J1f

10~

*Pre-approval Required

DATE: TIME:

I I ,■, Ulg 3 \j

01 ~ g~ "° ~t=! :::::..- t;; 0

~ ~ 2- <::)

= \lO \.. ~ I NOTES0 "" -z ::; :,:: :c

~ MEOH VIAL #

sl ~ ~ 0 'It

~ j. )( 7

METALS: ~ 13 PP FE, MN PB, Cu

OTHER METALS: _ _____ _____

SAMPLES FIELD FILTERED? 0 YES O NO

NOTEl: (IE: SPECIAL DETECTION LIMITS, BILLING ltlFO, IF DIFFERENT)

*See "\r\-.)G'wo..a J. S\.u.4,\.- w \ co~lt.~t:

L~~r llC:- f>"a'l'?,rv-a,\,~r :>

SITE HISTORY: ____________

SUSPECTED (ONTAMINATION:_________

FIELD READINGS: ___________RELINQUISHED BY: DATE: TIME: RECEIVED BY:

• Eastern Analytical, Inc. 51 Antrim Avenue / CONCORD, NH 03301 J TEL: 603,228.0525 / 1.800.287.0525 / E-MAIL: CUSTOMERSERVICE@EASTERNANALYTICALCOM / www.EASTERNANALYTICALCOM prqfessional /aboratonJ and drilling· services (WHITE: Lab Copy GREEN: Customer Copy) www.EASTERNANALYTICALCOM

/SNF POLYDYNE 1

SAFETY DATA SHEET

According to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Productidentifier

Product name: CLARIFLOC™ NE-2090

Type ofproduct: Mixture.

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses: Processing aid for industrial applications.

Uses advised against: None.

1.3. Details of the supplier of the safety data sheet

Polydyne Inc.

Company: 1 Chemical Plant Road

PO BOX 279, Riceboro, GA 31323 United States

Telephone: 1-800-848-7659

Telefax: (912)-884-8770

E-mail address:

104. Emergency telephone number

24-hour emergency number: 1-800-424-9300

SECTION 2: Hazards identification

2. 1. Classification of the substance or mixture

Classification according to paragraph {d} of29 CFR 1910.1200:

Not classified.

2.2. Label elements

Labelling according to paragraph (0 of29 CFR 1910.1200:

Print Date: 06/12/2019 Revision date: 10/14/2019 Page: 1114

SAFETY DATA SHEET CLARIFLOC™ NE-2090

Hazard symbol(s):

Signal word:

Hazard statement(s):

Precautionary statement(s):

2.3. Other hazards

Spills produce exi:remely slippery surfaces.

For explanation of abbreviations see Section 16.

SECTION 3: Composition/Information on ingredients

3.1. Substances

Not applicable, this product is a mixture.

3.2. Mixtures

This product is a mixture.

Hazardous components

Distillates (petroleum), hydrotreated light

Concentration/ -range:

CASNumber:

Classification according to paragraph (d) of29 CFR 1910.1200:

Notes

None.

None.

None.

None.

20 - 30%

64742-47-8

Asp. Tox. l;H304

Does not result in classification ofthe mixture ifthe kinematic viscosity is greater than 20.5 mm2/s measured at 40°C.

Poly(oxy-1, 2-ethanediyl), a-tridecyl-w-hydroxy-, branched

Concentration/ -range:

CASNumber:

Classification according to paragraph (d) of29 CFR 1910.1200:

For explanation of abbreviations see section 16

<5%

69011-36-5

AcuteTox. 4;H302, Eye Dam. l;H318

Print Date: 06/12/2019 Revision date: 10/14/2019 Page: 2/ 14

CLARIFLOC™ NE-2090SAFETY DATA SHEET

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

Move to fresh air. No hazards which require special first aid measures.

Skin contact:

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. In case of persistent skin irritation, consult a physician.

Eye contact:

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately.

Ingestion:

Rinse mouth with water. Do NOT induce vomiting. Call a physician or poison control centre immediately.

4.2. Most important symptoms and effects, both acute and delayed

None under normal use.

4.3. Indication ofany immediate medical attention and special treatment needed

None reasonably foreseeable.

Other information:

None.

SECTION 5: Firefighting measures

5. 1. Extinguishing media

Suitable extinguishing media:

Water. Water spray. Foam. Carbon dioxide (CO2). Dry powder.

Warning! Spills produce extremely slippery surfaces.

Unsuitable extinguishing media:

None known.

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition products:

Ammonia. Carbon oxides (COx). Nitrogen oxides (NOx). Hydrogen chloride. Hydrogen cyanide (hydrocyanic acid) may be produced in the event of combustion in an oxygen deficient atmosphere.

5.3. Advice for firefighters

Protective measures:

Wear self-contained breathing apparatus and protective suit.

Other information:

Spills produce exiremely slippery surfaces.

Print Date: 06/12/2019 Revision date: 10/14/2019 Page: 3/ 14

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions:

Do not touch or walk through spilled material. Spills produce e.xiremely slippery surfaces.

Protective equipment:

Wear adequate personal protective equipment (see Section 8 Exposure Controls/Personal Protection).

Emergency procedures:

Keep people away from spilVleak. Prevent further leakage or spillage if safe to do so.

6.2. Environmental precautions

As with all chemical products, do not flush into surface water.

6.3. Methods and material for containment and cleaning up

Small spills:

Do not flush with water.Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal.

Large spills:

Do not flush with water.Dam up. Soak up with inert absorbent material. Clean up promptly by scoop or vacuum.

Residues:

After cleaning, flush away traces with water.

6.4. Reference to other sections

SECTION 7: Handling and storage; SECTION 8: Exposure controls/personal protection; SECTION 13: Disposal considerations;

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid contact with skin and eyes. Renders surfaces extremely slippery when spille<l. When using, do not eat, drink or smoke.

7.2. Conditions for safe storage, including any incompatibilities

Keep away from heat and sources of ignition. Freezing will affect the physical condition and may damage the material.

Incompatible with oxidizing agents.

7.3. Specific end use(s)

This information is not available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits:

Print Date: 06/12/2019 Revision date: 10/14/2019 Page: 4/ 14

Distillates (petroleum), hydrotreated light ACGIH:200 mg/m3 (8 hours) (vapors)

8.2. Exposure controls

Appropriate engineering controls:

Ensure adequate ventilation, especially in confined areas. Use local exhaust if misting occurs. Natural ventilation is adequate in absence of mists.

Individual protection measures, such as personal protective equipment:

a) Eye/face protection:

Safety glasses with side-shields.

b} Skin protection:

i) Hand protection: PVC or other plastic material gloves.

ii) Other: Wear coveralls and/or chemical apron and rubber footwear where physical contact can occur.

,,,,----.. c) Respiratory protection:

No personal respiratory protective equipment normally required.

d) Additional advice:

Wash hands before breaks and immediately after handling the product. Wash hands before breaks and at the end of workday. Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls.·

Do not allow uncontrolled discharge of product into the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

a) Appearance: Viscous liquid, Milky.

b) Odour: Aliphatic.

c) Odour Threshold: No data available.

d)pH: 3.5 - 6.5 @ 5 g/L (See Technical Bulletin or Product Specifications for precise value)

e) Melting point/freezing point: <5°C

OInitial boiling point and boiling range: > 100°C

g) Flash point: Does not flash.

h) Evaporation rate: No data available.

Print Date: 06/12/2019 Revision date: 10/14/2019 Page: 5/ 14

SAFETY DATA SHEET

i) Flammability (solid, gas):

j) Upper/lower flammability or explosive limits:

k) Vapour pressure:

I) Vapour density:

m) Relative density:

n) Solubility(ies):

o) Partition coefficient:

p) Autoignition temperature:

q) Decomposition temperature:

r) Viscosity:

s) Explosive properties:

t) Oxidizing properties:

9.2. Other information

None.

SECTION 10: Stability and reactivity

10. 1. Reactivity

Stable under recommended storage conditions.

10.2. Chemical stability

Stable under re.commended storage conditions.

10.3. Possibility of hazardous reactions

Oxidizing agents may cause exothermic reactions.

10.4. Conditions to avoid

Protect from frost, heat and sunlight.

10.5. Incompatible materials

Oxidizing agents.

10.6. Hazardous decomposition products

CLARIFLOC™ NE-2090 ,'------'.

Not applicable.

Not expected to create explosive atmospheres.

2.3 kPa @ 20°C

0.804 g/litre@ 20°c

1.0 - 1.2

Completely miscible.

Not applicable.

Not applicable.

> 150°C

> 20.5 mm2/s @ 40°C

Not expected to be explosive based on the chemical structure.

Not expected to be oxidising based on the chemical structure.

Thermal decomposition may produce: hydrogen chloride gas, nitrogen oxides (NOx), carbon oxides (COx). Ammonia.

Hydrogen cyanide (hydrocyanic acid) may be produced in the event of combustion in an oxygen deficient atmosphere.

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SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on the product as supplied:

Acute oral toxicity:

Acute dermal toxicity:

Acute inhalation toxicity:

Skin corrosion/irritation:

Serious eye damage/eye irritation:

Respiratory/skin sensitisation:

Mutagenicity:

Carcinogenicity:

Reproductive toxicity:

,,,..--, STOT - Single exposure:

STOT - Repeated exposure:

Aspiration hazard:

LD50/oral/rat > 5000 mg/kg (Estimated)

LD50/dermal/rat > 5000 mg/kg. (Estimated)

The product is not expected to be toxic by inhalation.

Non-irritating to skin.

Not irritating. (OECD 437)

Not sensitizing.

Not mutagenic.

Not carcinogenic.

Not toxic for reproduction.

No known effects.

No known effect.

Due to the viscosity, this product does not present an aspiration hazard.

Relevant information on the hazardous components:

Distillates (petroleum), hydrotreated light

Acute oral toxicity:

Acute dermal toxicity:

Acute inhalation toxicity:

Skin corrosion/irritation:

Serious eye damage/eye irritation:

Respiratory/skin sensitisation:

Mutagenicity:

LD50/oral/rat > 5000 mg/kg (OECD 401)

LD50/dermal/rabbit > 5000 mg/kg (OECD 402)

LC0/inhalation/4 hours/rat>= 4951 mg/m3 (OECD 403) (Based on results obtained from tests on analogous products)

Not irritating. (OECD 404) Repeated exposure may cause skin dryness or cracking.

Not irritating. (OECD 405)

By analogy with similar products, this product is not expected to be sensitizing.

(OECD406)

Not mutagenic. (OECD 471, 473, 474, 476, 478, 479)

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Carcinogenicity:

Reproductive toxicity:

STOT - Single exposure:

STOT - Repeated exposure:

Aspiration hazard:

Carcinogenicity study in rats (OECD 451): Negative.

By analogy with sinular substances, this substance is not expected to be toxic for reproduction. NOAEL/rat = 300 ppm. (OECD 421)

No known effects.

NOAEL/oral/rat/90 days >= 3000 mg/kg/day (OECD 408) (Based on results obtained from tests on analogous products)

May be fatal if swallowed and enters airways.

Poly(oxy-1,2-ethanediyl), a-tridecyl-w-hydrmy-, branched

Acute oral toxicity:

Acute dermal toxicity:

Acute inhalation toxicity:

Skin corrosionlirdtation:

Serious eye damage/eye irritation:

Respiratory/skin sensitisation:

Mutagenicity:

Carcinogenicity:

Reproductive toxicity:

STOT - Single exposure:

STOT - Repeated exposure:

Aspiration hazard:

LOSO/oral/rat= 500 - 2000 mg/kg

LD50/dennal/rabbit > 2000 mg/kg

No data available.

Not irritating. (OECD 404)

Causes serious eye irritation. (OECD 405)

The results of testing on guinea pigs showed this material to be non-sensitizing.

In vitro tests did not show mutagenic effects. In vivo tests did not show mutage1uc effects.

Based on the absence of mutagenicity, it is unlikely that the substance is carcinogenic.

Two-Generation Reproduction Toxicity (OECD 416)

- NOAEL/rat > 250 mg/kg/day Prenatal Development Toxicity Study (OECD 414)

- NOAEL/Maternal toxicity/rat> 50 mg/kg/day

- NOAEL/Developmental toxicity/rat> 50 mg/kg/day

No known effects.

NOAEL/oral/rat/600 days = 50 mg/kg/day

No known effects.

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SECTION 12: Ecological information

12. 1. Toxicity

Information on the product as supplied:

Acute toxicity to fish:

Acute toxicity to invertebrates:

Acute toxicity to algae:

Chronic toxicity to fish:

Chronic toxicity to invertebrates:

Toxicity to microorganisms:

Effects on terrestrial organisms:

Sediment toxicity:

LC50/Fish/96 hours == 10 - 100 mg/L (Estimated)

EC50/Daphnia magna/48 hours == 10 - 100 mg/L (Estimated)

Algal inhibition tests are not appropriate. The flocculation characteristics of the product interfere directly in the test medium preventing homogenous distribution which invalidates the test.

No data available.

No data available.

No data available.

No data available.

No data available.

Relevant information on the hazardous components:

Distillates (petroleum), hydrotreated light

Acute toxicity to fish:

Acute toxicity to invertebrates:

Acute toxicity to algae:

Chronic toxicity to fish:

Chronic toxicity to invertebrates:

Toxicity to microorganisms:

Effects on terrestrial organisms:

Sediment toxicity:

LC0/Oncorhynchus mykiss/96 hours> 1000 mg/L. (OECD 203)

EC0/Daphnia magna/48 hours> 1000 mg/L (OECD 202)

IC0/Pseudokirchneriella subcapitata/72 hours> 1000 mg/L. (OECD 201)

NOEC/Oncorhynchus mykiss/28 days > 1000 mg/L

NOEC/Daphnia magna/21 days > 1000 mg/L

EC50/Tetrahymena pyriforrnis/ 48h > 1000 mg/L.

No data available.

No data available. Readily biodegradable, exposure to sediment is unlikely.

Poly(oxy-1, 2-ethanediyl), a-tridecyl-w-hydroxy-, branched

Acute toxicity to fish: LC50/Cyprinus carpio/96 hours == 1 - 10 mg/L (OECD 203)

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Acute toxicity to invertebrates:

Acute toxicity to algae:

Chronic toxicity to fish:

Chronic toxicity to invertebrates:

Toxicity to microorganisms:

Effects on terrestrial organisms:

Sediment toxicity:

12.2. Persistence and degradability

Information on the product as supplied:

Degradation:

Hydrolysis:

Photolysis:

ECS0/Daphnia/48 hours= 1 - 10 mg/L (OECD 202)

IC50/Desmodesmus subspicatus/72 hours= 1 - 10 mg/L (OECD 201)

No data available.

NOEC/Daphnia magna/21 days > 1 mg/L (OECD 202)

ECl0/activated sludge/17 hours> 10000 mg/L (DIN 38412-8)

No data available.

No data available.

Based on degradation data of components, this product is expected to be readily (bio )degradable.

At natural pHs (>6) the polymer degrades due to hydrolysis to more than 70% in 28 days. The hydrolysis products are not harmful to aquatic organisms.

No data available.

Relevant information on the hazardous components:

Distillat…