007_Setfast_Traffic_Marking_Paint_Safety_Data_Sheet.pdf

SETFAST® Low VOC Acrylic Traffic Marking Paint White

Not available.

Liquid.

(216) 566-2917

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Emergency telephone number of the company

Section 1. Identification

Manufacturer : THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

TM5626

TM5626Product code :

Product Information Telephone Number

: (800) 524-5979

Regulatory Information Telephone Number

: (216) 566-2902

Transportation Emergency Telephone Number

: (800) 424-9300

CAS # : Not applicable.

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

Classification of the substance or mixture

Signal word : Danger

Hazard pictograms :

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 6.2%

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Highly flammable liquid and vapor.

Causes serious eye irritation.

May cause cancer.

May cause respiratory irritation.

May cause drowsiness or dizziness.

May cause damage to organs through prolonged or repeated exposure.

:Hazard statements

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 1/14

Section 2. Hazards identification Precautionary statements

Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.

Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling.

Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF IN EYES:

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Store locked up. Store in a well-ventilated place. Keep cool.

Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

: None known.

Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.

Supplemental label elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:

This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure.

Section 3. Composition/information on ingredients

Acetone 26.86 67-64-1 Titanium Dioxide 6.15 13463-67-7 Xylene 2.36 1330-20-7 Ethylbenzene 0.42 100-41-4 Crystalline Silica, respirable powder 0.18 14808-60-7

Ingredient name CAS number% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Other means of identification

: Not available.

Substance/mixture

CAS number/other identifiers

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 2/14

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Description of necessary first aid measures

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:

respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness

No specific data.

No specific data.

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 3/14

Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon dioxide carbon monoxide metal oxide/oxides

Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.

Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 4/14

Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill :

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area.

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.

Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

Acetone ACGIH TLV (United States, 3/2016).

TWA: 250 ppm 8 hours.

STEL: 500 ppm 15 minutes.

NIOSH REL (United States, 10/2013).

TWA: 250 ppm 10 hours.

TWA: 590 mg/m³ 10 hours.

OSHA PEL (United States, 6/2016).

TWA: 1000 ppm 8 hours.

TWA: 2400 mg/m³ 8 hours.

Titanium Dioxide ACGIH TLV (United States, 3/2016).

TWA: 10 mg/m³ 8 hours.

OSHA PEL (United States, 6/2016).

TWA: 15 mg/m³ 8 hours. Form: Total dust

Xylene ACGIH TLV (United States, 3/2016).

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits (OSHA United States)

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 5/14

Section 8. Exposure controls/personal protection TWA: 100 ppm 8 hours.

TWA: 434 mg/m³ 8 hours.

STEL: 150 ppm 15 minutes.

STEL: 651 mg/m³ 15 minutes.

OSHA PEL (United States, 6/2016).

TWA: 100 ppm 8 hours.

TWA: 435 mg/m³ 8 hours.

Ethylbenzene ACGIH TLV (United States, 3/2016).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 10/2013).

TWA: 100 ppm 10 hours.

TWA: 435 mg/m³ 10 hours.

STEL: 125 ppm 15 minutes.

STEL: 545 mg/m³ 15 minutes.

OSHA PEL (United States, 6/2016).

TWA: 100 ppm 8 hours.

TWA: 435 mg/m³ 8 hours.

Crystalline Silica, respirable powder OSHA PEL Z3 (United States, 6/2016).

TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:

Respirable TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:

Respirable OSHA PEL (United States, 6/2016).

TWA: 50 µg/m³ 8 hours. Form: Respirable dust ACGIH TLV (United States, 3/2016).

TWA: 0.025 mg/m³ 8 hours. Form:

Respirable fraction NIOSH REL (United States, 10/2013).

TWA: 0.05 mg/m³ 10 hours. Form: respirable dust

Acetone CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 1200 mg/m³ 8 hours.

15 min OEL: 1800 mg/m³ 15 minutes.

8 hrs OEL: 500 ppm 8 hours.

15 min OEL: 750 ppm 15 minutes.

CA British Columbia Provincial (Canada, 5/2015).

TWA: 250 ppm 8 hours.

STEL: 500 ppm 15 minutes.

CA Ontario Provincial (Canada, 7/2015).

TWA: 500 ppm 8 hours.

STEL: 750 ppm 15 minutes.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 500 ppm 8 hours.

TWAEV: 1190 mg/m³ 8 hours.

STEV: 1000 ppm 15 minutes.

STEV: 2380 mg/m³ 15 minutes.

CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 750 ppm 15 minutes.

TWA: 500 ppm 8 hours.

Ingredient name Exposure limits

Occupational exposure limits (Canada)

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 6/14

Section 8. Exposure controls/personal protection

Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

Respiratory protection :

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls

Section 9. Physical and chemical properties

Physical state

Melting point

Liquid.

Not available.

Not available.Odor pH

Not available.Color

Evaporation rate 5.6 (butyl acetate = 1)

Flash point Closed cup: -17°C (1.4°F) [Pensky-Martens Closed Cup]

Not available.

Not available.Odor threshold

Appearance

Boiling point : 55°C (131°F)

Flammability (solid, gas) : Not available.

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 7/14

Section 9. Physical and chemical properties

Vapor pressure

Relative density

Vapor density

Solubility

1.4

2 [Air = 1]

3.2 kPa (23.998 mm Hg) [at 20°C]

Not available.

Auto-ignition temperature Not available.

Not available.

Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)

Partition coefficient: n-octanol/water

Lower and upper explosive (flammable) limits

: Lower: 1% Upper: 12.8%

Decomposition temperature : Not available.

Heat of combustion : 9.719 kJ/g

Aerosol product

Molecular weight : Not applicable.

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Reactive or incompatible with the following materials:

oxidizing materials

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

Acetone LD50 Oral Rat 5800 mg/kg - Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours

LD50 Oral Rat 4300 mg/kg - Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -

LD50 Oral Rat 3500 mg/kg -

Product/ingredient name Result Species Dose Exposure

Irritation/Corrosion

Information on toxicological effects

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 8/14

Section 11. Toxicological information

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Acetone Eyes - Mild irritant Human - 186300 parts per million

Eyes - Mild irritant Rabbit - 10 microliters - Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams

Eyes - Severe irritant Rabbit - 20 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams

Skin - Mild irritant Rabbit - 395 milligrams

Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent

Xylene Eyes - Mild irritant Rabbit - 87 milligrams - Eyes - Severe irritant Rabbit - 24 hours 5 milligrams

Skin - Mild irritant Rat - 8 hours 60 microliters

Skin - Moderate irritant Rabbit - 24 hours 500 milligrams

Skin - Moderate irritant Rabbit - 100 Percent - Ethylbenzene Eyes - Severe irritant Rabbit - 500 milligrams

Skin - Mild irritant Rabbit - 24 hours 15 milligrams

Product/ingredient name Result Score Exposure Observation

Sensitization

Not available.

Species

Specific target organ toxicity (single exposure)

Classification

Titanium Dioxide - 2B - Xylene - 3 - Ethylbenzene - 2B - Crystalline Silica, respirable powder

- 1 Known to be a human carcinogen.

Product/ingredient name NTPIARCOSHA

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 9/14

Section 11. Toxicological information

Specific target organ toxicity (repeated exposure)

Acetone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects

Xylene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects

Ethylbenzene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects

Name Category

Name Category

Acetone Category 2 Not determined Not determined Xylene Category 2 Not determined Not determined Ethylbenzene Category 2 Not determined Not determined Crystalline Silica, respirable powder Category 1 Inhalation Not determined

Aspiration hazard

Name Result

Xylene ASPIRATION HAZARD - Category 1 Ethylbenzene ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Route of exposure

Target organs

Information on the likely routes of exposure

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:

respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness

No specific data.

No specific data.

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

Delayed and immediate effects and also chronic effects from short and long term exposure

: Not available.

Potential acute health effects

Short term exposure

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 10/14

Not available.

May cause damage to organs through prolonged or repeated exposure.General :

May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Potential chronic health effects

Numerical measures of toxicity

Oral 182293.2 mg/kg Inhalation (gases) 211968.8 ppm

Route ATE value

Acute toxicity estimates

Potential immediate effects

: Not available.

Potential delayed effects : Not available.

Potential immediate effects

: Not available.

Long term exposure

Potential delayed effects : Not available.

Section 12. Ecological information Toxicity

Acetone Acute EC50 7200000 µg/l Fresh water Algae - Selenastrum sp. 96 hours Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours Acute LC50 6900 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna -

Neonate 21 days

Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours Xylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours

Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours

Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata

96 hours

Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. - Nauplii

48 hours

Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna - Neonate

48 hours

Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 11/14

Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

Xylene - 8.1 to 25.9 low

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Acetone - - Readily Xylene - - Readily Ethylbenzene - - Readily

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Section 14. Transport information

PAINT

II

PAINT

II

UN1263 UN1263

DOT

Classification

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Environmental hazards

No. No.

TDG

Classification

UN1263

PAINT

II

No.

Mexico Classification

UN1263

PAINT

II

No.

IATA

UN1263

PAINT

II

No.

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Section 14. Transport information

- Emergency schedules (EmS) F-E, S-E

Additional information

Special precautions for user

Transport in bulk according to Annex II of MARPOL and the IBC Code

Not available.

Proper shipping name :

Ship type : Not available.

Pollution category : Not available.

Not available.

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.

18-2.19 (Class 3).

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.

ERG No.

128 128

ERG No. ERG No.

Section 15. Regulatory information

SARA 313

SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

California Prop. 65

Section 16. Other information Hazardous Material Information System (U.S.A.)

*Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.

1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Procedure used to derive the classification

Classification Justification

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 13/14

Section 16. Other information

11/16/2016

History

Date of printing

Date of issue/Date of revision

Version

It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.

Notice to reader

Date of previous issue

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

11/16/2016

6/16/2016

FLAMMABLE LIQUIDS - Category 2 On basis of test data SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 1A Calculation method

SPECIFIC TARGET ORGAN TOXICITY (SINGLE

EXPOSURE) (Respiratory tract irritation) - Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (SINGLE

EXPOSURE) (Narcotic effects) - Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (REPEATED

EXPOSURE) - Category 2

Calculation method

Date of issue/Date of revision : 11/16/2016 Date of previous issue : 6/16/2016 Version : 4 14/14