3. Safety Data Sheet.pdf

PHOS-CHEK® LC95A-Fx

Concentrate Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.

Date of issue: 03/18/2019 Revision date: 02/25/2022 Version: 1.2

02/25/2022 EN (English US) Page 1

SECTION 1: Identification

1.1. Identification

Product form : Mixture Product name : PHOS-CHEK® LC95A-Fx Concentrate

1.2. Recommended use and restrictions on use

Use of the substance/mixture : Fire retardant used for wildland fire control

1.3. Details of the supplier or manufacturer or distributor of the safety data sheet Perimeter Solutions 10667 Jersey Blvd.

Rancho Cucamonga CA, 91730 T 1-800-682-3626

1.4. Emergency telephone number

Emergency number : CHEMTREC 800-424-9300

CANUTEC 613-996-6666

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture

GHS US classification Not classified

2.2. GHS Label elements, including precautionary statements

GHS US labeling No labeling applicable

2.3. Other hazards which do not result in classification

No additional information available

2.4. Unknown acute toxicity (GHS US)

Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances

3.2. Mixtures

Name Product identifier % Ammonium Polyphosphate Solution (CAS-No.) Trade secret > 85 Attapulgus Clay (CAS-No.) 8031-18-3 < 5 Performance Additives

(CAS-No.) Trade secret < 8

*Chemical name, CAS number and/or exact concentration have been withheld as a trade secret

SECTION 4: First-aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell.

First-aid measures after skin contact : If skin irritation occurs: Wash skin with plenty of water. Obtain medical attention if irritation persists.

First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

First-aid measures after ingestion : Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell.

4.2. Most important symptoms and effects (acute and delayed)

Symptoms/effects after inhalation : May cause irritation to the respiratory tract.

PHOS-CHEK® LC95A-Fx Concentrate Safety Data Sheet

02/25/2022 EN (English US) 2/5

Symptoms/effects after skin contact : May cause skin irritation. Repeated exposure may cause skin dryness or cracking.

Symptoms/effects after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling.

Symptoms/effects after ingestion : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea.

4.3. Immediate medical attention and special treatment, if necessary Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

Unsuitable extinguishing media : None known.

5.2. Specific hazards arising from the chemical

Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. Ammonia and phosphoric acid may be formed when product is heated above 90 °C (194 °F).

5.3. Special protective equipment and precautions for fire-fighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

6.2. Environmental precautions

Prevent entry to sewers and public waters.

6.3. Methods and material for containment and cleaning up

For containment : Absorb and/or contain spill with inert material (sand, vermiculite or other appropriate material), then place in suitable container. Do not flush into surface water or sewer system. Wear recommended personal protective equipment.

Methods for cleaning up : Sweep or shovel spills into appropriate container for disposal. Avoid dust formation. Provide ventilation.

6.4. Reference to other sections

For further information refer to section 8: "Exposure controls/personal protection"

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid breathing dust, mist. Avoid generating dust. Avoid contact with skin, eyes and clothing.

Do not swallow. Handle and open container with care. When using do not eat, drink or smoke.

Use only outdoors or in a well-ventilated area.

Hygiene measures : Wash contaminated clothing before reuse. Always wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in well ventilated area.

Store locked up.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Ammonium polyphosphate solution (Trade secret)

Attapulgus Clay (8031-18-3)

02/25/2022 EN (English US) 3/5

Performance Additives (Trade secret)

8.2. Appropriate engineering controls

Appropriate engineering controls : Ensure good ventilation of the work station.

Environmental exposure controls : Not applicable when used as intended.

8.3. Individual protection measures/Personal protective equipment

Hand protection:

Wear suitable gloves

Eye protection:

Safety glasses or goggles are recommended when using product.

Skin and body protection:

Wear suitable protective clothing

Respiratory protection:

Avoid breathing vapour or mist. Use NIOSH/MSHA approved respiratory protection equipment when airborne exposure limits are exceeded.

Consult respirator manufacturer to determine appropriate type equipment for given application. Observe respirator use limitations specified by NIOSH / MSHA or the manufacturer. Refer to U.S. OSHA regulations 29 CFR 1910.134 or European Standard EN 149."

Other information:

Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Appearance : Pinkish Liquid Color : No data available

Odor : Odorless

Odor threshold : No data available pH : 5 - 6.5

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Relative evaporation rate (butyl acetate=1) : No data available

Flammability (solid, gas) : No data available

Vapor pressure : No data available

Relative vapor density at 20 °C : No data available

Relative density : 1.445 - 1.485 g/ml @ 25 ºC / 77 °F

Solubility : Water: > 95 %

Partition coefficient n-octanol/water : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : 101 - 400 cP

Explosion limits : No data available

Explosive properties : No data available

Oxidizing properties : No data available

9.2. Other information

02/25/2022 EN (English US) 4/5

SECTION 10: Stability and reactivity

10.1. Reactivity

No dangerous reactions known under normal conditions of use.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

Heat.

10.5. Incompatible materials

None known.

10.6. Hazardous decomposition products

May include, and are not limited to: oxides of carbon. Ammonia and phosphoric acid may be formed when product is heated above 90 °C (194 °F).

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Not classified

LD50 oral rat > 5050 mg/kg LD50 dermal rabbit > 2020 mg/kg

Skin corrosion/irritation : Not classified pH: 5 - 6.5

Skin Irritation rabbit 0.0/8.0 (24-hr. exp.) nonirritating

Serious eye damage/irritation : Not classified pH: 5 - 6.5

Eye Irritation rabbit 10.2/110.0 minimally irritating

Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity – single exposure : Not classified Specific target organ toxicity – repeated exposure

: Not classified

Aspiration hazard : Not classified Symptoms/effects after inhalation : May cause irritation to the respiratory tract.

Symptoms/effects after skin contact : May cause skin irritation. Repeated exposure may cause skin dryness or cracking.

Symptoms/effects after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling.

Symptoms/effects after ingestion : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : May cause long-term adverse effects in the aquatic environment.

LC50 fish 1 399 mg/l

02/25/2022 EN (English US) 5/5

12.2. Persistence and degradability

Persistence and degradability Not established.

12.3. Bioaccumulative potential

Bioaccumulative potential Not established.

12.4. Mobility in soil

12.5. Other adverse effects

Other information : No other effects known.

SECTION 13: Disposal considerations

13.1. Disposal methods

Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.

SECTION 14: Transport information

Department of Transportation (DOT) In accordance with DOT

SECTION 15: Regulatory information

15.1. US Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory.

15.2. International regulations

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

Date of issue : 03/18/2019 Revision date : 02/25/2022 Other information : None.

Prepared by : Nexreg Compliance Inc.

www.Nexreg.com

NFPA health hazard : 0

NFPA fire hazard : 0 NFPA reactivity : 0

Hazard Rating Health : 0 Minimal Hazard Flammability : 0 Minimal Hazard Physical : 0 Minimal Hazard

SDS US (GHS HazCom 2012)_NEXREG_NEW

Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use.

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