Attachment_4_Seed_Task_Order_2.pdf

140R3024R0035

Attachment 4: Seed Task Order Statement of Work

Hazardous Waste Services

The Bureau of Reclamation, Lower Colorado Regional Office would like to schedule a hazardous waste pick up. Pickup shall be within 30 days after award of task order.

Contractor shall supply all services in the pickup and disposal of all non-hazardous, hazardous, and universal waste in accordance with all federal, state, and local regulations. This service includes preparing waste for shipment in DOT approved containers, Waste Profiles, Land Disposal Restrictions Form, Hazardous Waste Manifest, DOT container Labeling and Markings and Certificate of Disposal or Recycling.

Contractor shall abide by the requirements of a task order issued by the Contracting Office and the Contracting Office call request for services.

The following Items are listed for disposal:

Regional IT Office

USGS Lab

USGS

Pick up location:

Lower Colorado Regional Office 500 Fir Street Boulder City NV 89005

Period of Performance: Date of award of task order through 60 days.

Item Number of Containers Container Size

Methanol 4 2.5L BaCl2 Dihydrate 1 500g Acetone 1 2.5L Acetone 1 2.5L

Item Number of Size

Mercury Thermometers 6 to 12 Small Thermometer

Item Pounds Lithium Batteries 500

SAFETY DATA SHEET

Creation Date 28-Apr-2009 Revision Date 24-Dec-2021 Revision Number 8

1. Identification Product Name Acetone

Cat No. : AC177170000; AC177170010; AC177170025; AC177170050;

AC177170100; AC177170250

CAS No 67-64-1 Synonyms 2-Propanone

Recommended Use Laboratory chemicals.

Uses advised against Food, drug, pesticide or biocidal product use.

Details of the supplier of the safety data sheet

Emergency Telephone Number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887

2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Label Elements

Signal Word Danger

Hazard Statements

Company Fisher Scientific Company One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100

Acros Organics One Reagent Lane Fair Lawn, NJ 07410

Serious Eye Damage/Eye Irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Target Organs - Central nervous system (CNS).

Specific target organ toxicity - (repeated exposure) Category 2 Target Organs - Kidney, Liver, spleen, Blood.

Flammable liquids

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Category 2

Acetone Revision Date 24-Dec-2021

Highly flammable liquid and vapor Causes serious eye irritation May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure

Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Keep cool Response Get medical attention/advice if you feel unwell Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Fire In case of fire: Use CO2, dry chemical, or foam for extinction Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Repeated exposure may cause skin dryness or cracking

3. Composition/Information on Ingredients

Component CAS No Weight % Acetone 67-64-1 >95

4. First-aid measures

General Advice If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get

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Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water.

Most important symptoms and effects

. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting:

May cause pulmonary edema

Notes to Physician Treat symptomatically

5. Fire-fighting measures

Suitable Extinguishing Media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable Extinguishing Media Water may be ineffective

Flash Point -20 °C / -4 °F

Method - CC (closed cup)

Autoignition Temperature 465 °C / 869 °F

Explosion Limits Upper 12.8 vol % Lower 2.5 vol %

Oxidizing Properties Not oxidising

Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available

Specific Hazards Arising from the Chemical Flammable. Risk of ignition. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Hazardous Combustion Products Carbon monoxide (CO). Carbon dioxide (CO2). Formaldehyde. Methanol.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

NFPA

6. Accidental release measures Personal Precautions Use personal protective equipment as required. Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges.

Environmental Precautions Should not be released into the environment.

Methods for Containment and Clean Up

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

7. Handling and storage

Health

Flammability

Instability

Physical hazards N/A

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Handling Do not get in eyes, on skin, or on clothing. Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage. Flammables area. Keep containers tightly closed in a dry, cool and well-ventilated place.

Keep away from heat, sparks and flame. Incompatible Materials. Strong oxidizing agents.

Strong reducing agents. Strong bases. Peroxides. Halogenated compounds. Alkali metals.

Amines.

8. Exposure controls / personal protection Exposure Guidelines

9. Physical and chemical properties Physical State Liquid Appearance Colorless Odor sweet Odor Threshold 19.8 ppm pH 7 Melting Point/Range -95 °C / -139 °F Boiling Point/Range 56 °C / 132.8 °F Flash Point -20 °C / -4 °F

Method - CC (closed cup) Evaporation Rate 5.6 (Butyl Acetate = 1.0) Flammability (solid,gas) Not applicable

Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA) Acetone TWA: 250 ppm

STEL: 500 ppm (Vacated) TWA: 750 ppm

(Vacated) TWA: 1800 mg/m3

(Vacated) STEL: 2400 mg/m3

(Vacated) STEL: 1000 ppm TWA: 1000 ppm

TWA: 2400 mg/m3

IDLH: 2500 ppm TWA: 250 ppm

TWA: 590 mg/m3

TWA: 500 ppm STEL: 750 ppm

Legend

ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH IDLH: NIOSH - National Institute for Occupational Safety and Health

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof electrical/ventilating/lighting equipment.

Personal Protective Equipment

Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard

EN166.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

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Flammability or explosive limits Upper 12.8 vol % Lower 2.5 vol %

Vapor Pressure 247 mbar @ 20 °C Vapor Density 2.0 Specific Gravity 0.790 Solubility Soluble in water Partition coefficient; n-octanol/water No data available Autoignition Temperature 465 °C / 869 °F Decomposition Temperature > 4°C Viscosity 0.32 mPa.s @ 20 °C Molecular Formula C3 H6 O Molecular Weight 58.08 Refractive index 1.358 - 1.359

10. Stability and reactivity

Reactive Hazard None known, based on information available

Stability Stable under normal conditions.

Conditions to Avoid Heat, flames and sparks. Incompatible products. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible Materials Strong oxidizing agents, Strong reducing agents, Strong bases, Peroxides, Halogenated compounds, Alkali metals, Amines

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Formaldehyde, Methanol

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

11. Toxicological information Acute Toxicity

Product Information Component Information

Component LD50 Oral LD50 Dermal LC50 Inhalation Acetone 5800 mg/kg ( Rat ) > 15800 mg/kg (rabbit)

> 7400 mg/kg (rat) 76 mg/l, 4 h, (rat)

Toxicologically Synergistic Products

Carbon tetrachloride; Chloroform; Trichloroethylene; Bromodichloromethane;

Dibromochloromethane; N-nitrosodimethylamine; 1,1,2-Trichloroethane; Styrene;

Acetonitrile, 2,5-Hexanedione; Ethanol; 1,2-Dichlorobenzene

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation Irritating to eyes

Sensitization No information available

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component CAS No IARC NTP ACGIH OSHA Mexico Acetone 67-64-1 Not listed Not listed Not listed Not listed Not listed

Mutagenic Effects No information available

Reproductive Effects No information available.

Developmental Effects No information available.

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Teratogenicity No information available.

STOT - single exposure Central nervous system (CNS) STOT - repeated exposure Kidney Liver spleen Blood

Aspiration hazard No information available

Symptoms / effects,both acute and delayed

Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting:

May cause pulmonary edema

Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated.

12. Ecological information Ecotoxicity

Component Freshwater Algae Freshwater Fish Microtox Water Flea Acetone NOEC = 430 mg/l (algae; 96

h) Oncorhynchus mykiss: LC50

= 5540 mg/l 96h Alburnus alburnus: LC50 =

11000 mg/l 96h Leuciscus idus: LC50 =

11300 mg/L/48h Salmo gairdneri: LC50 =

6100 mg/L/24h

EC50 = 14500 mg/L/15 min EC50 = 8800 mg/L/48h EC50 = 12700 mg/L/48h EC50 = 12600 mg/L/48h

Persistence and Degradability Persistence is unlikely based on information available.

Bioaccumulation/ Accumulation No information available.

Mobility Will likely be mobile in the environment due to its volatility.

Component log Pow Acetone -0.24

13. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Component RCRA - U Series Wastes RCRA - P Series Wastes Acetone - 67-64-1 U002 -

14. Transport information

DOT

UN-No UN1090 Proper Shipping Name ACETONE Hazard Class 3 Packing Group II

TDG

UN-No UN1090 Proper Shipping Name ACETONE Hazard Class 3 Packing Group II

IATA

UN-No UN1090 Proper Shipping Name ACETONE Hazard Class 3

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Packing Group II

IMDG/IMO

UN-No UN1090 Proper Shipping Name ACETONE Hazard Class 3 Packing Group II

15. Regulatory information

United States of America Inventory

Component CAS No TSCA TSCA Inventory notification - Active-Inactive

TSCA - EPA Regulatory Flags

Acetone 67-64-1 X ACTIVE -

Legend:

TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710) X - Listed '-' - Not Listed

TSCA 12(b) - Notices of Export Not applicable

International Inventories Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), China (IECSC), Korea

(KECL).

Component CAS No DSL NDSL EINECS PICCS ENCS ISHL AICS IECSC KECL Acetone 67-64-1 X - 200-662-2 X X X X X KE-29367

KECL - NIER number or KE number (http://ncis.nier.go.kr/en/main.do)

U.S. Federal Regulations

SARA 313 Not applicable

SARA 311/312 Hazard Categories See section 2 for more information

CWA (Clean Water Act) Not applicable

Clean Air Act Not applicable

OSHA - Occupational Safety and Health Administration

Not applicable

CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Component Hazardous Substances RQs CERCLA EHS RQs

Acetone 5000 lb -

California Proposition 65 This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Acetone X X X - X

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U.S. Department of Transportation

Reportable Quantity (RQ): Y DOT Marine Pollutant N DOT Severe Marine Pollutant N

U.S. Department of Homeland Security

This product does not contain any DHS chemicals.

Other International Regulations

Mexico - Grade Serious risk, Grade 3

Authorisation/Restrictions according to EU REACH

Component REACH (1907/2006) - Annex XIV - Substances Subject to

Authorization

REACH (1907/2006) - Annex XVII - Restrictions on Certain Dangerous

Substances

REACH Regulation (EC 1907/2006) article 59 - Candidate List of Substances of Very High

Concern (SVHC) Acetone - Use restricted. See item 75.

(see link for restriction details) https://echa.europa.eu/substances-restricted-under-reach

Safety, health and environmental regulations/legislation specific for the substance or mixture

Component CAS No OECD HPV Persistent Organic Pollutant

Ozone Depletion Potential

Restriction of Hazardous

Substances (RoHS) Acetone 67-64-1 Listed Not applicable Not applicable Not applicable

Component CAS No Seveso III Directive

(2012/18/EC) -

Qualifying Quantities for Major Accident

Notification

Seveso III Directive

(2012/18/EC) -

Qualifying Quantities for Safety Report

Requirements

Rotterdam Convention (PIC)

Basel Convention (Hazardous Waste)

Acetone 67-64-1 Not applicable Not applicable Not applicable Annex I - Y42

16. Other information Prepared By Regulatory Affairs

Thermo Fisher Scientific Email: EMSDS.RA@thermofisher.com

Creation Date 28-Apr-2009 Revision Date 24-Dec-2021 Print Date 24-Dec-2021 Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR 1910.1200 to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of SDS

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