Cleace Hand Sanitizer SDS.docx

Effective

Dat,e:

2020/03/0

DG2001191

E

Page of

SAFETY DATA SHEET

CLEACE HAND SANITIZER

NANJING AOGRAND INTERNATIONAL TRADE CORPORATION.

· According to GHS (Seventh Revised Edition)

SDS

· Product Identifier Product Name Synonyms

Section 1 Product and Company Identification

CLEACE HAND SANITIZER

· Relevant Identified Uses of the Substance or Mixture and Uses Advised Against

Relevant Identified Uses Uses Advised Against

Please consult manufacturer. Please consult manufacturer.

· Details of the Supplier of the Safety Data Sheet Applicant Name NANJING AOGRAND INTERNATIONAL TRADE CORPORATION.

Application Address Applicant Post Code Applicant Telephone Applicant Fax Applicant E-mail Supplier Name Supplier Address Supplier Post Code Supplier Telephone Supplier Fax Supplier E-mail

NO.205 SHUANGGAO ROAD, QIQIAO INDUSTRIAL PARK, GAOCHUN DISTRICT NANJING CITY, P.R.CHINA 211302 211302 +86-25-57853789 doc@aogrand.com

NANJING AOGRAND INTERNATIONAL TRADE CORPORATION.

NO.205 SHUANGGAO ROAD, QIQIAO INDUSTRIAL PARK, GAOCHUN DISTRICT NANJING CITY, P.R.CHINA 211302 211302 +86-25-57853789

S@aogrand.com

· Emergency Phone Number

Emergency Phone Number

+86-25-57850785

Section 2 Hazards Identification

Hazard class and label elements of the product according to GHS (the seventh revised edition):

· GHS Hazard Class

Flammable Liquids

· GHS Label Elements

Category 2

Pictogram

HAND

SANITIZER

DG2001191E

Page of

Signal Word

· Hazard Statements H225

Danger

Highly flammable liquid and vapour

· Precautionary Statements Prevention

P210 P233 P240 P241 P242 P243 P280 Response P370+P378 P303+P361 +P353 Storage P403+P235 Disposal P501

Keep away from heat, hot surfaces, sparks,open flames and other ignition sources. No smoking.

Keep container tightly closed.

Ground and bond container and receiving equipment.

Use explosion-proof [electrical/ventilating/lighting] equipment. Use non-sparking tools.

Take action to prevent static discharges.

Wear protective gloves/protective clothing/eye protection/face protection.

In case of fire: Use dry chemical, carbon dioxide or alcohol-resistant foam to extinguish.

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

Store in a well-ventilated place. Keep cool.

Dispose of contents/container in accordance with local/regional/national/ international regulations.

Section 3 Composition/Information on Ingredients percent,%) Ethanol Commercial secrets 64-17- 200-578- Acrylic acid

Polymers Commercial secrets 9003-01- 202-415- Trolamine Commercial secrets 102-71- 203-049- Water Commercial secrets 7732-18- 231-791- )Component Concentration (weight CAS No.

EC No.

Section 4 First Aid Measures

· Description of First Aid Measures

General Advice Eye Contact Skin Contact Ingestion Inhalation

Immediate medical attention is required. Show this safety data sheet (SOS) to the doctor in attendance.

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician if feel uncomfortable.

Take off contaminated clothing and shoes immediately. Wash off with plenty of water for at least 15 minutes and consult a physician if feel uncomfortable.

Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately.

Move victim into fresh air. If breathing is difficult, give oxygen. Do not use mouth to mouth resuscitation if victim ingested or inhaled the substance. If not

Protecting of First-aiders breathing, give artificial respiration and consult a physician immediately.

Ensure that medical personnel are aware of the substance involved. Take precautions to protect themselves and prevent spread of contamination.

· Most Important Symptoms and Effects, both Acute and Delayed 1 Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.

· Indication of Any Immediate Medical Attention and Special Treatment Needed 1 Treat symptomatically.

2 Symptoms may be delayed.

Section 5 Fire Fighting Measures

>Extinguishing Media Suitable Extinguishing Media Unsuitable Extinguishing Media

Dry chemical, carbon dioxide or alcohol-resistant foam.

Do not use a solid water stream as it may scatter or spread fire.

> Specific Hazards Arising from the Substance or Mixture 1 Will form explosive mixtures with air.

2 Fire exposed containers may vent contents through pressure relief valves thereby increasing fire intensity and/ or vapour concentration.

3 Vapours may travel to source of ignition and flash back.

4 Liquid and vapour are flammable.

5 Containers may explode when heated.

6 Fire exposed containers may vent contents through pressure relief valves.

7 May expansion or decompose explosively when heated or involved in fire.

· Advice for Firefighters 1 As in any fire, wear self-contained breathing apparatus (MSHA/NIOSH approved or equivalent)and full protective gear.

2 Fight fire from a safe distance, with adequate cover.

3 Prevent fire extinguishing water from contaminating surface water or the ground water system.

Section 6 Accidental Release Measure

>Personal Precautions, Protective Equipment and Emergency Procedures 1 Avoid breathing vapors and contacting with skin and eye.

2 Beware of vapours accumulating to form explosive concentrations.

3 Vapours can accumulate in low areas.

)Emergency personnel wear positive pressure self-contained breathing apparatus. Wear protective and anti-static clothing. Wear chemical impermeable gloves.

5 Ensure adequate ventilation. Remove all sources of ignition.

6 Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

7 Use personal protective equipment. Avoid breathing vapours, mist, gas or dust.

> Environmental Precautions

1 Prevent further leakage or spillage if safe to do so.

2 Discharge into the environment must be avoided.

> Methods and Materials for Containment and Cleaning Up 1 Absorb spilled material in dry sand or inert absorbent. In case of large amount of spillage, contain a spill by bunding.

2 Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

3 Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

Section 7 Handling and Storage

>Precautions for Handling 1 Avoid inhalation of vapors.

2 Use only non-sparking tools.

)To prevent fire caused by electrostatic discharge steam, equipment on all metal parts should be grounded.

4 Use explosion proof equipment.

5 Handling is performed in a well ventilated place.

6 Wear suitable protective equipment.

7 Avoid contact with skin and eyes.

8 Keep away from heat/sparks/open flames/ hot surfaces.

9 Take precautionary measures against static discharges.

> Precautions for Storage 1 Keep containers tightly closed.

2 Keep containers in a dry, cool and well-ventilated place.

3 Keep away from heat/sparks/open flames/ hot surfaces.

4 Store away from incompatible materials and foodstuff containers.

Section 8 Exposure Controls/Personal Protection

> Control Parameters I Exposure Limit Val

Component

Country/Region

Ethanol 64-17-5

Troiamine , 102-71-6

Biological Limit Values No information available Monitoring Methods 1 EN 14042 Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.

)GBZ/T 160 Determination of toxic substances in workplace air(Series effective standard)and GBZ/T 300 Determination of toxic substances in workplace air(Series standard).

> Engineering Controls 1 Ensure adequate ventilation, especially in confined areas.

2 Ensure that eyewash stations and safety showers are close to the workstation location.

3 Use explosion-proof electrical/ventilating/lighting/equipment.

4 Set up emergency exit and necessary risk-elimination area.

> Personal Protection Equipment Eye Protection Tightly fitting safety goggles (approved by EN 166(EU) or NIOSH (US).

Hand Protection

Wear protective gloves (such as butyl rubber) , passing the tests according to EN 374(EU),US F739 or AS/NZS 2161.1 standard.

If exposure limits are exceeded or if irritation or other symptoms are

Respiratory protection experienced, use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges.

Skin and Protection

Body Wear fire/flame resistant/retardant clothing and antistatic boots.

Section 9 Physical and Chemical Properties

Upper/lower explosive limits[%(v/v)]: Upper limit:

Flammability: Not applicable

Vapor Pressure (KPa): No information available Relative Density(Water=1): No information available

No information available; Lower limit: No information available Relative Vapour Density(Air = 1): No information available Solubility: No information available

Particle characteristics: Not applicable

Section 10 Stability and Reactivity

Reactivity Contact with incompatible substances can cause decomposition or other chemical reactions.

Hazardous Reactions explosion. In contact with active metals (alkali metals, Na, Ca etc.) causes a reaction and release hydrogen.

Conditions to Avoid Incompatible materials, heat, flame and spark.

Incompatible Materials Oxidants, alkali metals, alkaline earth metals and aluminum. Alkali, sodium, calcium, and other active metal, halogen, metal oxide, nonmetal oxide, acyl halide and metal phosphide.

Hazardous Decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 11 Toxicological Information

· Acute Toxicity

Acrylic acid Polymers

9003-01-4

2500mg/kg(Rat)

102-71-6

5846mg/kg(Mouse)

Ethanol

64-17-5

7060mg/kg(Rat) No information available

39mg/L(Mouse)

· Skin Corrosion/Irritation No information available

· Serious Eye Damage/Irritation No information available

· Skin Sensitization No information available

· Respiratory Sensitization No information available

· Germ Cell Mutagenicity No information available

· Carcinogenicity

· Reproductive Toxicity

· Reproductive Toxicity {Additional) No information available

· STOT-Single Exposure No information available

· STOT-Repeated Exposure No information available

· Aspiration Hazard

Section 12 Ecological Information

· Acute Aquatic Toxicity

102-71-6 LCso: 11800mg/L (96h)(Fish)

ECso: 610mg/L (48h) No information available

Ethanol

64-17-5 Cso: 11000mg/L (96h)(Fish)

ECso: 9950mg/L (48h) No information available

· Chronic Aquatic Toxicity

· Others

Persistence and Degradability Bioaccumulative Potential Mobility in Soil

Results of PBT and vPvB Assessment

No information available No information available Ethanol does not meet the criteria for PBT and vPvB according to Regulation (EC) No 1907/2006, annex XIII.

Acrylic acid Polymers does not meet the criteria for PBT and vPvB according to Regulation (EC) No 1907/2006, annex XIII.

Trolamine does not meet the criteria for PBT and vPvB according to Regulation (EC) No 1907/2006, annex XIII.

Water does not meet the criteria for PBT and vPvB according to Regulation (EC) No 1907/2006, annex XIII.

Section 13 Disposal Considerations

Waste Chemicals

Contaminated Packaging

Before disposal should refer to the relevant national and local laws and regulation. Recommend the use of incineration disposal.

Containers may still present chemical hazard when empty. Keep away from hot and ignition source of fire. Return to supplier for recycling if possible.

Disposal Recommendations

Refer to section 13.1and 13.2.

Marine pollutant

UN Number UN Proper Shipping Name Transport Hazard Class Transport Subsidiary Hazard Class Packing Group

None

ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 3

NONE

II

Section 15 Regulatory Information

· International Chemical Inventory

Ethanol

Acrylic acid Polymers

X

X

Trolamine

Water

X

[EINECS] [TSCA]

[DSL] [IECSC] [NZloC] [PICCS] [KECI]

[AICS]

[ENCS]

European Inventory of Existing Commercial Chemical Substances. United States Toxic Substances Control Act Inventory.

Canadian Domestic Substances List.

China Inventory of Existing Chemical Substances. New Zealand Inventory of Chemicals.

Philippines Inventory of Chemicals and Chemical Substances. Existing and Evaluated Chemical Substances.

Australia Inventory of Chemical Substances. Existing And New Chemical Substances.

Note "v" Indicates that the substance included in the regulations "x" That no data or included in the regulations

Section 16 Additional Information

Creation Date

2020/03/04

Reason for Revision

· Disclaimer This Safety Data Sheet (SOS) was prepared according to UN GHS (the 7th revised edition). The data included was derived from international authoritative database and provided by the enterprise. Other information was based on the present state of our knowledge. We try to ensure the correctness of all information. However, due to the diversity of information sources and the limitations of our knowledge, this document is only for user' s reference. Users should make their independent judgment of suitability of this information for their particular purposes. We do not assume responsibility for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product.