South Elizabeth Channel Upland Data Tables - Final.pdf

South Elizabeth Channel Upland - 2020

South Elizabeth Channel Upland - COMP A - Sediment Volatiles

Volatiles Action Level Action Level Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200627 #20200629 #20200629 ug/kg ug/L COMP A Q A COMP A Q A COMP A Q

Chloromethane (Methyl Chloride) 4000 30 14 U 12 U 1.0 U

Bromomethane 25000 10 14 U 12 U 1.0 U

Vinyl chloride 700 5 14 U 12 U 1.0 U

Chloroethane 220000 NA 14 U 12 U 1.0 U

Methylene chloride (Dichloromethane) 34000 3 14 U * 12 U * 11

Acetone 70000000 700 15 J 23 J 72

Carbon disulfide 7800000 NA 14 U 12 U 1.0 U

1,1-Dichloroethene 11000 2 14 U 12 U 1.0 U

1,1-Dichloroethane 8000 50 14 U 12 U 1.0 U

1,2-Dichloroethene (total) 10 27 U 23 U 2.0 U

Chloroform 600 6 14 U 12 U 1.0 U

1,2-Dichloroethane 900 NA 14 U 12 U 1.0 U

2-Butanone (MEK) 3100000 300 14 U 12 U 5.0 U

1,1,1-Trichloroethane 290000 30 14 U 12 U 1.0 U

Carbon tetrachloride 600 2 14 U 12 U 1.0 U

Bromodichloromethane 1000 1 14 U 12 U 1.0 U

1,2-Dichloropropane 2000 1 14 U 12 U 1.0 U cis-1,3-Dichloropropene NA NA 14 U 12 U 1.0 U

Trichloroethene 7000 1 14 U 12 U 1.0 U

Dibromochloromethane 3000 10 14 U 12 U 1.0 U

1,1,2-Trichloroethane 2000 3 14 U 12 U 1.0 U

Benzene 2000 1 14 U 12 U 1.0 U trans-1,3-dichloropropene NA NA 14 U 12 U 1.0 U

Bromoform 81000 4 14 U 12 U 1.0 U

Tetrachloroethene 2000 1 14 U 12 U 1.0 U

1,1,2,2-Tetrachloroethane 1000 NA 14 U 12 U 1.0 U

Toluene 6300000 1000 14 U 12 U 1.0 U

Chlorobenzene 510000 50 14 U 12 U 1.0 U

Ethyl benzene 7800000 700 14 U 12 U 1.0 U

Styrene 90000 100 14 U 12 U 1.0 U

Xylenes(Total) 12000000 1000 27 U 23 U 2.0 U

Acrolein 500 270 U 230 U 20 U

Acrylonitrile 900 140 U 120 U 20 U

1,2-Dibromo-3-chloropropane 80 14 U 12 U 1.0 U

1,2-Dibromoethane 8 14 U 12 U 1.0 U

Dichlorodifluoromethane 490000 14 U 12 U 1.0 U

1,2-Dichloroethene (cis) 230000 14 U 12 U 1.0 U

1,2-Dichloroethene (trans) 300000 14 U 12 U 1.0 U

Methyl acetate 78000000 68 U 58 U 5.0 U

Methyl tert-butyl ether (MTBE) 110000 14 U 12 U 1.0 U

Tertiary butyl alcohol (TBA) 1400000 140 U 120 U 40 U

Trichlorofluoromethane 23000000 14 U 12 U 1.0 U

1,4-dioxane 2700 U 2300 U 200 U n-propylbenzene 14 U 12 U 1.0 U sec-butylbenzene 14 U 12 U 1.0 U tert-butylbenzene 14 U 12 U 1.0 U

1,2,4-trimethylbenzene 14 U 12 U 1.0 U

1,3,5-trimethylbenzene 14 U 12 U 1.0 U n‐Butylbenzene 14 U 12 U 1.0 U

South Elizabeth Channel Upland - COMP A - Sediment Semivolatiles

Semivolatiles Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200627 #20200629 #20200629 ug/kg ug/kg mg/L mg/L COMP A Q A COMP A Q A COMP A Q

Phenol 18000000 660 4 0.01 890 U 580 U 0.001 U bis(2-Chloroethyl)ether 400 660 0.01 0.01 180 U 120 U 0.00019 U

2-Chlorophenol 310000 660 0.005 0.01 890 U 580 U 0.001 U

1,3-Dichlorobenzene 5300000 660 0.6 0.01 14 U 12 U 0.001 U

1,4-Dichlorobenzene 5000 660 0.075 0.01 14 U 12 U 0.001 U

1,2-Dichlorobenzene 5300000 660 0.6 0.01 14 U 12 U 0.001 U

2-Methylphenol (o-cresol) 310000 660 NA 0.01 890 U 580 U 0.001 U

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 180 U 120 U 0.00019 U

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 890 U 580 U 0.001 U

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 180 U 120 U 0.00019 U

Hexachloroethane 35000 660 0.01 0.01 890 U 580 U 0.001 U

Nitrobenzene 31000 660 0.01 0.01 1800 U 1200 U 0.002 U Isophorone 510000 660 0.1 0.01 890 U 580 U 0.00047 J

2,4-Dimethylphenol 1200000 660 0.1 0.01 890 U 580 U 0.001 U

2,4-Dichlorophenol 180000 660 0.02 0.01 180 U 120 U 0.00019 U

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 14 U 12 U 0.001 U

Naphthalene 6000 660 0.3 0.01 56 J 58 J 0.00023

Hexachloro-1,3-butadiene 6000 660 NA 0.01 180 U 120 U 0.00019 U

2-Methylnaphthalene 230000 660 NA 0.01 46 J 43 J 0.00032

Hexachlorocyclopentadiene 45000 660 0.05 0.01 890 U 580 U 0.001 U

2,4,6-Trichlorophenol 19000 660 0.02 0.01 890 U 580 U 0.001 U

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 890 U 580 U 0.001 U

2-Chloronaphthalene NA 660 NA 0.01 180 U 120 U 0.00019 U

2-Nitroaniline 39000 3300 NA 0.05 4600 U 3000 U 0.005 U

Acenaphthylene 300000000 660 NA 0.01 150 J 130 0.00019 U

2,6-Dinitrotoluene 700 660 0.01 0.01 890 U 580 U 0.001 U

South Elizabeth Channel Upland - COMP A - Sediment Semivolatiles, con't.

Semivolatiles, continued Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200627 #20200629 #20200629 ug/kg ug/kg mg/L mg/L COMP A Q A COMP A Q A COMP A Q

Acenaphthene 3400000 660 0.4 0.01 58 J 54 J 0.00019 U

2,4-Dinitrophenol 120000 3300 0.04 0.05 8900 U 5800 U 0.01 U

Dibenzofuran NA 660 NA 0.01 890 U 39 J 0.001 U

2,4-Dinitrotoluene 700 660 0.01 0.01 890 U 580 U 0.001 U

Diethylphthalate 49000000 660 5 0.01 890 U 580 U 0.001 U

Fluorene 2300000 660 0.3 0.01 77 J 66 J 0.00019 U

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 4600 U 3000 U 0.005 U

N-Nitrosodiphenylamine 99000 660 0.02 0.01 890 U 580 U 0.001 U

Hexachlorobenzene 300 660 0.01 0.01 180 U 120 U 0.00019 U

Pentachlorophenol 3000 3300 0.001 0.05 4600 U 3000 U 0.005 U

Phenanthrene 300000000 6600 NA 0.01 200 200 0.00014 J

Anthracene 17000000 6600 2 0.01 140 J 120 0.000057 J

Carbazole 24000 330 NA 0.01 180 U 120 U 0.00019 U

Di-n-butylphthalate 6100000 330 0.9 0.01 890 U 580 U 0.001 U

Fluoranthene 2300000 660 0.3 0.01 560 490 0.00019 U

Pyrene 1700000 660 0.2 0.01 540 470 0.00019 U

Butylbenzylphthalate 1200000 660 0.1 0.01 890 U 580 U 0.00072 J B

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 890 U 580 U 0.001 U

Benzo(a)anthracene 600 660 NA 0.01 280 270 0.00019 U

Chrysene 62000 660 NA 0.01 310 290 0.00019 U bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 8900 U 740 J 0.01 U

DI-n-octylphthalate 2400000 660 0.1 0.01 890 U 580 U 0.001 U

Benzo(b)fluoranthene 600 660 NA 0.01 460 430 0.00019 U

Benzo(k)fluoranthene 6000 660 NA 0.01 110 J 87 J 0.00019 U

Benzo(a)pyrene 200 660 NA 0.01 350 320 0.00019 U

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 240 210 0.00019 U

Dibenzo(a,h)anthracene 200 660 NA 0.01 180 U 120 U 0.00019 U

Benzo(ghi)perylene 30000000 660 NA 0.01 290 270 0.00019 U

Acetophenone 2000 1800 U 1200 U 0.00015 J

Atrazine 210000 1800 U 1200 U 0.001 U

Benzaldehyde 6100000 1800 U 1200 U 0.0011 *

Benzidine 700 18000 U 12000 U 0.02 U

1,1'-Biphenyl 3100000 890 U 580 U 0.001 U

Caprolactam 31000000 4600 U 3000 U 0.005 U

1,2-Diphenylhydrazine 700 890 U 580 U 0.001 U

N-Nitrosodimethylamine 700 890 U 580 U 0.001 U

South Elizabeth Channel Upland - COMP A - Pesticides/Aroclors

Pesticides/Aroclors Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200627 #20200629 #20200629 ug/kg ug/kg mg/L mg/L COMP A Q A COMP A Q A COMP A Q alpha-BHC 100 1.9 0.00002 0.00005 0.56 U 0.47 U 0.000012 p beta-BHC 400 3.3 0.0002 0.00005 0.56 U 0.47 U 0.0000013 U delta-BHC NA 1.7 NA 0.00005 0.56 U 0.47 U 0.0000013 U gamma-BHC (Lindane) 400 2 0.0002 0.00005 0.56 U 0.47 U 0.0000013 U

Heptachlor 100 2.1 0.0004 0.00005 0.56 U 0.47 U 0.000002

Aldrin 40 2 0.00004 0.00005 0.56 U 0.47 U 0.0000013 U

Heptachlor epoxide 70 2.1 0.0002 0.00005 0.56 U 0.47 U 0.0000017

Endosulfan I NA 2.1 0.0004 0.00005 0.56 U 0.47 U 0.0000013 U

Dieldrin 40 3.3 0.00003 0.0001 0.56 U 0.47 U 0.0000013 U

4,4'-DDE 2000 4.2 0.0001 0.0001 24 19 0.0000013 U

Endrin 23000 3.6 0.002 0.0001 4.4 3.5 0.0000013 U

Endosulfan II NA 3.3 0.0004 0.0001 0.56 U 0.47 U 0.0000013 U

4,4'-DDD 3000 4.2 0.0001 0.0001 5.9 p 4.9 p 0.0000013 U

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.56 U 0.47 U 0.0000013 U

4,4'-DDT 2000 3.6 0.0001 0.0001 3.1 p 21 0.0000013 U

Methoxychlor 390000 17 0.04 0.001 0.56 U 0.47 U 0.0000013 U alpha-Chlordane 200 1.7 NA 0.00005 2.1 1.6 0.0000013 U gamma-Chlordane 200 1.7 0.0005 0.00005 4.7 3.7 0.0000013 U

Toxaphene 600 170 0.003 0.005 22 U 19 U 0.000097 U

Mirex 0.56 U 0.47 U 0.0000013 U

Aroclor‐1016 11 U 9.5 U 0.0000097 U

Aroclor‐1221 11 U 9.5 U 0.0000097 U

Aroclor‐1232 11 U 9.5 U 0.0000097 U

Aroclor‐1242 11 U 9.5 U 0.0000097 U

Aroclor‐1248 110 56 0.0000097 U

Aroclor‐1254 11 U 9.5 U 0.0000097 U

Aroclor‐1260 57 32 0.0000097 U

Total Aroclor(SUM)

South Elizabeth Channel Upland - COMP A - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200627 #20200629 #20200629

COMP A Q A COMP A Q A COMP A Q

2,4,5-TP (Silvex) NA NA NA NA 54 U 46 U 0.98 U

South Elizabeth Channel Upland ‐ COMP A ‐ Metals

Metals Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200627 #20200629 #20200629 mg/kg mg/kg mg/L mg/L COMP A Q A COMP A Q A COMP A Q

Aluminum 78000 40 0.2 0.2 14000 15000 2 B

Antimony 31 12 0.02 0.06 0.63 0.71 0.0017 J

Arsenic 19 2 0.008 0.01 14 13 0.0053

Barium 16000 40 2 0.2 100 110 0.01

Beryllium 16 1 0.02 0.005 0.96 0.77 0.001 U

Cadmium 78 1 0.004 0.005 0.87 0.76 0.001 U

Chromium NA 2 0.1 0.01 72 65 0.0095

Hexavalent Chromium 120000 1.1 U 0.94 U 0.010 U

Trivalent Chromium 20 72 65 0.0095 J

Cobalt 1,600 10 NA 0.05 11 11 0.0016

Copper 590 5 1 0.025 100 95 0.068 B

Lead 400 0.6 0.01 0.003 110 96 0.00016 J B

Manganese 5900 3 0.05 0.015 520 510 0.005 U

Mercury 23 0.1 0.002 0.0002 1.6 1.2 0.0002 U

Nickel 1,600 8 0.1 0.04 31 30 0.0074

Selenium 390 1 0.05 0.015 0.73 0.64 0.0027 J

Silver 390 2 NA 0.01 1.5 1.2 0.001 U

Vanadium 78 10 NA 0.05 36 36 0.062

Zinc 23,000 4 5 0.02 210 260 0.005 U

Cyanide, total 1,600 0.5 0.2 0.01 0.34 J 0.24 J 0.01 U

%Solids NA NA NA NA 36.8 43

South Elizabeth Channel Upland ‐ COMP A ‐ Dioxin/Furan

Dioxin/Furan Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP

(Units: pg/L)

ASI ID # Soil Leachate #20200627 #20200629 #20200629 ng/kg pg/L COMP A Q A COMP A Q A COMP A Q

2,3,7,8‐TCDD NA NA NA NA 30 32 9.5 U

1,2,3,7,8‐PeCDD NA NA NA NA 4.8 J B q 3.4 J B q 48 U

1,2,3,4,7,8‐HxCDD NA NA NA NA 5.2 J B 4.2 J B 1.0 J B q

1,2,3,6,7,8‐HxCDD NA NA NA NA 18 B 14 B 48 U

1,2,3,7,8,9‐HxCDD NA NA NA NA 19 B 14 B 0.88 J B q

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 350 B 300 B 48 U

OCDD NA NA NA NA 3200 B 2800 B 3.4 J B

2,3,7,8‐TCDF NA NA NA NA 15 13 9.5 U

1,2,3,7,8‐PeCDF NA NA NA NA 6.4 J 4.7 J q 48 U

2,3,4,7,8‐PeCDF NA NA NA NA 11 8.1 48 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 35 B 24 B 48 U

1,2,3,6,7,8‐HxCDF NA NA NA NA 13 I B 10 I B 48 U

2,3,4,6,7,8‐HxCDF NA NA NA NA 6.3 J B 4.8 J B 48 U

1,2,3,7,8,9‐HxCDF NA NA NA NA 6.5 U 5.6 U 48 U

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 180 B 130 B 0.57 J B

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 10 B 6.3 B 48 U

OCDF NA NA NA NA 310 B 210 B 1.5 J B q

South Elizabeth Channel Upland ‐ COMP A ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt)

SPLP

(Units: pg/L)

ASI ID # #20200608 #20200629 #20200629

COMP A Q A COMP A Q A COMP A Q

2,3,7,8‐TCDD 1 30.00 32.00 9.50 U

1,2,3,7,8‐PeCDD 1 4.80 J B q 3.40 J B q 48.00 U

1,2,3,4,7,8‐HxCDD 0.1 0.52 J B 0.42 J B 0.10 J B q

1,2,3,6,7,8‐HxCDD 0.1 1.80 B 1.40 B 4.80 U

1,2,3,7,8,9‐HxCDD 0.1 1.90 B 1.40 B 0.09 J B q

1,2,3,4,6,7,8‐HpCDD 0.01 3.50 B 3.00 B 0.48 U

1,2,3,4,6,7,8,9‐OCDD 0.0003 0.96 B 0.84 B 0.00 J B

2,3,7,8‐TCDF 0.1 1.50 1.30 0.95 U

1,2,3,7,8‐PeCDF 0.03 0.19 J 0.14 J q 1.44 U

2,3,4,7,8‐PeCDF 0.3 3.30 2.43 14.40 U

1,2,3,4,7,8‐HxCDF 0.1 3.50 B 2.40 B 4.80 U

1,2,3,6,7,8‐HxCDF 0.1 1.30 I B 1.00 I B 4.80 U

2,3,4,6,7,8‐HxCDF 0.1 0.63 J B 0.48 J B 4.80 U

1,2,3,7,8,9‐HxCDF 0.1 0.65 U 0.56 U 4.80 U

1,2,3,4,6,7,8‐HpCDF 0.01 1.80 B 1.30 B 0.01 J B

1,2,3,4,7,8,9‐HpCDF 0.01 0.10 B 0.06 B 0.48 U

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.09 B 0.06 B 0.00 J B q

TOTAL TEF as 2,3,7,8‐TCDD 56.55 52.20 99.45

South Elizabeth Channel Upland - 2020

South Elizabeth Channel Upland - COMP B - Sediment Volatiles

Volatiles Action Level Action Level Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200628 #20200630 #20200630 ug/kg ug/L COMP B Q A COMP B Q A COMP B Q

Chloromethane (Methyl Chloride) 4000 30 13 U 11 U 1.0 U

Bromomethane 25000 10 13 U 11 U 1.0 U

Vinyl chloride 700 5 13 U 11 U 1.0 U

Chloroethane 220000 NA 13 U 11 U 1.0 U

Methylene chloride (Dichloromethane) 34000 3 13 U * F1 11 U * 11

Acetone 70000000 700 20 J 16 J 58

Carbon disulfide 7800000 NA 13 U 11 U 1.0 U F1

1,1-Dichloroethene 11000 2 13 U 11 U 1.0 U F1

1,1-Dichloroethane 8000 50 13 U 11 U 1.0 U

1,2-Dichloroethene (total) 10 26 U 23 U 2.0 U F1

Chloroform 600 6 13 U 11 U 1.0 U F1

1,2-Dichloroethane 900 NA 13 U 11 U 1.0 U

2-Butanone (MEK) 3100000 300 13 U 11 U 4.5 J

1,1,1-Trichloroethane 290000 30 13 U 11 U 1.0 U

Carbon tetrachloride 600 2 13 U 11 U 1.0 U

Bromodichloromethane 1000 1 13 U 11 U 1.0 U

1,2-Dichloropropane 2000 1 13 U 11 U 1.0 U cis-1,3-Dichloropropene NA NA 13 U 11 U 1.0 U

Trichloroethene 7000 1 13 U 11 U 1.0 U F1

Dibromochloromethane 3000 10 13 U 11 U 1.0 U

1,1,2-Trichloroethane 2000 3 13 U 11 U 1.0 U

Benzene 2000 1 13 U 11 U 1.0 U trans-1,3-dichloropropene NA NA 13 U 11 U 1.0 U

Bromoform 81000 4 13 U 11 U 1.0 U

Tetrachloroethene 2000 1 13 U 11 U 1.0 U

1,1,2,2-Tetrachloroethane 1000 NA 13 U 11 U 1.0 U F1

Toluene 6300000 1000 13 U 11 U 1.0 U

Chlorobenzene 510000 50 13 U 11 U 1.0 U

Ethyl benzene 7800000 700 13 U 11 U 1.0 U F1

Styrene 90000 100 13 U 11 U 1.0 U F1

Xylenes(Total) 12000000 1000 26 U 23 U 2.0 U F1

Acrolein 500 260 U 230 U 20 U F1

Acrylonitrile 900 130 U 110 U 20 U

1,2-Dibromo-3-chloropropane 80 13 U 11 U 1.0 U

1,2-Dibromoethane 8 13 U 11 U 1.0 U

Dichlorodifluoromethane 490000 13 U 11 U 1.0 U

1,2-Dichloroethene (cis) 230000 13 U 11 U 1.0 U F1

1,2-Dichloroethene (trans) 300000 13 U 11 U 1.0 U F1

Methyl acetate 78000000 65 U 56 U 5.0 U F1

Methyl tert-butyl ether (MTBE) 110000 13 U 11 U 1.0 U

Tertiary butyl alcohol (TBA) 1400000 130 U 110 U 40 U

Trichlorofluoromethane 23000000 13 U F2 11 U 1.0 U

1,4-dioxane 2600 U 2300 U 200 U n-propylbenzene 13 U F2 11 U 1.0 U sec-butylbenzene 13 U 11 U 1.0 U tert-butylbenzene 13 U 11 U 1.0 U F1

1,2,4-trimethylbenzene 13 U 11 U 0.53 J

1,3,5-trimethylbenzene 13 U 11 U 1.0 U n‐Butylbenzene 13 U 11 U 1.0 U

South Elizabeth Channel Upland - COMP B - Sediment Semivolatiles

Semivolatiles Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP (Units:

mg/L)

ASI ID # Soil Leachate #20200628 #20200630 #20200630 ug/kg ug/kg mg/L mg/L COMP B Q A COMP B Q A COMP B Q

Phenol 18000000 660 4 0.01 1100 U F1 560 U 0.001 U F1 bis(2-Chloroethyl)ether 400 660 0.01 0.01 220 U F1 F2 110 U 0.00019 U F1

2-Chlorophenol 310000 660 0.005 0.01 1100 U F1 F2 560 U 0.001 U F1

1,3-Dichlorobenzene 5300000 660 0.6 0.01 13 U 11 U 0.001 U

1,4-Dichlorobenzene 5000 660 0.075 0.01 13 U 11 U 0.001 U

1,2-Dichlorobenzene 5300000 660 0.6 0.01 13 U 11 U 0.001 U

2-Methylphenol (o-cresol) 310000 660 NA 0.01 1100 U 560 U 0.001 U F1

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 23000 660 0.3 0.01 220 U F1 F2 110 U 0.00019 U F1

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 31000 660 NA 0.01 1100 U 560 U 0.001 U F1

N-Nitroso-Di-N-Propylamine 200 660 0.02 0.01 220 U F1 F2 110 U 0.00019 U F1

Hexachloroethane 35000 660 0.01 0.01 1100 U F1 F2 560 U 0.001 U F1

Nitrobenzene 31000 660 0.01 0.01 2200 U F1 1100 U 0.002 U F1 Isophorone 510000 660 0.1 0.01 1100 U F2 560 U 0.00053 J F1

2,4-Dimethylphenol 1200000 660 0.1 0.01 1100 U 560 U 0.001 U F1

2,4-Dichlorophenol 180000 660 0.02 0.01 220 U 110 U 0.00019 U F1

1,2,4-Trichlorobenzene 73000 660 0.009 0.01 13 U 11 U 0.001 U

Naphthalene 6000 660 0.3 0.01 220 U F1 F2 55 J 0.0002 F1

Hexachloro-1,3-butadiene 6000 660 NA 0.01 220 U 110 U 0.00019 U F1

2-Methylnaphthalene 230000 660 NA 0.01 220 U 39 J 0.00029 F1

Hexachlorocyclopentadiene 45000 660 0.05 0.01 1100 U F1 560 U 0.001 U F1

2,4,6-Trichlorophenol 19000 660 0.02 0.01 1100 U 560 U 0.001 U F1 F2

2,4,5-Trichlorophenol 6100000 660 0.7 0.01 1100 U 560 U 0.001 U F1 F2

2-Chloronaphthalene NA 660 NA 0.01 220 U 110 U 0.00019 U F1

2-Nitroaniline 39000 3300 NA 0.05 5600 U 2900 U 0.005 U F1 F2

Acenaphthylene 300000000 660 NA 0.01 300 120 0.00019 U F1

2,6-Dinitrotoluene 700 660 0.01 0.01 1100 U 560 U 0.001 U F1

South Elizabeth Channel Upland - COMP B - Sediment Semivolatiles, con't.

Semivolatiles, continued Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200628 #20200630 #20200630 ug/kg ug/kg mg/L mg/L COMP B Q A COMP B Q A COMP B Q

Acenaphthene 3400000 660 0.4 0.01 220 U 38 J 0.00019 U F1

2,4-Dinitrophenol 120000 3300 0.04 0.05 11000 U 5600 U 0.01 U F1

Dibenzofuran NA 660 NA 0.01 1100 U 25 J 0.001 U F1

2,4-Dinitrotoluene 700 660 0.01 0.01 1100 U 560 U 0.001 U F1

Diethylphthalate 49000000 660 5 0.01 1100 U 560 U 0.001 U F1

Fluorene 2300000 660 0.3 0.01 220 U 48 J 0.00019 U F1

4,6-Dinitro-2-methylphenol 6000 3300 NA 0.05 5600 U 2900 U 0.005 U F1 F2

N-Nitrosodiphenylamine 99000 660 0.02 0.01 1100 U 560 U 0.001 U F1 F2

Hexachlorobenzene 300 660 0.01 0.01 220 U 110 U 0.00019 U F1

Pentachlorophenol 3000 3300 0.001 0.05 5600 U F1 2900 U 0.005 U F1 F2

Phenanthrene 300000000 6600 NA 0.01 110 J 150 0.000088 J F1

Anthracene 17000000 6600 2 0.01 93 J 130 0.00019 U F1

Carbazole 24000 330 NA 0.01 220 U 110 U 0.00019 U F1 F2

Di-n-butylphthalate 6100000 330 0.9 0.01 1100 U 560 U 0.001 U F1

Fluoranthene 2300000 660 0.3 0.01 310 470 0.00011 J F1

Pyrene 1700000 660 0.2 0.01 390 F1 470 0.00019 U F1

Butylbenzylphthalate 1200000 660 0.1 0.01 1100 U F1 560 U 0.001 U F1

3,3'-Dichlorobenzidine 1000 1300 0.06 0.02 1100 U 560 U 0.001 U F1

Benzo(a)anthracene 600 660 NA 0.01 210 J 260 0.00019 U F1

Chrysene 62000 660 NA 0.01 220 F1 290 0.00019 U F1 bis(2-Ethylhexyl)phthalate 35000 660 0.03 0.01 11000 U 790 J 0.01 U

DI-n-octylphthalate 2400000 660 0.1 0.01 1100 U F1 560 U 0.001 U *3

Benzo(b)fluoranthene 600 660 NA 0.01 340 370 0.00019 U *3 F1

Benzo(k)fluoranthene 6000 660 NA 0.01 70 J 120 0.00019 U *3 F1

Benzo(a)pyrene 200 660 NA 0.01 270 310 0.00019 U *3 F1

Indeno(1,2,3-cd)pyrene 600 660 NA 0.01 190 J 200 0.00019 U *3 F1

Dibenzo(a,h)anthracene 200 660 NA 0.01 220 U 110 U 0.00019 U *3

Benzo(ghi)perylene 30000000 660 NA 0.01 230 270 0.00019 U *3 F1

Acetophenone 2000 2200 U F1 F2 1100 U 0.00019 J F1

Atrazine 210000 2200 U 1100 U 0.001 U F1

Benzaldehyde 6100000 2200 U F1 1100 U 0.00098 J *

Benzidine 700 22000 U 11000 U 0.02 U F1

1,1'-Biphenyl 3100000 1100 U 560 U 0.001 U F1

Caprolactam 31000000 5600 U F1 2900 U 0.005 U F1

1,2-Diphenylhydrazine 700 1100 U 560 U 0.001 U F1

N-Nitrosodimethylamine 700 1100 U F1 560 U 0.001 U F1

South Elizabeth Channel Upland - COMP B - Pesticides/Aroclors

Pesticides/Aroclors Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200628 #20200630 #20200630 ug/kg ug/kg mg/L mg/L COMP B Q A COMP B Q A COMP B Q alpha-BHC 100 1.9 0.00002 0.00005 0.53 U 0.46 U 0.000021 p beta-BHC 400 3.3 0.0002 0.00005 0.53 U 0.46 U 0.0000013 U delta-BHC NA 1.7 NA 0.00005 0.53 U 0.46 U 0.0000013 U gamma-BHC (Lindane) 400 2 0.0002 0.00005 0.53 U 0.46 U 0.0000013 U

Heptachlor 100 2.1 0.0004 0.00005 0.53 U 0.46 U 0.0000013 U

Aldrin 40 2 0.00004 0.00005 0.53 U 0.46 U 0.0000013 U

Heptachlor epoxide 70 2.1 0.0002 0.00005 0.53 U 0.46 U 0.0000013 U

Endosulfan I NA 2.1 0.0004 0.00005 0.53 U 0.46 U 0.0000013 U

Dieldrin 40 3.3 0.00003 0.0001 0.69 0.46 U 0.0000026 p

4,4'-DDE 2000 4.2 0.0001 0.0001 25 21 0.0000013 U

Endrin 23000 3.6 0.002 0.0001 4.3 F1 3.7 0.0000013 U

Endosulfan II NA 3.3 0.0004 0.0001 0.53 U 0.46 U 0.0000013 U

4,4'-DDD 3000 4.2 0.0001 0.0001 5.2 p 7.7 0.0000013 U

Endosulfan sulfate 470000 3.6 0.0004 0.0001 0.53 U 0.46 U 0.0000013 U

4,4'-DDT 2000 3.6 0.0001 0.0001 0.53 U F1 F2 9.8 p 0.0000013 U

Methoxychlor 390000 17 0.04 0.001 0.53 U F1 F2 0.46 U 0.0000013 U alpha-Chlordane 200 1.7 NA 0.00005 1.7 1.7 0.0000013 U gamma-Chlordane 200 1.7 0.0005 0.00005 5.0 F1 0.46 U 0.0000013 U F1

Toxaphene 600 170 0.003 0.005 21 U 18 U 0.000097 U

Mirex 0.53 U 0.46 U 0.0000013 U

Aroclor‐1016 11 U F1 9.3 U 0.0000097 U

Aroclor‐1221 11 U 9.3 U 0.0000097 U

Aroclor‐1232 11 U 9.3 U 0.0000097 U

Aroclor‐1242 11 U 9.3 U 0.0000097 U

Aroclor‐1248 120 74 0.0000097 U

Aroclor‐1254 11 U 9.3 U 0.0000097 U

Aroclor‐1260 59 F1 44 p 0.0000097 U

Total Aroclor(SUM)

South Elizabeth Channel Upland - COMP B - Herbicides

Herbicides Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: ug/kg) Amended Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # Soil Leachate #20200628 #20200630 #20200630

COMP B Q A COMP B Q A COMP B Q

2,4,5-TP (Silvex) NA NA NA NA 52 U 45 U 0.98 U

South Elizabeth Channel Upland - COMP B - Metals

Metals Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: mg/kg) Amended Sediment

(Units: mg/kg)

SPLP

(Units: mg/L)

ASI ID # Soil Leachate #20200628 #20200630 #20200630 mg/kg mg/kg mg/L mg/L COMP B Q A COMP B Q A COMP B Q

Aluminum 78000 40 0.2 0.2 14000 15000 6.1 F2 F1 B

Antimony 31 12 0.02 0.06 0.65 F1 0.72 F1 0.0016 J

Arsenic 19 2 0.008 0.01 16 13 F1 0.0037

Barium 16000 40 2 0.2 110 110 F1 0.014

Beryllium 16 1 0.02 0.005 0.75 0.79 F1 0.001 U

Cadmium 78 1 0.004 0.005 1.2 0.88 F1 0.001 U

Chromium NA 2 0.1 0.01 81 70 F1 0.0042

Hexavalent Chromium 120000 1.1 U F1 0.90 U 0.010 U F1

Trivalent Chromium 20 81 70 0.0042 J

Cobalt 1,600 10 NA 0.05 12 11 F1 0.0013

Copper 590 5 1 0.025 120 100 F1 0.036 B

Lead 400 0.6 0.01 0.003 130 110 F1 0.001 U

Manganese 5900 3 0.05 0.015 540 500 0.005 U

Mercury 23 0.1 0.002 0.0002 1.6 1.5 0.0002 U

Nickel 1,600 8 0.1 0.04 35 31 F1 0.0063

Selenium 390 1 0.05 0.015 0.78 0.68 F1 0.0017 J

Silver 390 2 NA 0.01 1.7 1.4 F1 0.001 U

Vanadium 78 10 NA 0.05 39 36 F1 0.03

Zinc 23,000 4 5 0.02 220 240 0.005 U

Cyanide, total 1,600 0.5 0.2 0.01 0.42 J F1 0.47 U F1 F2 0.01 U

%Solids NA NA NA NA 38.2 44.3

South Elizabeth Channel Upland - COMP B - Dioxin/Furan

Dioxin/Furan Action Level NJDEP DL Action Level NJDEP DL Unamended Sediment

(Units: pg/g) Amended Sediment

(Units: pg/g)

SPLP

(Units: pg/L)

ASI ID # Soil Leachate #20200628 #20200630 #20200630 ng/kg pg/L COMP B Q A COMP B Q A COMP B Q

2,3,7,8‐TCDD NA NA NA NA 43 F1 33 9.5 U

1,2,3,7,8‐PeCDD NA NA NA NA 5.5 J B q 3.3 J B q 48 U

1,2,3,4,7,8‐HxCDD NA NA NA NA 5.4 J B 3.8 J B 48 U

1,2,3,6,7,8‐HxCDD NA NA NA NA 18 B 13 B 48 U

1,2,3,7,8,9‐HxCDD NA NA NA NA 19 B 13 B 48 U

1,2,3,4,6,7,8‐HpCDD NA NA NA NA 410 F1 B 270 B 48 U

OCDD NA NA NA NA 3900 B 2600 B 3.1 J q B

2,3,7,8‐TCDF NA NA NA NA 16 11 9.5 U

1,2,3,7,8‐PeCDF NA NA NA NA 7.9 6.0 48 U

2,3,4,7,8‐PeCDF NA NA NA NA 12 8.5 48 U

1,2,3,4,7,8‐HxCDF NA NA NA NA 35 B 28 B 48 U

1,2,3,6,7,8‐HxCDF NA NA NA NA 14 I B 11 I B 48 U

2,3,4,6,7,8‐HxCDF NA NA NA NA 6.6 B 5.2 J B 48 U

1,2,3,7,8,9‐HxCDF NA NA NA NA 6.3 U 5.5 U 48 U

1,2,3,4,6,7,8‐HpCDF NA NA NA NA 190 F1 B 130 B 0.75 J q B

1,2,3,4,7,8,9‐HpCDF NA NA NA NA 11 B 7.2 B 48 U

OCDF NA NA NA NA 360 B 230 B 1.8 J q B

South Elizabeth Channel Upland ‐ COMP B ‐ Dioxin/Furan ‐TEQ Converted values

Dioxin/Furan TEF

Unamended

Sediment

(Units: ppt)

Amended Sediment

(Units: ppt)

SPLP

(Units: pg/L)

ASI ID # #20200628 #20200630 #20200630

COMP B Q A COMP B Q A COMP B Q

2,3,7,8‐TCDD 1 43.00 F1 33.00 9.50 U

1,2,3,7,8‐PeCDD 1 5.50 J B q 3.30 J B q 48.00 U

1,2,3,4,7,8‐HxCDD 0.1 0.54 J B 0.38 J B 4.80 U

1,2,3,6,7,8‐HxCDD 0.1 1.80 B 1.30 B 4.80 U

1,2,3,7,8,9‐HxCDD 0.1 1.90 B 1.30 B 4.80 U

1,2,3,4,6,7,8‐HpCDD 0.01 4.10 F1 B 2.70 B 0.48 U

1,2,3,4,6,7,8,9‐OCDD 0.0003 1.17 B 0.78 B 0.00 J q B

2,3,7,8‐TCDF 0.1 1.60 1.10 0.95 U

1,2,3,7,8‐PeCDF 0.03 0.24 0.18 1.44 U

2,3,4,7,8‐PeCDF 0.3 3.60 2.55 14.40 U

1,2,3,4,7,8‐HxCDF 0.1 3.50 B 2.80 B 4.80 U

1,2,3,6,7,8‐HxCDF 0.1 1.40 I B 1.10 I B 4.80 U

2,3,4,6,7,8‐HxCDF 0.1 0.66 B 0.52 J B 4.80 U

1,2,3,7,8,9‐HxCDF 0.1 0.63 U 0.55 U 4.80 U

1,2,3,4,6,7,8‐HpCDF 0.01 1.90 F1 B 1.30 B 0.01 J q B

1,2,3,4,7,8,9‐HpCDF 0.01 0.11 B 0.07 B 0.48 U

1,2,3,4,6,7,8,9‐OCDF 0.0003 0.11 B 0.07 B 0.00 J q B

TOTAL TEF as 2,3,7,8‐TCDD 71.76 53.00 108.86

South Elizabeth Channel Upland - 2020 - Method Detection Limits

Volatiles

Unamended Sediment

(Units: ug/kg)

Amended

Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

Unamended Sediment (Units:

ug/kg)

Amended

Sediment (Units:

ug/kg)

SPLP (Units:

ug/L)

ASI ID # #20200627 #20200629 #20200629 #20200628 #20200630 #20200630

COMP A A COMP A A COMP A COMP B A COMP B A COMP B

Chloromethane (Methyl Chloride) 5.4 4.6 0.90 5.2 4.5 0.90

Bromomethane 6.2 5.3 0.89 6.0 5.1 0.89

Vinyl chloride 9.8 8.4 0.41 9.4 8.1 0.41

Chloroethane 7.9 6.8 0.90 7.6 6.6 0.90

Methylene chloride (Dichloromethane) 12 10 0.89 12 10 0.89

Acetone 11 9.1 3.4 10 8.8 3.4

Carbon disulfide 11 9.3 0.88 10 9.0 0.88

1,1-Dichloroethene 6.1 5.3 0.55 5.9 5.1 0.55

1,1-Dichloroethane 4.3 3.7 0.31 4.2 3.6 0.31

1,2-Dichloroethene (total) 11 9.5 1.3 11 9.2 1.3

Chloroform 4.4 3.7 0.60 4.2 3.6 0.60

1,2-Dichloroethane 3.9 3.3 0.57 3.8 3.2 0.57

2-Butanone (MEK) 6.9 5.9 2.6 6.6 5.7 2.6

1,1,1-Trichloroethane 4.5 3.9 0.60 4.4 3.8 0.60

Carbon tetrachloride 5.5 4.7 0.88 5.3 4.6 0.88

Bromodichloromethane 6.3 5.4 0.64 6.1 5.3 0.64

1,2-Dichloropropane 3.6 3.1 0.66 3.5 3.0 0.66 cis-1,3-Dichloropropene 6.0 5.1 0.59 5.8 5.0 0.59

Trichloroethene 4.3 3.6 0.69 4.1 3.5 0.69

Dibromochloromethane 6.7 5.8 0.84 6.5 5.6 0.84

1,1,2-Trichloroethane 2.7 2.3 0.45 2.6 2.2 0.45

Benzene 3.8 3.3 0.60 3.7 3.2 0.60 trans-1,3-dichloropropene 6.1 5.2 0.58 5.9 5.1 0.58

Bromoform 6.8 5.9 0.98 6.6 5.7 0.98

Tetrachloroethene 5.5 4.7 0.47 5.3 4.5 0.47

1,1,2,2-Tetrachloroethane 4.1 3.5 0.60 4.0 3.4 0.60

Toluene 3.9 3.3 0.46 3.8 3.2 0.46

Chlorobenzene 3.5 3.0 0.50 3.4 2.9 0.50

Ethyl benzene 5.0 4.3 0.51 4.8 4.2 0.51

Styrene 4.1 3.5 0.47 3.9 3.4 0.47

Xylenes(Total) 20 17 0.89 19 16 0.89

Acrolein 93 79 16 89 77 16

Acrylonitrile 73 63 7.8 70 61 7.8

1,2-Dibromo-3-chloropropane 8.8 7.5 0.89 8.4 7.3 0.89

1,2-Dibromoethane 3.7 3.2 0.50 3.6 3.1 0.50

Dichlorodifluoromethane 6.8 5.8 0.83 6.5 5.6 0.83

1,2-Dichloroethene (cis) 4.1 3.5 0.71 3.9 3.4 0.71

1,2-Dichloroethene (trans) 4.7 4.1 0.67 4.6 3.9 0.67

Methyl acetate 20 17 1.7 19 17 1.7

Methyl tert-butyl ether (MTBE) 4.0 3.4 0.59 3.8 3.3 0.59

Tertiary butyl alcohol (TBA) 83 71 7.5 80 69 7.5

Trichlorofluoromethane 11 9.6 0.87 11 9.4 0.87

1,4-dioxane 96 82 38 93 80 38 n-propylbenzene 4.8 4.1 0.47 4.7 4.0 0.47 sec-butylbenzene 6.7 5.7 0.52 6.4 5.5 0.52 tert-butylbenzene 5.7 4.9 0.48 5.5 4.8 0.48

1,2,4-trimethylbenzene 4.7 4.0 0.48 4.5 3.9 0.48

1,3,5-trimethylbenzene 5.0 4.3 0.47 4.9 4.2 0.47 n‐Butylbenzene 6.7 5.8 0.61 6.5 5.6 0.61

South Elizabeth Channel Upland Method Detection Limits - Sediment Semivolatiles

Semivolatiles

Unamended Sediment

(Units: ug/kg)

Amended

Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

Unamended Sediment

(Units: ug/kg)

Amended

Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # #20200627 #20200629 #20200629 #20200628 #20200630 #20200630

COMP A A COMP A A COMP A COMP B A COMP B A COMP B

Phenol 270 180 0.00049 330 170 0.00049 bis(2-Chloroethyl)ether 33 21 0.00004 40 20 0.00004

2-Chlorophenol 42 27 0.000064 51 26 0.000064

1,3-Dichlorobenzene 8.4 7.2 0.0005 8.1 6.9 0.0005

1,4-Dichlorobenzene 4.1 3.5 0.00054 3.9 3.4 0.00054

1,2-Dichlorobenzene 4.6 3.9 0.00036 4.4 3.8 0.00036

2-Methylphenol (o-cresol) 260 170 0.0003 310 160 0.0003

1-Chloropropane-2,2'-oxybis/ bis(2-chloroisopropyl)ether 67 43 0.000058 81 42 0.000058

4-Methylphenol (p-cresol) (co-elutes with 3-methylphenol (m-cresol)) 270 170 0.00037 320 170 0.00037

N-Nitroso-Di-N-Propylamine 61 39 0.000071 74 38 0.000071

Hexachloroethane 47 30 0.000062 56 29 0.000062

Nitrobenzene 330 210 0.0005 400 210 0.0005

Isophorone 46 30 0.000054 56 29 0.000054

2,4-Dimethylphenol 56 36 0.000041 68 35 0.000041

2,4-Dichlorophenol 70 45 0.000051 85 44 0.000051

1,2,4-Trichlorobenzene 6.9 5.9 0.00077 6.6 5.7 0.00077

Naphthalene 35 23 0.000059 43 22 0.000059

Hexachloro-1,3-butadiene 53 34 0.000069 64 33 0.000069

2-Methylnaphthalene 43 28 0.000062 52 27 0.000062

Hexachlorocyclopentadiene 92 59 0.0005 110 57 0.0005

2,4,6-Trichlorophenol 50 32 0.000068 60 31 0.000068

2,4,5-Trichlorophenol 64 41 0.000061 78 40 0.000061

2-Chloronaphthalene 41 27 0.000059 50 26 0.000059

2-Nitroaniline 410 260 0.00055 500 260 0.00055

Acenaphthylene 39 25 0.000065 48 25 0.000065

2,6-Dinitrotoluene 56 36 0.00006 68 35 0.00006

South Elizabeth Channel Upland Method Detection Limits - Sediment Semivolatiles, con't.

Semivolatiles, continued

Unamended Sediment

(Units: ug/kg)

Amended

Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

Unamended Sediment

(Units: ug/kg)

Amended

Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # #20200627 #20200629 #20200629 #20200628 #20200630 #20200630

COMP A A COMP A A COMP A COMP B A COMP B A COMP B

Acenaphthene 52 33 0.000065 63 32 0.000065

2,4-Dinitrophenol 5000 3200 0.0015 6100 3100 0.0015

Dibenzofuran 39 25 0.000073 48 25 0.000073

2,4-Dinitrotoluene 140 88 0.000051 160 85 0.000051

Diethylphthalate 320 200 0.00057 380 200 0.00057

Fluorene 35 23 0.000069 43 22 0.000069

4,6-Dinitro-2-methylphenol 1600 1000 0.0015 1900 970 0.0015

N-Nitrosodiphenylamine 300 190 0.00012 360 190 0.00012

Hexachlorobenzene 65 42 0.000056 79 40 0.000056

Pentachlorophenol 1500 930 0.00085 1800 900 0.00085

Phenanthrene 48 31 0.000055 59 30 0.000055

Anthracene 47 30 0.000049 57 29 0.000049

Carbazole 42 27 0.000051 51 26 0.000051

Di-n-butylphthalate 390 250 0.00074 480 250 0.00074

Fluoranthene 48 31 0.00006 58 30 0.00006

Pyrene 43 28 0.000054 52 27 0.000054

Butylbenzylphthalate 620 400 0.00046 750 390 0.00046

3,3'-Dichlorobenzidine 840 540 0.00058 1000 530 0.00058

Benzo(a)anthracene 81 52 0.000075 99 51 0.000075

Chrysene 100 64 0.000081 120 62 0.000081 bis(2-Ethylhexyl)phthalate 960 620 0.0062 1200 600 0.0062

DI-n-octylphthalate 520 340 0.00069 640 330 0.00069

Benzo(b)fluoranthene 44 29 0.000097 54 28 0.000097

Benzo(k)fluoranthene 54 35 0.000088 66 34 0.000088

Benzo(a)pyrene 78 50 0.000053 95 49 0.000053

Indeno(1,2,3-cd)pyrene 90 58 0.000085 110 56 0.000085

Dibenzo(a,h)anthracene 120 74 0.000072 140 72 0.000072

Benzo(ghi)perylene 39 25 0.000069 47 24 0.000069

Acetophenone 49 32 0.000062 59 31 0.000062

Atrazine 390 250 0.00063 480 250 0.00063

Benzaldehyde 110 72 0.00011 140 70 0.00011

Benzidine 6800 4400 0.0091 8300 4200 0.0091

1,1'-Biphenyl 38 24 0.000059 46 24 0.000059

Caprolactam 590 380 0.00047 710 370 0.00047

1,2-Diphenylhydrazine 62 40 0.000049 75 39 0.000049

N-Nitrosodimethylamine 90 58 0.000067 110 56 0.000067

South Elizabeth Channel Upland Method Detection Limits - Pesticides/Aroclors

Pesticides/Aroclors

Unamended Sediment

(Units: ug/kg)

Amended

Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

Unamended Sediment

(Units: ug/kg)

Amended

Sediment

(Units: ug/kg)

SPLP

(Units: mg/L)

ASI ID # #20200627 #20200629 #20200629 #20200628 #20200630 #20200630

COMP A A COMP A A COMP A COMP B A COMP B A COMP B

alpha-BHC 0.14 0.12 0.00000023 0.13 0.11 0.00000023 beta-BHC 0.15 0.13 0.00000036 0.15 0.13 0.00000036 delta-BHC 0.18 0.15 0.00000062 0.17 0.15 0.00000062 gamma-BHC (Lindane) 0.14 0.12 0.00000028 0.14 0.12 0.00000028

Heptachlor 0.17 0.15 0.00000044 0.17 0.14 0.00000044

Aldrin 0.17 0.15 0.00000035 0.16 0.14 0.00000035

Heptachlor epoxide 0.14 0.12 0.00000033 0.14 0.12 0.00000033

Endosulfan I 0.15 0.13 0.00000067 0.14 0.13 0.00000067

Dieldrin 0.14 0.12 0.00000027 0.13 0.12 0.00000027

4,4'-DDE 0.11 0.096 0.00000029 0.11 0.094 0.00000029

Endrin 0.10 0.088 0.00000022 0.099 0.086 0.00000022

Endosulfan II 0.12 0.10 0.00000031 0.12 0.10 0.00000031

4,4'-DDD 0.24 0.20 0.00000052 0.23 0.20 0.00000052

Endosulfan sulfate 0.14 0.12 0.00000062 0.14 0.12 0.00000062

4,4'-DDT 0.40 0.34 0.00000029 0.38 0.33 0.00000029

Methoxychlor 0.22 0.18 0.00000075 0.21 0.18 0.00000075 alpha-Chlordane 0.14 0.12 0.00000036 0.13 0.12 0.00000036 gamma-Chlordane 0.13 0.11 0.0000004 0.12 0.11 0.0000004

Toxaphene 15 13 0.000048 14 13 0.000048

Mirex 0.10 0.088 0.0000002 0.099 0.086 0.0000002

Aroclor‐1016 3.6 3.1 0.0000046 3.5 3.0 0.0000046

Aroclor‐1221 3.9 3.4 0.0000056 3.8 3.3 0.0000056

Aroclor‐1232 2.7 2.3 0.0000051 2.6 2.3 0.0000051

Aroclor‐1242 1.6 1.4 0.0000035 1.6 1.4 0.0000035

Aroclor‐1248 2.7 2.3 0.0000029 2.6 2.3 0.0000029

Aroclor‐1254 3.3 2.9 0.0000044 3.2 2.8 0.0000044

Aroclor‐1260 3.2 2.7 0.0000038 3.1 2.7 0.0000038

Total Aroclor(SUM)

South Elizabeth Channel Upland Method Detection Limits - Herbicides

Herbicides

Unamended Sediment

(Units: ug/kg)

Amended

Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

Unamended Sediment

(Units: ug/kg)

Amended

Sediment

(Units: ug/kg)

SPLP

(Units: ug/L)

ASI ID # #20200627 #20200629 #20200629 #20200628 #20200630 #20200630

COMP A A COMP A A COMP A COMP B A COMP B A COMP B

2,4,5-TP (Silvex) 30 26 0.30 29 25 0.30

South Elizabeth Channel Upland Method Detection Limits - Metals

Metals

Unamended Sediment

(Units: mg/kg)

Amended

Sediment

(Units: mg/kg)

SPLP

(Units: mg/L)

Unamended Sediment

(Units: mg/kg)

Amended

Sediment

(Units: mg/kg)

SPLP

(Units: mg/L)

ASI ID # #20200627 #20200629 #20200629 #20200628 #20200630 #20200630

COMP A A COMP A A COMP A COMP B A COMP B A COMP B

Aluminum 7.9 6.7 0.013 7.5 6.4 0.013

Antimony 0.060 0.050 0.00038 0.057 0.049 0.00038

Arsenic 0.043 0.037 0.00031 0.041 0.035 0.00031

Barium 0.17 0.15 0.0016 0.16 0.14 0.0016

Beryllium 0.098 0.082 0.00018 0.093 0.080 0.00018

Cadmium 0.023 0.019 0.00022 0.022 0.019 0.00022

Chromium 0.11 0.096 0.0015 0.11 0.093 0.0015

Hexavalent Chromium 0.59 0.50 0.0036 0.57 0.48 0.0036

Trivalent Chromium 0.21 0.21 0.0032 0.21 0.21 0.0032

Cobalt 0.018 0.015 0.00013 0.017 0.014 0.00013

Copper 0.28 0.24 0.00063 0.27 0.23 0.00063

Lead 0.14 0.11 0.00013 0.13 0.11 0.00013

Manganese 0.58 0.49 0.00087 0.55 0.48 0.00087

Mercury 0.028 0.024 0.00013 0.027 0.023 0.00013

Nickel 0.13 0.11 0.00034 0.12 0.10 0.00034

Selenium 0.17 0.14 0.0015 0.16 0.13 0.0015

Silver 0.038 0.032 0.00018 0.036 0.031 0.00018

Vanadium 0.13 0.11 0.00099 0.12 0.10 0.00099

Zinc 0.65 0.55 0.0032 0.62 0.53 0.0032

Cyanide, total 0.16 0.13 0.0044 0.17 0.14 0.0044

%Solids

South Elizabeth Channel Upland Method Detection Limits - Dioxin/Furan

Dioxin/Furan

Unamended Sediment

(Units: pg/g)

Amended

Sediment

(Units: pg/g)

SPLP

(Units: pg/L)

Unamended Sediment

(Units: pg/g)

Amended

Sediment

(Units: pg/g)

SPLP

(Units: pg/L)

ASI ID # #20200627 #20200629 #20200629 #20200628 #20200630 #20200630

COMP A A COMP A A COMP A COMP B A COMP B A COMP B

2,3,7,8‐TCDD 0.39 0.28 0.50 0.37 0.21 0.62

1,2,3,7,8‐PeCDD 1.0 0.83 0.50 1.2 0.99 0.46

1,2,3,4,7,8‐HxCDD 1.2 1.0 0.27 1.3 1.1 0.49

1,2,3,6,7,8‐HxCDD 1.1 0.94 0.26 1.1 1.1 0.50

1,2,3,7,8,9‐HxCDD 1.1 0.93 0.25 1.1 1.0 0.47

1,2,3,4,6,7,8‐HpCDD 0.16 0.20 0.80 0.30 0.28 1.1

OCDD 0.083 0.11 0.20 0.21 0.14 0.076

2,3,7,8‐TCDF 0.62 0.53 0.43 1.1 0.81 0.71

1,2,3,7,8‐PeCDF 0.64 0.84 0.55 0.69 0.66 0.77

2,3,4,7,8‐PeCDF 0.55 0.73 0.49 0.58 0.54 0.71

1,2,3,4,7,8‐HxCDF 0.82 0.51 0.31 0.99 0.58 0.38

1,2,3,6,7,8‐HxCDF 0.87 0.57 0.33 1.0 0.64 0.44

2,3,4,6,7,8‐HxCDF 0.91 0.60 0.33 1.1 0.67 0.45

1,2,3,7,8,9‐HxCDF 1.1 0.74 0.39 1.2 0.76 0.51

1,2,3,4,6,7,8‐HpCDF 0.43 0.39 0.33 0.57 0.37 0.41

1,2,3,4,7,8,9‐HpCDF 0.58 0.51 0.44 0.68 0.46 0.59

OCDF 0.12 0.15 0.15 0.23 0.17 0.17

Qualifiers

GC/MS VOA

Qualifier Qualifier Description

* LCS or LCSD is outside acceptance limits.

E Result exceeded calibration range.

F1 MS and/or MSD Recovery is outside acceptance limits.

F2 MS/MSD RPD exceeds control limits

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

U Indicates the analyte was analyzed for but not detected

X Surrogate recovery exceeds control limits

GC/MS Semi VOA

Qualifier Qualifier Description

* LCS or LCSD is outside acceptance limits.

*3 ISTD response or retention time outside acceptable limits.

B Compound was found in the blank and sample.

D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution may be flagged with a D.

F1 MS and/or MSD Recovery is outside acceptance limits.

F2 MS/MSD RPD exceeds control limits

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

U Indicates the analyte was analyzed for but not detected.

X Surrogate recovery exceeds control limits

GC Semi VOA

Qualifier Qualifier Description

*3 ISTD response or retention time outside acceptable limits.

4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable.

D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution may be flagged with a D.

F1 MS and/or MSD Recovery is outside acceptance limits.

F2 MS/MSD RPD exceeds control limits

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

p The %RPD between the primary and confirmation column/detector is >40%. The lower value has been reported.

S1‐ Surrogate recovery exceeds control limits, low biased.

S1+ Surrogate recovery exceeds control limits, high biased.

U Indicates the analyte was analyzed for but not detected.

X Surrogate recovery exceeds control limits

Dioxin

Qualifier Qualifier Description

4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable.

*5 Isotope dilution analyte is outside acceptance limits.

B Compound was found in the blank and sample.

F1 MS and/or MSD Recovery is outside acceptance limits.

I Value is EMPC (estimated maximum possible concentration).

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

q The reported result is the estimated maximum possible concentration of this analyte, quantitated using the theoretical ion ratio.

The measured ion ratio does not meet qualitative identification criteria and indicates a possible interference.

U Indicates the analyte was analyzed for but not detected.

Metals

Qualifier Qualifier Description

4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable.

B Compound was found in the blank and sample.

F1 MS and/or MSD Recovery is outside acceptance limits.

F2 MS/MSD RPD exceeds control limits

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

U Indicates the analyte was analyzed for but not detected.

V Serial Dilution exceeds the control limits

W PS: Post‐digestion spike was outside control limits