Purell Advanced Hand Sanitizer SDS.docx

)SAFETY DATA SHEET "-Goio>, PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SOS Number: 400000005869 Revision Date: 04/21/2020

SECTION 1. IDENTIFICATION

Product name PURELL® Advanced Hand Sanitizer Sanitizing Gel Manufacturer or supplier's details Company name of supplier GOJO Industries, Inc. Address One GOJO Plaza, Suite 500 Akron, Ohio 44311 Telephone 1 (330) 255-6000

Emergency telephone number

CHEMTREC 1-800-424-9300

CHEMTREC +1-703-527-3887: Outside USA & CANADA

Recommended use of the chemical and restrictions on use

Recommended use Restrictions on use

Hand Sanitizer This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SOS for the consumer. While this material is not considered hazardous, this SOS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SOS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification Flammable liquids Eye irritation GHS label elements Hazard pictograms

Signal word Hazard statements

Precautionary statements

Category 3 Category 2A

Warning

H226 Flammable liquid and vapour. H319 Causes serious eye irritation.

Prevention:

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P233 Keep container tightly closed.

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Version 1.0 SOS Number: 400000005869 Revision Date: 04/21/2020

P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge. P280 Wear eye protection/ face protection.

Response:

P305 + P351 + P338 IF IN_EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 If eye irritation persists: Get medical advice/ attention.

P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Storage:

P403 + P235 Store in a well-ventilated place. Keep cool.

Disposal:

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

SECTION 4. FIRST AID MEASURES

General advice

If inhaled

In case of skin contact In case of eye contact

If swallowed

Most important symptoms and effects, both acute and delayed Protection of first-aiders

In the case of accident or if you feel unwell, seek medical advice immediately.

When symptoms persist or in all cases of doubt seek medical advice.

If inhaled, remove to fresh air.

If symptoms persist, call a physician.

Wash with water and soap as a precaution.

Get medical attention if irritation develops and persists.

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.

If easy to do, remove contact lens, if worn. Seek medical advice.

If swallowed, DO NOT induce vomiting. Rinse mouth with water.

Obtain medical attention. Causes serious eye irritation.

First Aid responders should pay attention to self-protection and use the recommended protective clothing

SECTION 5. FIREFIGHTING MEASURES

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Suitable extinguishing media

Unsuitable extinguishing media Specific hazards during firefighting

Hazardous combustion products

Specific extinguishing methods

Further information

Special protective equipment for firefighters

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

High volume water jet

Do not use a solid water stream as it may scatter and spread fire.

Cool closed containers exposed to fire with water spray. Flash back possible over considerable distance.

May form explosive mixtures in air.

Exposure to decomposition products may be a hazard to health.

Carbon oxides Carbon oxides

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Use water spray to cool unopened containers.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Environmental precautions

Methods and materials for containment and cleaning up

Use personal protective equipment. Ensure adequate ventilation.

Remove all sources of ignition. Evacuate personnel to safe areas.

Keep people away from and upwind of spill/leak. Material can create slippery conditions.

Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water.

Local authorities should be advised if significant spillages cannot be contained.

Non-sparking tools should be used. Soak up with inert absorbent material.

Suppress (knock down) gases/vapours/mists with a water spray jet.

Keep in suitable, closed containers for disposal.

Clean contaminated floors and objects thoroughly while observing environmental regulations.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling For personal protection see section 8.

Keep away from heat.

Use with local exhaust ventilation. Avoid contact with eyes.

GOJ

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Version 1.0 SOS Number: 400000005869 Revision Date: 04/21/2020

Conditions for safe storage Take measures to prevent the build up of electrostatic charge.

Keep in properly labelled containers.

Keep container tightly closed in a dry and well-ventilated place.

Store in accordance with the particular national regulations.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Permissible concentration Basis

1,900 m /m3

NIOSH REL

1,900 mg/m3

OSHAZ-1

Personal protective equipment Respiratory protection

Hand protection Remarks Eye protection

Skin and body protection Protective measures

Hygiene measures

No personal respiratory protective equipment normally required.

No special protective equipment required.

Wear face-shield and protective suit for abnormal processing problems.

No special protective equipment required.

Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.

Ensure that eye flushing systems and safety showers are located close to the working place.

Handle in accordance with good industrial hygiene and safety practice.

Avoid contact with eyes.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Colour Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas)

Flammability (liquids) gel clear, colourless, yellow citrus No data available 6.5 - 8.5, (20 °c) No data available 70 ·c 25 ·c No data available Not applicable No data available

SAFETY DATA SHEET "-Goj6) :PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SOS Number: 400000005869 Revision Date: 04/21/2020

Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Density Solubility(ies) Water solubility

Partition coefficient: n octanol/water Auto-ignition temperature Thermal decomposition Viscosity Viscosity, kinematic

Explosive properties Oxidizing properties

No data available No data available No data available No data available

0.87 g/cm3 soluble

Not applicable not determined The substance or mixture is not classified self-reactive.

3500 - 23000 mm2/s (20 °C)

Not explosive

The substance or mixture is not classified as oxidizing.

SECTION 10. STABILITY AND REACTIVITY

Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products

Not classified as a reactivity hazard. Stable under normal conditions.

Vapours may form explosive mixture with air.

Heat, flames and sparks. Oxidizing agents No hazardous decomposition products are known.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure Inhalation Eye contact Skin contact Acute toxicity Not classified based on available information.

Components:

Ethyl Alcohol:

Acute oral toxicity Acute inhalation toxicity

LOSO (Rat): > 5,000 mg/kg LCS0 (Rat): 124.7 mg/I

GOJO

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Version 1.0 SOS Number: 400000005869 Revision Date: 04/21/2020

Exposure time: 4 h Test atmosphere: vapour

Skin corrosion/irritation Not classified based on available information.

Components:

Ethyl Alcohol:

Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation

Serious eye damage/eye irritation Causes serious eye irritation.

Components:

Ethyl Alcohol:

Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405

Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information.

Components:

Ethyl Alcohol:

Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: negative

Germ cell mutagenicity Not classified based on available information.

Components:

Ethyl Alcohol:

Genotoxicity in vitro

Genotoxicity in vivo

Test Type: In vitro mammalian cell gene mutation test Result: negative

Test Type: Rodent dominant lethal test (germ cell) (in vivo) Test species: Mouse Application Route: Ingestion Result: negative

Carcinogenicity Not classified based on available information.

IARC

OSHA

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential

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"-Goio>

)PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SOS Number: 400000005869 Revision Date: 04/21/2020 carcinogen by OSHA.

NTP

No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity

Components:

Ethyl Alcohol:

Effects on fertility Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion . Method: OECD Test Guideline 416 Result: negative

STOT - single exposure Not classified based on available information.

STOT - repeated exposure Not classified based on available information.

Repeated dose toxicity Components:

Ethyl Alcohol:

Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y

Aspiration toxicity

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity Components:

Ethyl Alcohol:

Toxicity to fish

Toxicity to daphnia and other aquatic invertebrates

Toxicity to algae

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

LC50 (Pimephales promelas (fathead minnow)):> 1,000 mg/I Exposure time: 96 h

EC50 (Daphnia magna (Water flea)): > 1,000 mg/I Exposure time: 48 h

EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/I Exposure time: 72 h Method: OECD Test Guideline 201

NOEC (Daphnia magna (Water flea)): 9.6 mg/I Exposure time: 9 d

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Toxicity to bacteria EC50 (Photobacterium phosphoreum): 32.1 mg/I Exposure time: 0.25 h Persistence and degradability Components:

Ethyl Alcohol:

Biodegradability Result: Readily biodegradable.

Biodegradation: 84 % Exposure time: 20 d

Bioaccumulative potential Components: Ethyl Alcohol:

Partition coefficient: n octanol/water Mobility in soil No data available Other adverse effects No data available Product:

Regulation

Remarks log Pow: -0.35

40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances

This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A+ B).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods Waste from residues Contaminated packaging

Dispose of in accordance with local regulations. Dispose of as unused product.

Empty containers should be taken to an approved waste handling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulation IATA-DGR UN/ID No.

Proper shipping name Class Packing group Packing instruction (cargo aircraft) Packing instruction (passenger aircraft)

UN 1170

Ethanol solution Ill 366

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)PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SOS Number: 400000005869 Revision Date: 04/21/2020

IMDG-Code UN number Proper shipping name Class Packing group Labels Ems Code Marine pollutant National Regulations

49 CFR

UN/ID/NA number Proper shipping name Class Packing group ERG Code Marine pollutant

ETHANOL SOLUTION 3

Ill F-E, S-D no

Ethanol solutions 3 Ill 127 no

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

SARA 311/312 Hazards

SARA 302

SARA 313

Fire Hazard Acute Health Hazard

No chemicals in this material are subject to the reporting requirements of SARA Title Ill, Section 302.

This material does not contain any chemical components with known GAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title Ill, Section 313.

Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61).

This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).

The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489):

Ethyl Alcohol 64-17-5 65.2815 % This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450.

Clean Water Act This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307

California Prop 65 This product does not require a warning label under California Proposition 65.

The components of this product are reported in the following inventories:

TSCA : On TSCA Inventory

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Version 1.0 SOS Number: 400000005869 Revision Date: 04/21/2020

AICS DSL ENCS ISHL KECI PICCS IECSC

NZloC

On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory

Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZloC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS Ill:

Flammability

:5 <ii Q) I

5" igfr

Special hazard.

HEALTH FLAMMABILITY

I

)I PHYSICAL HAZA

0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, • = Chronic

Revision Date : 04/21/2020 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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