2025_066_ITB___Chemicals Odor Control_Appendi.pdf

APPENDICES: SAFETY DATA SHEETS FOR

ODOR CONTROL CHEMICALS

(Line Item Nos. 1–11)

APPENDIX 1: Line Item No. 1

SAFETY DATA SHEET

ZEP DEO-3_1GAL_4CT

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Material name : ZEP DEO-3_1GAL_4CT

Material number : 000000000000177924

Manufacturer or supplier's details

Company : Zep Inc.

Address : 350 Joe Frank Harris Parkway, SE Emerson, GA 30137

Telephone : Compliance Services - 877-428-9937

Emergency telephone numbers

For SDS Information : Compliance Services - 877-428-9937

For a Medical Emergency : 877-541-2016 Toll Free - All Calls Recorded

For a Transportation Emergency

: CHEMTREC: 800-424-9300 - All Calls Recorded.

In the District of Columbia 202-483-7616

Recommended use of the chemical and restrictions on use

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance liquid

Colour blue, clear

Odour strong, sweet

GHS Classification

Eye irritation : Category 2A Skin sensitisation : Category 1

GHS label elements

Hazard pictograms :

Exclamation mark

Signal word : Warning

Hazard statements : H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

Precautionary statements : Prevention:

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

P264 Wash skin thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves/ eye protection/ face protection.

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Response:

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.

P337 + P313 If eye irritation persists: Get medical advice/ attention.

P363 Wash contaminated clothing before reuse.

Disposal:

P501 Dispose of contents/container in accordance with local regulation.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous components

Chemical name CAS-No. Concentration [%]

2-methylpentane-2,4-diol 107-41-5 >= 5 - < 10

Alcohols, C12-16, ethoxylated 68551-12-2 >= 3 - < 5

Alcohols, C9-11, ethoxylated 68439-46-3 >= 1 - < 3 cinnamaldehyde 104-55-2 >= 0.1 - < 1

Oils, sweet orange (terpenes and terpenoids) 68647-72-3 >= 0.1 - < 1

The exact percentages of disclosed substances are withheld as trade secrets.

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Show this safety data sheet to the doctor in attendance.

Do not leave the victim unattended.

If inhaled : Call a physician or poison control centre immediately.

If unconscious, place in recovery position and seek medical advice.

In case of skin contact : If skin irritation persists, call a physician.

Wash off immediately with plenty of water for at least 15 minutes.

Remove contaminated clothing and shoes.

Wash contaminated clothing before reuse.

In case of eye contact : Rinse immediately with plenty of water for at least 15 minutes.

Remove contact lenses.

Protect unharmed eye.

Keep eye wide open while rinsing.

If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear.

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Do not give milk or alcoholic beverages.

Never give anything by mouth to an unconscious person.

If symptoms persist, call a physician.

Take victim immediately to hospital.

Most important symptoms and effects, both acute and delayed

: Effects are dependent on exposure (dose, concentration, contact time).

Effects are immediate and delayed.

Symptoms may include irritation, redness, pain, and rash.

Symptoms may include shortness of breath, dry cough, and irritation of the nose, eyes, lips, mouth, and throat.

May cause an allergic skin reaction.

Causes serious eye irritation.

Review section 2 of SDS to see all potential hazards.

Causes skin irritation.

Notes to physician : Treat symptomatically. Symptoms may be delayed.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media

: High volume water jet

Specific hazards during firefighting

: Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion products

: Carbon dioxide (CO2) Carbon monoxide Smoke

Specific extinguishing methods

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Special protective equipment for firefighters

: Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Use personal protective equipment.

Ensure adequate ventilation.

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.

If the product contaminates rivers and lakes or drains, inform respective authorities.

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Methods and materials for containment and cleaning up

: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Avoid formation of aerosol.

Do not breathe vapours/dust.

Avoid exposure - obtain special instructions before use.

Avoid contact with skin and eyes.

For personal protection see section 8.

Smoking, eating and drinking should be prohibited in the application area.

Provide sufficient air exchange and/or exhaust in work rooms.

Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place.

Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Electrical installations / working materials must comply with the technological safety standards.

Materials to avoid : Oxidizing agents Do not store near acids.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type (Form of exposure)

Control parameters / Permissible concentration

Basis

2-methylpentane-2,4-diol 107-41-5 C 25 ppm ACGIH

C 25 ppm 125 mg/m3

NIOSH REL

C 25 ppm 125 mg/m3

OSHA P0

C 25 ppm 125 mg/m3

CAL PEL

Engineering measures : effective ventilation in all processing areas

Personal protective equipment

Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.

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Hand protection Material : Protective gloves Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves.

Eye protection : Access to clean water to rinse eyes must be available, options include: eye wash stations or showers, or eye wash bottles with pure water.

Tightly fitting safety goggles

Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Hygiene measures : When using do not eat or drink.

When using do not smoke.

Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : blue, clear

Odour : strong, sweet

Odour Threshold : No data available pH : 8 - 8.5

Melting point/freezing point : No data available

Boiling point : 100 °C

Flash point : > 93.3 °C Method: closed cup

Evaporation rate : 1

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapour pressure : No data available

Relative vapour density : No data available

Density : 1.003 g/cm3

Bulk density : No data available

Solubility(ies)

Water solubility : soluble in hot water, soluble in cold water

Solubility in other solvents : soluble

Partition coefficient: n-octanol/water

: No data available

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Auto-ignition temperature : not determined

Thermal decomposition : No data available

Viscosity

Viscosity, dynamic : No data available

Viscosity, kinematic : 4.8 mm2/s (20 °C)

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Stable

Chemical stability : Stable under normal conditions.

Possibility of hazardous reactions

: No decomposition if stored and applied as directed.

Conditions to avoid : No data available

Incompatible materials : Oxidizing agents Acids

Hazardous decomposition products

: Carbon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects

Aggravated Medical Condition

: None known.

Symptoms of Overexposure : Effects are dependent on exposure (dose, concentration, contact time).

Effects are immediate and delayed.

Symptoms may include irritation, redness, pain, and rash.

Symptoms may include shortness of breath, dry cough, and irritation of the nose, eyes, lips, mouth, and throat.

May cause an allergic skin reaction.

Causes serious eye irritation.

Review section 2 of SDS to see all potential hazards.

Causes skin irritation.

Treat symptomatically. Symptoms may be delayed.

Carcinogenicity:

IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

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ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

Acute toxicity

Product:

Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method

Components:

2-methylpentane-2,4-diol:

Acute oral toxicity : LD50 Oral Rat: 3,700 mg/kg

Alcohols, C9-11, ethoxylated:

Acute oral toxicity : LD50 Oral Rat: 1,400 mg/kg cinnamaldehyde:

Acute oral toxicity : LD50 Oral Rat: 2,220 mg/kg

Skin corrosion/irritation

Product:

Remarks: Irritating to skin.

Serious eye damage/eye irritation

Product:

Remarks: Severe eye irritation

Respiratory or skin sensitisation

Product:

Remarks: Causes sensitisation.

Components:

cinnamaldehyde:

Classification: May cause sensitisation by skin contact.

Oils, sweet orange (terpenes and terpenoids):

Classification: May cause sensitisation by skin contact.

Germ cell mutagenicity

No data available

Carcinogenicity

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No data available

Reproductive toxicity

No data available

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available

Further information

Product:

Remarks: No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

No data available

Persistence and degradability

No data available Bioaccumulative potential

Product:

Partition coefficient: n-octanol/water

: Remarks: No data available

Components:

2-methylpentane-2,4-diol :

Partition coefficient: n-octanol/water

: Pow: 0.58 cinnamaldehyde :

Partition coefficient: n-octanol/water

: Pow: 1.83

Mobility in soil

No data available

Other adverse effects

No data available Product:

Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances

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Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S.

Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological information

: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Toxic to aquatic life.

The GHS H401 statement “Toxic to aquatic life” noted above is an Acute Aquatic Toxicity Category 2 classification. Although the product has the potential to harm the environment, it is not classified as a marine pollutant or regulated under transportation regulations.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : The product should not be allowed to enter drains, water courses or the soil.

Do not contaminate ponds, waterways or ditches with chemical or used container.

Dispose of in accordance with local regulations.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.

Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

Transportation Regulation: 49 CFR (USA):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IMDG (Vessel):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IATA (Cargo Air):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IATA (Passenger Air):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: TDG (Canada):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

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The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging for shipment under these alternative transport regulations.

SECTION 15. REGULATORY INFORMATION

TSCA list : No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification requirements.

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Components CAS-No. Component RQ (lbs)

Calculated product RQ (lbs) pentyl acetate 628-63-7 5000 *

*: Calculated RQ exceeds reasonably attainable upper limit.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Serious eye damage or eye irritation Respiratory or skin sensitisation

SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

California Prop. 65

WARNING: This product can expose you to chemicals including 1,4-dioxane, which is/are known to the State of California to cause cancer, and methanol, which is/are known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.

The components of this product are reported in the following inventories:

DSL All components of this product are on the Canadian DSL

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For information on the country notification status for other regions please contact the manufacturer’s regulatory group.

Inventory Acronym and Validity Area Legend:

TSCA (USA), DSL (Canada), NDSL (Canada)

SECTION 16. OTHER INFORMATION

Further information

NFPA:

HMIS III:

OSHA - GHS Label Information:

Hazard pictograms :

Exclamation mark

Signal word : Warning:

Hazard statements : May cause an allergic skin reaction. Causes serious eye irritation.

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic

FLAMMABILITY

INSTABILITY

HEALTH

0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme

SPECIAL HAZARD.

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Precautionary statements :

Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/ eye protection/ face protection.

Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Wash contaminated clothing before reuse.

Disposal: Dispose of contents/container in accordance with local regulation.

Version: 5.0

Revision Date: 12/27/2023

Print Date: 03/17/2025

We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes.

This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.

APPENDIX 2: Line Item No. 2

Big D Para Products

Safety Data Sheet

Product Identifier Big D Para Products

Other Means of Identification

900, 903, 930, 950, 960, 970, 980, 317500 & 990

Other Identification Para Product

Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541, BigDInd.com

Recommended Use

SDS No.

Product Family Dry Deodorants

Emergency Phone No.

SECTION 1. IDENTIFICATION

Manufacturer

Dry Deodorants.

InfoTrac, 800 535 5053, 24hr

Restrictions on Use None known.

Date of Preparation May 15, 2023

Label Elements

SECTION 2. HAZARD IDENTIFICATION

Signal Word:

Warning

H319 Causes serious eye irritation.

H351 Suspected of causing cancer.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statement(s):

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Wear personal protective equipment/face protection.

P273 Avoid release to the environment.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P405 Store locked up.

P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Classification

Eye irritation - Category 2A; Carcinogenicity - Category 2; Aquatic hazard (Acute) - Category 1; Aquatic hazard (Chronic) - Category 1

SDS No.:

Date of Preparation:

0277 Page of 0601

May 15, 2023

Product Identifier: Big D Para Products

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No. Other Identifiers%

Mixture:

1,4-Dichlorobenzene 106-46-7 99.9

Fragrance Trade Secret .01

Inhalation

Move to fresh air. Get medical advice or attention if you feel unwell or are concerned.

Skin Contact

Get medical advice or attention if you feel unwell or are concerned.

Eye Contact

Rinse the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open.

Ingestion

Get medical advice or attention if you feel unwell or are concerned.

First-aid Comments

Get medical advice or attention if you feel unwell or are concerned.

Special Instructions

Not applicable.

SECTION 4. FIRST-AID MEASURES

First-aid Measures

Immediate Medical Attention and Special Treatment

Medical Conditions Aggravated by Exposure

None known.

Most Important Symptoms and Effects, Acute and Delayed

None known.

Extinguishing Media

Suitable Extinguishing Media

Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog.

Unsuitable Extinguishing Media

None known.

Specific Hazards Arising from the Product

Can ignite if strongly heated.

In a fire, the following hazardous materials may be generated: irritating chemicals; very toxic chemicals.

Special Protective Equipment and Precautions for Fire-fighters

Toxic gases or vapours.

Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary.

SECTION 5. FIRE-FIGHTING MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures

Use the personal protective equipment recommended in Section 8 of this safety data sheet. Increase ventilation to area or move leaking container to a well-ventilated and secure area.

Environmental Precautions

It is good practice to prevent releases into the environment. If the spill is inside a building, prevent product from entering drains, ventilation systems and confined areas.

SECTION 6. ACCIDENTAL RELEASE MEASURES

SDS No.:

Date of Preparation:

0277 Page of 0602

It is good practice to prevent releases into the environment. If the spill is inside a building, prevent product from entering drains, ventilation systems and confined areas.

Methods and Materials for Containment and Cleaning Up

Review Section 7 (Handling) of this safety data sheet before proceeding with clean-up.

Precautions for Safe Handling

When handling concentrated product: avoid repeated or prolonged skin contact. Do not get in eyes, on skin or on clothing. Avoid generating dusts.

Conditions for Safe Storage

Store in an area that is: cool, well-ventilated, out of direct sunlight and away from heat and ignition sources.

SECTION 7. HANDLING AND STORAGE

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ACGIH TLV® OSHA PEL

Chemical Name TWA STEL TWA Ceiling

Control Parameters

AIHA WEEL

8-hr TWA TWA

1,4-Dichlorobenzene 60 mg/m3 450 mg/m3

Appropriate Engineering Controls

Individual Protection Measures

Skin Protection

Respiratory Protection

Eye/Face Protection

Not usually required when working with small quantities.

Not required, if used as directed.

Not required but it is good practice to wear safety glasses or chemical safety goggles.

General ventilation is usually adequate.

Appearance Colourless white crystalline crystals.

Odour Aromatic (1,4-Dichlorobenzene)

Initial Boiling Point/Range 345 ºF (174 ºC)

Flash Point 151 ºF (66 ºC) (1,4-Dichlorobenzene)

Melting Point/Freezing Point 129 ºF (54 ºC) (melting)

Upper/Lower Flammability or Explosive Limit

5.9% (1,4-Dichlorobenzene) (upper); 1.7% (1,4-Dichlorobenzene) (lower)

Solubility 79 mg/L in water; Highly soluble in common organic solvents.

Auto-ignition Temperature 1184 ºF (640 ºC)

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density 0.078 lb/ft3 (0.001 kg/L)

Basic Physical and Chemical Properties

SolidPhysical State

Other Information

Flammability (solid, gas) Not applicable

Chemical Stability

SECTION 10. STABILITY AND REACTIVITY

Reactivity

Not reactive under normal conditions of use.

SDS No.:

Date of Preparation:

0277 Page of 0603

Chemical Stability

Normally stable.

Conditions to Avoid

High temperatures. Generation of dust.

Incompatible Materials

Acid anhydrides (e.g. acetic anhydride), strong acids (e.g. hydrochloric acid), inorganic acids (e.g. hydrofluoric acid), organic acids (e.g. acetic acid), strong oxidizing agents (e.g. perchloric acid).

Hazardous Decomposition Products

Very toxic chemicals.

Possibility of Hazardous Reactions

None expected under normal conditions of storage and use.

Skin Corrosion/Irritation

Human experience shows very mild irritation.

Serious Eye Damage/Irritation

There is limited evidence of serious eye irritation.

SECTION 11. TOXICOLOGICAL INFORMATION

STOT (Specific Target Organ Toxicity) - Single Exposure

Inhalation

No information was located.

Skin Absorption

No information was located.

Ingestion

No information was located.

No information was located.

STOT (Specific Target Organ Toxicity) - Repeated Exposure

Respiratory and/or Skin Sensitization

Not known to be a skin sensitizer.

Carcinogenicity

May cause cancer. (1,4-Dichlorobenzene)

Development of Offspring

No information was located.

Reproductive Toxicity

Key to Abbreviations

ACGIH® = American Conference of Governmental Industrial Hygienists. A3 = Animal carcinogen.

IARC = International Agency for Research on Cancer. Group 2B = Possibly carcinogenic to humans.

Acute Toxicity

Not known to be an aspiration hazard.

Aspiration Hazard

Inhalation; skin contact; eye contact.

Likely Routes of Exposure

Chemical Name LC50 LD50 (oral) LD50 (dermal)

1,4-Dichlorobenzene 500 mg/kg (male rat) > 2000 mg/kg (rabbit)

Chemical Name IARC ACGIH® NTP OSHA

1,4-Dichlorobenzene Group 2B A3

SDS No.:

Date of Preparation:

0277 Page of 0604

Development of Offspring

No information was located.

No information was located.

Germ Cell Mutagenicity

Not known to be a mutagen.

Interactive Effects

No information was located.

Sexual Function and Fertility

Effects on or via Lactation

No information was located.

Very toxic to fish.

No information was located.

If released into the environment, this product can move slowly through the soil.

There is no information available.

SECTION 12. ECOLOGICAL INFORMATION

No information was located.

Ecotoxicity

Persistence and Degradability

Mobility in Soil

Other Adverse Effects

Bioaccumulative Potential

Acute Aquatic Toxicity

Chemical Name LC50 Fish EC50 Crustacea ErC50 Aquatic Plants

ErC50 Algae

1,4-Dichlorobenzene 4.2 mg/L (Pimephales promelas (fathead minnow); 96-hour)

.70 mg/L (Daphnia magna (water flea))

28 mg/L (Desmodesmus subspicatus (algae);

48-hour)

SECTION 13. DISPOSAL CONSIDERATIONS

Contact local environmental authorities for approved disposal or recycling methods in your jurisdiction.

Disposal Methods

SECTION 14. TRANSPORT INFORMATION

UN No. Proper Shipping Name Packing Group

Transport Hazard Class(es)

Regulation

3007 Environmentally Hazardous Substances, Solid n.o.s.

(p-dichlorobenzene)

9.2 IIICanadian TDG

3077 Environmentally Hazardous Substances, Solid n.o.s.

(p-dichlorobenzene)

9 IIIUS DOT

3077 Environmentally Hazardous Substances, Solid n.o.s.

(p-dichlorobenzene) p IIIIMO (Marine)

3077 Environmentally Hazardous Substances, Solid n.o.s.

(p-dichlorobenzene) p IIIIATA (Air)

Special Precautions Please note: US DOT: In inner containers of 100 lbs capacity or less, this product is exempt from DOT regulations (non-regulated).

Environmental Hazards

Marine Pollutant (1,4-Dichlorobenzene)

SDS No.:

Date of Preparation:

0277 Page of 0605

Special Precautions Please note: US DOT: In inner containers of 100 lbs capacity or less, this product is exempt from DOT regulations (non-regulated).

Environmental Hazards

Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code

Not applicable

SECTION 15. REGULATORY INFORMATION

Canada

Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)

All ingredients are listed on the DSL or are not required to be listed.

CEPA - National Pollutant Release Inventory (NPRI)

Part 1A, Part 5.

USA

Toxic Substances Control Act (TSCA) Section 8(b)

All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all of the information required by the Controlled Products Regulations.

Custom Regulatory 1

This Product may not be sold for use in the following US states: California Michigan Maryland Delaware New York New Jersey Connecticut Rhode Island Massachusetts Maine Pennsylvania Indiana Utah Vermont Virginia Washington D.C.

(1,4-Dichlorobenzene)

Safety, Health and Environmental Regulations

Disclaimer This Safety Data Sheet has been prepared in accordance with the Globally Harmonized System for the Classification and Labeling of Chemical (GHS) TO the best of our knowledge the information herein is accurate. However, the supplier makes no warranty and assume no liability resulting from its use. In No event shall the supplier be liable for any claims, losses, or damages of any third party resulting from the use of or reliance upon this information.

SECTION 16. OTHER INFORMATION

NFPA Rating Health - 1 Flammability - 2 Instability - 0

SDS No.:

Date of Preparation:

0277 Page of 0606

APPENDIX 3: Line Item No. 3

NOTICE: Judgment may be based on indirect test and technical literature. The OSHA Hazard Communication Standard only requires SDS's and special labeling for materials defined as "HAZARDOUS"; see 29 CFR 1910.1200 (c). This document may be about a product which is NOT hazardous but is provided as information for our customers. See references for information.

SECTION 1. IDENTIFICATION

Product Identifier: New Power Product Use: All Purpose Cleaner & Degreaser Product Identification # (PIF): 04049 Date Prepared: October 26, 2015

SECTION 2. HAZARD(S) IDENTIFICATION_______________________________________

GHS Hazard Codification:

Signal Word: WARNING

Hazard Class Category Code Hazard Statement

Eye Irritation 2B H320 Causes eye irritation

Skin Irritation 2 H315 Causes skin irritation

Precautionary Code Statement

Prevention P264 P280

Wash thoroughly after handling.

Wear protective gloves/protective clothing/eye protection/face protection.

Response P302+P352 P321 P332+P313 P362 P305+P351+P338

P337+P313

IF ON SKIN: Wash with soap and water.

Specific treatments: See Section 4 First Aid Measures.

If skin irritation occurs: Get medical advice/attention.

Take off contaminated clothing and wash before reuse.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if easy to do so. Continue rinsing.

If eye irritation persists: Get medical advice/attention.

Storage None None

Disposal P501 Dispose of contents/container in compliance with all Federal, State/Provincial and local laws and regulations.

Description of any hazards not otherwise classified: Potential health effects – Repeated skin exposure can cause drying and flaking of the skin (dermatitis). Inhaling mists/sprays of product may cause irritation to respiratory tract. Ingestion may result in irritation of entire gastrointestinal tract.

SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS____________________________

Ingredient Common Names CAS # Concentration Range %

Disodium trioxosilicate Silicic Acid, disodium salt 6834-92-0 1 – 4

SECTION 4. FIRST AID MEASURES

Eyes: Flush well with water for at least 15 minutes, holding eyelids open. Remove any contact lenses and continue rinsing. If irritation persists, seek medical attention.

Skin: Wash with soap and water. Remove contaminated clothing and launder before reuse. If irritation persists, seek medical attention.

Inhalation: If symptoms develop, move victim to fresh air. If breathing is difficult, have a trained person administer oxygen. If respiration stops, have a trained person administer artificial respiration and call a physician.

Ingestion: DO NOT INDUCE VOMITING. Call a physician immediately. If victim is completely conscious and aware, have him rinse out mouth, then drink 8 oz. water to dilute. Never give anything by mouth to an unconscious person.

SECTION 5. FIRE-FIGHTING MEASURES______________________________________

Flammability: Not flammable Flash Point: Not flammable Extinguishing Media: Use media appropriate for surrounding fire.

Specific hazards arising from chemical: None known.

Hazardous combustion products: Carbon monoxide and carbon dioxide.

Firefighting protective equipment: Wear a self-contained breathing apparatus with a full face piece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipment.

Sensitivity to static discharge: This product is not combustible.

SECTION 6. ACCIDENTAL RELEASE MEASURES____________________________________

Personal Precautions: Use personal protective equipment (Section 8). Ventilate area. Wash thoroughly after handling.

For Small Spills: Spilled material may be slippery. Avoid dispersal of material and runoff into soil, waterways, drains and sewers.

Neutralize spill with mild acid, such as citric acid. Absorb spill with vermiculite or other inert material, then place in a container for

General Info Phone: (404) 363-2226 Emergency Phone: Domestic/Canada 1-800-633-8253

International 1-801-629-0667

Supplier:

PEOPLES JANITORIAL SUPPLIES

955 MAIN STREET FOREST PARK, GA 30298

chemical waste. Wash walking surfaces with water to reduce slipping hazard. Dispose of contaminated absorbent material in accordance with local, state and federal regulations.

For Large Spills: Large spills cannot occur due to packaging.

SECTION 7. HANDLING AND STORAGE

Handling: Wear personal protection equipment (Section 8). Use with adequate ventilation. Do not premix with other chemicals. Do not eat, drink or smoke in work areas. Wash thoroughly after handling. Empty containers may contain residue and can be dangerous.

Storage: Keep away from heat, flame, or sunlight. Keep from freezing. Keep container closed when not in use. Protect from physical damage. Store away from oxidizing agents, acids, aluminum, zinc, tin, copper and their alloys.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Ingredient CAS # OSHA/PEL ACGIH/TLV STEL

Disodium trioxosilicate 6834-92-0 Not established Not established Not established

Engineering Controls: Provide adequate ventilation. Keep the risk of exposure to a minimum.

Personal protective equipment:

Eye: Safety glasses with side shields or splash proof goggles.

Skin: Chemical resistant gloves. Normal materials handling clothing.

Respirator: Use NIOSH approved protection if mists/sprays are generated and are causing irritation.

Other: Use only in a well ventilated area. Do not eat, drink or smoke in work areas. Wash thoroughly after handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES_________________________________

Appearance Green, clear liquid Upper/Lower flammability limits Not determined

Odor Pleasant Vapor pressure Not determined

Odor threshold Not determined Vapor density (Air = 1) <1 pH 12 – 13 Specific gravity (water = 1.0) 1.025 g/ml

Melting point Not determined Solubility Complete in water

Freezing point Not determined Partition coefficient (n-octanol/water) Not determined

Boiling point Not determined Auto-ignition temperature Not determined

Flash point Not flammable Decomposition temperature Not determined

Evaporation rate (n-butyl acetate=1) <1 Viscosity Water thin

Flammability Not flammable %Volatile/Volume 95

SECTION 10. STABILITY AND REACTIVITY_________________________________________

Reactivity: Not reactive under normal conditions.

Chemical stability: Stable under normal, ambient temperature and conditions.

Possibility of hazardous reactions: Hazardous polymerization will not occur.

Conditions to avoid: Keep from freezing. Do not mix with other chemicals Incompatible materials: Avoid oxidizing agents, acids, aluminum, zinc, tin, copper and their alloys.

Hazardous combustion products: Carbon monoxide and carbon dioxide.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute and Chronic Toxicity (short and long term):

Oral (LD50 Rat): >5000mg/kg Dermal (LD50 Rabbit): Not determined Inhalation (LC50 Rat): Not determined NTP/IARC/OSHA Carcinogen: No

Eye Contact: Causes eye irritation.

Skin Contact: Causes skin irritation. Repeated exposure to skin can cause drying and flaking of the skin (dermatitis).

Inhalation: Inhaling mists/sprays of product may cause irritation to respiratory tract.

Ingestion: Ingestion may result in irritation of entire gastrointestinal tract.

SECTION 12. ECOLOGICAL INFORMATION

Acute Aquatic Effects:

96h LC-50 (fish): >100ppm 48h LC-50 (invertebrates): >100ppm 192h EC0 (algae): >100ppm

Biodegradability: No data available Bioaccumulation: No data available Mobility: This product is soluble in water and may spread in water systems. Soil mobility not determined.

Effects on Aquatic Life: This product can raise the pH of an aquatic environment, and thus be toxic to fish and aquatic plants. As with all chemicals, work practices should be aimed at eliminating environmental releases.

SECTION 13. DISPOSAL CONSIDERATIONS_______________________________________

Disposal of Wastes: Do not dump into sewers, on the ground or into any waterways. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations.

Contaminated Packaging: Since emptied containers retain product residue, follow label warnings even after container is emptied.

Do not cut, drill, grind or weld on or near the container.

RCRA: Not applicable.

SECTION 14. TRANSPORT INFORMATION

United States D.O.T.:

Not regulated

IATA and IMDG:

Not regulated Marine Pollutant (IMDG Code): No Transportation in bulk (IMDG - Annex II of MARPOL 73/78 and IBC Code): Not offered in bulk for transport overseas

SECTION 15. REGULATORY INFORMATION

TSCA: All components of this product are on the TSCA inventory or are exempt from TSCA inventory requirements under 40 CFR 720.30.

SARA Section 302: The components of this product are either not regulated or regulated, but present in negligible concentrations.

SARA TITLE III Section 311/312:

Immediate (Acute) Health Yes Fire Hazard No

Delayed (Chronic) Health No Reactive Hazard No

SARA Title 313: This material does not contain any chemical components with known CAS numbers that exceed the De Minimis reporting levels (40 CFR 372).CERCLA: This product does not have a reportable quantity.

CERCLA: This product does not have a reportable quantity.

United States Right-To-Know: None known.

Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.

RCRA: Not applicable.

SECTION 16. OTHER INFORMATION

Date prepared: October 26, 2015 HMIS Ratings: Health 2, Fire 0, Reactivity 0 (scale 0 – 4). Personal Protection Rating to be supplied by user based on use conditions.

Product VOC: 0% Carefully read all instructions on label before handling this product.

Keep out of reach of children.

“FOR INDUSTRIAL USE ONLY”

Abbreviation Full Name/Explanation

ACGIH American Conference of Government Industrial Hygienists

CAS Chemical Abstract Service

CERCLA Comprehensive Environmental Response Compensation and Liability Act

CNS Central Nervous System

CFR Code of Federal Regulations

DOT Department of Transportation

EC Effective Concentration

HMIS Hazardous Material Information System

LC Lethal Concentration

LD Lethal Dose

NA Not Applicable

ND Not Determined

NE Not Established

NIOSH National Institute for Occupational Safety and Health

OSHA Occupational Safety and Health Administration

PEL Permissible Exposure Limit

RCRA Resource Conservation Recovery Act

SARA Superfund Amendments and Reauthorization Act

STEL Short-Term Exposure Limit

TLV Threshold Limit Value

TSCA Toxic Substance Control Act

VOC Volatile Organic Compounds

The information contained herein is based on data available to us and is believed to be correct. We make no warranty, however, expressed or implied regarding the accuracy of these data or the results obtained from the use thereof.

Regulatory Standards: DOT TITLE 49, Code of Federal Regulations 172.101: Parts 100 to 177, Revised 10/1/92.

SUPER FUND AMENDMENTS REAUTHORIZATION ACT OF 1986, TITLE III TOXIC SUBSTANCE CONTROL ACT LIST (TSCA)- INGREDIENTS LISTED. REGISTRY OF

TOXIC EFFECTS OF CHEMICAL SUBSTANCES NATIONAL TOXICOLOGICAL PROGRAM (NTP) REPORT OF CARCINOGENS INTERNATIONAL AGENCY FOR

RESEARCH ON CANCER (IARC) MONOGRAPHS, OCCUPATIONAL SAFETY & HEALTH REGULATIONS. CODE OF FED. REGS. FOOD & DRUG, 21 PARTS 170 to 199, Revised 4/1/91, 173.310.

APPENDIX 4: Line Item No. 4

ZEP MORADO SUPER CLEANER 4/1GL

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Material name : ZEP MORADO SUPER CLEANER 4/1GL

Material number : 000000000000085624

Manufacturer or supplier's details

Company : Zep Inc.

Address : 350 Joe Frank Harris Parkway, SE Emerson, GA 30137

Telephone : Compliance Services - 877-428-9937

Emergency telephone numbers

For SDS Information : Compliance Services - 877-428-9937

For a Medical Emergency : 877-541-2016 Toll Free - All Calls Recorded

For a Transportation Emergency

: CHEMTREC: 800-424-9300 - All Calls Recorded.

In the District of Columbia 202-483-7616

Recommended use of the chemical and restrictions on use

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance liquid

Colour purple

Odour ether-like

GHS Classification

Skin corrosion : Category 1 Serious eye damage : Category 1

GHS label elements

Hazard pictograms :

Corrosion

Signal word : Danger

Hazard statements : H314 Causes severe skin burns and eye damage.

Precautionary statements : Prevention:

P264 Wash skin thoroughly after handling.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response:

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303 + P361 + P353 IF ON SKIN (or hair): Take off

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P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.

P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.

P363 Wash contaminated clothing before reuse.

Storage:

P405 Store locked up.

Disposal:

P501 Dispose of contents/container in accordance with local regulation.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous components

Chemical name CAS-No. Concentration [%]

Alcohols, C9-11, ethoxylated 68439-46-3 >= 3 - < 5

2-butoxyethanol 111-76-2 >= 1 - < 3 sodium hydroxide 1310-73-2 >= 1 - < 3

Benzenesulfonic acid, mono-C10-16-alkyl derivs., sodium salts

68081-81-2 >= 1 - < 3

The exact percentages of disclosed substances are withheld as trade secrets.

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Show this safety data sheet to the doctor in attendance.

Do not leave the victim unattended.

Get medical attention immediately.

If inhaled : If unconscious, place in recovery position and seek medical advice.

If symptoms persist, call a physician.

In case of skin contact : Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty.

Wash off immediately with plenty of water for at least 15 minutes.

If skin irritation persists, call a physician.

Remove contaminated clothing and shoes.

Wash contaminated clothing before reuse.

In case of eye contact : Small amounts splashed into eyes can cause irreversible

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Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Continue rinsing eyes during transport to hospital.

Remove contact lenses.

Protect unharmed eye.

Keep eye wide open while rinsing.

If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear.

Never give anything by mouth to an unconscious person.

DO NOT induce vomiting unless directed to do so by a physician or poison control center.

Take victim immediately to hospital.

Do not give milk or alcoholic beverages.

Most important symptoms and effects, both acute and delayed

: Effects are immediate and delayed.

Symptoms may include blistering, irritation, burns, and pain.

Effects are dependent on exposure (dose, concentration, contact time).

Causes severe skin burns and eye damage.

Review section 2 of SDS to see all potential hazards.

Notes to physician : Treat symptomatically. Symptoms may be delayed.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Dry chemical Water spray jet Alcohol-resistant foam Carbon dioxide (CO2)

Unsuitable extinguishing media

: High volume water jet

Specific hazards during firefighting

: Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion products

: Carbon dioxide (CO2) Carbon monoxide Smoke

Specific extinguishing methods

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Standard procedure for chemical fires.

Special protective equipment for firefighters

: Wear self-contained breathing apparatus for firefighting if necessary.

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SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Use personal protective equipment.

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.

If the product contaminates rivers and lakes or drains, inform respective authorities.

Methods and materials for containment and cleaning up

: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Avoid exposure - obtain special instructions before use.

Avoid contact with skin and eyes.

For personal protection see section 8.

Smoking, eating and drinking should be prohibited in the application area.

Do not breathe vapours or spray mist.

Take precautionary measures against static discharges.

Provide sufficient air exchange and/or exhaust in work rooms.

Dispose of rinse water in accordance with local and national regulations.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place.

Observe label precautions.

Electrical installations / working materials must comply with the technological safety standards.

Materials to avoid : Store and keep away from, oxidizing agents and acids.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type (Form of exposure)

Control parameters / Permissible concentration

Basis

2-butoxyethanol 111-76-2 TWA 20 ppm ACGIH

TWA 5 ppm 24 mg/m3

NIOSH REL

TWA 50 ppm 240 mg/m3

OSHA Z-1

TWA 25 ppm 120 mg/m3

OSHA P0

PEL 20 ppm 97 mg/m3

CAL PEL

sodium hydroxide 1310-73-2 C 2 mg/m3 ACGIH

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C 2 mg/m3 NIOSH REL

TWA 2 mg/m3 OSHA Z-1

C 2 mg/m3 OSHA P0

C 2 mg/m3 CAL PEL

Biological occupational exposure limits

Component CAS-No. Control parameters

Biological specimen

Sampling time

Permissible concentration

Basis

2-BUTOXYETHANOL 111-76-2 Butoxyacetic acid (BAA)

Urine End of shift (As soon as possible after exposure ceases)

200.mg/g Creatinine

ACGIH BEI

Engineering measures : effective ventilation in all processing areas

Personal protective equipment

Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.

Hand protection Material : Protective gloves Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves.

Eye protection : Access to clean water to rinse eyes must be available, options include: eye wash stations or showers, or eye wash bottles with pure water.

Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems.

Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Hygiene measures : When using do not eat or drink.

When using do not smoke.

Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : purple

Odour : ether-like

Odour Threshold : No data available

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Melting point/freezing point : No data available

Boiling point : 98.9 °C

Flash point :

does not flash

Evaporation rate : 1

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapour pressure : not determined

Relative vapour density : No data available

Density : 1.0230 g/cm3

Solubility(ies)

Water solubility : soluble

Solubility in other solvents : not determined

Partition coefficient: n-octanol/water

: No data available

Auto-ignition temperature : not determined

Thermal decomposition : No data available

Viscosity

Viscosity, kinematic : 6.6 mm2/s (20 °C)

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Stable

Chemical stability : Stable under normal conditions.

Possibility of hazardous reactions

: No decomposition if stored and applied as directed.

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Acids Oxidizing agents This product contains sodium hydroxide or potassium hydroxide that may corrode some soft metals and may react with tin, zinc, aluminum to form hydrogen gas.

Hazardous decomposition products

: Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke).

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SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects

Aggravated Medical Condition

: None known.

Symptoms of Overexposure : Effects are immediate and delayed.

Symptoms may include blistering, irritation, burns, and pain.

Effects are dependent on exposure (dose, concentration, contact time).

Causes severe skin burns and eye damage.

Review section 2 of SDS to see all potential hazards.

Treat symptomatically. Symptoms may be delayed.

Carcinogenicity:

IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH Confirmed animal carcinogen with unknown relevance to humans 2-butoxyethanol 111-76-2

OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

Acute toxicity

Product:

Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method

Acute inhalation toxicity : Acute toxicity estimate : > 200 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method

Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method

Components:

Alcohols, C9-11, ethoxylated:

Acute oral toxicity : LD50 Oral Rat: 1,400 mg/kg

2-butoxyethanol:

Acute oral toxicity : LD50 Oral…